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At least 559 records · Page 31

Graph-Based Representations and Applications to Process Simulation

Rapid and robust convergence of a process flowsheet is critical to enable large-scale simulations that address core scientific questions related to process design, optimization, and sustainability. However, due to the highly coupled and nonlinear nature of chemical processes, efficiently solving a flowsheet remains a challenge. In this work, we show that graph representations of the underlying physical phenomena in unit operations may help identify potential avenues to systematically reformulate the network of equations and enable more robust topology-based convergence of flowsheets. To this end, we developed graph abstractions of the governing equations of vapor-liquid and liquid-liquid equilibrium separation equipment. These graph abstractions consist of a mesh of interconnected variable nodes and equation nodes that are systematically generated through PhenomeNode, a new open-source library in Python developed in this study. We show that partitioning the graph into separate mass, energy, and equilibrium subgraphs can help decouple nonlinearities and guide decomposition algorithms. By employing the graph abstraction on an industrial separation process for separating glacial acetic acid from water, we implemented a new block decomposition scheme in BioSTEAM and demonstrated that this can accelerate convergence over a traditional sequential modular approach.

Distillation↗

Photoexcitation and ionization in carbon dioxide - Theoretical studies in the separated-channel static-exchange approximation

Vertical-electronic static-exchange photoexcitation and ionization cross sections are reported which provide a first approximation to the complete dipole spectrum of CO2. Separated-channel static-exchange calculations of vertical-electronic transition energies and oscillator strengths, and Stieltjes-Chebyshev moment methods were used in the development. Detailed comparisons were made of the static-exchange excitation and ionization spectra with photoabsorption, electron-impact excitation, and quantum-defect estimates of discrete transition energies and intensities, and with partial-channel photoionization cross sections obtained from fluorescence measurements and from tunable-source and (e, 2e) photoelectron spectroscopy. Results show that the separate-channel static-exchange approximation is generally satisfactory in CO2.

Padial, N.↗

Mid-infrared imaging of Orion BN/KL - Astrometry of IRc2 and the SiO maser

Array images of Orion BN/KL at nine midinfrared (5-20 microns) wavelengths have revealed a subarcsecond structure near IRc2 which provides new constraints on the relationship between IRc2 and the Orion SiO maser. The infrared source positions have been improved, and IRc2 is found to be displaced 0.8 +/- 0.2 arcsec (at least 400 AU) from the SiO maser, an order of magnitude greater than the separation assumed in the current maser model. The SiO maser and the IRc2 midinfrared source may be physically independent objects. There are indications that IRc2 is eroded on the south side adjacent to the SiO/H2O maser cluster, suggesting that another luminous object near IRc2, most likely a stellar object associated with radio continuum point source 'I', is the host for the Orion SiO maser.

Gezari, Daniel Y.↗

Submilliarcsecond VLBI Observations of the Close Pair GC 1342+662 and GC 1342+663

Differential VLBI was simultaneously performed on the source pair GC 1342+662 and GC 1342+663 (4.4-arcminute separation) using S-band on the Goldstone/Madrid baseline. These measurements were acquired on two separate observing sessions: 30 December 1982 and 14 May 1983. The change in separation of GC 1342+662 relative to GC 1342+663 between the two epochs was 0.03 + or 0.08 milliarcsecond. The differences of the relative position measurements between epochs of GC 1342+662 relative to GC 1342+663 were -0.29 + or - 0.05 milliarcsecond in right ascension and 0.14 + or - 0.09 milliarcsecond in declination. These measurements demonstrate submilliarcsecond accuracy and repeatability. The discrepancies outside of the formal uncertainties could be attributed to the intrinsic properties of the sources such as structure and to a lesser probability, proper motion. These discrepancies could also be attributed to excursions in UT1-UTC of about four times the quoted BIH uncertainty.

