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At least 577 records · Page 32

Balloon materials degradation (S1006)

The objective of this experiment is to assess the effects of long-term exposure of candidate balloon films, tapes, and lines to the hostile environment above the Earth's atmosphere. Degradation of mechanical and radiometric properties will be observed by a series of tests on exposed materials. The experiment is passive and will test candidate balloon films, tapes, and lines. The experiment will occupy one-third of a 3-in.-deep peripheral tray. Two additional identical sets of material will be prepared. The first set will be tested immediately and the second will be held in a controlled environment until the recovery of the samples placed on orbit. Tests will then be performed on this second set to determine any effects of aging. The specimens that are recovered from the Long Duration Exposure Facility will also be tested and the effects of long-duration exposure noted. In addition to these specimens, another set of specimens will be exposed at an accelerated exposure facility and the results will be compared with those of specimens exposed in situ.

Allen, D. H.↗

Environmental fatigue of an Al-Li-Cu alloy. Part 1: Intrinsic crack propagation kinetics in hydrogenous environments

Deleterious environmental effects on steady-state, intrinsic fatigue crack propagation (FCP) rates (da/dN) in peak aged Al-Li-Cu alloy 2090 are established by electrical potential monitoring of short cracks with programmed constant delta K and K(sub max) loading. The da/dN are equally unaffected by vacuum, purified helium, and oxygen but are accelerated in order of decreasing effectiveness by aqueous 1 percent NaCl with anodic polarization, pure water vapor, moist air, and NaCl with cathodic polarization. While da/dN depends on delta K(sup 4.0) for the inert gases, water vapor and chloride induced multiple power-laws, and a transition growth rate 'plateau'. Environmental effects are strongest at low delta K. Crack tip damage is ascribed to hydrogen embrittlement because of the following: (1) accelerated da/dN due to part-per-million levels of H2O without condensation; (2) impeded molecular flow model predictions of the measured water vapor pressure dependence of da/dN as affected by mean crack opening; (3) the lack of an effect of film-forming O2; (4) the likelihood for crack tip hydrogen production in NaCl, and (5) the environmental and delta K-process zone volume dependencies of the microscopic cracking modes. For NaCl, growth rates decrease with decreasing loading frequency, with the addition of passivating Li2CO3, and upon cathodic polarization. These variables increase crack surface film stability to reduce hydrogen entry efficiency. The hydrogen environmental FCP resistance of 2090 is similar to other 2000 series alloys and is better than 7075.

Piascik, Robert S.↗

Environmental fatigue of an Al-Li-Cu alloy. I - Intrinsic crack propagation kinetics in hydrogenous environments

Deleterious environmental effects on steady-state, intrinsic fatigue crack propagation (FCP) rates (da/dN) in peak aged Al-Li-Cu alloy 2090 are established by electrical potential monitoring of short cracks with programmed constant delta K and K(sub max) loading. The da/dN are equally unaffected by vacuum, purified helium, and oxygen but are accelerated in order of decreasing effectiveness of aqueous 1 percent NaCl with anodic polarization, pure water vapor, moist air, and NaCl with cathodic polarization. While da/dN depends on delta K(sup 4.0) for the inert gases, water vapor and chloride induced multiple power-laws, and a transition growth rate 'plateau'. Environmental effects are strongest at low delta K. Crack tip damage is ascribed to hydrogen embrittlement because of the following: (1) accelerated da/dN due to part-per-million levels of H2O without condensation; (2) impeded molecular flow model predictions of the measured water vapor pressure dependence of da/dN as affected by mean crack opening; (3) the lack of an effect of film-forming O2; (4) the likelihood for crack tip hydrogen production in NaCl; and (5) the environmental and delta K-process zone volume dependencies of the microscopic cracking modes. For NaCl, growth rates decrease with decreasing loading frequency, with the addition of passivating Li2CO3, and upon cathodic polarization. These variables increase crack surface film stability to reduce hydrogen entry efficiency. The hydrogen environmental FCP resistance of 2090 is similar to other 2000 series alloys and is better than 7075.

