A Platform Approach for Designing Sustainable Indole Thiosemicarbazone Corrosion Inhibitors with Enhanced Adsorption Properties
Explore the source record for details and available documents.
Koushik, A. K. S. [Department of Chemical and Biol↗
SEARCH · Search NASA
Results for “Chemical Engineering”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Liquid lubricants for advanced aircraft engines
An overview of liquid lubricants for use in current and projected high performance turbojet engines is discussed. Chemical and physical properties are reviewed with special emphasis placed on the oxidation and thermal stability requirements imposed upon the lubrication system. A brief history is given of the development of turbine engine lubricants which led to the present day synthetic oils with their inherent modification advantages. The status and state of development of some eleven candidate classes of fluids for use in advanced turbine engines are discussed. Published examples of fundamental studies to obtain a better understanding of the chemistry involved in fluid degradation are reviewed. Alternatives to high temperature fluid development are described. The importance of continuing work on improving current high temperature lubricant candidates and encouraging development of new and improved fluid base stocks are discussed.
Loomis, William R.↗
Liquid lubricants for advanced aircraft engines
An overview of liquid lubricants for use in current and projected high performance turbojet engines is discussed. Chemical and physical properties are reviewed with special emphasis placed on the oxidation and thermal stability requirements imposed upon the lubrication system. A brief history is given of the development of turbine engine lubricants which led to the present day synthetic oils with their inherent modification advantages. The status and state of development of some eleven candidate classes of fluids for use in advanced turbine engines are discussed. Published examples of fundamental studies to obtain a better understanding of the chemistry involved in fluid degradation are reviewed. Alternatives to high temperature fluid development are described. The importance of continuing work on improving current high temperature lubricant candidates and encouraging development of new and improved fluid base stocks are discussed.
Loomis, William R.↗
The Strutjet Rocket Based Combined Cycle Engine
The multi stage chemical rocket has been established over many years as the propulsion System for space transportation vehicles, while, at the same time, there is increasing concern about its continued affordability and rather involved reusability. Two broad approaches to addressing this overall launch cost problem consist in one, the further development of the rocket motor, and two, the use of airbreathing propulsion to the maximum extent possible as a complement to the limited use of a conventional rocket. In both cases, a single-stage-to-orbit (SSTO) vehicle is considered a desirable goal. However, neither the "all-rocket" nor the "all-airbreathing" approach seems realizable and workable in practice without appreciable advances in materials and manufacturing. An affordable system must be reusable with minimal refurbishing on-ground, and large mean time between overhauls, and thus with high margins in design. It has been suggested that one may use different engine cycles, some rocket and others airbreathing, in a combination over a flight trajectory, but this approach does not lead to a converged solution with thrust-to-mass, specific impulse, and other performance and operational characteristics that can be obtained in the different engines. The reason is this type of engine is simply a combination of different engines with no commonality of gas flowpath or components, and therefore tends to have the deficiencies of each of the combined engines. A further development in this approach is a truly combined cycle that incorporates a series of cycles for different modes of propulsion along a flight path with multiple use of a set of components and an essentially single gas flowpath through the engine. This integrated approach is based on realizing the benefits of both a rocket engine and airbreathing engine in various combinations by a systematic functional integration of components in an engine class usually referred to as a rocket-based combined cycle (RBCC) engine. RBCC engines exhibit a high potential for lowering the operating cost of launching payloads into orbit. Two sources of cost reductions can be identified. First, RBCC powered vehicles require only 20% takeoff thrust compared to conventional rockets, thereby lowering the thrust requirements and the replacement cost of the engines. Second, due to the higher structural and thermal margins achievable with RBCC engines coupled with a higher degree of subsystem redundance lower maintenance and operating cost are obtainable.
