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At least 577 records · Page 32

Carbonaceous chondrites. II - Carbonaceous chondrite phyllosilicates and light element geochemistry as indicators of parent body processes and surface conditions

Petrographic analyses of CM matrices characterized four phyllosilicates in Murray and Murchison meteorites and Fe- and Mg-serpentines in Nogoya. All phyllosilicates and bulk matrices show enrichment of K relative to Na when compared with bulk meteorites; the loss of Na and some Cl, and the addition of H2O, CO2, and water-soluble organics during alteration indicates a partially open system. Synthesis of soluble organic materials may have occurred in CM matrices before aqueous alteration of the precursive phases. Nogoya was 95% altered and has a bulk C content of 5.2%, higher than any meteorite; also, it has the lowest measured C-13/C-12 ratio of any carbonaceous chondrite except for Karoonda.

Bunch, T. E.↗

Investigation of the asymptotic state of rotating turbulence using large-eddy simulation

Study of turbulent flows in rotating reference frames has long been an area of considerable scientific and engineering interest. Because of its importance, the subject of turbulence in rotating reference frames has motivated over the years a large number of theoretical, experimental, and computational studies. The bulk of these previous works has served to demonstrate that the effect of system rotation on turbulence is subtle and remains exceedingly difficult to predict. A rotating flow of particular interest in many studies, including the present work, is examination of the effect of solid-body rotation on an initially isotropic turbulent flow. One of the principal reasons for the interest in this flow is that it represents the most basic turbulent flow whose structure is altered by system rotation but without the complicating effects introduced by mean strains or flow inhomogeneities. The assumption of statistical homogeneity considerably simplifies analysis and computation. The principal objective of the present study has been to examine the asymptotic state of solid-body rotation applied to an initially isotropic, high Reynolds number turbulent flow. Of particular interest has been to determine the degree of two-dimensionalization and the existence of asymptotic self-similar states in homogeneous rotating turbulence.

Squires, Kyle D.↗

The morphology of faint galaxies in Medium Deep Survey images using WFPC2

First results from Hubble Space Telescope (HST) Medium Deep Survey images taken with Wide Field/Planetary Camera-2 (WFPC2) demonstrate that galaxy classifications can be reliably performed to magnitudes I814 approximately less than 22.0 in the F815W band. Published spectroscopic surveys to this depth indicate a mean redshift of bar-z approximately 0.5. We have classified over 200 galaxies in nine WFPC2 fields according to a basic morphological scheme. The majority of these faint galaxies appear to be similar to regular Hubble-sequence examples observed at low redshift. To the precision of our classification scheme, the relative proportion of spheroidal and disk systems of normal appearance is as expected from nearby samples, indicating that the bulk of the local galaxy population was in place at half the Hubble time. However, the most intriguing result is the relatively high proportion (approximately 40%) of objects which are in some way anomalous, and which may be of relevance in understanding the origin of the familiar excess population of faint galaxies established by others. These diverse objects include apparently interacting pairs whose multiple structure is only revealed with HST's angular resolution, galaxies with superluminous star-forming regions, diffuse low surface brightness galaxies of various forms, and compact galaxies. These anomalous galaxies contribute a substantial fraction of the excess counts at our limiting magnitude, and may provide insights into the 'faint blue galaxy' problem.