Piascik, Robert S.↗

Wear and Tear - Mechanical

The focus of this chapter is on the long term wear and tear, or aging, of the mechanical subsystem of a spacecraft. The mechanical subsystem is herein considered to be the primary support structure (as in a skeleton or exoskeleton) upon which all other spacecraft systems rest, and the associated mechanisms. Mechanisms are devices which have some component that moves at least once, in response to some type of passive or active control system. For the structure, aging may proceed as a gradual degradation of mechanical properties and/or function, possibly leading to complete structural failure over an extended period of time. However, over the 50 years of the Space Age such failures appear to be unusual. In contrast, failures for mechanisms are much more frequent and may have a very serious effect on mission performance. Just as on Earth, all moving devices are subject to normal (and possibly accelerated) degradation from mechanical wear due to loss or breakdown of lubricant, misalignment, temperature cycling effects, improper design/selection of materials, fatigue, and a variety of other effects. In space, such environmental factors as severe temperature swings (possibly 100's of degrees C while going in and out of direct solar exposure), hard vacuum, micrometeoroids, wear from operation in a dusty or contaminated environment, and materials degradation from radiation can be much worse. In addition, there are some ground handling issues such as humidity, long term storage, and ground transport which may be of concern. This chapter addresses the elements of the mechanical subsystem subject to wear, and identifies possible causes. The potential impact of such degradation is addressed, albeit with the recognition that the impact of such wear often depends on when it occurs and on what specific components. Most structural elements of the mechanical system typically are conservatively designed (often to a safety factor of greater than approximately 1.25 on yield for unmanned spacecraft) but do not have backup structure due to the added mass this would impose, and also due to the fact that structural elements can be accurately modeled mathematically and in test. Critical mechanisms or devices may have backups, or alternate work-arounds, since characterization of these systems in a 1g environment is less accurate than structure, and repair in-space is often impossible.

Swanson, Theodore↗

Gain stability of Hamamatsu R5912-MOD photomultipliers at low temperature

The Photon Detection System (PDS) is a crucial component of the ICARUS detector in the Short Baseline Neutrino (SBN) Program at Fermi National Accelerator Laboratory (FNAL). It consists of 360 PhotoMultiplier Tubes (PMTs) 8” Hamamatsu R5912-MOD and, since June 2020, it has been operating at the liquid Argon cryogenic temperature. During these years, the PMTs have shown gain losses as an aging effect. Using a climatic chamber at the INFN Sezione di Catania, we confirmed a stable gain for a single PMT 8” Hamamatsu R5912-MOD when operated at room temperature, and a persistent gain loss at temperatures around -70 °C, although this temperature is rather higher than that of the liquid Argon.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Impact of environmental variables on the degradation of photovoltaic components and perspectives for the reliability assessment methodology

Backsheet cracking has been a major issue observed in the field; however, standardized qualification tests, such as IEC61215, are inadequate to reliably identify such failures of PV modules due to the lack of the critical weathering factors applied sequentially or in combination, such as those found in the service environments. To address this problem, in this work we investigated the effects of various environmental variables on the degradation and failure behaviors of the polyamide-based backsheet in PV modules retrieved from five different locations, encompassing a variety of climates, including humid subtropical, hot-summer Mediterranean, tropical savanna climate and hot arid. The correlations between the degradation indicators and the weathering variables were further demonstrated by principle components analysis (PCA). We found strong relationships between: carbonyl formation and reflected solar radiation; hydroxyl formation and module temperature; yellowness and NO2 concentration, while no simple correlation could be found between a specific weathering factor and cracking. By introducing additional stress factors to the aged polyamide-based backsheet films with the novel 'fragmentation test', we successfully reproduced the field cracking behaviour. This study has demonstrated that different degradation modes of PV components respond differently to the environmental stresses encountered in service. Thereby, any accelerated laboratory test based on a single set condition or lacking key environmental variables would be inadequate to assess the long-term performance of PV modules and components. A new reliability-based methodology is proposed to quantitatively link laboratory testing with field results for the service life prediction of PV materials.

14 SOLAR ENERGY↗

Influence of Transition Metal Ion Contaminants on the Performance of Amine-Based Solid Sorbents in Direct Air Capture

Amine-functionalized solid sorbents are a class of sorbent materials proposed for direct air capture (DAC) of CO 2 , yet their long-term performance is susceptible to degradation under realistic operating conditions. Many amines are not thermodynamically stable in air, and amine sorbents oxidize while in use during DAC temperature swing adsorption processes. In this study, we investigate the role of transition metal ion contaminants, specifically Cu 2+ , Fe 2+ , and Ni 2+ , on the oxidative degradation of poly(ethylenimine) (PEI)-impregnated SBA-15 sorbents. By introducing metal ions via different modes mimicking both synthesis-related impurities and impurities derived from environmental exposure, we systematically evaluate sorbent stability after exposure to dry air at an elevated temperature. Thermogravimetric CO 2 uptake measurements reveal that even trace levels of Cu and Fe (as low as ∼4 ppm) can lead to measurable sorbent deactivation after oxidative aging, despite negligible loss in the performance of the control samples. In situ infrared, UV–vis, and X-ray photoelectron spectroscopies indicate that these metals catalyze radical-driven oxidation pathways, altering the chemical structure of the sorbent and accelerating degradation. Our findings underscore the need to account for trace metal contamination during DAC sorbent synthesis and deployment and highlight the importance of environmental contamination pathways.

