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At least 559 records · Page 31

Estimating soil thermal inertia profiles from the passive equilibration of a temperature probe: Supporting data and code

This dataset contains measurements of soil thermal properties and organic layer thickness at three field sites on the Seward Peninsula near Nome, Alaska, USA. Code is also provided for estimation of soil thermal properties from temperature data, including a forward heat transfer mode, a library of simulated temperature data, and an inversion scheme to retrieve thermal properties from temperature measurements (Lamb et al., 2025). This dataset and code is published in support of the manuscript “Estimating Soil Thermal Inertia Profiles from the Passive Equilibration of a Temperature Probe” by Lamb et al., 2025, in which an experimental thermal measurements technique is developed. The dataset contains measurements of soil thermal properties and organic layer thickness obtained with an industry standard thermal properties analyzer and direct observations, as well as data generated using the experimental technique to estimate thermal properties and soil structure from temperature observations. All data is reported in .csv format, and all code is written in Python 3.7 using standard packages. This research was performed as a part of the NGEE Arctic project, which aims to advance model predictions of arctic carbon cycle responses to a changing climate over the 21st Century.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗

A second order yield-temperature relation for accurate inference of burn-averaged quantities in multi-species plasmas

Measured yields and ion temperatures inferred from the fusion product energy spectra can be used as metrics for the performance of an ICF implosion. This can be used to infer species separation, thermal decoupling, flows, or other effects that can cause the inferred ion temperatures to deviate from the true underlying thermal temperature and the yield ratio to deviate from the expected value. Direct inference of the impact of these effects on observed temperatures and yields can be difficult to uncover due to the underlying dependence on the shape and time evolution of the temperature and density profiles of the fusing plasma. Due to differences in the temperature dependence of the reactivities, different fusion products are emitted from different regions and times within the implosion. In order to properly account for this, a second-order analytical expression relating the apparent temperatures and yield ratios is developed. This expression can be coupled to models of yield and/or temperature altering effects to infer their burn-averaged impact on an implosion. The second-order expression shows significant improvement over lower-order expressions in synthetic data studies. Demonstrations of its applications to synthetic data coupled with models of ion thermal decoupling and radial flows are presented. In the case of thermal decoupling, both first and second-order expressions show reasonable levels of accuracy. To consistently infer the amplitude of radial flow with a <10% error, the second-order equation is required.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Stabilizing homogeneous CaMn6Sn6via oscillatory crystal growth: structural complexity in a kagome metal

CaMn6Sn6 is a member of the large family of Mn-based kagome metals derived by filling voids of the prototypical CoSn structure. We observed Ca-deficiency and structural complexity, with approximately 10% deficiency of calcium relative to the ideal 166 stoichiometry. These features are common in related Ca-based materials. We find that growth conditions stabilize different phases with varying Curie temperatures. Diffraction and magnetization measurements reveal that conventional growth profiles yield inhomogeneity both within and between crystals in a given batch, whereas an oscillatory temperature profile promotes homogeneous crystals that adopt a superstructure beyond the parent hexagonal structure type. We present the physical properties of crystals grown using the oscillatory approach. The crystals are highly conductive, with a c-axis residual resistivity ratio ρ(300 K)/ρ(2 K) exceeding 100 and a positive, linear magnetoresistance at base temperature. Magnetically, the crystals are quite similar to MgMn6Sn6, with easy-plane ferromagnetic behavior and a Curie temperature of TC ≈ 237 K. These results highlight the critical role of growth conditions in stabilizing homogeneous crystals of complex phases such as Ca0.9Mn6Sn6. The oscillatory growth approach provides an effective route for accessing the intrinsic properties of this complex material and may be broadly useful for the growth of related kagome systems.

