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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Trace element partitioning between ionic crystal and liquid

The partitioning of trace elements between ionic crystals and the melt has been correlated with lattice energy of the host. The solid-liquid partition coefficient has been expressed in terms of the difference in relative ionic radius of the trace element and the homogeneous and heterogeneous strain of the host lattice. Predictions based on this model appear to be in general agreement with data for alkali nitrates and for rare-earth elements in natural garnet phenocrysts.

Tsang, T.↗
NASA NTRS1978

Chemistry, mineralogy and petrology of seven greater than 1 mm fragments from Mare Crisium

Results are summarized for a consortium study of the chemistry, mineralogy, and petrology of seven Luna 24 fragments greater than 1 mm in size and having a mass of about 2 mg each. The fragments include four samples of mare ferrobasalt composition, one vitrophyre with the composition of a Mg-rich VLT mare basalt, one agglutinate, and one plagioclase fragment. It is found that: (1) the ferrobasalt is a highly fractionated mare rock very low in alkalis and TiO2, is similar to the less fractionate Apollo 17 VLT basalts, and is quite low in large-ion lithophile trace-element content; (2) the rare-earth-element patterns of the ferrobasalts are typical of VLT basalt, but some ophitic basalts have positive Eu anomalies, while others have negative Eu anomalies typical of mare basalts; and (3) the agglutinate is feldspathic and similar in composition to soil fines in Fe, Cr, Ca, and Al.

Laul, J. C.↗
NASA NTRS1979

A petrogenetic model of the relationships among achondritic meteorites

Petrological evidence is used to support the hypothesis that although the magma source regions and parent bodies of basaltic achondrite, shergottite, nakhlite, and chassignite meteorites are clearly distinct, they may be simply related. It is proposed that the peridotites which on partial melting generated the parent magmas of the shergottite meteorites differed from those which gave rise to eucritic magmas by being enriched in a component rich in alkalis and other volatiles. Similarly, the source regions of the parent magmas of the nakhlite and chassignite meteorites differed from those on the shergottite parent body by being still richer in this volatile-rich component. These regions could have been related by processes such as mixture of variable amounts of volatile-rich and volatile-poor components in planetary or nebular settings, or alternatively by variable varying degrees of volatile loss from volatile-rich materials.

Stolper, E.↗
NASA NTRS1979

The distribution of zirconium and hafnium in terrestrial rocks, meteorites and the moon

It is shown that Zr and Hf are not always fractionated in terrestrial igneous differentiation or regional metamorphism. Data do support a Zr-Hf fractionation in the differentiation of the alkali olivine magma at St. Helena Island. A strong Zr-Hf fractionation exists among lunar rocks and minerals. Ilmenite is an excellent concentrator of Zr and Hf and always exhibits high Zr/Hf ratios. Chondritic meteorites exhibit rather uniform Zr abundances and Zr/Hf ratios but a distinct Zr-Hf fractionation is observed among the eucrite and diogenite achondrites.

Ehmann, W. D.↗
NASA NTRS1979

The petrogenesis of L-6 chondrites - Insights from the chemistry of minerals

Measurements of the major, minor and trace element abundances of the major minerals of the L-6 chondrites Alfianello, Colby (WI) and Leedey are used to investigate the formation mechanisms of L-6 chondrites. Electron microprobe analysis was performed on individual grains of each mineral, and separated minerals were analyzed by instrumental and radiochemical neutron activation analysis. The compositions of the three meteorites are observed to be generally uniform, however different abundances and distributions of rare earth elements and Co and Ni indicate that the meteorites have different petrogenetic histories. Alkali element distributions are found to be incompatible with internal equilibration of a closed system.

Curtis, D. B.↗
NASA NTRS1979

The structure of small, vapor-deposited particles. II - Experimental study of particles with hexagonal profile

'Multiply-twinned' gold particles with hexagonal bright field TEM profile were determined to be icosahedra composed of 20 identical and twin-related tetrahedral building units that do not have an fcc structure. The crystal structure of these slightly deformed tetrahedra is rhombohedral. Experimental evidence supporting this particle model was obtained by selected-zone dark field and weak beam dark field electron microscopy. In conjunction with the results of part I, it has been concluded that multiply-twinned gold particles of pentagonal or hexagonal profile that are found during the early stages of the vapor deposition growth process on alkali halide surfaces do not have an fcc crystal structure, which is in obvious contrast to the structure of bulk gold.

