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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1979

The distribution of zirconium and hafnium in terrestrial rocks, meteorites and the moon

It is shown that Zr and Hf are not always fractionated in terrestrial igneous differentiation or regional metamorphism. Data do support a Zr-Hf fractionation in the differentiation of the alkali olivine magma at St. Helena Island. A strong Zr-Hf fractionation exists among lunar rocks and minerals. Ilmenite is an excellent concentrator of Zr and Hf and always exhibits high Zr/Hf ratios. Chondritic meteorites exhibit rather uniform Zr abundances and Zr/Hf ratios but a distinct Zr-Hf fractionation is observed among the eucrite and diogenite achondrites.

Ehmann, W. D.↗
NASA NTRS1980

Venus upper atmosphere structure

Atmospheric densities of Venus were measured from the orbital decay of the Pioneer Venus from Dec. 9, 1978 to Aug. 7, 1979 near the 16 deg latitude between 140 and 190 km during the entire day. Comparative atmospheric densities on earth at 150 km are higher by a factor of 3.5 with only a 1% diurnal variation; an atmospheric composition, temperature, and density model based on the orbiter atmospheric drag (OAD) vertical structure is presented. The model shows that atomic oxygen is the major component in the Venus atmosphere above 145 km at night and above 160 km during the day with mixing ratios over 0.1 near 140 km; drag measurements indicate O concentrations from 1 x 10 to the 9th/cu cm in daytime to 3 x 10 to the 7th/cu cm at night. It is concluded that the neutral upper atmosphere of Venus is surprisingly insensitive to solar extreme UV variations and changes in the solar wind.

Keating, G. M.↗
NASA NTRS1984

Compositional trends and cooling rates of group IVB iron meteorites

It is found, on the basis of new neutron activation data for group IVB, that log-element - log-Ni trends are best understood in terms of core formation and fractional crytstallizaion. The limited compositional range found in gorup IVB is thought to reflect the fact that, owing to the low concentrations of S, P, and C and the high concentration of Ni, the k sub x (the solid/liquid partition ratio) values are closer to unity than are those in other magmatic groups. Mean volatile abundances in group IVB are significantly lower than those found in any group of chondritic meteorites, indicating that these low abundances are not entirely the result of nebular processes and that planetary outgassing was also involved.

Rasmussen, K. L.↗
NASA NTRS1985

An evaluation of 685 nm fluorescence imagery of coastal waters

To evaluate the possible application of sunlight-illuminated fluorescence at 685 nm for remote sensing of phytoplankton concentrations, an ocean-color scanner is flown on an aircraft. The results of an analysis of the scanner data, obtained from a series of test flights conducted along the Elbe River and its estuary in the North Sea, show that 685 nm fluorescence is a promising remote-sensing method. The observation of a strong correlation between the fluorescence yields and the chlorophyll concentrations determined by the absorption method which uses the reflectance ratio of blue/green channels, is discussed. The two methods are compared and it is shown that the fluorescence method has an edge over the other due to the data-processing algorithm and its applicability for surveying bio-resources in all types of water. Photographs of the chlorophyll patterns are presented.

Kim, H. H.↗
NASA NTRS1993

In situ observations of aerosol and chlorine monoxide after the 1991 eruption of Mount Pinatubo - Effect of reactions on sulfate aerosol

Highly resolved aerosol size distributions measured from high-altitude aircraft can be used to describe the effect of the 1991 eruption of Mount Pinatubo on the stratospheric aerosol. In some air masses, aerosol mass mixing ratios increased by factors exceeding 100 and aerosol surface area concentrations increased by factors of 30 or more. Increases in aerosol surface area concentration were accompanied by increases in chlorine monoxide at mid-latitudes when confounding factors were controlled. This observation supports the assertion that reactions occurring on the aerosol can increase the fraction of stratospheric chlorine that occurs in ozone-destroying forms.

