Search NASA⌕ Search

SEARCH · Search NASA

Results for “CO2 Flux”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

The ionosphere and airglow of Venus - Prospects for Pioneer Venus

The paper presents model calculations for the Cytherean nighttime and daytime ionosphere. It is shown how some of the proposed mechanisms can be tested with the aid of the Pioneer Venus observations scheduled for December 1978. Theoretical calculations of the energetics of the Cytherean ionosphere are performed, and it is concluded that the Project Venus measurements will find elevated ion and electron temperatures, resulting primarily from energy fluxes associated in some manner with the solar wind. According to this model, the energy flux will act directly on the ion gas. Ultraviolet dayglow intensities were calculated, and it is anticipated that hundreds of kR's of CO2-related emission features such as the CO Cameron bands will be observed. Nightside ionosphere calculations were made assuming the precipitation of energetic electrons as an ionization source, and the intensities of some of the resulting emission features are calculated.

Cravens, T. E.↗
NASA NTRS1982

Modulation of dayside on and neutral distributions at Venus Evidence of direct and indirect solar energy inputs

The details of solar variability and its coupled effects on the Venusian dayside are examined for evidence of short-term perturbations and associated energy inputs. Ion and neutral measurements obtained from the Orbiter Ion Mass Spectrometer and Orbital Neutral mass Spectrometer are used to show that the dayside concentrations of CO2(+) and the neutral gas temperature are smoothly modulated with a 28-day cycle reasonably matching that of the solar F(10.7) and EUV fluxes. Earlier measurements show less pronounced and more irregular modulations and more conspicuous short-term day-to-day fluctuations in the ions and neutrals, as well as relatively large enhancements in the solar wind, which appear consistent with differences in solar coronal behavior during the two periods. It is suggested that the solar wind variations cause fluctuations in joule heating, producing the observed short-term ion and neutral variations.

Taylor, H. A., Jr.↗
NASA NTRS1988

Heat transfer by fluids in granulite metamorphism

The thermal role of fluids in granulite metamorphism was presented. It was shown that for granulites to be formed in the middle crust, heat must be advected by either magma or by volatile fluids, such as water or CO2. Models of channelized fluid flow indicate that there is little thermal difference between channelized and pervasive fluid flow, for the same total fluid flux, unless the channel spacing is of the same order or greater than the thickness of the layer through which the fluids flow. The volumes of volatile fluids required are very large and are only likely to be found associated with dehydration of a subducting slab, if volatile fluids are the sole heat source for granulite metamorphism.

Morgan, Paul↗
NASA NTRS1998

Tropospheric- Stratospheric Measurement Studies Summary

The two high altitude aircraft, ER-2 NASA #706 and 709 and the DC-8 NASA #717 are in active use in several programs of upper atmospheric research to study polar ozone changes, stratospheric-tropospheric exchange processes and atmospheric effects of aviation aircraft. The ER-2 has participated in seven major missions which mainly concentrated on vortex dynamics and the large losses of Ozone in the Polar regions (Ozone hole) observed in the spring. One mission verified the complex dynamical chemical and physical processes that occur during sunrise and sunset. Stratospheric Tracers of Atmospheric Transport (STRAT) obtained background measurements using the full ER-2 suite of instruments. Photochemistry of Ozone Loss in the Arctic Region in Summer (POLARIS) in 1997 assisted in understanding the mid-latitude and Arctic Ozone losses during the Northern Summer. The DC-8 with the Meteorological Measurement System (MMS) has participated in the Subsonic Aircraft: Cloud and Contrail Effects Special Study (SUCCESS), in 1996 and the Subsonic assessment Ozone and Nitrogen oxide experiment (SONEX) in 1997 missions. The MMS with its sophisticated software accurately measures ground speed and attitude, in-situ static and dynamic pressure total temperature, which are used to calculate the three dimensional wind fields, static pressure, temperature and turbulence values to meteorological accuracy. The meteorological data is not only of interest for its own sake in atmospheric dynamical processes such as mountain waves and flux measurements; but is also required by other ER-2 experiments that simultaneously measure water vapor, O3, aerosols, NO, HCl, CH4, N2O, ClO, BrO, CO2, NOy, HOx and temperature gradients. MMS products are extensively used to assist in the interpretation of their results in understanding the importance of convective effects relative to in-situ chemical changes, as may be noted by examining the list of references attached. The MMS consists of three subsystems: (a) aircraft instrumentation, inertial navigation system (INS), static and dynamic pressure taps, (b) additional dedicated instrumentation measuring angle of attack, yaw, total temperature, and a GPS which on the DC-8 measures position, velocity and attitude (c) an on board data, storage and computing acquisition system. This instrumentation and the associated software requires both an on-going laboratory ground calibration procedure for the total air temperature, static and total pressure inputs, verification of the INS dynamic response and also extensive air measurements and intercomparisons which ultimately verify and calibrate the complete system and its software. More than the usual accuracy is required because of the near cancellation occurring in the difference between the ground speed and true airspeed vectors used to give the wind vector. In the past year we have redesigned, recalibrated and used the MMS system on the NASA DC-8 that was previously used in the SUCCESS mission for the SONEX mission. Two papers were co-authored based on SUCCESS flights. Several reports and handouts were written for SONEX. Calibrations of the DC-8 pressure transducer temperature measuring thermistors was completed and an extensive analysis spanning several years of data files of the DC-8 Rosemount pressure transducer calibrations was done.