Morabito, D. D.↗

Submilliarcsecond VLBI observations of the close pair GC 1342 + 662 and GC 1342 + 663

Differential VLBI was simultaneously performed on the source pair GC 1342 + 662 and GC 1342 + 663 (4.4-arcminute separation) using S-band on the Goldstone/Madrid baseline. These measurements were acquired on two separate observing sessions: 30 December 1982 and 14 May 1983. The change in separation of GC 1342 + 662 relative to GC 1342 + 663 between the two epochs was 0.03 + or - 0.08 milliarcsecond. The differences of the relative position measurements between epochs of GC 1342 + 662 relative to GC 1342 + 663 were -0.29 + or - 0.05 milliarcsecond in right ascension and 0.14 + or 0.09 milliarcsecond in declination. These measurements demonstrate submilliarcsecond accuracy and repeatability. The discrepancies outside of the formal uncertainties could be attributed to the intrinsic properties of the sources such as structure and to a lesser probability, proper motion. These discrepancies could also be attributed to excursions in UT1-UTC of about four times the quoted BIH uncertainty.

Morabito, D. D.↗

Effect of a buried-wire gage on the separation bubble Numerical study

A numerically simulated buried-wire separation gage is investigated with emphasis on its effect on the separation bubble. The conjugated problem of a supersonic, time-dependent, two-dimensional flowfield above a conductive solid wall with an embedded heat source is solved using implicit finite difference algorithms. Steady-state and transient cases were computed for different locations of the heat source within the bubble. Results show that by using a steady heat source, the flow direction near the wall can be detected, without distorting the flowfield, only if the source is located in regions where the bubble is thick (i.e., not too close to the separation). The flow direction near separation can be detected by using a temperature pulse at the solid/fluid interface with insignificant distortion of the flowfield.

Degani, D.↗

Pyroshock Environments Characterized for Spacecraft Missions

Pyrotechnic shock, or pyroshock, is the transient response of a structure to loading induced by the ignition of pyrotechnic (explosive or propellant activated) devices. These devices are typically used to separate structural systems (e.g., separate a spacecraft from a launch vehicle) and deploy appendages (e.g., solar panels). Pyroshocks are characterized by high peak acceleration, high-frequency content, and short duration. Because of their high acceleration and high-frequency, pyroshocks can cause spaceflight hardware to fail. Verifying by test that spaceflight hardware can withstand the anticipated shock environment is considered essential to mission success. The Earth Observing System (EOS) AM-1 spacecraft for NASA's Mission to Planet Earth is scheduled to be launched on an Atlas IIAS vehicle in 1999, and the NASA Lewis Research Center is the launch vehicle integrator for this NASA Goddard Space Flight Center spacecraft. The EOS spacecraft was subjected to numerous ground shock tests to verify that its scientific instruments and avionics components will withstand the shock-induced vibration produced when the spacecraft separates from the launch vehicle. Shock test data from these tests represent the third largest available pyroshock database in the United States. Future spacecraft missions will directly benefit from the knowledge gained from these tests. The payload separation system used for EOS is a new system that operates by firing six separation nuts. This system was tested to verify its functional operation and to characterize the resulting shock levels. The launch vehicle contractor (Lockheed Martin Astronautics) and spacecraft contractor (Lockheed Martin Missiles & Space) completed 16 separation test firings. This resulted in an unusually large amount of pyroshock data. Typically, only one or two pyroshock test firings are performed for a spacecraft mission. Because of the size of this separation system shock database, engineers were able to perform unique statistical analyses to characterize the distribution of the test data. For example, it was proven that the shock data follow a lognormal distribution, a concept often assumed but rarely proven. The test-to-test repeatability of the shock source level was analyzed, and the effects of various test configurations and separation nut production lots were examined and quantified. Engineers investigated the change in shock level as the shock traveled from the spacecraft separation interface to the avionics components of the upper stage and analyzed the effects of the structural fidelity (simulator versus real) of the components and their weight on vibrational response. In addition, the shock attenuation with distance and across joints was quantified and compared with concepts originally generated in 1970, and the effects of separation nut preload and firing sequences effects were examined. Because of this EOS shock testing and the analyses performed at NASA Lewis, a significant amount of new information on pyroshock and its characteristics is now available to the aerospace industry. We hope that this information will help future spacecraft test planners to perform better and cheaper spacecraft separation shock tests and to better understand their test data.