Wilson, J. C.↗
NASA NTRS1993

A prediction method for broadband shock associated noise from supersonic rectangualr jets

Braodband shock associated noise is an important aircraft noise component of the proposed high-speed civil transport (HSCT) at take-offs and landings. For noise certification purpose one would, therefore, like to be able to predict as accurately as possible the intensity, directivity and spectral content of this noise component. The purpose of this work is to develop a semi-empirical prediction method for the broadband shock associated noise from supersonic rectangular jets. The complexity and quality of the noise prediction method are to be similar to those for circular jets. In this paper only the broadband shock associated noise of jets issued from rectangular nozzles with straight side walls is considered. Since many current aircraft propulsion systems have nozzle aspect ratios (at nozzle exit) in the range of 1 to 4, the present study has been confined to nozzles with aspect ratio less than 6. In developing the prediction method the essential physics of the problem are taken into consideration. Since the braodband shock associated noise generation mechanism is the same whether the jet is circular or round the present prediction method in a number of ways is quite similar to that for axisymmetric jets. Comparisons between predictions and measurements for jets with aspect ratio up to 6 will be reported. Efforts will be concentrated on the fly-over plane. However, side line angles and other directions will also be included.

Tam, Christopher K. W.↗
NASA NTRS1994

Evidence for a Meteoritic Component in Impact Melt Rock from the Chicxulub Structure

The Chicxulub structure in Yucatan, Mexico, has recently been recognized as a greater then 200-km-diameter multi-ring impact crater of K-T boundary age. Crystalline impact melt rocks and breccias from within the crater, which have compositions similar to those of normal continental crustal rocks and which show shock metamorphic effects, have been studied for trace element and Re-Os isotope compositions. Re-Os isotope systematics allow the sensitive and selective determination of an extraterrestrial component in impact-derived rocks. A melt rock sample shows elevated iridium concentrations, an osmium concentration of 25 ppb, and a low Os-187/Os-188 ratio of 0.113, which are incompatible with derivation from the continental crust. Even though the Os-187/Os-188 ratio is slightly lower than the range so far measured in meteorites, a mantle origin seems unlikely for mass balance reasons and because the cratering event is unlikely to have excavated mantle material. The data support the hypothesis of a heterogeneously distributed meteoritic component in the Chicxulub melt rock. A sample of impact glass from the Haitian K-T boundary at Beloc yielded about 0.1 ppb osmium and an Os-187/0s-188 ratio of 0.251, indicating the presence of a small meteoritic component in the impact ejecta as well.

Koeberl, Christian↗
NASA NTRS2001

Structure and Characteristics of Precipitation Systems Observed by TRMM

Multi-sensor measurements of total lightning (in-cloud plus cloud-to-ground) from the Lightning Imaging Sensor (LIS) aboard the TRMM satellite has been combined with passive microwave ice scattering and precipitation radar reflectivity profile information previously cataloged for precipitation features observed by TRMM. These precipitation features are defined by their surface rainfall or ice scattering signatures, with horizontal scales approx. 100 - 10000 sq km. Additionally, convective scale (approx. 100 sq km) storms are defined by the lightning data. Over the U.S. the national cloud-to-ground lightning observations are used to also determine the ratio of in-cloud to cloud-to-ground lightning, where it is hypothesized these ratios are related to the vertical profile of reflectivity and concentration of precipitation-sized ice. Combining the LIS, TRMM Microwave Imager (TMI), and Precipitation Radar (PR) for these storms allows investigation of the convective structures and convective regimes leading to observed lightning, scattering, and reflectivity signatures. Application of this approach to a global, multi-year data set (1998-2000) furthers our understanding of convective processes in different climatological regimes. The figure shows the distribution of high flash rate storms.

Goodman, Steve↗
NASA NTRS2002

Coastal Atmosphere and Sea Time Series (CoASTS)

In this document, the first three years of a time series of bio-optical marine and atmospheric measurements are presented and analyzed. These measurements were performed from an oceanographic tower in the northern Adriatic Sea within the framework of the Coastal Atmosphere and Sea Time Series (CoASTS) project, an ocean color calibration and validation activity. The data set collected includes spectral measurements of the in-water apparent (diffuse attenuation coefficient, reflectance, Q-factor, etc.) and inherent (absorption and scattering coefficients) optical properties, as well as the concentrations of the main optical components (pigment and suspended matter concentrations). Clear seasonal patterns are exhibited by the marine quantities on which an appreciable short-term variability (on the order of a half day to one day) is superimposed. This short-term variability is well correlated with the changes in salinity at the surface resulting from the southward transport of freshwater coming from the northern rivers. Concentrations of chlorophyll alpha and total suspended matter span more than two orders of magnitude. The bio-optical characteristics of the measurement site pertain to both Case-I (about 64%) and Case-II (about 36%) waters, based on a relationship between the beam attenuation coefficient at 660nm and the chlorophyll alpha concentration. Empirical algorithms relating in-water remote sensing reflectance ratios and optical components or properties of interest (chlorophyll alpha, total suspended matter, and the diffuse attenuation coefficient) are presented.