Browen, Stuart W.↗
NASA NTRS2004

Quantitative Relationships between Photosynthetic, Nitrogen Fixing, and Fermentative H2 Metabolism in a Photosynthetic Microbial Mat

The ultimate potential of any microbial ecosystem to contribute chemically to its environment - and therefore, to impact planetary biogeochemistry or to generate recognizable biosignatures - depends not only on the individual metabolic capabilities of constituent organisms, but also on how those capabilities are expressed through interactions with neighboring organisms. This is particularly important for microbial mats, which compress an extremely broad range of metabolic potential into a small and dynamic system. H2 participates in many of these metabolic processes, including the major elemental cycling processes of photosynthesis, nitrogen fixation, sulfate reduction, and fermentation, and may therefore serve as a mediator of microbial interactions within the mat system. Collectively, the requirements of energy, electron transfer, and biomass element stoichiometry suggest quantitative relationships among the major element cycling processes, as regards H2 metabolism We determined experimentally the major contributions to 32 cycling in hypersaline microbial mats from Baja California, Mexico, and compared them to predicted relationships. Fermentation under dark, anoxic conditions is quantitatively the most important mechanism of H2 production, consistent with expectations for non-heterocystous mats such as those under study. Up to 16% of reducing equivalents fixed by photosynthesis during the day may be released by this mechanism. The direct contribution of nitrogen fixation to H2 production is small in comparison, but this process may indirectly stimulate substantial H2 generation, by requiring higher rates of fermentation. Sulfate reduction, aerobic consumption, diffusive and ebulitive loss, and possibly H2-based photoreduction of CO2 serve as the principal H2 sinks. Collectively, these processes interact to create an orders-of-magnitude daily variation in H2 concentrations and fluxes, and thereby in the oxidation-reduction potential that is imposed on microbial processes occuring within the mat matrix.

Hoehler, Tori M.↗
NASA NTRSDate not supplied

Detectability of anthropogenic impacts on terrestrial carbon storage through space-based greenhouse gas observations

While changes in human activity and their impact on the terrestrial biosphere may be apparent in inventory and land-surface satellite data, reliably matching these changes to signals in atmospheric greenhouse gases remains challenging. The dominant signals in atmospheric carbon dioxide (CO2) are those of the seasonal and diurnal variability of the terrestrial biosphere. As a result, the historically large short-term change in anthropogenic fossil fuel emissions due to COVID-19 produced an atmospheric CO2 signal near the threshold of detectability of the current space-based observing system. Impacts of anthropogenic activity on terrestrial carbon storage are likewise expected to be difficult, if not impossible, to detect and validate with atmospheric observations. For example, many forest management projects involve reduction of wood removals that would otherwise be taken off site and decompose years later and are thus not reflected in immediate onsite carbon fluxes. Nevertheless, changes implemented over a jurisdictional scale, as opposed to individual projects, may be detectable. This presentation will analyze to what extent NASA’s Goddard Earth Observing System (GEOS)/Orbiting Carbon Observatory 2 (OCO-2) assimilated column CO2 (XCO2) product is able to detect anthropogenic changes to terrestrial carbon storage and the results of several simulation experiments meant to represent potential forest management scenarios. As examples, we consider past and future changes due to conversion in the Tropics to agricultural land use from slash-and-burn, e.g., from Reducing emissions from deforestation and forest degradation in developing countries (REDD+) efforts. This has the potential to inform what practices may be observable with current and future technology, e.g., Europe’s upcoming CO2 monitoring mission (CO2M), and where improvement is needed.