May, Andrew [ORNL] (ORCID:0000000307778539)↗

Distributed Fiber Sensors With High Spatial Resolution in Extreme Radiation Environments in Nuclear Reactor Cores

This paper is a comprehensive experimental report on the neutron radiation effects of distributed optical fiber sensors with enhanced Rayleigh scattering profiles in an in-pile environment. Femtosecond laser direct writing was used to inscribe Type-II modifications in standard telecom fibers and radiation-hardened fibers with fluorine-doped cores. Rayleigh backscattering signals were enhanced for continuous 1.5 m. In-pile lead-out sensors tests were carried out at the MIT Research Reactor for two months, which was operated at a nominal power of 5.7 MW with fast neutron (>0.1 MeV) flux of 1.29 × 1014 n/cm2/s and an in-core temperature of up to 560°C. Using the Optical Frequency Domain Reflectometry technique, the backscattering profiles of fiber sensors were interrogated with a 3-cm spatial resolution to monitor the temperature profile of the reactor. Results show that laser inscribed Type-II modifications in the form of nanogratings are highly stable against extreme temperature and ionizing radiation. Both standard telecom fibers and radiation-hardened fibers with laser-enhanced Rayleigh profiles can continuously perform distributed temperature measurements over the entire duration of the in-pile testing. Temperature coefficients of sensors and spectral shift quality were studied as functions of total radiation fluence. To the best of our knowledge, we present for the first time, the temperature profile of an operating nuclear reactor core with 3-cm spatial resolution, enabled by distributed fiber sensors with laser-enhanced Rayleigh scattering profiles. The high spatial resolution measurements can provide valuable data for the design and validation of digital twin and virtual reality of nuclear energy systems.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Experimental study of high-k turbulence during an energy confinement degradation phase in EAST ohmic plasmas

In this paper, we present experimental studies of both high-k(r) ( cm(-1), and , respectively; ) and high- ( cm(-1), and , respectively; ) turbulence behavior during an ohmic energy confinement degradation phase in experimental advanced superconducting tokamak (EAST). High-k(r) turbulence from density fluctuation at and high- turbulence from density fluctuation at -0.97 were measured by tangential and poloidal CO2 laser collective scattering diagnostics, respectively. Note that k(r), , and are radial wavenumber, poloidal wavenumber, perpendicular wavenumber and ion gyroradius at electron temperature, respectively. Both high-k(r)/ turbulence power and energy confinement time are found to be temporally correlated to line-averaged electron density n(e) in the plasma current flat-top phase (I-p = 0.4 MA): when the n(e) shows continuous increase/decrease, the high-k(r)/ turbulence power increases/decreases correspondingly and the shows corresponding decrease/increase; the stable n(e) is related to stable both and high-k(r)/ turbulence power. Statistical results of high-k(r)/ turbulence power versus further imply that high-k(r)/ turbulence shows a strong correlation with plasma energy confinement degradation in high line-averaged n(e) condition, but high-k(r) and high- turbulence have relatively weak and no dependence on the transition between linear range in low-n(e) condition and energy confinement degradation in the high-n(e) condition, respectively. Moreover, profiles of electron temperature T-e and n(e) as well as their normalized gradients in a part of high- density fluctuation measurement region also have been given to qualitatively explain the enhancement of turbulence power with the increase of line-averaged n(e).

EAST tokamak↗

Near-wall model for compressible turbulent boundary layers based on an inverse velocity transformation

In this work, a near-wall model, which couples the inverse of a recently developed compressible velocity transformation (Griffin et al., Proc. Natl Acad. Sci., vol. 118, 2021, p. 34) and an algebraic temperature–velocity relation, is developed for high-speed turbulent boundary layers. As input, the model requires the mean flow state at one wall-normal height in the inner layer of the boundary layer and at the boundary-layer edge. As output, the model can predict mean temperature and velocity profiles across the entire inner layer, as well as the wall shear stress and heat flux. The model is tested in an a priori sense using a wide database of direct numerical simulation high-Mach-number turbulent channel flows, pipe flows and boundary layers (48 cases, with edge Mach numbers in the range 0.77–11, and semi-local friction Reynolds numbers in the range 170–5700). The present model is significantly more accurate than the classical ordinary differential equation (ODE) model for all cases tested. The model is deployed as a wall model for large-eddy simulations in channel flows with bulk Mach numbers in the range 0.7–4 and friction Reynolds numbers in the range 320–1800. When compared to the classical framework, in the a posteriori sense, the present method greatly improves the predicted heat flux, wall stress, and temperature and velocity profiles, especially in cases with strong heat transfer. In addition, the present model solves one ODE instead of two, and has a computational cost and implementation complexity similar to that of the commonly used ODE model.