Yacaman, M. J.↗
NASA NTRS1979

A global geochemical model for the evolution of the mantle

It is proposed that the upper mantle transition region, 220 to 670 km, is composed of eclogite which has been derived from primitive mantle by about 20 percent partial melting and that this is the source and sink of oceanic crust. The remainder of the upper mantle is garnet peridotite which is the source of continental basalts and hotspot magmas. This region is enriched in incompatible elements by hydrous and CO2 rich metasomatic fluids which have depleted the underlying layers in the L.I.L. elements and L.R.E.E. The volatiles make this a low-velocity, high attenuation, low viscosity region. The eclogite layer is internally heated and its controls the convection pattern in the upper mantle. Plate tectonics is intermittent. The continental thermal anomaly at a depth of 150-220 km triggers kimberlite and carbonatite activity, alkali and flood basalt volcanism, vertical tectonics and continental breakup. Hot spots remain active after the continents leave and build the oceanic islands. Mantle plumes rise from a depth of about 220 km. Midocean ridge basalts rise from the depleted layer below this depth. Material from this layer can also be displaced upwards by subducted oceanic lithosphere to form back-arc basins.

Anderson, D. L.↗
NASA NTRS1979

A Conceptual Design Study on the Application of Liquid Metal Heat Transfer Technology to the Solar Thermal Power Plant

Alkali metal heat transfer technology was used in the development of conceptual designs for the transport and storage of sensible and latent heat thermal energy in distributed concentrator, solar Stirling power conversion systems at a power level of 15 kWe per unit. Both liquid metal pumped loop and heat pipe thermal transport were considered; system configurations included: (1) an integrated, focal mounted sodium heat pipe solar receiver (HPSR) with latent heat thermal energy storage; (2) a liquid sodium pumped loop with the latent heat storage, Stirling engine-generator, pump and valves located on the back side of the concentrator; and (3) similar pumped loops serving several concentrators with more centralized power conversion and storage. The focus mounted HPSR was most efficient, lightest and lowest in estimated cost. Design confirmation testing indicated satisfactory performance at all angles of inclination of the primary heat pipes to be used in the solar receiver.

Zimmerman, W. F.↗
NASA NTRS1980

An extended soft-cube model for the thermal accommodation of gas atoms on solid surfaces

A numerical soft cube model was developed for calculating thermal accommodation coefficients alpha and trapping fractions f sub t for the interaction of gases incident upon solid surfaces. A semiempirical correction factor c which allows the calculation of alpha and f sub t when the collision times are long compared to the surface oscillator period were introduced. The processes of trapping, evaporation, and detailed balancing were discussed. The numerical method was designed to treat economically and with moderate (+ or - 20 percent) accuracy the dependence of alpha and f sub t on finite and different surface and gas temperatures for a large number of gas/surface combinations. Comparison was made with experiments of rare gases on tungsten and on alkalis, as well as one astrophysical case of H2 on graphite. The dependence of alpha on the soft cube dimensionless parameters is presented graphically.

Burke, J. R.↗
NASA NTRS1980

High-temperature molten salt thermal energy storage systems

The results of comparative screening studies of candidate molten carbonate salts as phase change materials (PCM) for advanced solar thermal energy storage applications at 540 to 870 C (1004 to 1600 F) and steam Rankine electric generation at 400 to 540 C (752 to 1004 F) are presented. Alkali carbonates are attractive as latent heat storage materials because of their relatively high storage capacity and thermal conductivity, low corrosivity, moderate cost, and safe and simple handling requirements. Salts were tested in 0.1 kWhr lab scale modules and evaluated on the basis of discharge heat flux, solidification temperature range, thermal cycling stability, and compatibility with containment materials. The feasibility of using a distributed network of high conductivity material to increase the heat flux through the layer of solidified salt was evaluated. The thermal performance of an 8 kWhr thermal energy storage (TES) module containing LiKCO3 remained very stable throughout 5650 hours and 130 charge/discharge cycles at 480 to 535 C (896 to 995 F). A TES utilization concept of an electrical generation peaking subsystem composed of a multistage condensing steam turbine and a TES subsystem with a separate power conversion loop was defined. Conceptual designs for a 100 MW sub e TES peaking system providing steam at 316 C, 427 C, and 454 C (600 F, 800 F, and 850 F) at 3.79 million Pa (550 psia) were developed and evaluated. Areas requiring further investigation have also been identified.

Petri, R. J.↗
NASA NTRS1980

High-temperature molten salt thermal energy storage systems for solar applications

Alkali and alkaline earth carbonate latent-heat storage salts, metallic containment materials, and thermal conductivity enhancement materials were investigated to satisfy the high temperature (704 to 871 C) thermal energy storage requirements of advanced solar-thermal power generation concepts are described. Properties of the following six salts selected for compatibility studies are given: three pure carbonates, K2CO3, Li2CO3 and Na2CO3; two eutectic mixtures, BaCO3/Na2CO3 and K2CO3/NaCO3, and one off-eutectic mixture of Na2CO3/K2CO3.