Hughes, William O.↗

3C 279 - The case for 'superluminal' expansion

The compact extragalactic radio source 3C 279 was observed with the Haystack-Goldstone interferometer (wavelength approximately 3.8 cm) during six separate sessions spread between October 1970 and April 1972. The fringe amplitudes from each of these observation sessions were consistent with a two-component model of the brightness distribution of the source. The position angle of the line joining the components remained at 38 + or - 2 deg, while the angular separation between the components increased nearly linearly at the rate of 0.5 + or 0.1 milliarcsec/yr during this period. The corresponding apparent expansion speed is (21 + or - 4)c, for H = 50 km/s per Mpc and q = 0.05

Cotton, W. D.↗

Two Variable Radio Sources Near the Position of GRB 940301

We report on the results of a search for a radio counterpart to the strong gamma-ray burst GRB 940301. Observations with the Westerbork Synthesis Radio Telescope of the Compton Telescope error box region of GRB 940301 began on March 4, 1994, at 21 cm and April 2, 1994, at 92 cm. No flux density variations were detected at 92 cm above S= 10 mJy (5 (sigma)) within a period of 1 to 4 months after the burst. However, when we compared the field with Westerbork Northern Sky Survey data, taken two years prior to GRB 940301, we found two radio sources with significantly increased flux densities. These sources, only 17 min. apart, are located at the 2.3 and 2.6(sigma) Compton Telescope confidence contours. Their separation from the Inter Planetary Network annulus virtually excludes association with GRB 940301. Further observations in January 1996 reveal that the sources continued to change in flux density. The relatively large flux density variations at 92 cm, compared to those at higher frequencies, and the inverted spectra in the frequency range from 325-38O MHz make the sources somewhat unusual. Because the sources were already detected at 5 GHz in 1986 most, if not all, of the radio emission is probably associated with activity in Active Galactic Nuclei in distant galaxies.

Galama, T. J.↗

X-ray diagnostics of globular clusters

The presence of compact X-ray sources in globular clusters allows diagnostic studies of both the X-ray sources themselves and the globular clusters to be carried out. A review of much of this work, primarily based on Einstein X-ray observations and supporting studies of globular clusters at radio through UV wavelengths, is presented. The compact X-ray sources in globular clusters are found to be compact binaries containing neutron stars and - in a separate lower luminosity component of an apparently bimodal luminosity function - possibly white dwarfs. Implications for the formation and evolution of compact binary X-ray sources in globular clusters and in the galactic bulge are discussed. In particular, new evidence is presented that the galactic bulge sources may be compact binaries in the remnants of disrupted globular clusters.

Grindlay, J. E.↗

Acoustic Phased Array Quantification of Quiet Technology Demonstrator 3 Advanced Inlet Liner Noise Component

