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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS1993

Liquid oxygen (LO2) propellant conditioning concept testing

Testing of a simplified LO2 propellant conditioning concept for future expendable launch vehicles is discussed. Four different concepts are being investigated: no-bleed, low-bleed, use of a recirculation line, and He bubbling. A full-scale test article, which is a facsimile of a propellant feed duct with an attached section to simulate heat input from an LO2 turbopump, is to be tested at the Cold Flow Facility of the Marshall Space Flight Center West Test Area. Work to date includes: design and fabrication of the test article, design of the test facility and initial fabrication, development of a test matrix and test procedures, initial predictions of test output, and heat leak calibration and heat exchanger tests on the test articles.

Perry, Gretchen L. E.↗
NASA NTRS2005

Tholins as Coloring Agents on Outer Solar System Bodies

The red colors of many solid bodies in outer Solar System may be caused by tholins, which are refractory organic complexes, incorporated in their surface materials. Tholins synthesized in the laboratory are shown to match the colors of these bodies when their optical properties are used in rigorous scattering models. We review recent successes in modeling the spectra of icy outer Solar System bodies with tholins as the coloring agents. New work on the systematic laboratory synthesis and analysis of tholins made by cold plasma discharge in mixtures of gaseous CH4/N2 shows that the composition of the tholin depends strongly on the pressure in the reaction chamber, and only weakly on the mixing fraction of CH4 relative to N2. In tholins made at high pressure (e.g., 23 hPa) the abundance of aliphatic hydrocarbons is greater and the abundance of aromatic hydrocarbons is less than in tholins made at low pressure (e.g., 0.13 hPa). Tholins made at low deposition pressures show a greater abundance of N-H bonds.

Cruikshank, Dale P.↗
NASA NTRS2016

Transient Thermal Analysis of the 12.5 KW HERMeS Hall Thruster

NASA’s Dawn spacecraft entered orbit around the dwarf planet Ceres on March 6, 2015 thereby becoming the first mission to orbit two celestial bodies outside of the Earth-moon system. This feat was made possible due to the use of electric propulsion (EP) to provide the 11 km/s of delta-V that was necessary. This type of propulsion is also enabling for many of NASA’s future missions, such as the proposed Asteroid Redirect Robotic Mission (ARRM). Specifically, the Hall Effect Rocket with Magnetic Shielding (HERMeS) is the propulsive design baseline due to its long operational lifetime and high specific impulse. Extensive modeling is required to verify the thruster's predicted thermal performance and survival during the bounding mission phases. Since the thruster would constrain plasma on the order of tens of thousands of hours, components in the thruster must be able to accommodate much higher sustained temperatures than typical spacecraft hardware. Furthermore, the high temperatures necessitate care in analyzing thermal gradients within the thruster. In this paper, we describe a thermal model of the HERMeS thruster and focus upon the thruster's transient performance under different initial firing conditions. The thruster's transient thermal response is critical to verify margin in the thermal stresses inherent in the thruster and to determine safe start-up procedures to protect the thruster's critical components. This model is used to perform transient thermal analysis of the thruster during startup and shutdown, provide temperature maps for structural analysis, and plan for thermal cycle testing conducted at JPL. The thermal cycle testing includes thruster starts at the cold temperature limits and operation at maximum expected external heat flux. This work will support laboratory environmental testing of the HERMeS thruster, which is being conducted at JPL in 2016.

Reilly, Sean↗
NASA NTRSDate not supplied

Cold Conditions Promote Mg and Si Incorporation in Fe/Si-Rich and Al-Poor X-Ray Amorphous Material in Mars-Relevant Field Environments

X-ray amorphous material that is variably Fe/Si-rich, Al-poor, and volatile containing is prevalent (~15-73 wt.%) within ancient fluvial-lacustrine and eolian sediments examined by the CheMin instrument in Gale crater. Al-rich X-ray amorphous material within Mars-analog environments on Earth has previously been proposed to result from aqueous alteration under cold and icy conditions. However, to the best of our knowledge, no work to date has examined the effects of climate upon the formation of Al-poor and Fe/Si-rich X-ray amorphous material. This study therefore investigates the production of Al-poor and Fe-containing X-ray amorphous material and the chemical heterogeneity within that material under varying temperature conditions to better interpret the formation of Fe-containing X-ray amorphous material detected on Mars.