Petri, R. J.↗
NASA NTRS1979

Symposium /International/ on Combustion, 17th, Leeds University, Leeds, England, August 20-25, 1978, Proceedings

The Symposium focused on deflagration to detonation transition, coal combustion, turbulent-combustion interactions, kinetics, furnace combustion, inhibition and ignition, flame structure and chemistry, combustion studies, measurement techniques, fire and explosion, engine combustion, soot, and propellants and explosives. Papers were presented on numerical modeling of the deflagration-to-detonation transition, the interaction between turbulence and combustion, turbulent flame propagation in premixed gases, spray evaporation in recirculating flow, dissociation of nitric oxide in shock waves, pollutant emissions from partially mixed turbulent flames, energy transfer and quenching rates of laser-pumped electronically excited alkalis in flames, a study of flammability limits using counterflow flames, the unified theory of explosions with fuel consumption, and the dynamics and radiant intensity of large hydrogen flames.

Source record↗
NASA NTRS1979

Decay of the zincate concentration gradient at an alkaline zinc cathode after charging

The study was carried out by observing the decay of the zincate concentration gradient at a horizontal zinc cathode after charging. This decay was found to approximate first order kinetics as expected from a proposed boundary layer model. The decay half life was shown to be a linear function of the thickness of porous zinc deposit on the cathode indicating a very rapid transport of zincate through porous zinc metal. The rapid transport is attributed to an electrochemical mechanism. The data also indicated a relatively sharp transition between the diffusion and convection transport regions. The diffusion of zincate ion through asbestos submerged in alkaline electrolyte was shown to be comparable with that predicted from the bulk diffusion coefficient of the zincate ion in alkali.

Kautz, H. E.↗
NASA NTRS1979

A new approach to the correlation of boundary layer mass transfer rates with thermal diffusion and/or variable properties

A rational approach to the correlation of boundary layer mass transport rates, applicable to many commonly encountered laminar flow conditions with thermal diffusion and/or variable properties, is outlined. The correlation scheme builds upon already available constant property blowing/suction solutions by introducing appropriate correction factors to account for the additional ('pseudo' blowing and source) effects identified with variable properties and thermal diffusion. Applications of the scheme to the particular laminar boundary layer mass transfer problems considered herein (alkali and transition metal compound vapor transport) indicates satisfactory accuracy up to effective blowing factors equivalent to about one third of the 'blow off' value. As a useful by-product of the variable property correlation, we extend the heat-mass transfer analogy, for a wide range of Lewis numbers, to include variable property effects.

Srivastava, R.↗
NASA NTRS1979

The Sr and Nd isotopic record of Apollo 12 basalts - Implications for lunar geochemical evolution

Alkali, alkaline earth, and rare earth element data are reported for several Apollo 12 basalts which are representative of the four Apollo 12 magma types. Results confirm the heterogeneity of the lunar mantle and show that the Sm/Nd ratio of at least the Apollo 12 ilmenite basalts was decreased by 13-24% during magma genesis. In addition, whole mare basalt Sm-Nd data are not collinear on an isochron diagram; thus it is no longer possible to explain these data via mixing of 'primitive material' and 'early differentiates' as in the hybridization and assimilation models.

Nyquist, L. E.↗
NASA NTRS1979

The Apollo 17 drill core - Petrologic systematics and the identification of a possible Tycho component

Modal data support a five-unit stratigraphy for the Apollo 17 drill core. The upper unit E (0-22 cm depth) is marked by high content of fused soil, brown glass, and mare basalt fragments. This unit corresponds with a portion of the core excavated and refilled within the last 2 m.y. The underlying unit D (22071 cm depth) has a low abundance of fused soil (i.e., low maturity) and is rich in coarse (less than 200 microns) mare fragments. A large section of the core, unit C (71-224 cm depth), is finer-grained, more mature (richer in agglutinates), more feldspathic and has more highland lithic, mineral and glass fragments than unit D. The next underlying unit, B (224-256 cm depth), has yellow/colorless KREEP glasses with a high Si, low-alkali composition unlike the common Apollo 15 or Apollo 17 KREEP series. The petrologic (fused soil) and Is/FeO maturity of this layer is also lower than the units above and below. The deepest unit, A (256-284 cm depth), is marked by its relatively higher maturity and lower yellow/colorless KREEP glass content. The most prominent petrographic/stratigraphic indicators are the pyroxene-rich immature mare unit D and the abundance of KREEP glass in unit B. This KREEP glass is distinctive petrographically and compositionally, and is probably exotic to the Apollo 17 site. It is suggested here that the KREEP glass in unit B is derived from Tycho, which implies widespread distribution of KREEP on the lunar nearside.

Vaniman, D. T.↗
NASA NTRS1980

Na + Xe collisions in the presence of two nonresonant lasers

Na+Xe collisions in the presence of two distinct laser fields (rhodamine 110 and Nd:glass) are investigated with reference to the response to nonresonant radiation of alkali metals collisionally perturbed by a buffer gas. It is found that the excited Na-asterisk (4s)+Xe state is produced with a measurable cross section due to two-photon absorption with field intensities as low as 10 MW/sq cm.

De Vries, P. L.↗