Griffiths, R. E.↗

Marangoni Effects in the Boiling of Binary Fluid Mixtures

Results of very recent experimental studies indicate that during nucleate boiling in some binary mixture, Marangoni effects augment the gravity driven flow of liquid towards the heated surface. With gravity present, it is impossible to separate the two effects. The reduced gravity environment gives an unique opportunity to explore th role of Marangoni effects on the boiling mechanisms free of gravitational body forces that obscure the role of such effects. However, recent experimental results suggest that under reduced gravity conditions, Marangoni effects is the dominant mechanism of vapor-liquid exchange at the surface for some binary mixture. To further explore such effects, experiments have been conducted with water/2-propanol mixtures at three different concentrations under normal gravity with different orientations of the heater surface and under reduce gravity aboard the DC-9 aircraft at NASA Lewis Research Center. The system pressure was sub atmospheric (approx. 8 kP at 1g(n)) and the bulk liquid temperature varied from low subcooling to near saturation. The molar concentrations of 2-propanol tested were 0.015, 0.025, and 0.1. Boiling curves were obtained both for high gravity (approx. 2g(n)) and reduce gravity (approx. 0.01g(n)). For each concentration of 2-propanol, the critical heat flux has been determined in the flight experiments only for reduced gravity conditions. Comparison of boiling curves and CHF obtained under l-g(n) an reduced gravity indicates that boiling mechanism in this mixtures is nearly independent of gravity. The results also indicate that the Marangoni mechanism is strong enough in these mixtures to sustain the boiling under reduced gravity conditions.

Ahmed, Sayeed↗

Software Package Completed for Alloy Design at the Atomic Level

As a result of a multidisciplinary effort involving solid-state physics, quantum mechanics, and materials and surface science, the first version of a software package dedicated to the atomistic analysis of multicomponent systems was recently completed. Based on the BFS (Bozzolo, Ferrante, and Smith) method for the calculation of alloy and surface energetics, this package includes modules devoted to the analysis of many essential features that characterize any given alloy or surface system, including (1) surface structure analysis, (2) surface segregation, (3) surface alloying, (4) bulk crystalline material properties and atomic defect structures, and (5) thermal processes that allow us to perform phase diagram calculations. All the modules of this Alloy Design Workbench 1.0 (ADW 1.0) are designed to run in PC and workstation environments, and their operation and performance are substantially linked to the needs of the user and the specific application.

Bozzolo, Guillermo H.↗

Micro-Scale Distributions of Major and Trace Elements in Chondrites

The Hayabusa spacecraft has successfully returned to Earth after two touchdowns on the surface of Asteroid 25143 Itokawa. This asteroid is classified as an S-type and inferred to consist of materials similar to ordinary chondrites or primitive achondrites [1]. More than 1500 particles have been identified consisting of olivine, pyroxene, plagioclase, Fe sulfide and Fe metal, with compositions consistent with being of LL origin. While the chondritic components are familiar to us, the level of detail to which the Itokawa samples will be exposed to will be unprecedented given that the samples are reasonably large and accessible to a wide variety of techniques. In many ways, we expect that our knowledge base of the comparator chondrites will be found to be wanting. Chondrites are the building blocks of the solar system. However, these rocks are essentially breccias and they are quite variable in bulk element compositions as well as compositions of the individual components. We have initiated a program of analysis for chondrites focusing on major and trace element distributions between the mineral components and the matrix. The issues to be addressed include the homogeneity of matrix and chondrule components and the representivity of any given sample to the bulk meteorite. This may be particularly important given the limited numbers of Itokawa grains that may be available for a specific analysis. As an initial study, we have taken thin sections of carbonaceous chondrites to study the representivity of the matrix compositions. Spot locations were constrained to limited regions of the sections so as to assess the variability of a local scale. Further work will be required to assess variability over a centimeter scale.

Ireland, T. R.↗

Petrology and Cosmochemistry of a Suite of R Chondrites

Chondrites are among the most primitive surviving materials from the early solar system. They are divided into groups based on chemical types defined by mineralogy, bulk composition, and oxygen isotope compositions. Chondrites range in petrographic grade from type 1 to type 7. Type 3 chondrites are the most primitive and are little changed from the nebular solids accreted to form asteroids. They are composed of chondrules, fine-grained matrix, metal and sulfide, plus or minus Ca-Al-rich inclusions. With increasing aqueous alteration at low temperatures, members of some chondrite classes transformed from type 3 towards type 1. With increasing thermal metamorphism and low fluid content, members of other classes changed from type 3 towards type 7. Rumuruti (R) chondrites are a rare group (0.1% of falls) similar to ordinary chondrites in some properties but different in others. They are characterized by low chondrule/matrix modal abundance ratios, high oxidation state, small mean chondrule size, abundant sulfides and low metal contents. R chondrites vary in petrologic type from 3 to 6. They are important objects to study because some of them have undergone metamorphism at high temperatures in the presence of aqueous fluids. In contrast, CM and CI chondrites were heated to low temperatures in the presence of aqueous fluids leading to alteration; they contain low-T hydrous phases (phyllosilicates) and little or no remaining metal. Ordinary chondrites were heated to high temperatures in a low-fluid environment resulting in anhydrous metamorphic rocks. R6 chondrites are highly metamorphosed and some contain the high-T hydrous phases mica and amphibole. R chondrites are thus unique and give us an opportunity to examine whether there are compositional effects caused by high-T, highfluid metamorphism of nebular materials.