A D Feldman↗
NASA NTRSDate not supplied

Development and Testing of a Lab-Scale Electrochemical Refrigerator

Eta Space and NASA have been developing a lab-scale electrochemical hydrogen refrigerator (ECHR) capable of providing isothermal heat exchange for applications in the 20-Kelvin range. The cryocooler utilizes an electrochemical compressor paired with Joule-Thomson expansion to cool the hydrogen working fluid down to its saturation point within a purpose-built cold box. The use of electrochemical compression allows the cycle to operate with no moving parts presenting several key advantages for a variety of applications. Testing of the integrated system occurred in Eta Space’s cryogenic test facility where the system was able to achieve and maintain saturated temperatures at low pressure. Results of this test campaign demonstrate the feasibility of the ECHR concept in practice.

D J Hollibaugh↗
DOE OSTI2025

Molecular Mass Growth Processes to Polycyclic Aromatic Hydrocarbons through Radical–Radical Reactions Exploiting Photoionization Reflectron Time-of-Flight Mass Spectrometry

Polycyclic aromatic hydrocarbons (PAHs) represent critical building blocks in molecular mass growth processes to carbonaceous nanoparticles, referred to as interstellar and circumstellar grains along with soot particles in astrophysical environments and combustion systems, respectively. Recent advancements on elucidating elementary steps to PAHs have utilized reactions of aromatic radicals, resonantly stabilized free radicals, and aliphatic radicals with closed shell hydrocarbons. However, the role of radical–radical reactions (RRRs) leading to PAHs has remained largely unexplored on the molecular level due to preceding experimental challenges in producing sufficiently high number densities of radical reactants for isomer-selective detection of products from bimolecular and termolecular reactions. This Account offers the latest developments in our knowledge on the mechanisms and pathways to PAHs via RRRs probed in a chemical microreactor at temperatures as high as 1600 K. Product preservation in a molecular beam coupled with synchrotron vacuum ultraviolet photoionization reflectron time-of-flight mass spectrometry and photoelectron photoion coincidence spectroscopy enabled isomer-selective detection of PAHs of up to three rings by their photoionization efficiency curves, which were fit with a linear combination of reference curves for identification. Experiments were combined with computational fluid dynamics modeling of the physicochemical processes in the microreactor, as well as high-level electronic structure calculations to reveal the reaction pathways of each system. Six distinct reaction mechanisms were discovered in this work: propargyl addition─benzannulation (PABA), methyl addition─ring expansion (MARE), cyclopentadienyl addition─naphthylization (CPAN), fulvenallenyl addition─cyclization─aromatization (FACA), benzyl addition─aromatization (BAA), and phenyl addition─pentacyclization (PAP). By systematically varying the number of carbon atoms in the radical reactants, molecular mass growth processes involving reactions between radicals with odd numbers of carbon atoms access aromatics carrying one, two, or three six-membered rings, whereas reactions between even- and odd-carbon-numbered radicals produce aromatics combining five- and six-membered rings. Our investigations reveal unconventional cycloadditions on excited state triplet surfaces, additions of radicals to low spin density carbon-centered radicals, spiroaromatic and fulvene-type intermediates, and highly strained bicyclic reaction intermediates, challenging current perceptions of PAH molecular mass growth processes. All of the listed mechanisms, except for FACA, feature endoergic reactions or barriers which lie above the separated reactants and therefore might be central to circumstellar environments of carbon-rich stars and planetary nebulae as their descendants, but they play no role in the gas phase of cold molecular clouds where temperatures as low as 10 K dominate. Altogether, this work provides detailed reaction mechanisms of PAH growth processes, advancing our knowledge of the chemistry of carbonaceous matter in the universe.

Addition reactions↗
DOE OSTI2018

Cold rolling texture evolution of TiB2 particle reinforced Al-based composites by Neutron Diffraction and EBSD analysis

Highlights: • Texture development of in-situ TiB{sub 2} particle reinforced Al matrix composites after cold rolling were characterized. • The sum of rolling texture volume fractions has been significantly reduced by the weak texture in particle deformation zone. • Recrystallization nuclei with the Cube and Rotated-Cube orientations were observed in the particle deformation zones. • Small TiB{sub 2} particles within Al grains kept the parallel relationship with surrounding matrix during the deformation. - Abstract: Texture development of particle-reinforced metal matrix materials (P-MMCs) has not been understood well, especially the effects of second-phase particles during the deformation. In this work, we have investigated the texture evolution of TiB{sub 2}/Al composites during cold rolling by Neutron Diffraction and EBSD analysis. Two forms of TiB{sub 2} particles influenced the texture evolution in different ways. The particle-clusters aggregated along grain boundaries led to a reduction of texture volume fraction; recrystallization nuclei with weak texture appeared around these particle-clusters. Small non-shearable TiB{sub 2} particles dispersed inside Al matrix contributed to strong Copper texture component at high strains; the individual particles rotated together with Al matrix during the deformation. These revealed effects of particles on the texture development in TiB{sub 2}/Al composites provide a reference for the texture control of P-MMCs.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Corrosion Behavior of Zinc Cold Spray Coatings in a Simulated Natural Gas Environment Containing H2O, CO2, and H2S

