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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 559 records · Page 31
All sourcesNASA NTRSDOE OSTI
DOE OSTI2014

Enhancing efficiency and power of quantum-dots resonant tunneling thermoelectrics in three-terminal geometry by cooperative effects

We propose a scheme of multilayer thermoelectric engine where one electric current is coupled to two temperature gradients in three-terminal geometry. This is realized by resonant tunneling through quantum dots embedded in two thermal and electrical resisting polymer matrix layers between highly conducting semiconductor layers. There are two thermoelectric effects, one of which is pertaining to inelastic transport processes (if energies of quantum dots in the two layers are different), while the other exists also for elastic transport processes. These two correspond to the transverse and longitudinal thermoelectric effects, respectively, and are associated with different temperature gradients. We show that cooperation between the two thermoelectric effects leads to markedly improved figure of merit and power factor, which is confirmed by numerical calculation using material parameters. Such enhancement is robust against phonon heat conduction and energy level broadening. Therefore, we demonstrated cooperative effect as an additional way to effectively improve performance of thermoelectrics in three-terminal geometry.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2013

Light-induced cross transport phenomena in a single-component gas

The cross transport processes that occur in a single-component gas in a capillary and are caused by resonance laser radiation and pressure and temperature gradients are studied. An expression for entropy production is derived using a system of kinetic Boltzmann equations in a linear approximation. The kinetic coefficients that determine the transport processes are shown to satisfy the Onsager reciprocal relations at any Knudsen numbers and any character of the elastic interaction of gas particles with the capillary surface. The light-induced baro- and thermoeffects that take place in a closed heat-insulated system in the field of resonance laser radiation are considered. Analytical expressions are obtained for the Onsager coefficients in an almost free-molecular regime. The light-induced pressure and temperature gradients that appear in a closed heat-insulated capillary under typical experimental conditions are numerically estimated.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Thermoelectric energy recovery at ionic-liquid/electrode interface

A thermally chargeable capacitor containing a binary solution of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide in acetonitrile is electrically charged by applying a temperature gradient to two ideally polarisable electrodes. The corresponding thermoelectric coefficient is −1.7 mV/K for platinum foil electrodes and −0.3 mV/K for nanoporous carbon electrodes. Stored electrical energy is extracted by discharging the capacitor through a resistor. The measured capacitance of the electrode/ionic-liquid interface is 5 μF for each platinum electrode while it becomes four orders of magnitude larger, ≈36 mF, for a single nanoporous carbon electrode. Reproducibility of the effect through repeated charging-discharging cycles under a steady-state temperature gradient demonstrates the robustness of the electrical charging process at the liquid/electrode interface. The acceleration of the charging by convective flows is also observed. This offers the possibility to convert waste-heat into electric energy without exchanging electrons between ions and electrodes, in contrast to what occurs in most thermogalvanic cells.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2015

Identification of new turbulence contributions to plasma transport and confinement in spherical tokamak regime

Highly distinct features of spherical tokamaks (ST), such as National Spherical Torus eXperiment (NSTX) and NSTX-U, result in a different fusion plasma regime with unique physics properties compared to conventional tokamaks. Nonlinear global gyrokinetic simulations critical for addressing turbulence and transport physics in the ST regime have led to new insights. The drift wave Kelvin-Helmholtz (KH) instability characterized by intrinsic mode asymmetry is identified in strongly rotating NSTX L-mode plasmas. While the strong E x B shear associated with the rotation leads to a reduction in KH/ion temperature gradient turbulence, the remaining fluctuations can produce a significant ion thermal transport that is comparable to the experimental level in the outer core region (with no "transport shortfall"). The other new, important turbulence source identified in NSTX is the dissipative trapped electron mode (DTEM), which is believed to play little role in conventional tokamak regime. Due to the high fraction of trapped electrons, long wavelength DTEMs peaking around k θρ s ~ 0.1 are destabilized in NSTX collisionality regime by electron density and temperature gradients achieved there. Surprisingly, the E x B shear stabilization effect on DTEM is remarkably weak, which makes it a major turbulence source in the ST regime dominant over collisionless TEM (CTEM). The latter, on the other hand, is subject to strong collisional and E x B shear suppression in NSTX. DTEM is shown to produce significant particle, energy and toroidal momentum transport, in agreement with experimental levels in NSTX H-modes. Furthermore, DTEM-driven transport in NSTX parametric regime is found to increase with electron collision frequency, providing one possible source for the scaling of confinement time observed in NSTX H-modes. Most interestingly, the existence of a turbulence-free regime in the collision-induced CTEM to DTEM transition, corresponding to a minimum plasma transport in advanced ST collisionality regime, is predicted.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2012