42 ENGINEERING↗

Linear instabilities in the hot-ion regime in a high-field spherical tokamak

Abstract The present operating high-field compact spherical tokamak ST40 is an important step toward an ST-based fusion reactor (Gryaznevich and Asunta 2017 Fusion Eng. Des. 123 177; McNamara 2023 Nucl. Fusion 63 054002). Temperature and density profiles and their uncertainties in recent hot ion ST40 plasmas with central ion temperatures exceeding 8.6 keV, have been inferred using an integrated analysis of several diagnostics including line-of-sight integration and volume average measurements, as well as limited profile information from a charge-exchange-recombination spectrometer. A linear gyrokinetic stability analysis has been carried out to identify the most unstable micro-instabilities in these hot ion plasmas. In one of these plasmas, it is found that linear growth rates of both ion- and electron-scale ( k θ ρ s ⩾ 0.2 where k θ is the poloidal wavenumber and ρ s is the ion gyro-radius with sound speed) modes decrease from the edge toward the core of the plasma (i.e. from ρ = 0.8 to 0.3 where ρ is the square root of the normalized magnetic flux), while the change of linear growth rates at k θ ρ s < 0.2 is non-monotonic. In particular, at ρ = 0.3 no unstable mode was found at k θ ρ s > 5 , and about an order of magnitude reduction in the maximum linear growth rate in the ion-scale wavenumber range of 0.2 ⩽ k θ ρ s < 1 is seen at ρ = 0.3 compared with the ρ = 0.8 location. It is found through parametric scans that while the ion temperature gradient (ITG) mode/trapped electron mode (TEM) and kinetic ballooning mode (KBM)/kinetic shear Alfvén (KSA) mode are more important in the plasma core, ubiquitous mode (UM) is found to be the important ion-scale instability at ρ ⩾ 0.6 . At ρ = 0.8, two instabilities are found at the electron scale, with one being the typical electrostatic electron temperature gradient (ETG) mode at ρ e scale and beyond and the other being an unidentified low-real-frequency instability (at the intermediate scale between electron and ion gyroradii) which can propagate in the ion direction and is driven by ETG. The existence of UM at the ion scale and the low-real-frequency instability and ETG mode at the electron scale at ρ = 0.8 is supported by an extensive linear gyrokinetic stability analysis of another ST40 hot ion plasma in a wider parametric range, taking into account the uncertainties in the experimental profiles.

ubiquitous mode↗

Estimating Soil Thermal Inertia Profiles From the Passive Equilibration of a Temperature Probe

Knowledge of the distribution of soil thermal properties is important for understanding subsurface hydrological and biogeochemical processes. This study describes and evaluates quick thermal profiling (QTP), a new measurement technique aimed at providing rapid, depth-resolved measurements of soil thermal inertia at numerous locations across the landscape. A cylindrical probe with temperature sensors at multiple depths is quickly inserted into the ground, and soil thermal inertia is estimated from how quickly the probe temperature equilibrates with the soil. To this end, a finite volume heat transfer model is used to generate temperature equilibration time series across combinations of controlling factors, and a gridded search inversion approach is applied to infer soil thermal inertia. Field tests in the Arctic indicate that QTP measurements have a minimum uncertainty of 0.14 J m −2 K −1 s −1/2 and covary with dual-probe heat pulse thermal analyzer measurements (concordance correlation coefficient = 0.56) with a root-mean-square error of 0.40 J m −2 K −1 s −1/2 . Besides demonstrating the value of QTP for estimating thermal inertia, this study identifies various sources of measurement uncertainty, particularly probe-soil contact resistance and frictional heating. Further, analysis of soil samples indicates that thermal inertia can be used to estimate thermal conductivity and dry bulk density in the studied area, although such inferences are highly site-specific. Overall, the QTP method holds promise to generate thermal inertia data products and to complement other characterization approaches for advancing understanding of soil properties across far more locations than is currently possible.