Acoustic phased array flyover noise measurements were acquired as part of the Boeing 737 MAX-7 NASA Advanced Inlet Liner segment of the Quiet Technology Demonstrator 3 (QTD3) flight test program. This paper reports on the processes used for separating and quantifying the engine inlet, exhaust and airframe noise source components and provides sample phased array-based comparisons of the component noise source levels associated with the inlet liner treatment configurations. Full scale flyover noise testing of NASA advanced inlet liners was conducted as part of the Quiet Technology Demonstrator 3 flight test program in July and August of 2018. Details on the inlet designs and testing are provided in the companion paper of Reference 1. The present paper provides supplemental details relating to the acoustic phased array portion of the analyses provided in Ref. 1. In brief, the test article was a Boeing 737MAX-7 aircraft with a modified right hand (starboard side) engine inlet, which consisted of either a production inlet liner, a NASA designed inlet liner or a simulated hard wall configuration (accomplished by applying speed tape over the inlet acoustic treatment areas). In all three configurations, the engine forward fan case acoustic panel was replaced with a unperforated (hardwall) panel. No other modifications to any other acoustic treatment areas were made. The left hand (port side) engine was a production engine and was flown at idle thrust for all measurements in order to isolate the effects of the inlet liners to the right hand engine. As described in Ref. 1, the NASA inlet treatment consists of laterally cut slots (cut perpendicular to the flow direction) which are designed to reduce excrescence drag while maintaining or exceeding the liner acoustic noise reduction capabilities. The NASA inlet liner consists of a Multi-Degree of Freedom (MDOF) design with two breathable septum layers inserted into each honeycomb cell [1]. The aircraft noise measurements were acquired for both takeoff (flaps 1 setting, gear up) and approach (flaps 30 gear up and gear down) configurations. The inlet and flight test configurations are summarized in Table 1. Table 1: Inlet Treatment and Flight Configurations Inlet Forward Fan Case Aircraft Production Hardwall Flaps 1, gear up; flaps 30 gear up; flaps 30 gear down NASA Hardwall Flaps 1, gear up; flaps 30 gear up; flaps 30 gear down Hardwall Hardwall Flaps 1, gear up; flaps 30 gear up; flaps 30 gear down III.Test Description and Hardware The flight testing was conducted at the Grant County airport in Moses Lake, WA, between 27 July and 6 August 2018. The noise measurement instrumentation included 8 flush dish microphones arranged in a noise certification configuration as well as an 840 microphone phased array. The flush dish microphones were used to quantify the levels and differences in levels between the various inlet treatments. The phased array was used to separate and quantify the narrowband (tonal) and broadband noise component levels from the engine inlet/exhaust and from the airframe. Phased array extraction of the broadband component was critical to this study because it allowed for the separation of the inlet component from the total airplane level noise even when it was significantly below the total level. Figure 1 provides an overview of the phased array microphone layout as well as a detailed image of an individual phased array microphone mounted in a plate holder (the microphone sensor is the dot in the center of the plate). The ground plane ensemble array microphones (referred to as “ensemble array” in this paper) were mounted in plates with “flower petal” edges designed to minimize edge scattering effects. Fig. 1 Flyover test microphone layout. The phased array configuration was the result of a progressive development of concepts originally implemented in Ref. 2 and refined over the following years, consisting namely of multiple multi-arm logarithmic spiral subarrays designed to cover overlapping frequency ranges and optimized for various aircraft emission angles. For the present case, the signals from all 840 microphones were acquired on a single system. The 840 microphones were parsed into 11 primary subarray sets spanning from smallest to largest aperture size and labeled accordingly as “a, b, …, k”, where “a” corresponds to the smallest fielded subarray and “k” corresponds to the largest aperture subarray. The apertures ranged from approximately 10 ft to 427 ft in size (in the flight direction) with the subarrays consisting of between 215 and 312 microphones. Figure 2 shows three such subarrays, k, h and a. As done in Ref. 2, microphones were shared between subarrays in order to reduce total channel count. Fig. 2 Sample subarray sizes (20° from overhead – refer to Figure 3a discussion). In addition to the above, each of the 11 primary subarray sets consisted of four subarrays optimized to provide near equivalent array spatial resolution in both the flight and lateral directions within 30 degrees of overhead (i.e., airplane directly above the center of the array), namely, at angles  of 0, ±10, ±20 and ±30 degrees relative to overhead where angle  is defined as shown in Figure 3a. This allowed for optimized aircraft noise measurements from 60 to 120 degree emission angle.6 An example of this pletharray design is shown in Figure 3b for the k subarray. When the aircraft is at overhead, the microphones indicated by the blue markers are used for beamforming. When the aircraft is at angles ±10 degrees from overhead, both the blue and red colored microphones are used, and so on for the ±20 and ±30 degree aircraft locations. See Ref. 3 for extensive details on pletharray design for aeroacoustic phased array testing. 6 In the discussions that follow, emission angle values are used. These are the angles at the time sound is emitted relative to the engine axis and are calculated based on flight path angle, body aircraft body angle with respect to the relative wind direction, and engine axis angle relative to aircraft body angle.