Suppressing electron turbulence and triggering internal transport barriers with reversed magnetic shear in the National Spherical Torus Experiment

The National Spherical Torus Experiment (NSTX) [M. Ono et al., Nucl. Fusion 40, 557 (2000)] can achieve high electron plasma confinement regimes that are super-critically unstable to the electron temperature gradient driven (ETG) instability. These plasmas, dubbed electron internal transport barriers (e-ITBs), occur when the magnetic shear becomes strongly negative. Using the gyrokinetic code GYRO [J. Candy and R. E. Waltz, J. Comput. Phys. 186, 545 (2003)], the first nonlinear ETG simulations of NSTX e-ITB plasmas reinforce this observation. Local simulations identify a strongly upshifted nonlinear critical gradient for thermal transport that depends on magnetic shear. Global simulations show e-ITB formation can occur when the magnetic shear becomes strongly negative. Finally, while the ETG-driven thermal flux at the outer edge of the barrier is large enough to be experimentally relevant, the turbulence cannot propagate past the barrier into the plasma interior.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2012

BUOYANCY INSTABILITIES IN A WEAKLY COLLISIONAL INTRACLUSTER MEDIUM

The intracluster medium (ICM) of galaxy clusters is a weakly collisional plasma in which the transport of heat and momentum occurs primarily along magnetic-field lines. Anisotropic heat conduction allows convective instabilities to be driven by temperature gradients of either sign: the magnetothermal instability (MTI) in the outskirts of clusters and the heat-flux buoyancy-driven instability (HBI) in their cooling cores. We employ the Athena magnetohydrodynamic code to investigate the nonlinear evolution of these instabilities, self-consistently including the effects of anisotropic viscosity (i.e., Braginskii pressure anisotropy), anisotropic conduction, and radiative cooling. We find that, in all but the innermost regions of cool-core clusters, anisotropic viscosity significantly impairs the ability of the HBI to reorient magnetic-field lines orthogonal to the temperature gradient. Thus, while radio-mode feedback appears necessary in the central few Multiplication-Sign 10 kpc, heat conduction may be capable of offsetting radiative losses throughout most of a cool core over a significant fraction of the Hubble time. Magnetically aligned cold filaments are then able to form by local thermal instability. Viscous dissipation during cold filament formation produces accompanying hot filaments, which can be searched for in deep Chandra observations of cool-core clusters. In the case of MTI, anisotropic viscosity leads to a nonlinear state with a folded magnetic field structure in which field-line curvature and field strength are anti-correlated. These results demonstrate that, if the HBI and MTI are relevant for shaping the properties of the ICM, one must self-consistently include anisotropic viscosity in order to obtain even qualitatively correct results.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

Effects of magnetic islands on drift wave instability

Magnetic islands have been implemented in the gyrokinetic toroidal code to study the effects of the islands on microturbulence. The pressure profile flattening is verified in the simulation with the islands. Simulations of ion temperature gradient instability find that different toroidal modes are linearly coupled together and that toroidal spectra become broader when the island width increases. The real frequencies and growth rates of different toroidal modes approach each other with the averaged value independent of the island width. The linear mode structures are enhanced at the island separatrices and weakened at the island centers, consistent with the flattening of the pressure profile inside the islands.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1993