Siebenhaar, A.↗
A Study of the Transition to Turbulence in a Bed of 67 Spherical Pebbles
Packed beds are commonly found in many engineering systems and have been widely studied for decades. A relatively new packed bed system is the Pebble Bed Reactor, a type of generation-IV nuclear reactor. Unlike many of the packed beds encountered in chemical and process engineering applications, Pebble Bed Reactors are larger and operate at significantly higher Reynolds numbers. As a result of these differences, there is a very limited amount of information on the detailed flow physics that exist in these complex geometries. This work seeks to contribute to a growing database of flow data for Pebble Bed Reactor systems by performing Direct Numerical Simulations of the flow in an experimental bed of 67 pebbles for a range of conditions. Simulations are performed at a Prandtl number of 0.66 and Reynolds numbers from 300–600. These Reynolds numbers are chosen to gain additional knowledge on the spatial development of turbulence in these systems. Analysis of the Turbulent Kinetic Energy, turbulence anisotropy, and Turbulent Heat Flux is performed. Results demonstrate significant development of the TKE across the tested range of Reynolds numbers. Examination of both the TKE and THF reveal that development first occurs near the center of the bed and propagates radially as the flow moves further into the bed. Notable regions of negative production of turbulent kinetic energy are observed in regions where flow accelerates around pebble contact points. Furthermore, these regions are found to coincide with regions of 1-component turbulence.Kindly check and confirm, all authors email id is correctly identified.These are correct
Direct numberical simulation↗
Optogenetics Illuminates Applications in Microbial Engineering
Optogenetics has been used in a variety of microbial engineering applications, such as chemical and protein production, studies of cell physiology, and engineered microbe–host interactions. These diverse applications benefit from the precise spatiotemporal control that light affords, as well as its tunability, reversibility, and orthogonality. This combination of unique capabilities has enabled a surge of studies in recent years investigating complex biological systems with completely new approaches. We briefly describe the optogenetic tools that have been developed for microbial engineering, emphasizing the scientific advancements that they have enabled. In particular, we focus on the unique benefits and applications of implementing optogenetic control, from bacterial therapeutics to cybergenetics. Lastly, we discuss future research directions, with special attention given to the development of orthogonal multichromatic controls. With an abundance of advantages offered by optogenetics, the future is bright in microbial engineering.
59 BASIC BIOLOGICAL SCIENCES↗
Effect of inert propellant injection on Mars ascent vehicle performance
A Mars ascent vehicle is limited in performance by the amount of propellant which can be brought from earth. In some cases the vehicle performance can be improved by injecting inert gas into the engine, if the inert gas is available as an in situ resource. CO2, N2 and Ar are constituents of the Martian atmosphere which are available at every point on the Martian surface and could be produced by a very simple processing technique, consisting essentially of compressing the atmosphere. The effect of inert gas injection on rocket engine performance was analyzed with a numerical code calculating chemical equilibrium in the engine, for engines of varying combustion chamber pressure, expansion ratio, oxidizer/fuel ratio, and inert injection fraction. Results of this analysis were applied to several candidate missions to determine how the required mass of return propellant needed in LEO could be decreased using inert propellant injection.
Colvin, James E.↗
Platform for Rapidly Identifying and Engineering Novel Tissue Targeted Antibody Therapeutics for Chemical and Biological Threats.
Abstract not provided.
Harmon, Brooke Nicole↗
Electrochemical reduction of ammonia-captured CO 2 to CO over a nickel single-atom catalyst
Carbon reactive capture and conversion offers a sustainable route to valuable chemicals and fuels while aiding Green House Gas (GHG) reduction. Direct electrochemical conversion of capture solutions like bicarbonate avoids the energy demands of conventional CO 2 regeneration. Ammonium bicarbonate (NH 4 HCO 3 ) is particularly attractive due to its low decomposition temperature and ability to supply in situ CO 2 from dilute sources without requiring purified CO 2 . Meanwhile, single-atom catalysts (SACs) with nitrogen-coordinated metal sites further enhance CO 2 reduction efficiency using Earth-abundant materials. In this study, we demonstrate a nickel single-atom catalyst (Ni-SAC)-based electrolyzer that utilizes NH 4 HCO 3 as the CO 2 source, achieving significantly improved CO production performance compared to the conventional silver cathodes used in the CO 2 reduction reaction (CO 2 RR) to produce CO. The Ni-SAC cathode exhibited a Faradaic efficiency of 60.1% for CO production at −200 mA cm −2 , while the silver cathode achieved a Faradaic efficiency of only 2%, likely due to ammonium-induced poisoning. Furthermore, the integration of a customized microporous layer onto the electrode significantly increased the Faradaic efficiency from 64% to 83% at −100 mA cm −2 , emphasizing the crucial role of electrode structure optimization in enhancing CO selectivity. These findings demonstrate a sustainable and economically viable strategy for green CO production directly from CO 2 capture solutions.