Hooker, Stanford B.↗
NASA NTRS1998

Incorporation of Solar Noble Gases from a Nebula-Derived Atmosphere During Magma Ocean Cooling

The presence of solar noble gases in the deep interior of the Earth is inferred from the Ne isotopic compositions of MORB (Mid-ocean Ridge Basalts) and OIB (Oceanic Island Basalt); Ar data may also consistent with a solar component in the deep mantle. Models of the transport and distribution of noble gases in the earth's mantle allow for the presence of solar Ar/Ne and Xe/Ne ratios and permit the calculation of lower mantle noble gas concentrations. These mantle data and models also indicate that the Earth suffered early (0.7 to 2 x 10(exp 8) yr) and large (greater than 99 percent) losses of noble gases from the interior, a result previously concluded for atmospheric Xe. We have pursued the suggestion that solar noble gases were incorporated in the forming Earth from a massive, nebula-derived atmosphere which promoted large-scale melting, so that gases from this atmosphere dissolved in the magma ocean and were mixed downward. Models of a primitive atmosphere captured from the solar nebula and supported by accretion luminosity indicate that pressures at the Earth's surface were adequate (and largely more than the required 100 Atm) to dissolve sufficient gases. We have calculated the coupled evolution of the magma ocean and the overlying atmosphere under conditions corresponding to the cessation (or severe attenuation) of the sustaining accretion luminosity, prior to the complete removal of the solar nebula. Such a condition was likely to obtain, for instance, when most of the unaccumulated mass resided in large bodies which were only sporadically accreted. The luminosity supporting the atmosphere is then that provided by the cooling Earth, consideration of which sets a lower limit to the time required to solidify the mantle and terminate the incorporation of atmospheric gases within it. In our initial calculations, we have fixed the nebula temperature at To = 300K, a value likely to be appropriate for nebular temperatures at lAU in the early planet-building epoch. We treated the background (nebula) pressure as an adjustable, time-dependent parameter. Additional information is contained within the original extended abstract.

Woolum, D. S.↗
NASA NTRS2005

Noise and Spreading of a Subsonic Coannular Jet - Comparison with Single Equivalent Jet

The issue of scaling of noise as well as spreading of subsonic coannular jets is revisited. Far-field noise and centerline Pitot-static pressure surveys are conducted with concentric, circular nozzles having an outer-to-inner diameter ratio of 1.42. Both the inner nozzle and the outer annular passage are convergent. Outer-to-inner Mach number ratio (R) is varied over a large range from 0 to approximately 10. Results are examined on the basis of single equivalent jet parameters calculated by satisfying continuity, momentum and energy equations. The results confirm that coannular jets with normal velocity profiles are noisier than the single equivalent jet. Jets with "inverted" velocity profiles are also found to be noisier except in a narrow R-range of 1-1.5. In the latter range, contrasting the inference in previous studies of IVP jets, the present data do not exhibit a clear noise reduction. When normalized with equivalent jet parameters the asymptotic Mach number decay rate, as well as potential core length, are found to be comparable to those of a single jet. However, an abrupt shift in the virtual origin is noted across R=1.