Brad Weir↗
NASA NTRS1981

Stratospheric measurements of continuous absorption near 2400 per cm

Measurements of continuous absorption near 2400 per cm by N2 and CO2 over long path lengths in the lower stratosphere are presented. The continua were measured in a stratospheric solar spectrum obtained during sunset with a balloon-borne Michelson interferometer in the 2380-2500 per cm region, and transmittances were calculated by ratioing the amplitudes to those of a high-sun spectrum in order to eliminate the wavelength dependence of the measured flux. Comparison of the measured transmittances with those calculated for a multilayered atmospheric model using laboratory absorption measurements results in a fair agreement, and reveals the primary component of the absorption throughout most of the range to be N2, with the CO2 contribution equal to that of N2 only at the CO2 band head. In this region, the shape of the continuum is very sensitive to the sub-Lorentzian line shape assumed in the calculations, and so, if the shape of the N2 continuum at low temperatures can be determined through laboratory measurements, may be used to infer air-broadened far-wing CO2 line shape.

Rinsland, C. P.↗
NASA NTRS1987

Pulsed source of energetic atomic oxygen

A pulsed high flux source of nearly monoenergetic atomic oxygen was designed, built, and successfully demonstrated. Molecular oxygen at several atmospheres pressure is introduced into an evacuated supersonic expansion nozzle through a pulsed molecular beam valve. An 18 J pulsed CO2 TEA laser is focused to intensities greater than 10(9) W/sq cm in the nozzle throat to generate a laser-induced breakdown. The resulting plasma is heated in excess of 20,000 K by a laser supported detonation wave, and then rapidly expands and cools. Nozzle geometry confines the expansion to provide rapid electron-ion recombination into atomic oxygen. Average O atom beam velocities from 5 to 13 km/s were measured at estimated fluxes to 10(18) atoms per pulse. Preliminary materials testing has produced the same surface oxygen enrichment in polyethylene samples as obtained on the STS-8 mission. Scanning electron microscope examinations of irradiated polymer surfaces reveal an erosion morphology similar to that obtained in low Earth orbit, with an estimated mass removal rate of approx. 10(-24) cu cm/atom. The characteristics of the O atom source and the results of some preliminary materials testing studies are reviewed.

Caledonia, George E.↗
NASA NTRS1997

Regional Application of an Ecosystem Production Model for Studies of Biogeochemistry in the...

The degree to which primary production, soil carbon, and trace gas fluxes in tropical forests of the Amazon are limited by moisture availability and other environmental factors was examined using an ecosystem modeling application for the country of Brazil. A regional geographic information system (GIS) serves as the data source of climate drivers, satellite images, land cover, and soil properties for input to the NASA Ames-CASA (Carnegie-Ames-Stanford Approach) model over a 8-km grid resolution. Simulation results supports the hypothesis that net primary production (NPP) is limited by cloud interception of solar radiation over the humid northwestern portion of the region. Peak annual rates for NPP of nearly 1.4 kg C m-2yr -1are localized in the seasonally dry eastern Amazon in areas that we assume are primarily deep-rooted evergreen forest cover. Regional effects of forest conversion on NPP and soil carbon content are indicated in the model results, especially in seasonally dry areas. Comparison of model flux predictions along selected eco-climatic transects reveal moisture, soil, and land use controls on gradients of ecosystem production and soil trace gas emissions (CO2, N2O, and NO). These results are used to formulate a series of research hypotheses for testing in the next phase of regional modeling, which includes recalibration of the light-use efficiency term in CASA using field measurements of NPP, and refinements of vegetation index and soil property (texture and potential rooting depth) maps for the region.