30 DIRECT ENERGY CONVERSION↗
Bio Inspired Surface Structures to Mitigate Interfacial Particle Adhesion: A Review
Nature has perfected surface chemical and topographical engineering to enable survival in extreme environments. Biomimetics is a rapidly expanding field where biologically inspired design facilitates elegant, yet practical, solutions across many applications. NASA’s ARTEMIS program focused on lunar missions will require unique ways to solve the challenge of highly abrasive, chemically reactive and electrostatically charged lunar dust that adheres strongly to all exposed surfaces and degrades functionality. While seeking solutions to find a surface for mitigating lunar dust adhesion, we looked at natural terrestrial surfaces that successfully minimize dust adhesion and wear for inspiration. Lunar dust is comprised of highly abrasive particles, more than 90% of which are composed of silicate materials. Adapting to somewhat similar particulates in hot and arid deserts of the world, the sandfish lizard has a skin structure that allows it to swim in the sand with minimum friction and adhesion. Special surface adaptations of the tamarisk plant help protect it from severe sandstorms. The desert scorpion has grooves and bumps on its carapace that have been shown to minimize erosion in the sand. Beyond these examples, there are numerous other natural surfaces that have evolved to mitigate particle adhesion and wear. Several efforts have been made by different researchers to replicate these natural surfaces using methods such as laser patterning, 3D printing, chemical vapor deposition and other physical and chemical processes. The resulting bio-inspired patterned surfaces have shown reduction in interfacial particle adhesion, friction, and wear, among other properties. This paper aims to review published research on the subject that might help develop lunar dust adhesion and wear mitigating material surfaces for future lunar applications.
Lunar dust, Lunar surface, Adhesion mitigation, Bi↗
Sub‐5 Ångstrom Porosity Tuning in Calixarene‐Derived Porous Liquids via Supramolecular Complexation Construction
Abstract Sub‐Ångstrom‐level porosity engineering, which is appealing in gas separations, has been demonstrated in solid carbon, polymer, and framework materials but rarely achieved in the liquid phase. In this work, a gas molecular sieving effect in the liquid phase at sub‐5 Ångstrom scale is created via sophisticated porosity tuning in calixarene‐derived porous liquids (PLs). Type II PLs are constructed via supramolecular complexation between the sodium salts of calixarene derivatives and crown ether solvents. The chemical structure variation and assembly behavior of the porous host upon PL construction are monitored by spectroscopy‐, X‐ray‐, and neutron‐scattering techniques. The presence of permanent porosity in calixarene‐derived PLs is verified by pressure swing gas uptake, altered CO 2 physisorption behavior, and molecular simulations. Sub‐5 Ångstrom porosity tuning within the PL phase is achieved by introducing bulky substituted groups on the benzene ring of the calixarene host, which then greatly affects the dynamic motion and transport behavior of CO 2 molecules and the Xe uptake performance. The approach being demonstrated in this work represents a promising pathway to tune and leverage the porosity effect for enhanced gas uptake capacity and selectivity in liquid sorbents.
Li, Errui [Department of Chemistry University of T↗
Additive manufacturing: Frameworks for chemical understanding and advancement in vat photopolymerization
Abstract Three-dimensional printing, or additive manufacturing (AM), is a broad term for a wide range of fabrication methods utilizing materials such as small-molecule, polymer, and metal feedstocks. Each method requires different chemical, physical, and engineering needs to be successful. This article will discuss some of the considerations for polymer-based AM methods. Ultimately, we focus on the chemistries of vat photopolymerization, in which light is used to cure a resin from liquid to solid, to provide an example of how chemical advancements have led to increased speed, resolution, and multimaterial printing capabilities not previously possible. Graphical abstract
36 MATERIALS SCIENCE↗
¡Viva la mitochondria!: harnessing yeast mitochondria for chemical production
ABSTRACT The mitochondria, often referred to as the powerhouse of the cell, offer a unique physicochemical environment enriched with a distinct set of enzymes, metabolites and cofactors ready to be exploited for metabolic engineering. In this review, we discuss how the mitochondrion has been engineered in the traditional sense of metabolic engineering or completely bypassed for chemical production. We then describe the more recent approach of harnessing the mitochondria to compartmentalize engineered metabolic pathways, including for the production of alcohols, terpenoids, sterols, organic acids and other valuable products. We explain the different mechanisms by which mitochondrial compartmentalization benefits engineered metabolic pathways to boost chemical production. Finally, we discuss the key challenges that need to be overcome to expand the applicability of mitochondrial engineering and reach the full potential of this emerging field.