CO2 capture↗

Model of the formation of the low-latitude boundary layer for strongly northward interplanetary magnetic field

A model for the formation of the low-boundary layer in which a magnetosheath flux tube reconnects in the north and south beyond the cusp when the IMF is strongly northward is presented. For northward IMF the geomagnetic field captures solar wind flux tubes through intermittent reconnection at the cusp region. These newly captured flux tubes shorten and sink into the magnetosphere while the flux tubes reorient themselves as they become assimilated into the magnetosphere. There is no significant acceleration for the particles within the flux tubes. In the magnetosphere the interchange instability disperses the flux tube azimuthally along the magnetopause to form a boundary layer. Subsequent reconnection forms sublayers of the boundary layer and different sublayers represent different ages after reconnection. The interchange instability is stable radially, which keeps sharp boundaries between sublayers and between the boundary layer and magnetosphere.

Song, P.↗

Synthetic antibacterial minerals: harnessing a natural geochemical reaction to combat antibiotic resistance

The overuse of antibiotics in clinical and livestock settings is accelerating the selection of multidrug resistant bacterial pathogens. Antibiotic resistant bacteria result in increased mortality and financial strain on the health care and livestock industry. The development of new antibiotics has stalled, and novel strategies are needed as we enter the age of antibiotic resistance. Certain naturally occurring clays have been shown to have antimicrobial properties and kill antibiotic resistant bacteria. Harnessing the activity of compounds within these clays that harbor antibiotic properties offers new therapeutic opportunities for fighting the potentially devastating effects of the post antibiotic era. However, natural samples are highly heterogenous and exhibit variable antibacterial effectiveness, therefore synthesizing minerals of high purity with reproducible antibacterial activity is needed. Here we describe for the first time synthetic smectite clay minerals and Fe-sulfide microspheres that reproduce the geochemical antibacterial properties observed in natural occurring clays. We show that these mineral formulations are effective at killing the ESKAPE pathogens ( Enterococcus sp., Staphylococcus aureus, Klebsiella pneumoniae, Acinetobacter sp., Pseudomonas aeruginosa and Enterobacter sp.) by maintaining Fe 2+ solubility and reactive oxygen species (ROS) production while buffering solution pH, unlike the application of metals alone. Our results represent the first step in utilizing a geochemical process to treat antibiotic resistant topical or gastrointestinal infections in the age of antibiotic resistance.

58 GEOSCIENCES↗

Gain Stability of Hamamatsu R5912-MOD Photo-Multipliers at Low Temperature

The Photon Detection System is a crucial component of the ICARUS detector in the Short Baseline Neutrino (SBN) Program at Fermi National Accelerator Laboratory (FNAL). It consists of 360 Photo Multiplier Tubes (PMTs) 8” Hamamatsu R5912-MOD and, since June 2020, it has been operated at the liquid Argon cryogenic temperature. During these years, the PMTs have shown gain losses as an aging effect. Using a climatic chamber at the INFN Sezione di Catania, we confirmed a stable gain for a single PMT 8” Hamamatsu 5912-MOD when operated at room temperature, and a persistent gain loss at temperatures around -70°C, although far from the liquid Argon one. No gain recovery was obtained bringing the PMT back to room temperature. We suspect that dynode deterioration due to temperature gradient plays a significant role in this phenomenon. During our test, the PMT was illuminated by a 520 nm laser source and operated in current mode. The laser beam was split into two optical fibers, the first one transmitting light through Neutral Density filters and then diffusing it over the surface of the PMT photocathode. The other optical fiber was used for an independent reference measurement of the injected light via a bolometric photodetector. In this presentation, the main technical characteristics of the measurement system are shown together with preliminary results which need further investigation to elucidate the underlying mechanisms driving the gain loss and to propose new mitigation strategies.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

A high-resolution study of ultra-heavy cosmic-ray nuclei (A0178)

The main objective of the experiment is a detailed study of the charge spectra of ultraheavy cosmic-ray nuclei from zinc (Z = 30) to uranium (Z = 92) and beyond using solid-state track detectors. Special emphasis will be placed on the relative abundances in the region Z or - 65, which is thought to be dominated by r-process nucleosynthesis. Subsidiary objectives include the study of the cosmic-ray transiron spectrum a search for the postulated long-lived superheavy (SH) nuclei (Z or = 110), such as (110) SH294, in the contemporary cosmic radiation. The motivation behind the search for super-heavy nuclei is based on predicted half-lives that are short compared to the age of the Earth but long compared to the age of cosmic rays. The detection of such nuclei would have far-reaching consequences for nuclear structure theory. The sample of ultraheavy nuclei obtained in this experiment will provide unique opportunities for many tests concerning element nucleosynthesis, cosmic-ray acceleration, and cosmic-ray propagation.