Torrano, Z. A.↗

Aerosol Complexity and Implications for Predictability and Short-Term Forecasting

There are clear NWP and climate impacts from including aerosol radiative and cloud interactions. Changes in dynamics and cloud fields affect aerosol lifecycle, plume height, long-range transport, overall forcing of the climate system, etc. Inclusion of aerosols in NWP systems has benefit to surface field biases (e.g., T2m, U10m). Including aerosol affects has impact on analysis increments and can have statistically significant impacts on, e.g., tropical cyclogenesis. Above points are made especially with respect to aerosol radiative interactions, but aerosol-cloud interaction is a bigger signal on the global system. Many of these impacts are realized even in models with relatively simple (bulk) aerosol schemes (approx.10 -20 tracers). Simple schemes though imply simple representation of aerosol absorption and importantly for aerosol-cloud interaction particle-size distribution. Even so, more complex schemes exhibit a lot of diversity between different models, with issues such as size selection both for emitted particles and for modes. Prospects for complex sectional schemes to tune modal (and even bulk) schemes toward better selection of size representation. I think this is a ripe topic for more research -Systematic documentation of benefits of no vs. climatological vs. interactive (direct and then direct+indirect) aerosols. Document aerosol impact on analysis increments, inclusion in NWP data assimilation operator -Further refinement of baseline assumptions in model design (e.g., absorption, particle size distribution). Did not get into model resolution and interplay of other physical processes with aerosols (e.g., moist physics, obviously important), chemistry

Predictability↗

Bulk and integrated acousto-optic spectrometers for molecular astronomy with heterodyne spectrometers

A survey of acousto-optic spectrometers for molecular astronomy is presented, noting a technique of combining the acoustic bending of a collimated coherent light beam with a Bragg cell followed by an array of sensitive photodetectors. This acousto-optic spectrometer has a large bandwidth, a large number of channels, high resolution, and is energy efficient. Receiver development has concentrated on high-frequency heterodyne systems for the study of the chemical composition of the interstellar medium. RF spectrometers employing acousto-optic diffraction cells are described. Acousto-optic techniques have been suggested for applications to electronic warfare, electronic countermeasures and electronic support systems. Plans to use integrated optics for the further miniaturization of acousto-optic spectrometers are described. Bulk acousto-optic spectrometers with 300 MHz and 1 GHz bandwidths are being developed for use in the back-end of high-frequency heterodyne receivers for astronomical research.

Chin, G.↗

Sensitivity of a Cloud-Resolving Model to Bulk and Explicit Bin Microphysical Schemes: Cloud Microphysics and Storm Dynamics Interactions - Part 2

Part I of this paper compares two simulations, one using a bulk and the other a detailed bin microphysical scheme, of a long-lasting, continental mesoscale convective system with leading convection and trailing stratiform region. Diagnostic studies and sensitivity tests are carried out in Part II to explain the simulated contrasts in the spatial and temporal variations by the two microphysical schemes and to understand the interactions between cloud microphysics and storm dynamics. It is found that the fixed raindrop size distribution in the bulk scheme artificially enhances rain evaporation rate and produces a stronger near surface cool pool compared with the bin simulation. In the bulk simulation, cool pool circulation dominates the near-surface environmental wind shear in contrast to the near-balance between cool pool and wind shear in the bin simulation. This is the main reason for the contrasting quasi-steady states simulated in Part I. Sensitivity tests also show that large amounts of fast-falling hail produced in the original bulk scheme not only result in a narrow trailing stratiform region but also act to further exacerbate the strong cool pool simulated in the bulk parameterization. An empirical formula for a correction factor, r(q(sub r)) = 0.11q(sub r)(exp -1.27) + 0.98, is developed to correct the overestimation of rain evaporation in the bulk model, where r is the ratio of the rain evaporation rate between the bulk and bin simulations and q(sub r)(g per kilogram) is the rain mixing ratio. This formula offers a practical fix for the simple bulk scheme in rain evaporation parameterization.