Lamb, J. R. [Lawrence Berkeley National Laboratory↗

Multiscale CFD simulation of biomass fast pyrolysis with a machine learning derived intra-particle model and detailed pyrolysis kinetics

Coupling particle and reactor scale models is as essential as reactor fluid dynamics and particle motion for accurate Computational Fluid Dynamic (CFD) simulations of biomass fast pyrolysis reactors due to intraparticle heat transfer and chemical reactions controlling conversion time and product distributions. Direct online coupling of a particle model with a reactor model is computationally expensive, while offline coupling is case-dependent. In this research, solutions from a series of particle pyrolysis simulations were regressed with Artificial Neural Network (ANN). Furthermoer, this machine learning-derived model predicted the same temperature and conversion profiles compared with particle resolved simulation while the isothermal approach overpredicted the temperature by 130 K and underpredicted the conversion time by 30 s. The ANN model was then integrated into CFD simulations of fluidized bed biomass fast pyrolysis with varied feedstocks via coupling PyTorch and MFiX. The averaged error of simulation predicted bio-oil yields with four feedstocks is 6.4%. This multi-scale approach provides an efficient tool for the coupled particle and reactor scale simulations of biomass pyrolysis.

09 BIOMASS FUELS↗

Probabilistic estimation of depth-resolved profiles of soil thermal diffusivity from temperature time series

Abstract. Improving the quantification of soil thermal and physical properties is key to achieving a better understanding and prediction of soil hydro-biogeochemical processes and their responses to changes in atmospheric forcing. Obtaining such information at numerous locations and/or over time with conventional soil sampling is challenging. The increasing availability of low-cost, vertically resolved temperature sensor arrays offers promise for improving the estimation of soil thermal properties from temperature time series, and the possible indirect estimation of physical properties. Still, the reliability and limitations of such an approach need to be assessed. In the present study, we develop a parameter estimation approach based on a combination of thermal modeling, sliding time windows, Bayesian inference, and Markov chain Monte Carlo simulation to estimate thermal diffusivity and its uncertainty over time, at numerous locations and at an unprecedented vertical spatial resolution (i.e., down to 5 to 10 cm vertical resolution) from soil temperature time series. We provide the necessary framework to assess under which environmental conditions (soil temperature gradient, fluctuations, and trend), temperature sensor characteristics (bias and level of noise), and deployment geometries (sensor number and position) soil thermal diffusivity can be reliably inferred. We validate the method with synthetic experiments and field studies. The synthetic experiments show that in the presence of median diurnal fluctuations ≥ 1.5 ∘C at 5 cm below the ground surface, temperature gradients > 2 ∘C m−1, and a sliding time window of at least 4 d the proposed method provides reliable depth-resolved thermal diffusivity estimates with percentage errors ≤ 10 % and posterior relative standard deviations ≤ 5 % up to 1 m depth. Reliable thermal diffusivity under such environmental conditions also requires temperature sensors to be spaced precisely (with accuracy to a few millimeters), with a level of noise ≤ 0.02 ∘C, and with a bias defined by a standard deviation ≤ 0.01 ∘C. Finally, the application of the developed approach to field data indicates significant repeatability in results and similarity with independent measurements, as well as promise in using a sliding time window to estimate temporal changes in soil thermal diffusivity, as needed to potentially capture changes in bulk density or water content.

54 ENVIRONMENTAL SCIENCES↗

Temperature and water vapor mixing ratio profiles retrieved from the MWR

The purpose of this study was to look at the thermodynamic and microphysical evolution the atmosphere during fog events at Summit. These cases were selected due to the presence of fog during a period when additional aerosol sensors where deployed on the colocated tower.