Potter, C. S.↗
NASA NTRS2004

[CO2 Budget and Atmospheric Rectification (COBRA) Over North America]

The purpose of the CO2 Budget and Rectification Airborne (COBRA) study was to assess terrestrial sources and sinks of carbon dioxide using an air-borne study. The study was designed to address the measurement gap between plot-scale direct flux measurements and background hemispheric-scale constraints and to refine techniques for measuring terrestrial fluxes at regional to continental scales. The initial funded effort (reported on here) was to involve two air-borne campaigns over North America, one in summer and one in winter. Measurements for COBRA (given the acronym C02BAR in the initial proposal) were conducted from the University of North Dakota Citation 11, a twin-engine jet aircraft capable of profiling from the surface to 12 km and cruising for up to 4 hours and 175m/s. Onboard instrumentation measured concentrations of CO2, CO, and H2O, and meteorological parameters at high rates. In addition, two separate flask sampling systems collected discrete samples for laboratory analysis of CO2,CO, CH4, N2O, SF6, H2, 13CO2, C18O16O,O2/N2, and Ar/N2. The project involved a collaboration between a number of institutions, including (but not limited to) Harvard, NOAA-CMDL, the University of North Dakota, and Scripps.

Source record↗
NASA NTRSDate not supplied

Bioreactor Development for CO2-Based In Situ Resource Utilization Manufacturing

Sustainable long-duration manned missions on both the Moon and Mars will require in situ resource utilization (ISRU). Carbon dioxide (CO2) has great potential as a harvestable resource, making up 95% of the atmosphere on Mars and being produced as respiratory waste in spacecraft and future planetary habitats. Through ISRU, biomanufacturing has the capability to produce a near limitless array of products from local space resources, which include pharmaceuticals, bioplastics, chemical feedstocks, and industrial enzymes. Here, a CO2-based ISRU recombinant protein bioreactor and associated biomanufacturing organisms were designed to produce a highly stable carbonic anhydrase (CA). Initial work characterized candidate organisms for growth on acetate and formic acid, carbon substrates that can be synthesized via electrochemical conversion of CO2. To improve growth on the CO2 producing substrate formic acid and for direct integration of ISRU CO2, a synthetic Calvin-Benson-Bassam cycle was designed for use in Cyberlindnera jadinii and Escherichia coli. Genetic modifications in E. coli will be facilitated by a tailored CRISPR/Cas9 and λ red recombineering two-vector system. For expression of CA, a blue light regulated T7 promoter was employed for dynamic and small molecule free induction. Efficient bioproduction through a fed-batch exponential feeding strategy was determined via mass balance calculations from ISRU substrates to biomass and CA yield. Flux balance analysis was used to model ISRU substrate metabolism and metabolic pathway engineering in candidate organisms under cultivation strategy conditions for both metabolism reconstruction and pathway design optimization. Finally, a small-scale, disposable bag bioreactor concept for use in the NASA Bioculture System infrastructure was designed to enable CO2-based CA production in reduced-gravity environments.

Biomanufacturing, Pathway Engineering, Flux Balanc↗
NASA NTRS2021

Dynamical and Trace Gas Responses of the Quasi-Biennial Oscillation to Increased CO2

Long-term projections of the Quasi-Biennial Oscillation (QBO) remain uncertain. Using the high-top \Middle Atmosphere" (MA) version of the NASA Goddard Institute for Space Studies (GISS) ModelE (E2.2-AP), we show that increased CO2 reduces the QBO period and weakens its amplitude, consistent with results from recent multimodel studies. The amplitude response is asymmetric, with the easterly phase weakening more than the westerly phase. Results from both coupled atmosphere{ocean and climatologically fixed sea surface temperature simulations link the period response to changes in parameterized convective gravity wave fluxes, whereas the amplitude changes are more closely tied to changes in tropical upwelling. Comparisons of simulations with and without ozone-dynamical feedbacks reveal that ozone feedbacks increase the QBO amplitude and period in pre-industrial control simulations, and reduce the response of the amplitude to increased CO2. The response of stratospheric tracers to projected changes in the QBO is also investigated. Similarity between results using fully interactive (trace gas and aerosol) versus linearized ozone chemical mechanisms suggests that the QBO response to CO2 does not depend on additional chemical feedbacks beyond those associated with ozone, which implies that projected QBO changes may be credibly represented using simpli fied stratospheric ozone schemes.