Numerical modeling of physical vapor transport under microgravity conditions: Effect of thermal creep and stress

One of the most promising applications of microgravity (micro-g) environments is the manufacture of exotic and high-quality crystals in closed cylindrical ampoules using physical vapor transport (PVT) processes. The quality enhancements are believed to be due to the absence of buoyant convection in the weightless environment - resulting in diffusion-limited transport of the vapor. In a typical experiment, solid-phase sample material is initially contained at one end of the ampoule. The sample is made to sublime into the vapor phase and deposit onto the opposite end by maintaining the source at an elevated temperature with respect to the deposit. Identification of the physical factors governing both the rates and uniformity of crystal growth, and the optimization of the micro-g technology, will require an accurate modeling of the vapor transport within the ampoule. Previous micro-g modeling efforts have approached the problem from a 'classical' convective/diffusion formulation, in which convection is driven by the action of buoyancy on thermal and solutal density differences. The general conclusion of these works have been that in low gravity environments the effect of buoyancy on vapor transport is negligible, and vapor transport occurs in a diffusion-limited mode. However, it has been recently recognized than in the non-isothermal (and often low total pressure) conditions encountered in ampoules, the commonly-assumed no-slip boundary condition to the differential equations governing fluid motion can be grossly unrepresentative of the actual situation. Specifically, the temperature gradients can give rise to thermal creep flows at the ampoule side walls. In addition, temperature gradients in the vapor itself can, through the action of thermal stress, lead to bulk fluid convection.

Mackowski, Daniel W.↗
NASA NTRS1999

Directional Solidification of Bi-Sn on USMP-4

The experiments used MEPHISTO hardware to study the solidification and melting behavior of bismuth alloyed with 1 at% tin. Three samples, each approximately 900 mm long and 6mm in diameter, were used. A portion of each sample also included a 2 mm diameter growth capillary, to assist in the formation of a single grain. One sample provided the Seebeck voltage generated during melting and freezing processes. Another provided temperature data and Peltier pulsed demarcation of the interface shape for post flight analysis. The third sample provided resistance and growth velocity measurements, as well as additional thermal data. The third sample was also quenched at the end of the mission to preserve the composition of the liquid near the interface for post flight determination. A total of 450mm of directionally solidified samples were preserved for post mission structural and compositional characterization. Substantial differences were observed in the Seebeck signal between the ground-based experiments and the space-based experiments. The temperature gradient in the liquid for the ground-based experiments was significantly lower than the temperature gradient in the liquid for the space-based experiments.

Abbaschian, Reza↗
DOE OSTI2018

Interaction between laser radiation and metallic powder of 316L austenitic steel during selective laser melting

Highlights: • Single and multiple tracks on a loose bulk powder substrate were generated. • Understanding of the microstructure development during SLM was achieved. • Single tracks reveal a nearly symmetrical crystallography with elongated grains. • Multiple tracks show elongated grains perpendicular to the build direction. - Abstract: During selective laser melting (SLM), a complex heat state develops that leads to a characteristic crystallography and microstructure of the processed materials. Depending on the geometry of the processed part, most scan tracks of a new layer, so-called hatches, are located above a dense substrate or already solidified structures whereas others are located above loose powder. This is, inter alia, the case for overhanging structures. Attributable to the lower thermal conductivity of loose powder, temperature gradients and cooling rates of the melt pool differentiate in these areas, resulting in a different microstructural build-up. In this work, the microstructure and the crystallographic orientation of grade 316L austenitic stainless steel processed by SLM was investigated to understand the interaction between the laser radiation and the metallic powder during SLM-processing and to investigate the remelting of a track on a previous SLM-densified track. Single and multiple tracks on a loose bulk powder substrate, as well as single tracks on a dense substrate plate, were generated. A parameter study revealed that high energy densities are necessary to build continuous tracks on a loose bulk powder substrate. In addition, the amount of adhered particles, which are sintered on the fully melted and solidified tracks, is determined in comparison to the melted powder because the sintered particles strongly influence the surface roughness. To understand the microstructure development and, particularly, the influence of adjacent hatches during SLM-processing, investigations on the resulting microstructure and crystallographic orientation of a single track and two connected multiple tracks were carried out. During SLM processing of the tracks, the substrate plate and the solidified structures influence the temperature gradient and cooling rate of the melt pool, thus directionally solidified and elongated grains occur. Furthermore, the solidification is characterized by an epitaxial growth due to a distinct thermal gradient between the melt pool and the surrounding elements.