Zaman, K. B. M. Q.↗
NASA NTRS2005

Hematite Spherules in Basaltic Tephra Altered Under Aqueous, Acid-Sulfate Conditions on Mauna Kea Volcano, Hawaii: Possible Clues for the Occurrence of Hematite-Rich Spherules in the Burns Formation at Meridiani Planum, Mars

Iron-rich spherules (>90% Fe2O3 from electron microprobe analyses) approx.10-100 microns in diameter are found within sulfate-rich rocks formed by aqueous, acid-sulfate alteration of basaltic tephra on Mauna Kea volcano, Hawaii. Although some spherules are nearly pure Fe, most have two concentric compositional zones, with the core having a higher Fe/Al ratio than the rim. Oxide totals less than 100% (93-99%) suggest structural H2O and/or /OH. The transmission Moessbauer spectrum of a spherule-rich separate is dominated by a hematite (alpha-Fe2O3) sextet whose peaks are skewed toward zero velocity. Skewing is consistent with Al(3+) for Fe(3+) substitution and structural H2O and/or /OH. The grey color of the spherules implies specular hematite. Whole-rock powder X-ray diffraction spectra are dominated by peaks from smectite and the hydroxy sulfate mineral natroalunite as alteration products and plagioclase feldspar that was present in the precursor basaltic tephra. Whether spherule formation proceeded directly from basaltic material in one event (dissolution of basaltic material and precipitation of hematite spherules) or whether spherule formation required more than one event (formation of Fe-bearing sulfate rock and subsequent hydrolysis to hematite) is not currently constrained. By analogy, a formation pathway for the hematite spherules in sulfate-rich outcrops at Meridiani Planum on Mars (the Burns formation) is aqueous alteration of basaltic precursor material under acid-sulfate conditions. Although hydrothermal conditions are present on Mauna Kea, such conditions may not be required for spherule formation on Mars if the time interval for hydrolysis at lower temperatures is sufficiently long.

Morris, R. V.↗
NASA NTRS2010

Transport of Cs-137 from Boreal Biomass Burning in Summer of 2010

The summer of 2010 was a severe fire season in western Russia. Wildfires were detected in the Bryansk region, raising concerns that radionuclide contamination from the Chernobyl accident could be resuspended in the atmosphere. We simulate the transport of passive and particulate tracers of biomass burning from this region using the GEOS5 GOCART model driven by assimilated meteorology. Biomass burning emissions are based on MODIS fire detections. We validate the model against aerosol optical depth from MODIS. Using a range of estimates for Cs-137 emissions during wildfires, we estimate the downwind concentration and deposition of Cs-137 based on the emission ratios of Cs-137 to the simulated tracers. We discuss the sensitivity of our results to the location of the fires and the fraction of Cs-137 resuspended.

Strode, Sarah↗
NASA NTRS2010

Can Vertical Profiles of Tropospheric Methane on Titan Be Derived from Radio-Occultation Soundings?

The intensity of the received signal at Earth in the radio occultations of Titan is attenuated both by refractive defocusing and pressure-induced absorption from N2-N2 and CH4-N2 pairs. Because the absorption strength is different for the two sets of pairs, matching the retrieved absorptivity profile can in principle yield the vertical variation in gaseous methane in the troposphere. There are two factors that make this difficult. The first is the propagation of noise in the phase and amplitude of the received signal in the absorption retrieval. The phase data is first inverted to retrieve vertical profiles of refractivity, from which the refractive defocusing is calculated. This is then subtracted from the observed. intensity attenuation of the received signal to generate a profile of atmospheric absorption. The second problem is the uncertainty in the pressure-induced absorption coefficients. Laboratory data at radio wavelengths is only available near room temperature (see, e.g., [1] for N2-N2), and the extrapolation to the low temperatures in Titan's troposphere is not well established. Ab initio calculations by Borysow et al. [2, 3] provide absorption coefficients at low temperatures and long wavelengths, but their accuracy has come into question. We present examples from Cassini radio occultations of Titan to illustrate the difficulties. For methane mole fractions in the lower troposphere comparable to that inferred from the Huygens probe (approximately 0.05), it will be difficult to separate the contributions of N2-N2 collisions from those of N2-CH4, collisions to the retrieved absorption. However, higher concentrations of CH4 and/or a higher signal-to-noise ratio from a future uplink experiment could result in a successful separation of the two components. However, key to this are highly accurate estimates of the absorption from a combination of laboratory measurements at love temperatures and long wavelengths, and possibly improved theoretical calculations.