The natural gas transmission pipeline network in the U.S. consists of approximately 300,000 miles, is made mainly of carbon steel, and was installed in the 1950s and 1960s. Understanding the pipeline steel behavior in natural gas will inform new pipeline designs and repurposing of existing pipelines. Sulfide stress cracking (SSC) is a problem for steel pipelines transporting natural gas or CO2 containing partial pressures of H2S higher than 0.3 kPa (0.05 psi). Therefore, the objective of this work is to mitigate internal corrosion in steel pipelines transporting natural gas containing H2S using cold spray coatings.

Belarbi, Zineb↗
NASA NTRS2013

Recirculating 1-K-Pot for Pulse-Tube Cryostats

A paper describes a 1-K-pot that works with a commercial pulse tube cooler for astrophysics instrumentation testbeds that require temperatures <1.7 K. Pumped liquid helium-4 cryostats were commonly used to achieve this temperature. However, liquid helium-4 cryostats are being replaced with cryostats using pulse tube coolers. The closed-cycle 1K-pot system for the pulse tube cooler requires a heat exchanger on the pulse tube, a flow restriction, pump-out line, and pump system that recirculates helium-4. The heat exchanger precools and liquefies helium- 4 gas at the 2.5 to 3.5 K pulse tube cold head. This closed-cycle 1-K-pot system was designed to work with commercially available laboratory pulse tube coolers. It was built using common laboratory equipment such as stainless steel tubing and a mechanical pump. The system is self-contained and requires only common wall power to operate. The lift of 15 mW at 1.1 K and base temperature of 0.97 K are provided continuously. The system can be scaled to higher heat lifts of .30 to 50 mW if desired. Ground-based telescopes could use this innovation to improve the efficiency of existing cryo

Paine, Christopher T.↗
NASA NTRS2011

Charging and Subsequent Dissipation of a Rover Wheel in the Lunar Polar Regions

As a roving vehicle moves along the lunar surface, electric charge will build up through tribo-charging. This charge collected by the roving object will have a dissipative path to either the surface or the ambient plasma, depending upon which path is most conductive. At the lunar terminator region and into nightside regions, the surface is very cold and becomes a very poor conductor. leaving the plasma as the dominant remediating current for dissipation. However, within lunar craters, even plasma currents become substantially reduced which then greatly increases electric 'dissipation times, This work will involve the advancement of the stepping astronaut charge model, by considering the charging and plasma dissipation of a rolling rover wheel, The objective of this work is to determine the nature of charging and discharging for a rover wheel as it rolls along the cold, plasma-starved lunar polar regions. The rotating wheel accumulates charge via contact electrification (tribo-charging) with the lunar regolith. This tribo-charging is dependent on the composition of the objects in contact, with insulators and conductors charging differently. Given the environmental plasma in the region, we then determine the dissipation time for the wheel to bleed off its excess charge into the surrounding plasma. A model of the rover wheel rotating continuously over a surface regolith within a polar crater has been applied. The environmental plasma has been described previously. We define a new tribo-charging term specifically for the rotating system, with charge levels defined as a function of the wheel size, area in contact with the regolith, regolith particle size distribution, as well as the velocity at which the wheel is turning. We recognize that as charged dust accumulates and sticks to the wheel, this behaves effectively as a new current. Hence, the overall charging of the system should no longer vary linearly. and begin to show signs of saturation, We are devising a dust current term to model this charge-limiting effect, and will present the results in discussion.