Osullivan, D.↗

In-Situ Measurements of Cosmogenic Radionuclides on the Surface of Mars

Cosmogenic nuclides are produced by cosmic-ray nuclear interactions with target nuclei in rocks, soils, ice, and the atmosphere. Cosmogenic nuclides have been widely used for investigation of solar system matter for several decades. Stable nuclides, such as He-1, Ne-21, and Ar-38, are built up over time as the surface is exposed to cosmic rays. The concentrations of cosmogenic radionuclides, such as Be-10 (halflife = 1.5 Myr), Al-26 (0.705 Myr), and C-14 (5,730 yr) also build up with exposure time but reach saturation values after several half-lives. Especially after development of accelerator mass spectrometry (AMS), cosmogenic nuclides in terrestrial samples are routinely used for geomorphic studies such as glaciation, surface erosion, and tectonics, and studies of atmospheric and ocean circulation. Cosmogenic nuclides on Mars will be able to answer questions of exposure ages, erosion rates, tectonic events, and deposition rates of sediments and/or volatiles. The concentrations of cosmogenic stable nuclides gives the integrated exposure time of the rock/mineral, and the activities of radionuclides give recent records for times back as long as a few half-lives.

Nishiizumi, K.↗

Surficial Studies of Mars Using Cosmogenic Nuclides

Cosmogenic nuclides (CNs) are produced by cosmic-ray nuclear interactions with target nuclei in rocks, soils, ice, and the atmosphere. Cosmogenic nuclides have been widely used for investigation of solar system matter for several decades. Stable nuclides, such as He-3, Ne-21, and Ar-38, are built up over time as the surface is exposed to cosmic rays. The concentrations of cosmogenic radionuclides, such as Be-10, Al-26, and C-14 also build up with exposure time but reach saturation values after several half-lives. Especially since the development of accelerator mass spectrometry (AMS), CNs in terrestrial samples have been routinely used for geomorphic studies such as glaciation, surface erosion, and tectonics, and studies of atmospheric and ocean circulation. Cosmogenic nuclides on Mars will be able to answer questions of exposure ages, erosion rates, tectonic events, and deposition rates of sediments and/or volatiles. The concentrations of cosmogenic stable nuclides give the integrated exposure time of the rock/mineral, and the activities of radionuclides give recent records for times back as long as a few half-lives.

Nishiizumi, K.↗

Failure Analysis of a New Polyamide-Based Fluoropolymer-Free Backsheet After Combined-Accelerated Stress Testing

The viability of novel coextruded, fluoropolymer-free backsheets for photovoltaic (PV) modules has been questioned as a result of a large number of early-life backsheet failures in PV installations containing one of the earliest co-extruded polyamide (PA)-based backsheet to reach the market, “AAA.” New PV reliability testing protocols have been recently developed and applied to backsheets to reproduce failures observed in the field and evaluate the durability of novel backsheet materials and designs prior to commercialization. A new co-extruded PA-based backsheet was tested using combined-accelerated stress testing (C-AST) and demonstrated a greater lifetime than AAA, and some other fluoropolymer-based backsheets such as polyvinylidene fluoride. The improved PA-based backsheet also eventually failed by through-thickness cracking. Using surface and bulk material characterization techniques, we performed a comprehensive study of material properties before and after the stress testing. Aging of the backsheet resulted in an increase of surface roughness by erosion of the outer PA layer. However the failure is more likely related to an increase in crystallinity of the polyolefin core layer reducing the backsheet tearing energy. The analysis can ultimately inform on the specific weaknesses of the materials so that the manufacturer can improve the backsheet design to extend its lifetime.