36 MATERIALS SCIENCE↗
DOE OSTI2013

Magnetic stochasticity and transport due to nonlinearly excited subdominant microtearing modes

Subdominant, linearly stable microtearing modes are identified as the main mechanism for the development of magnetic stochasticity and transport in gyrokinetic simulations of electromagnetic ion temperature gradient driven plasma microturbulence. The linear eigenmode spectrum is examined in order to identify and characterize modes with tearing parity. Connections are demonstrated between microtearing modes and the nonlinear fluctuations that are responsible for the magnetic stochasticity and electromagnetic transport, and nonlinear coupling with zonal modes is identified as the salient nonlinear excitation mechanism. A simple model is presented, which relates the electromagnetic transport to the electrostatic transport. These results may provide a paradigm for the mechanisms responsible for electromagnetic stochasticity and transport, which can be examined in a broader range of scenarios and parameter regimes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2018

Modeling of Dendritic Evolution of Continuously Cast Steel Billet with Cellular Automaton

In order to predict the dendritic evolution during the continuous steel casting process, a simple mechanism to connect the heat transfer at the macroscopic scale and the dendritic growth at the microscopic scale was proposed in the present work. As the core of the across-scale simulation, a two-dimensional cell automaton (CA) model with a decentered square algorithm was developed and parallelized. Apart from nucleation undercooling and probability, a temperature gradient was introduced to deal with the columnar-to-equiaxed transition (CET) by considering its variation during continuous casting. Based on the thermal history, the dendritic evolution in a 4 mm × 40 mm region near the centerline of a SWRH82B steel billet was predicted. The influences of the secondary cooling intensity, superheat, and casting speed on the dendritic structure of the billet were investigated in detail. The results show that the predicted equiaxed dendritic solidification of Fe-5.3Si alloy and columnar dendritic solidification of Fe-0.45C alloy are consistent with in situ experimental results [Yasuda et al. Int J Cast Metals Res 22:15–21 (2009); Yasuda et al. ISIJ Int 51:402–408 (2011)]. Moreover, the predicted dendritic arm spacing and CET location agree well with the actual results in the billet. The primary dendrite arm spacing of columnar dendrites decreases with increasing secondary cooling intensity, or decreasing superheat and casting speed. Meanwhile, the CET is promoted as the secondary cooling intensity and superheat decrease. However, the CET is not influenced by the casting speed, owing to the adjusting of the flow rate of secondary spray water. Compared with the superheat and casting speed, the secondary cooling intensity can influence the cooling rate and temperature gradient in deeper locations, and accordingly exerts a more significant influence on the equiaxed dendritic structure.