Jackson, T. L.↗
DOE OSTI2020

Bench Scale Testing of Next Generation Hollow Fiber Membrane Modules

This project seeks to develop a next generation membrane material (PI-2) for application in Air Liquide’s (AL) hybrid process. Combining the cold membrane operation with an integrated CO 2 Compression and Purification Unit (CPU) significantly reduces the overall cost of CO 2 capture. The proposed work will accelerate the membrane bundle fabrication, scale-up and performance validation of this new material. The proposed novel membrane development, combined with the results of the previous Cold Membrane Project, will provide the best opportunity for AL to meet the long term development targets of the DOE with respect to timing, cost, and performance for CO 2 capture. Our previous field test program (DE-FE0013163) showed promising results for the hybrid process utilizing the existing commercial AL membrane bundles (PI-1 material). The project work has also shown the potential for significant improvements through initial laboratory tests with the novel material (PI-2). The initial PI-2 results show a step-change in membrane permeance. This will enable further reduction in the cost of CO 2 capture by reducing the number of membrane modules and associated equipment in the system. In order to capture this value, however, the new material needs to be validated by field testing of large bundles, representative of commercial production. Lastly, a comprehensive evaluation of novel hybrid processes and costs needs to be completed to ensure optimal use of this improved material performance. The current project seeks to develop this next generation membrane to TRL 5 (approximately 600 - 1,000 Nm3/h flue gas, 350 - 600 scfm, 0.2 - 0.3 MWe equivalent). Air Liquide manufacturing methodology will be applied to fabricate prototype (4”) membrane modules from PI-2 material. Once the manufacturing methods prove reliable with the new material, and performance is demonstrated in line with expectation, 6” commercial scale bundles will be fabricated. Recognizing that a low cost membrane solution by itself may not meet DOE’s LCOE target for CO 2 capture, we will also perform simulation studies of novel hybrid processes in combination with the next generation membrane technology. This approach has the best potential for exceeding the DOE targets. The best evaluation of the new commercial units will be performance testing under real flue gas at the NCCC. Finally, a rigorous TEA, which incorporates the novel process studies and field performance, will be completed.

36 MATERIALS SCIENCE↗
NASA NTRS2020

The role of blocking circulation and emerging open water feedbacks on Greenland cold‐season air temperature variability over the last century

Substantial marine, terrestrial, and atmospheric changes have occurred over the Greenland region during the last century. Several studies have documented record‐levels of Greenland Ice Sheet (GrIS) summer melt extent during the 2000s and 2010s, but relatively little work has been carried out to assess regional climatic changes in other seasons. Here, we focus on the less studied cold‐season (i.e., autumn and winter) climate, tracing the long‐term (1873–2013) variability of Greenland's air temperatures through analyses of coastal observations and model‐derived outlet glacier series and their linkages with North Atlantic sea ice, sea surface temperature (SST), and atmospheric circulation indices. Through a statistical framework, large amounts of west and south Greenland temperature variance (up to r^2~50%) can be explained by the seasonally‐contemporaneous combination of the Greenland Blocking Index (GBI) and the North Atlantic Oscillation (NAO; hereafter the combination of GBI and NAO is termed GBI). Lagged and concomitant regional sea‐ice concentration (SIC) and the Atlantic Multidecadal Oscillation (AMO) seasonal indices account for small amounts of residual air temperature variance (r^2<~10%) relative to the GBI. The correlations between GBI and cold‐season temperatures are predominantly positive and statistically‐significant through time, while regional SIC conditions emerge as a significant covariate from the mid‐20th century through the conclusion of the study period. The inclusion of the cold‐season Pacific Decadal Oscillation (PDO) in multivariate analyses bolsters the air temperature variance explained by the North Atlantic regional predictors, suggesting the remote, background climate state is important to long‐term Greenland temperature variability. These findings imply that large‐scale tropospheric circulation has a strong control on surface temperature over Greenland through dynamic and thermodynamic impacts and stress the importance of understanding the evolving two‐way linkages between the North Atlantic marine and atmospheric environment in order to more accurately predict Greenland seasonal climate variability and change through the 21st century.