54 ENVIRONMENTAL SCIENCES↗

Initial Developments in Modeling Graphite Behavior

Graphite is used in High Temperature Reactor designs as a moderator, reflector and core material responsible for protecting the fuel and maintaining structural stability. From a safety perspective, it is imperative to be able to predict how graphite will behave under reactor operating conditions which may compromise the core’s structural integrity or fuel’s safety performance. The following report summarizes recent modeling work undertaken at Idaho National Laboratory which focuses on graphite degradation behavior. One phenomenon which is explored in this report and can cause significant degradation to graphite properties is oxidation. Oxidation behavior in graphite is highly temperature dependent. At low temperatures, oxygen can fully penetrate a component and cause a homogeneous damage profile. At high temperatures, only the graphite near the surface of a component is affected. Understanding and modeling this temperature dependence is essential to predicting graphite behavior. In this report, three graphite models are discussed. The first model is used to investigate strength loss after low temperature oxidation. It does this by generating an approximate graphite microstructure then determining the required load to cause crack propagation. It has been shown that the model reproduces the quasi brittle stress versus strain relationship observed in graphite. Strength loss results from the model are shown to match experimental values. The second model investigates strength loss under high temperature oxidation conditions. This model is more applicable to full scale graphite components where the oxidation damage is often inhomogeneous throughout a component. The third model computes stresses in graphite under reactor conditions. Specifically, the model incorporates the effect of creep, irradiation dose, thermal strains, and oxidation in order to predict internal stresses in a component. All of these models are implemented in the Multiphysics Object-Oriented Simulation Environment (MOOSE), an open source, parallel finite element framework.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Length scales and scale-free dynamics of dislocations in dense solid solutions

The fundamental interactions between an edge dislocation and a random solid solution are studied by analyzing dislocation line roughness profiles obtained from molecular dynamics simulations of Fe 0.70 Ni 0.11 Cr 0.19 over a range of stresses and temperatures. These roughness profiles reveal the hallmark features of a depinning transition. Namely, below a temperature-dependent critical stress, the dislocation line exhibits roughness in two different length scale regimes which are divided by a so-called correlation length. This correlation length increases with applied stress and at the critical stress (depinning transition or yield stress) formally goes to infinity. Above the critical stress, the line roughness profile converges to that of a random noise field. Motivated by these results, a physical model is developed based on the notion of coherent line bowing over all length scales below the correlation length. Above the correlation length, the solute field prohibits such coherent line bow outs. Using this model, we identify potential gaps in existing theories of solid solution strengthening and show that recent observations of length-dependent dislocation mobilities can be rationalized.

36 MATERIALS SCIENCE↗

Water vapor oxidation behaviors of nuclear graphite IG-110 for a postulated accident scenario in high temperature gas-cooled reactors

Water leakage in accidental conditions of high temperature gas-cooled reactors is one of the most critical problems that can compromise the integrity of different nuclear components. In this study, oxidation behaviors of nuclear graphite IG-110 in water ingress accidental conditions were investigated. Mass loss and oxidation rates were evaluated after oxidation tests at temperatures up to 1400 °C in an Ar-20 vol% H 2 O mixed atmosphere. The activation energy decreased from 318.6 to 148.9 kJ/mol with temperature, indicating two different oxidation regimes. The cross-sections of the oxidized samples were systematically characterized. The corresponding logarithmic porosity profiles showed a temperature dependency. Pore formation moved toward near-surface regions with increasing temperature and preferential binder oxidation, with filler particle degradation. Furthermore, oxidant concentration profiles and oxidation depths were estimated using a theoretical model and compared with the experimental results. This work provides important benchmark data and safety analysis guidance for the accident scenario in high temperature gas-cooled reactors.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Impact of Soret effect on hydrogen and helium retention in PFC tungsten under ELM-like conditions

Abstract In our previous work, we have demonstrated using nonequilibrium molecular-dynamics simulations that the fluxes of helium and self-interstitial atoms in the presence of a thermal gradient in tungsten are directed opposite to the heat flux, indicating that species transport is governed by a Soret effect, namely, thermal-gradient-driven diffusion, characterized by a negative heat of transport that drives species transport uphill, i.e. from the cooler to the hot regions of the tungsten sample. In this work, the findings of our thermal and species transport analysis have been implemented in our cluster-dynamics code, Xolotl, which has been used to compute temperature and species profiles over spatiotemporal scales representative of plasma-facing component (PFC) tungsten under typical reactor operating conditions, including extreme heat loads at the plasma-facing surface characteristic of plasma instabilities that induce edge localized modes (ELMs). We demonstrate that the steady-state species profiles, when properly accounting for the Soret effect, vary significantly from those where temperature-gradient-driven transport is not accounted for and discuss the implications of such a Soret effect on the response to plasma exposure of plasma-facing tungsten. Although our cluster-dynamics simulations do not yet include self-clustering of helium or hydrogen blister formation, our simulation results show that the Soret effect substantially reduces helium and hydrogenic species retention inside PFC tungsten.