36 MATERIALS SCIENCE↗
DOE OSTI2015

Spin Seebeck devices using local on-chip heating

A micro-patterned spin Seebeck device is fabricated using an on-chip heater. Current is driven through a Au heater layer electrically isolated from a bilayer consisting of Fe{sub 3}O{sub 4} (insulating ferrimagnet) and a spin detector layer. It is shown that through this method it is possible to measure the longitudinal spin Seebeck effect (SSE) for small area magnetic devices, equivalent to traditional macroscopic SSE experiments. Using a lock-in detection technique, it is possible to more sensitively characterize both the SSE and the anomalous Nernst effect (ANE), as well as the inverse spin Hall effect in various spin detector materials. By using the spin detector layer as a thermometer, we can obtain a value for the temperature gradient across the device. These results are well matched to values obtained through electromagnetic/thermal modeling of the device structure and with large area spin Seebeck measurements.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2013

Sublimation-Condensation of Multiscale Tellurium Structures

This paper presents a simple technique for making tellurium (Te) nano and microtubes of widely varying dimensions with Multi-Scale Processing (MSP). In this process, the Te metal is placed in a reaction vessel (e.g., borosilicate or fused quartz), the vessel is evacuated, and then sealed under vacuum with a torch. The vessel is heat-treated in a temperature gradient where a portion of the tube that can also contain an additional substrate, is under a decreasing temperature gradient. Scanning and transmission electron microscopies have shown that multifaceted crystalline tubes have been formed extending from nano- up to micron-scale with diameters ranging from 51.2 ± 5.9 to 1042 ± 134 nm between temperatures of 157 and 224 °C, respectively. One-dimensional tubular features are seen at lower temperatures, while three-dimensional features, at the higher temperatures. These features have been characterized with X-ray diffraction and found to be trigonal Te with space group P3121. Our results show that the MSP can adequately be described using a simple Arrhenius equation.

nanotubes↗
DOE OSTI2016

Intrinsic rotation drive by collisionless trapped electron mode turbulence

For this work, both the parallel residual stress and parallel turbulent acceleration driven by electrostatic collisionless trapped electron mode (CTEM) turbulence are calculated analytically using gyrokinetic theory. Quasilinear results show that the parallel residual stress contributes an outward flux of co-current rotation for normal magnetic shear and turbulence intensity profile increasing outward. This may induce intrinsic counter-current rotation or flattening of the co-current rotation profile. The parallel turbulent acceleration driven by CTEM turbulence vanishes, due to the absence of a phase shift between density fluctuation and ion pressure fluctuation. This is different from the case of ion temperature gradient turbulence, for which the turbulent acceleration can provide co-current drive for normal magnetic shear and turbulence intensity profile increasing outward. Its order of magnitude is predicted to be the same as that of the divergence of the residual stress [L. Wang and P. H. Diamond, Phys. Rev. Lett. 110, 265006 (2013)]. A possible connection of these theoretical results to experimental observations of electron cyclotron heating effects on toroidal rotation is discussed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1999

In Situ Monitoring of Crystal Growth Using MEPHISTO, Mission STS 87-Program USMP-4: Experimental Analysis

This report summarizes the results of the In situ Monitoring of Crystal Growth Using MEPHISTO (Material por l'Etude des Phenomenes Interessant de la Solidification sur Terre et en Orbite) experiment on USMP-4. The report includes microstructural and compositional data obtained during the first year of the post flight analysis, as well as numerical simulation of the flight experiment. Additional analyses are being continued and will be reported in the near future. The experiments utilized MEPHISTO hardware to study the solidification and melting behavior of bismuth alloyed with 1 at% tin. The experiments involved repeated melting and solidification of three samples, each approximately 90 cm long and 6mm in diameter. Half of each sample also included a 2 mm. diameter growth capillary, to assist in the formation of single grain inside. One sample provided the Seebeck voltage generated during melting and freezing processes. Another one provided temperature data and Peltier pulsed demarcation of the interface shape for post flight analysis. The third sample provided resistance and velocity measurements, as well as additional thermal data. The third sample was also quenched at the end of the mission to preserve the interface composition for post flight determination. A total of more than 45cm of directionally solidified alloy were directionally solidified at the end of the flight for post mission structural and compositional characterization. Metallurgical analysis of the samples has shown that the interfacial kinetics play a key role in controlling the morphological stability of faceted alloys. Substantial differences were observed in the Seebeck signal between the ground-based experiments and the space-based experiments. The temperature gradient in the liquid for the ground-based experiments was also significantly lower than the temperature gradient in the liquid for the space-based experiments. Both of these observations indicate significant influence of liquid convection for the ground-based experiments.