Biotechnology & Applied Microbiology↗
Front-End Engineering Design for Carbon Capture from Shell's Deer Park Chemical Complex (Final Scientific/Technical Report)
This is the final scientific/technical report for a Front-End Engineering and Design (FEED) whose objective was to separate and capture over 820,000 tonnes per year (tpy) CO2 emissions from the commercially operated Shell Chemicals Complex located in Deer Park, Texas, USA reducing the overall facility CO2 emissions by 95% while providing energy transition jobs in a commercial area with a high concentration of refinery and chemical facilities producing CO2 emissions. The emission sources at the facility that were in scope were a total of Sixteen Furnaces – 8 OP3 furnaces and 8 OP3/HT2 Furnaces. Other minor sources were out of scope.
01 COAL, LIGNITE, AND PEAT↗
Amphiphilic nanopores that condense undersaturated water vapor and exude water droplets
Condensation of water vapor in confined geometries, known as capillary condensation, is a fundamental phenomenon with far-reaching implications. While hydrophilic pores enable liquid formation from undersaturated vapor without energy input, the condensate typically remains confined, limiting practical utility. Here, we explore the use of amphiphilic nanoporous polymer-infiltrated nanoparticle films that condense and release liquid water under isothermal and undersaturated conditions. By tuning the polymer fraction and nanoparticle size, we optimize condensation and droplet formation. As vapor pressure increases, voids fill with condensate, which subsequently exudes onto the surface as microscopic droplets. This behavior, enabled by a balance of polymer hydrophobicity and capillarity, reveals how amphiphilic nanostructures can drive accessible water collection. Our findings provide design insights for materials supporting energy-efficient water harvesting and heat management without external input.
Science & Technology - Other Topics↗
Enhancing Cycle Life in Superoxide‐Based Na–O 2 Batteries by Reducing Interface Reactivity
Abstract Sodium–oxygen (Na–O 2 ) batteries are considered a promising energy storage alternative to current state‐of‐the‐art technologies owing to their high theoretical energy density, along with the natural abundance and low price of Na metal. The chemistry of these batteries depends on sodium superoxide (NaO 2 ) or peroxide (Na 2 O 2 ) being formed/decomposed. Most Na–O 2 batteries form NaO 2 , but reversibility is usually quite limited due to side reactions at interfaces. By using new materials, including a highly active catalyst based on vanadium phosphide (VP) nanoparticles, an ether/ionic liquid‐based electrolyte, and an effective sodium bromide (NaBr) anode protection layer, the sources of interface reactivity can be reduced to achieve a Na–O 2 battery cell that is rechargeable for 1070 cycles with a high energy efficiency of more than 83%. Density functional theory calculations, along with experimental characterization confirm the three factors leading to the long cycle life, including the effectiveness of the NaBr protective layer on the anode, a tetraglyme/EMIM‐BF 4 based electrolyte that prevents oxidation of the VP cathode catalyst surface, and the EMIM‐BF 4 ionic liquid aiding in avoiding electrolyte decomposition on NaO 2 .
Azaribeni, Adel [Department of Chemical and Biolog↗
The effect of dogbone sample size in the tensile testing of TATB-based plastic‑bonded explosive materials
Mechanical properties are of interest for many plastic‑bonded explosive (PBX) materials with tensile properties being of particular interest. Direct tensile measurements using dogbone-shaped samples are considered the gold standard, but they are fairly large, making testing more costly and less desirable from a safety perspective. We investigated whether the measured tensile strength depends on the dogbone specimen size, which to our knowledge, has not been reported in the literature for PBX materials. Understanding this should inform the feasibility of employing smaller samples and how sample size should be considered when comparing PBX dogbone values in the literature. The TATB-based PBX dogbone sample size was varied by (a) scaling all dimensions proportionally and (b) varying only the length of the samples. It was observed that the measured tensile peak stress (strength) was a function of the sample size, and was more dependent on the diameter (cross-sectional area) than the length of the samples. Since peak stress is calculated as peak force normalized to the diameter of the sample, one might not expect an explicit diameter dependence for the peak stress. Therefore, these results suggest there may be an additional strengthening effect as the sample diameter is increased.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Mixture Distribution in a Single-row Radial Engine
The distribution of the fuel among the various cylinders of a Pratt and Whitney 1340 S1H1-G engine was determined by chemically analyzing samples of exhaust gas from each cylinder. The engine was operated in the 20-foot wind tunnel at different power outputs, specific fuel consumptions, and engine speeds. The results showed that the variation in the quality of the mixture among the different cylinders was approximately 4 percent and was independent of power output, specific fuel consumption, and engine speed. The results also showed that the top cylinders operated with a lower air-fuel ratio than the bottom cylinders.
Gerrish, Harold C↗