Li, Xiaowen↗

Research on computer systems benchmarking

This grant addresses the topic of research on computer systems benchmarking and is more generally concerned with performance issues in computer systems. This report reviews work in those areas during the period of NASA support under this grant. The bulk of the work performed concerned benchmarking and analysis of CPUs, compilers, caches, and benchmark programs. The first part of this work concerned the issue of benchmark performance prediction. A new approach to benchmarking and machine characterization was reported, using a machine characterizer that measures the performance of a given system in terms of a Fortran abstract machine. Another report focused on analyzing compiler performance. The performance impact of optimization in the context of our methodology for CPU performance characterization was based on the abstract machine model. Benchmark programs are analyzed in another paper. A machine-independent model of program execution was developed to characterize both machine performance and program execution. By merging these machine and program characterizations, execution time can be estimated for arbitrary machine/program combinations. The work was continued into the domain of parallel and vector machines, including the issue of caches in vector processors and multiprocessors. All of the afore-mentioned accomplishments are more specifically summarized in this report, as well as those smaller in magnitude supported by this grant.

Smith, Alan Jay↗

Periodically Discharging, Gas-Coalescing Filter

A proposed device would remove bubbles of gas from a stream of liquid (typically water), accumulate the gas, and periodically release the gas, in bulk, back into the stream. The device is intended for use in a flow system (1) in which there is a requirement to supply bubble-free water to a downstream subsystem and (2) that includes a sensor and valves, just upstream of the subsystem, for sensing bubbles and diverting the flow from the subsystem until the water stream is again free of bubbles. By coalescing the gas bubbles and then periodically releasing the accumulated gas, the proposed device would not contribute to net removal of gas from the liquid stream; nevertheless, it would afford an advantage by reducing the frequency with which the diverter valves would have to be activated. The device (see figure) would include an upper and a lower porous membrane made of a hydrophilic material. Both membranes would cover openings in a tube leading to an outlet. These membranes would allow water, but not gas bubbles, to pass through to the interior of the tube. Inside the tube, between the two membranes, there would be a flow restrictor that would play a role described below. Below both membranes there would be a relief valve. Water, possibly containing bubbles, would enter from the top and would pass through either the lower membrane or both membranes, depending how much gas had been accumulated thus far. When the volume of accumulated gas was sufficient to push the top surface of the liquid below the lower porous membrane, water could no longer flow through either membrane toward the outlet. This blockage would cause an increase in back pressure that would cause the relief valve to open. The opening of the relief valve would allow both the water and the bulk-accumulated gas to pass through to the outlet. Once the gas had been pushed out, water would once again flow through both membranes at a much lower pressure drop. The flow restrictor would maintain enough pressure drop to keep the relief valve open until gas had been cleared from both hydrophilic membranes.

Carter, Donald Layne↗

Development of an Integrated RVC-LWRD System for RESOLVE

Regolith & Environment Science and Oxygen & Lunar Volatile Extraction (RESOLVE) incorporates 5 modules: (1) EBRC (Excavation and Bulk Regolith Characterization) (2) ERPC (Environment and Regolith Physical Characterization) ROE (Regolith Oxygen Extraction) (3) RVC (Regolith Volatile Characterization) (5) LWRD (Lunar Water Resource Demonstration). The goal of this work is to identify and quantify volatiles, demonstrate ISRU, engage the public interest in 'living off the land' technology

Captain, Janine↗

Integrated Transmission and Distribution Co-Simulation Platform for Demonstration of Bulk Grid Services Using Distributed Energy Resources