Abbaschian, Reza↗
DOE OSTI2011

COSMOLOGICAL MAGNETOHYDRODYNAMIC SIMULATIONS OF CLUSTER FORMATION WITH ANISOTROPIC THERMAL CONDUCTION

The intracluster medium (ICM) has been suggested to be buoyantly unstable in the presence of magnetic field and anisotropic thermal conduction. We perform first cosmological simulations of galaxy cluster formation that simultaneously include magnetic fields, radiative cooling, and anisotropic thermal conduction. In isolated and idealized cluster models, the magnetothermal instability (MTI) tends to reorient the magnetic fields radially whenever the temperature gradient points in the direction opposite to gravitational acceleration. Using cosmological simulations of cluster formation we detect radial bias in the velocity and magnetic fields. Such radial bias is consistent with either the inhomogeneous radial gas flows due to substructures or residual MTI-driven field rearrangements that are expected even in the presence of turbulence. Although disentangling the two scenarios is challenging, we do not detect excess bias in the runs that include anisotropic thermal conduction. The anisotropy effect is potentially detectable via radio polarization measurements with LOFAR and the Square Kilometer Array and future X-ray spectroscopic studies with the International X-ray Observatory. We demonstrate that radiative cooling boosts the amplification of the magnetic field by about two orders of magnitude beyond what is expected in the non-radiative cases. This effect is caused by the compression of the gas and frozen-in magnetic field as it accumulates in the cluster center. At z = 0 the field is amplified by a factor of about 10{sup 6} compared to the uniform magnetic field that evolved due to the universal expansion alone. Interestingly, the runs that include both radiative cooling and thermal conduction exhibit stronger magnetic field amplification than purely radiative runs. In these cases, buoyant restoring forces depend on the temperature gradients rather than the steeper entropy gradients. Thus, the ICM is more easily mixed and the winding up of the frozen-in magnetic field is more efficient, resulting in stronger magnetic field amplification. We also demonstrate that thermal conduction partially reduces the gas accretion driven by overcooling despite the fact that the effective conductivity is suppressed below the Spitzer-Braginskii value.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2012

Simulation of microtearing turbulence in national spherical torus experiment

Thermal energy confinement times in National Spherical Torus Experiment (NSTX) dimensionless parameter scans increase with decreasing collisionality. While ion thermal transport is neoclassical, the source of anomalous electron thermal transport in these discharges remains unclear, leading to considerable uncertainty when extrapolating to future spherical tokamak (ST) devices at much lower collisionality. Linear gyrokinetic simulations find microtearing modes to be unstable in high collisionality discharges. First non-linear gyrokinetic simulations of microtearing turbulence in NSTX show they can yield experimental levels of transport. Magnetic flutter is responsible for almost all the transport ({approx}98%), perturbed field line trajectories are globally stochastic, and a test particle stochastic transport model agrees to within 25% of the simulated transport. Most significantly, microtearing transport is predicted to increase with electron collisionality, consistent with the observed NSTX confinement scaling. While this suggests microtearing modes may be the source of electron thermal transport, the predictions are also very sensitive to electron temperature gradient, indicating the scaling of the instability threshold is important. In addition, microtearing turbulence is susceptible to suppression via sheared E Multiplication-Sign B flows as experimental values of E Multiplication-Sign B shear (comparable to the linear growth rates) dramatically reduce the transport below experimental values. Refinements in numerical resolution and physics model assumptions are expected to minimize the apparent discrepancy. In cases where the predicted transport is strong, calculations suggest that a proposed polarimetry diagnostic may be sensitive to the magnetic perturbations associated with the unique structure of microtearing turbulence.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