Flasar, F. Michael↗
NASA NTRS1981

Laboratory tank studies of a single species of phytoplankton using a remote sensing fluorosensor

Phytoplankton were grown in the laboratory for the purpose of testing a remote fluorosensor. The fluorosensor uses a unique four-wavelength dye laser system to excite phytoplankton bearing chlorophyll and to measure the chlorophyll fluorescence generated by this excitation. Six different species were tested, one at a time, and each was grown two to four times. Fluorescence measured by the fluorosensor provides good quantitative measurement of chlorophyll concentrations for all species tested while the cultures were in log phase growth. Fluorescene cross section ratios obtained in the single species tank tests support the hypothesis that the shape of the fluorescence cross section curve remains constant with the species (differences in fluorescence cross section ratios are a basis for determining composition of phytoplankton according to color group when a multiwavelength source of excitation is used. Linear relationships exist between extracted chlorophyll concentration and fluorescence measured by the remote fluorosensor during the log phase growth of phytoplankton cultures tested.

Brown, C. A., Jr.↗
NASA NTRS1993

A carbon dioxide/methane greenhouse atmosphere on early Mars

One explanation for the formation of fluvial surface features on early Mars is that the global average surface temperature was maintained at or above the freezing point of water by the greenhouse warming of a dense CO2 atmosphere; however, Kasting has shown that CO2 alone is insufficient because the formation of CO2 clouds reduces the magnitude of the greenhouse effect. It is possible that other gases, such as NH3 and CH4, were present in the early atmosphere of Mars and contributed to the greenhouse effect. Kasting et al. investigated the effect of NH3 in a CO2 atmosphere and calculated that an NH3 mixing ratio of approximately 5 x 10 (exp -4) by volume, combined with a CO2 partial pressure of 4-5 bar, could generate a global average surface temperature of 273 K near 3.8 b.y. ago when the fluvial features are believed to have formed. Atmospheric NH3 is photochemically converted to N2 by ultraviolet radiation at wavelengths shortward of 230 nm; maintenance of sufficient NH3 concentrations would therefore require a source of NH3 to balance the photolytic destruction. We have used a one-dimensional photochemical model to estimate the magnitude of the NH3 source required to maintain a given NH3 concentration in a dense CO2 atmosphere. We calculate that an NH3 mixing ratio of 10(exp -4) requires a flux of NH3 on the order of 10(exp 12) molecules /cm-s. This figure is several orders of magnitude greater than estimates of the NH3 flux on early Mars; thus it appears that NH3 with CO2 is not enough to keep early Mars warm.

Brown, L. L.↗
NASA NTRS2004

Low and High Speed STOVL Configurations in Ground Effect

The problem of hot gas ingestion in V/STOL and STOVL aircraft has motivated a set of experimental studies. Two-, three-, and four-jet configurations in cross flow were studied in ground effect. The results presented here were based on a quantitative, concentration measurement technique know as marker nephelometry. The effects of configuration, velocity ratio (freestream over jet velocity), model height, and inlet suction were investigated. The experiments were conducted in three parts. In the first part, comparisons of low speed two-, three-, and four-jet configurations were made. Measurements were made in the planes beneath the models in ground effect. As the number of jets increased, the vortical structures in the flowfield were found to move further upstream due to the increased total momentum. In the second part of the experiments, measurements were made at the inlet entry plane of the low speed two- and three-jet configurations in ground effect. The results indicated that ingestion occurred intermittently, especially in the upper portions of the inlets. The highest levels of concentrations were measured at a model height of two jet diameters. As the model height increased, the concentration levels decreased. Finally, a high speed, two-jet configuration without inlet suction was studied. The flowfield structures were generally found to move further downstream as the jet velocity increased at a constant velocity ratio.

Holdeman, James D.↗
NASA NTRS1976

Spectroscopic detection and vertical distribution of HCl in the troposphere and stratosphere

HCl has been observed in both the troposphere and stratosphere from ground-based and airborne spectroscopic measurements of the 1-0 band at 3-micron wavelength. The results, which are specific to the HCl molecule in the gas phase, show a decreasing mixing ratio with altitude in the lower stratosphere. The stratospheric layer, which commences at about 15 km, reaches its maximum concentration at an altitude above 21 km (the limiting height of the observations to date). The local value for the volume mixing ratio at 21 km is 7 + or - 1 times 10 to the minus 10th. However, the zenith column abundance observed above 21 km implies that the mixing ratios at greater altitudes are unlikely to reach values much in excess of the local value at 21 km.

Farmer, C. B.↗