GISS Model E2.2-AP↗
NASA NTRS1985

Oxidant abundances in rainwater and the evolution of atmospheric oxygen

H2O2 is probably the dominant oxidant in rainwater at O2 levels lower than 0.01-0.001 present atmospheric levels (PAL), and the magnitude of its dissolved flux is sensitive to the concentration of the trace gases NO, CO, and CH4 in the atmosphere, as well as to the partial pressure of atmospheric CO2. The earlier interpretation of the paleosol data in terms of the ratio of p-O2/p-CO2 in the atmosphere must be modified by taking into account the effects of photochemically produced oxidants and reactants at p-O2 of les than 0.01 PAL.

Kasting, J. F.↗
NASA NTRSDate not supplied

Cryogenic Modules for Synergistic O2 Generation and CO2 Retention in Closed-Circuit Escape Respirators

Since 2018, NASA and the National Institute for Occupational Safety and Health (NIOSH) have been developing a liquid oxygen storage module (LOXSM) based on the NASA patent-pending Cryogenic Flux Capacitor (CFC) technology. LOXSM’s could potentially replace the gaseous or chemical-based oxygen supply in current closed-circuit escape respirators (CCER), with reducing CCER size being a primary goal. By virtue of the CFC functionality, cryogenic oxygen stored within the LOXSM is released in response to heat input, ideally from the breathing loop. Prior efforts focused on the oxygen storage potential of silica aerogel materials that the CFC utilizes, and were previously reported. Current work explored the LOXSM’s potential to remove and retain CO 2 produced by the CCER user, in conjunction with oxygen generation, creating a synergy that may be exploited to reduce or eliminate the chemical CO 2 absorber used in current CCERs. A test program for determining CO 2 retention is presented, as well as the evolution of LOXSM prototypes. Testing showed that it is possible to completely remove CO 2 out of an effluent stream at the flowrate required for the capacity of the CCER for an appreciable time, and that the LOXSM prototype design progression had a positive effect on that duration.

A.M. Swanger↗
NASA NTRS2016

Scientific and Technical Assistance for the Deployment of a Flexible Airborne Spectrometer System During C-MAPExp and COMEX: COMEX Version - 1.9T

The COMEX (CO2 and MEthane eXperiment) campaign supports the mission definition of CarbonSat and HyspIRI (Hyperspectral Infrared Imager) by providing representative airborne remote sensing data ‐ MAMAP (Methane Airborne MAPper) for CarbonSat; the Airborne Visual InfraRed Imaging Spectrometer (Classic & Next Generation) AVIRIS‐C/AVIRIS‐NG for HyspIRI ‐ as well as ground-based and airborne in‐situ data. The objectives of the COMEX campaign activities are (see Campaign Implementation Plan (RD‐4)): 1. Investigate spatial/spectral resolution trade‐offs for CH4 anomaly detection and flux inversion by comparison of MAMAP‐derived emission estimates with AVIRIS/AVIRIS‐NG derived data. 2. Evaluate sun‐glint observation geometry on CH4 retrievals for marine sources. 3. Characterize the effect of Surface Spectral Reflectance (SSR) heterogeneity on trace gas retrievals of CO2 and CH4 for medium and low‐resolution spectrometry. 4. Identify benefits from joint SWIR/TIR (ShortWave InfraRed/Thermal InfraRed ) data for trace gas detection and retrieval by comparison of MAMAP and AVIRIS/AVIRIS‐NG NIR/SWIR data with MAKO (Aerospace Corp.)TIR data. The ability to derive emission source strength for a range of strong emitting targets by remote sensing will be evaluated from combined AVIRIS‐NG and MAMAP data, adding significant value to the HyspIRI campaign AVIRIS‐NG dataset. The data will be used to quantify anomalies in atmospheric CO2 and CH4 from strong local greenhouse gas sources e.g. localized industrial complexes, landfills, etc. and to derive CO2 and CH4 emissions estimates from atmospheric gradient measurements. The original campaign concept was developed by University of Bremen and BRI. The COMEX campaign is funded bilaterally by NASA and ESA (European Space Agency). Whereas NASA funds the US part of the project via a contract with Dr. Ira Leifer, BRI (Bubbleology Research International), the contribution of MAMAP to the COMEX campaign is funded by ESA within the COMEX‐E project and NASA with respect to a 50 percent contribution to the flight-related costs of flying MAMAP on a US aircraft. The Data Acquisition Report (RD‐9) describes the instrumentation used, the measurements made by the team during the COMEX campaign in May/June 2014 and August/September 2014 in California, and an initial assessment of the data quality.