air temperatures↗
NASA NTRSDate not supplied

An LES Survey of Cold-Air Outbreaks Spanning ACTIVATE and COMBLE

Two recent field campaigns offer unique new opportunities to survey coupled aerosol and cloud processes operating within cold-air outbreaks (CAOs). NASA's 2019-2023 Aerosol Cloud meTeorology Interactions oVer the western Atlantic Experiment (ACTIVATE) project provided airborne in situ and remote sensing observations in multiple CAOs off the central US Eastern Seaboard. Contemporaneously, DOE's 2019-2020 Cold-air Outbreaks in the Marine Boundary Layer Experiment (COMBLE) provided continuous ground-based in situ and remote sensing measurements during hundreds of hours of CAO conditions at two sites flanking the Norwegian Sea. Here we highlight lessons learned from contrasting sets of aerosol-aware Lagrangian large-eddy simulation case studies derived from each campaign, as well as outstanding uncertainties. Cases simulated include all of the most extensively sampled CAO flights during ACTIVATE, and a wide range of CAO strengths and mesoscale structures during COMBLE. Each case study is also suitable for simulation with large-scale models in single-column model mode or with a limited-domain approach using periodic boundary conditions. We seek to address the central question: what microphysical process pathways control the Lagrangian evolution of surface and top-of-atmosphere radiative fluxes under ACTIVATE and COMBLE conditions? Many science team members, co-investigators, and collaborators will be gratefully acknowledged in association with their contributions to making this work possible.

cold-air outbreaks↗
NASA NTRS1986

Life problems of dc and RF-excited low-power CW CO2 waveguide lasers

A number of different, RF-excited 3-W CW CO2 waveguide lasers have been built. Four of these lasers, after continuously working for 15,000-30,000 h, still yield about 70 percent of their original power output. The design variations cover N2and CO-bearing gas mixtures, as well as internal- and external-capacitively coupled excitation electrodes. A similar laser survived 50,000 5-min-ON/5-min-OFF cycles without significant mirror damage. It was not possible to find suitable cold cathodes that allow the building of longitudinally dc-excited CW CO2 waveguide lasers that work for such extended periods of time.

Hochuli, U. E.↗
DOE OSTI2023

The diatom Fragilariopsis cylindrus : A model alga to understand cold-adapted life

Diatoms are significant primary producers especially in cold, turbulent, and nutrient-rich surface oceans. Hence, they are abundant in polar oceans, but also underpin most of the polar food webs and related biogeochemical cycles. The cold-adapted pennate diatom Fragilariopsis cylindrus is considered a keystone species in polar oceans and sea ice because it can thrive under different environmental conditions if temperatures are low. In this perspective paper, we provide insights into the latest molecular work that has been done on F. cylindrus and discuss its role as a model alga to understand cold-adapted life.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1983

A numerical investigation of the President's Day storm of February 18-19, 1979

The reported investigation is based on the use of a three-dimensional, primitive equation model. The President's Day storm, formed in the Gulf of Mexico as a massive anticyclone, affected the northern states with record-breaking cold temperatures. Attention is given to the physical processes relevant to storm formation, the forecast model, a description of experiments and model forecasts, and model results. An attempt is made to determine the important dynamic processes at work during the evolution of the storm. The jet streak interactions which occurred in the cyclogenetic environment, the effects of cold air damming, and the formation of a strong mesoscale coastal front are found to be of particular interest.

Nappi, A. J.↗
DOE OSTI2018

Achieving ultra-high strength and ductility in equiatomic CrCoNi with partially recrystallized microstructures

Despite having otherwise outstanding mechanical properties, many single-phase medium and high entropy alloys are limited by modest yield strengths. Although grain refinement offers one opportunity for additional strengthening, it requires significant and undesirable compromises to ductility. This work therefore explores an alternative, simple processing route to achieve strength by cold-rolling and annealing an equiatomic CrCoNi alloy to produce heterogeneous, partially recrystallized microstructures. Tensile tests reveal that our approach dramatically increases the yield strength (to ~1100 MPa) while retaining good ductility (total elongation ~23%) in the single-phase CrCoNi alloy. Scanning and transmission electron microscopy indicate that the strengthening is due to the non-recrystallized grains retaining their deformation-induced twins and very high dislocation densities. Furthermore, load-unload-reload tests and grain-scale digital image correlation are also used to study the accumulation of plastic deformation in our highly heterogeneous microstructures.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Invigoration or Enervation of Convective Clouds by Aerosols?

Are convective clouds strengthened by the addition of aerosol particles? We present new theoretical calculations which starkly contrast previous results. Prior foundational work suggested that aerosols strongly invigorate convective cloud updrafts via changes to cold-phase processes. We show that the peak magnitude of invigoration by this mechanism is substantially reduced for cold-based storms. For warm-based storms, the updrafts are weakened, not strengthened, by aerosol-induced changes to cold-phase processes. Our calculations show that if invigoration occurs, it is driven primarily by changes to warm-phase processes and may be largest well before the storm reaches maturity. The calculations are based on a new formulation of the moist adiabatic lapse rate that accounts for freezing, supersaturation, and condensate loading. The results significantly reshape our understanding of the impact of aerosols on convective updrafts.

58 GEOSCIENCES↗