14 SOLAR ENERGY↗

Separation of Lipoproteins for Quantitative Analysis of 14 C-Labeled Lipid-Soluble Compounds by Accelerator Mass Spectrometry

To date, 14 C tracer studies using accelerator mass spectrometry (AMS) have not yet resolved lipid-soluble analytes into individual lipoprotein density subclasses. The objective of this work was to develop a reliable method for lipoprotein separation and quantitative recovery for biokinetic modeling purposes. The novel method developed provides the means for use of small volumes (10–200 µL) of frozen plasma as a starting material for continuous isopycnic lipoprotein separation within a carbon- and pH-stable analyte matrix, which, following post-separation fraction clean up, created samples suitable for highly accurate 14 C/ 12 C isotope ratio determinations by AMS. Manual aspiration achieved 99.2 ± 0.41% recovery of [5- 14 CH 3 ]-(2R, 4'R, 8'R)-α-tocopherol contained within 25 µL plasma recovered in triacylglycerol rich lipoproteins (TRL = Chylomicrons + VLDL), LDL, HDL, and infranatant (INF) from each of 10 different sampling times for one male and one female subject, n = 20 total samples. Small sample volumes of previously frozen plasma and high analyte recoveries make this an attractive method for AMS studies using newer, smaller footprint AMS equipment to develop genuine tracer analyses of lipophilic nutrients or compounds in all human age ranges.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Stellar s-process neutron capture cross sections on 78,80,84,86 Kr determined via activation, atom trap trace analysis and decay counting

We present a detailed account of neutron capture experiments of astrophysical relevance on 78,80,84,86 Kr (n, γ) reactions at the border between weak and main s process. The experiments were performed with quasi-Maxwellian neutrons from the Liquid-Lithium Target (LiLiT) and the mA-proton beam at 1.93 MeV (2-3 kW) of the Soreq Applied Research Accelerator Facility (SARAF). The setup yields high-intensity approximate to 40 keV quasi-Maxwellian neutrons (3-5 x10 10 n/s) closely reproducing the conditions of s-process stellar nucleosynthesis. A sample of 100 mg of atmospheric, pre-nuclear-age Kr gas contained in a Ti spherical shell was activated in the LiLiT neutron field. The abundances of long-lived Kr isotopes ( 81,85g Kr) were measured by atom counting via atom trap trace analysis (ATTA) at Argonne National Laboratory and low-level counting (LLC) at University of Bern. This work is the first measurement of a nuclear cross section using atom counting via ATTA. The activities of short-lived Kr isotopes ( 79,85m,87 Kr) were measured by gamma-decay counting with a high-purity germanium detector. Maxwellian-averaged cross sections for s-process thermal energies are extracted. By comparison to reference values, our nucleosynthesis network calculations show that the experimental cross sections have a strong impact on calculated abundances of krypton and neighboring nuclides, in some cases improving agreement between theory and observations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Effect of hypovolemia, infusion, and oral rehydration on plasma electrolytes, ADH, renin activity, and +G/z/ tolerance

Effects on plasma volume, electrolyte shifts, and +G(z) tolerance induced by: (1) blood withdrawal; (2) blood infusion; and (3) oral fluid intake, were determined at 0.5 G/min in centrifugation tests of six ambulatory male patients, aged 21 to 27 yrs. Hypovolemia induced by withdrawal of 400 ml blood, blood infusion followed by repeated centrifugation, effects of consuming an isotonic drink (0.9% NaCl) to achieve oral rehydration, and donning of red adaptation goggles were studied for effects on acceleration tolerance, pre-acceleration and post-acceleration plasma renin activity (PRA) and plasma vasopressin levels. No significant changes in post-acceleration PRA compared to pre-acceleration PRA were found, and administration of oral rehydration is found as effective as blood replacement in counteracting hypovolemic effects.

Greenleaf, J. E.↗

Functional and transcriptional characterization of complex neuronal co-cultures

Brain-on-a-chip systems are designed to simulate brain activity using traditional in vitro cell culture on an engineered platform. It is a noninvasive tool to screen new drugs, evaluate toxicants, and elucidate disease mechanisms. However, successful recapitulation of brain function on these systems is dependent on the complexity of the cell culture. In this study, we increased cellular complexity of traditional (simple) neuronal cultures by co-culturing with astrocytes and oligodendrocyte precursor cells (complex culture). We evaluated and compared neuronal activity (e.g., network formation and maturation), cellular composition in long-term culture, and the transcriptome of the two cultures. Compared to simple cultures, neurons from complex co-cultures exhibited earlier synapse and network development and maturation, which was supported by localized synaptophysin expression, up-regulation of genes involved in mature neuronal processes, and synchronized neural network activity. Also, mature oligodendrocytes and reactive astrocytes were only detected in complex cultures upon transcriptomic analysis of age-matched cultures. Functionally, the GABA antagonist bicuculline had a greater influence on bursting activity in complex versus simple cultures. Collectively, the cellular complexity of brain-on-a-chip systems intrinsically develops cell type-specific phenotypes relevant to the brain while accelerating the maturation of neuronal networks, important features underdeveloped in traditional cultures.

59 BASIC BIOLOGICAL SCIENCES↗