Point Sources↗
NASA NTRS1986

Predicting earth's dynamic changes

Given a suitable strategy for conducting measurements, satellite-based remote sensing of the earth can furnish valuable information on the dynamic changes of such planetary characteristics as ocean surface temperatures and atmospheric CO2. Observations must be global and synoptic, quantitatively validated, and consistent over the long term. A program spanning 20 years will study such critical variables as solar flux, stratospheric temperature, aerosols and ozone, cloud cover, tropospheric gases and aerosols, radiation balance, surface temperature, albedo, precipitation, vegetation cover, moisture, snow and ice, as well as oceanic color, topography, and wind stress.

Rasool, S. I.↗
NASA NTRS2002

Mass Conservation in a Chemical Transport Model and its Effect on CO2 and SF6 Simulations

Chemical transport models (CTMs) must conserve mass to be useful for applications involving assessment of the effect of various pollutants on the troposphere and stratosphere. Furthermore, calculations of the evolution of constituents such as SF6 are used to evaluate overall model transport, and interpretation of such simulations is clouded if mass conservation is not assured. For realistic simulations or predictions, it is crucial that constituents are not produced or lost by transport or other processes in the CTMs. Analysis of CO2 and SF6 experiments using a CTM shows that problems with mass conservation can seriously degrade the simulations. Failure to conserve mass results from inconsistency of the surface pressure tendency and the divergence of horizontal mass flux when the model is forced by assimilated meteorological data. We have developed an effective method to eliminate the inconsistency by modifying the divergent part of the wind field. The changes in the wind fields are quite small but the impact on mass conservation is large. Parameterizations of physical processes such as convection or turbulent transport can also affect mass conservation. The lack of conservation is small but accumulates when integrations are lengthy such as required for SF6. This lack of conservation is found using winds from either a GCM or from an assimilation system. A simple adjustment removes much of the inaccuracy in the convective parameterization. A CO2 simulation using assimilated winds from the most recent version of the Goddard Earth Observing System Data Assimilation System will be used to illustrate the impact of these transport improvements.

Zhu, Z.↗
DOE OSTI2024

CFD modeling of high-flux plate-and-frame membrane modules for industrial carbon capture

In this work, we study the application of membrane-based separation systems for carbon capture, considering plate-and-frame membrane modules. The successful deployment of membrane CO2 capture system relies on high-performing membranes as well as effective membrane modules that can fully exploit the developed membranes. A plate-and-frame membrane module is especially attractive for CO2 capture from industrial flue gas due to its lower pressure drop compared to its counterparts such as spiral wound modules and hollow fiber modules. To design better plate-and-frame modules, we investigate their basic unit - a single membrane stack through a combination of computational modeling and experimental investigations. The modeling approach is based on Computational Fluid Dynamics (CFD) to represent a multiphysics problem, including the fluid flow and diffusion processes within a membrane module. We use experimental data collected under different operating conditions to validate the CFD model. Numerical results suggest a good agreement between experiments and model outputs for the CO2 recovery, CO2 mole fraction in the retentate and permeate, and stage-cut. The CFD model is able to predict accurately the flow behavior, providing valuable insights on the effects of fluid dynamics on mass transfer of CO2. We also carry out a sensitivity analysis to identify the effect of key parameters on the CO2 recovery and the CO2 purity of the outlet streams.

Dosso, Cheick↗