Brusniak, Leon↗

Radio Interferometric Determination of Source Positions, Intercontinental Baselines, and Earth Orientation with Deep Space Network Antennas: 1971 to 1980

Approximately 2400 observations of extragalactic radio sources were made between August 1971 and February 1980 during 48 separate sessions. These consisted of 259 delay rate observations at 2.3 GHz (S-band), 796 delay and delay rate observations at either S-band of 8.3 GHz (X-band) and 1325 delay and delay rate observations recorded simultaneously at both S- and X-band. A single multiparameter fit has been applied to the observed values of delay and delay rate to extract astrometric and geophysical parameters from this decade-long sequence. The fit produced estimates of 784 parameters, including station locations, radio source positions, polar motion, Universal Time, the precession constant, and solid earth tides. The a priori model included gravitational bending, the 1980 IAU nutation series, the 1976 IAU expressions for Greenwich mean sidereal time and precession, BIH estimates of Universal Time and polar motion, and monthly mean values for zenith troposphere delay. The rms residuals were 0.52 nsec for delay and 0.30 psec/sec for delay rate. Intercontinental baseline lengths were determined with formal uncertainties of 5 to 10 cm. Universal Time and polar motion were measured at 49 epochs, with formal uncertainties (for the more recent data) of 0.5 msec for UT1 and 6 and 2 mas, respectively, for the X and Y components of polar motion.

Thomas, J. B.↗

Radio interferometric determination of source positions utilizing deep space network antennas - 1971 to 1980

Approximately 2400 observations of extragalactic radio sources were made between August 1971 and February 1980 during 48 separate sessions. These consisted of 259 delay rate observations at 2.3 GHz (S-band), 796 delay and delay rate observations at either S-band of 8.3 GHz (X-band) and 1325 delay and delay rate observations recorded simultaneously at both S- and X-band. A single multiparameter fit has been applied to the observed values of delay and delay rate to extract astrometric and geophysical parameters from this decade-long sequence. The fit produced estimates of 784 parameters, including station locations, radio source positions, polar motion, Universal Time, the precession constant, and solid earth tides. The a priori model included gravitational bending, the 1980 IAU nutation series, the 1976 IAU expressions for Greenwich mean sidereal time and precession, BIH estimates of Universal Time and polar motion, and monthly mean values for zenith troposphere delay. The rms residuals were 0.52 nsec for delay and 0.30 psec/sec for delay rate. Intercontinental baseline lengths were determined with formal uncertainties of 5 to 10 cm. Universal Time and polar motion were measured at 49 epochs, with formal uncertainties (for the more recent data) of 0.5 msec for UT1 and 6 and 2 mas, respectively, for the X and Y components of polar motion. Previously announced in STAR as N83-28038

Fanselow, J. L.↗

The Wilkinson Microwave Anisotropy Probe (WMAP) Source Catalog

We present the list of point sources found in the WMAP 5-year maps. The technique used in the first-year and three-year analysis now finds 390 point sources, and the five-year source catalog is complete for regions of the sky away from the galactic plane to a 2 Jy limit, with SNR greater than 4.7 in all bands in the least covered parts of the sky. The noise at high frequencies is still mainly radiometer noise, but at low frequencies the CMB anisotropy is the largest uncertainty. A separate search of CMB-free V-W maps finds 99 sources of which all but one can be identified with known radio sources. The sources seen by WMAP are not strongly polarized. Many of the WMAP sources show significant variability from year to year, with more than a 2:l range between the minimum and maximum fluxes.