36 MATERIALS SCIENCE↗

Spectroscopic measurement of increases in hydrogen molecular rotational temperature with plasma-facing surface temperature and due to collisional-radiative processes in tokamaks

Abstract Spatially resolved rotational temperature of ground state hydrogen molecules desorbed from plasma-facing surface was measured in QUEST, LTX-β, and DIII-D tokamaks, and the increases of the rotational temperature with the surface temperature and due to collisional-radiative processes in the plasmas were evaluated. The increase due to collisional-radiative processes was calculated by solving rate equations considering electron and proton collisional excitation and deexcitation and spontaneous emission. The calculation results suggest a high sensitivity for the rotational temperature to electron and proton densities, but a negligible sensitivity to the electron, proton, and surface temperatures. In the three tokamaks with different plasma parameters and plasma-facing surface materials, the spatial profile of the rotational temperature was estimated using Fulcher-α emission lines (600–608 nm). In QUEST, the spatial profile of the rotational temperature was estimated from spatially resolved spectra. In the other tokamaks, the rotational temperature was evaluated assuming a single point emission with a location determined from the Fulcher-α emission profile as measured with a filtered camera. In metal-walled devices QUEST and LTX-β, the rotational temperature increased with the surface temperature, and the calculated collisional-radiative increase is consistent with measured increase assuming that the rotational temperature at the surface is approximately 500–600 K higher than the surface temperature. In DIII-D with carbon walls, a larger collisional-radiative increase than the other tokamaks was observed because of the higher density leading to a large difference from the calculated increase compared to the other smaller tokamaks. Measurement of the Fulcher-α emission profile with higher spatial resolution in DIII-D may reduce the difference and reveal the effect of the surface temperature on the rotational temperature. These results show the increases in the rotational temperature with the surface temperature and due to the collisional-radiative processes.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Evaluation of a land-atmosphere coupling metric computed from a ground-based infrared interferometer

Land-atmosphere feedbacks are a critical component of the hydrologic cycle. Vertical profiles of boundary layer temperature and moisture, together with information about the land surface, are used to compute land-atmosphere coupling metrics. Ground based remote sensing platforms, such as the Atmospheric Emitted Radiance Interferometer (AERI), can provide high temporal resolution vertical profiles of temperature and moisture. When co-located with soil moisture, surface flux, and surface meteorological observations, such as at the Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site, it is possible to observe both the terrestrial and atmospheric legs of land-atmosphere feedbacks. In this study, we compare a commonly used coupling metric computed from radiosonde-based data to that obtained from the AERI to characterize the accuracy and uncertainty in the metric derived from the two distinct platforms. This approach demonstrates the AERI’s utility where radiosonde observations are absent in time and/or space. Radiosonde and AERI based observations of the Convective Triggering Potential and Low-Level Humidity Index (CTP-HI low ) were computed during the 1200 UTC observation time and displayed good agreement during both 2017 and 2019 warm seasons. Furthermore, radiosonde and AERI derived metrics diagnosed the same atmospheric preconditioning based upon the CTP-HI low framework a majority of the time. When retrieval uncertainty was considered, even greater agreement was found between radiosonde and AERI derived classification. The AERI’s ability to represent this coupling metric well enabled novel exploration of temporal variability within the overnight period in CTP and HI low . Observations of CTP-HI low computed within a few hours of 1200 UTC were essentially equivalent, however with greater differences in time arose greater differences in CTP and HI low .

54 ENVIRONMENTAL SCIENCES↗