In September 2020, the Federal Energy Regulatory Commission (FERC) released Order 2222, which opens wholesale markets to small-capacity distributed energy resources (DERs), recognizing their potential in improving operational efficiency by providing bulk grid services. Therefore, a co-simulation capability that can connect transmission and distribution (T&D) simulations and evaluate the impacts of DER provision of bulk grid services is needed. In this paper, we present a new integrated T&D co-simulation platform that incorporates T&D system simulators, DER aggregator/group strategies, and a co-simulation coordinator. Industry-standard communication protocols are employed to mimic real-world conditions. Secondary frequency regulation is selected as the representative bulk grid service, and we simulate the responses of DERs to the frequency regulation signals. The simulation results for a solar-rich distribution feeder in Colorado, USA, demonstrate how the T&D co-simulation setup is used to evaluate the contributions of DERs to minimize the bulk grid frequency deviation.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Micro2Macro: Origins of Climate Change Uncertainty

Where we are: Global Earth system models (ESMs) are essential tools for seasonal-to decadal environmental predictions, which decision-makers across government and industry require. However, uncertainties originating at the microphysical scale, i.e., in processes occurring on scales smaller than typical ESM grid boxes, remain a major challenge. While resolution continues to improve in our predictive models, we will need to parameterize microphysical processes that contribute the bulk of prediction uncertainty for the foreseeable future. Microphysical uncertainties contribute broadly to remaining limitations on Earth system predictability on seasonal and decadal time scales.

54 ENVIRONMENTAL SCIENCES↗

Hydrogen generation through static-feed water electrolysis

A static-feed water electrolysis system (SFWES), developed under NASA sponsorship, is presented for potential applicability to terrestrial hydrogen production. The SFWES concept uses (1) an alkaline electrolyte to minimize power requirements and materials-compatibility problems, (2) a method where the electrolyte is retained in a thin porous matrix eliminating bulk electrolyte, and (3) a static water-feed mechanism to prevent electrode and electrolyte contamination and to promote system simplicity.

Jensen, F. C.↗

Structural effects of composition tuning in A-site disordered perovskite La0.5Li0.5−xMxTiO3 (M = Na, K) nanorods for fast interfacial transport for solid composite electrolyte design

Polymer-ceramic composite electrolytes (CPE) have emerged as promising replacements for currently used liquid organic electrolytes, which pose as safety hazards, in Li-ion batteries. Limits in conductivity enhancement in CPEs is often attributed to a high resistance for Li-ion transport along the interface due to the incompatibility of the polymer and ceramic phases. A clear understanding of the interfacial structure and how this impacts interfacial Li-ion transport is needed in order to efficiently design a CPE with optimal ionic conductivity. In this study, density functional theory (DFT) calculations, in conjunction with scanning transmission electron microscopy (STEM) and electron energy loss spectroscopy (EELS), are used to unveil the bulk and surface structure of La0.5Li0.5−xMxTiO3 (M = Na, K) (LMTO) nanorods, a newly-reported ceramic system with promising applications in CPEs, and the LMTO interactions with the poly(lithium sulfonyl (trifluoromethane sulfonyl)imide methacrylate) (p(MTFSILi)) polymerized ionic liquid. Substitution of lithium for sodium and potassium onto the A-site perovskite lattice is shown to increase the stability of the preferred pseudocubic perovskite phase because of their increased cation size which allows them to reduce the TiO6 octahedral rotations in the bulk and at the surface. STEM and EELS results show that LMTO nanorods with differing compositions have Ti-enriched (110)-oriented surfaces. Increased sodium and potassium compositions in LMTO is also shown using the DFT calculations to weaken the binding of the lithium atom to the MTFSI unit when LiMTFSI is adsorbed to the LMTO surface. This weakening of lithium binding to the polymer at the LMTO interface indicates that the lithium mobility is increased, correlating to an increase in interfacial Li-ion transport. Overall, this work provides insights into how to tune the interfacial interactions between the polymer (p(MTFSI)) and ceramic (LMTO) for optimal CPE design.

Shepard, Lauren B [Pennsylvania State University, ↗