Wright, E.L.↗

Hydrogen Analysis by Gas Chromatography–Mass Spectrometry

The detection of hydrogen in complex gas mixtures is essential for many applications. Conventional approaches such as gas chromatography (GC) with thermal conductivity detection (TCD) and residual gas analyzers (RGAs) face significant limitations: TCD exhibits poor response when helium is used as a carrier gas, whereas RGAs lack chromatographic separation, preventing reliable quantification of hydrogen because of interference from other species. Traditional GC methods rely on dual-column configurations with packed or molecular-sieve porous layer open tubular (PLOT) columns to separate hydrogen from O2, N2, CO, CO2, CH4, and other hydrocarbons, increasing system complexity and limiting compatibility with mass spectrometry (MS) detection. In this work, we developed and validated a robust GC–MS method capable of directly detecting and quantifying hydrogen using electron ionization (EI) without dopants, reagent gases, or ion–molecule reaction schemes. By integrating a modified EI source and a cryogenically cooled single capillary column configuration, we achieved baseline separation of hydrogen from all major permanent gases and hydrocarbons in a refinery gas mixture using helium as the carrier gas. The method demonstrated excellent linearity, high sensitivity, and exceptional reproducibility. Adjustable sample-loop volumes and split ratios enabled optimization of peak shape and signal-to-noise performance for trace-level and percent-level hydrogen concentrations. Beyond hydrogen quantitation, the method provides simultaneous compositional profiling of other gases in a mixture in a single run, making it valuable for a wide range of tasks.

Lobodin, Vlad [ORNL]↗

Impact of the magnetic horizon on the interpretation of the Pierre Auger Observatory spectrum and composition data

The flux of ultra-high energy cosmic rays reaching Earth above the ankle energy (5 EeV) can be described as a mixture of nuclei injected by extragalactic sources with very hard spectra and a low rigidity cutoff.Extragalactic magnetic fields existing between the Earth and the closest sources can affect the observed CR spectrum by reducing the flux of low-rigidity particles reaching Earth. We perform a combined fit of the spectrum and distributions of depth of shower maximum measured with the Pierre Auger Observatory including the effect of this magnetic horizon in the propagation of UHECRs in the intergalactic space.We find that, within a specific range of the various experimental and phenomenological systematics, the magnetic horizon effect can be relevant for turbulent magnetic field strengths in the local neighbourhood in which the closest sources lieof order B$_{rms}$ ≃ (50–100) nG (20 Mpc/d$_{s}$)( 100 kpc/L$_{coh}$)$^{1/2}$, with d$_{s}$ the typical intersource separation and L$_{coh}$ the magnetic field coherence length. When this is the case,the inferred slope of the source spectrum becomes softer and can be closer to the expectations of diffusive shock acceleration, i.e., ∝ E$^{-2}$.An additional cosmic-ray population with higher source density and softer spectra, presumably also extragalactic and dominating the cosmic-ray flux at EeV energies, is also required to reproduce the overall spectrum and composition results for all energies down to 0.6 EeV.

79 ASTRONOMY AND ASTROPHYSICS↗

Valorizing Hydrothermal liquefaction aqueous phase via nanofiltration: Enhancing biocrude production from algal biomass

The hydrothermal liquefaction aqueous phase (HTL-AP), a nutrient- and carbon-rich waste byproduct of the HTL process, can be recirculated to enhance biocrude production efficiency. To avoid dilution of the HTL feedstock and reduced fuel quality associated with recirculating untreated HTL-AP, this study investigated nanofiltration to concentrate organic compounds and separate nutrients from HTL-AP of three algal biomass sources: an algal wastewater treatment system and two from harmful algal blooms in lakes. Up to 99% of the organics were recovered in the concentrated HTL-AP (retentate), and significant increases in both permeate flux and permeation of nitrogenous compounds were achieved by increasing HTL-AP temperature to 45 °C and pH to 11. Recirculating the concentrated HTL-AP increased biocrude yield by 70%-116% and reduced biocrude nitrogen content by up to 12%. The carbon and energy capture in the biocrude also increased by 66% and 68%, respectively.

09 BIOMASS FUELS↗

Evaluation of Getters for Helium Purification

• Helium-3 is a vital commodity in both medical and defense applications • Ultra-low cryogenic coolant (MRI imaging, etc.) • Neutron detectors • Being investigated as possible fusion fuel • Managed and distributed by DOE-OS • New PDRD project exploring helium isotope separation • Limited supply • Only available from tritium decay • Prohibitively difficult to separate from helium-4 • SRS Tritium Facility provides a steady source

Angelette, Lucas M.↗