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At least 577 records · Page 32

Production and delivery of a fluid mixture to an annular volume of a wellbore

The methods described herein generally relate to preparing and delivering a fluid mixture to a confined volume, specifically an annular volume located between two concentrically oriented casing strings within a hydrocarbon fluid producing well. The fluid mixtures disclosed herein are useful in controlling pressure in localized volumes. The fluid mixtures comprise at least one polymerizable monomer and at least one inhibitor. The processes and methods disclosed herein allow the fluid mixture to be stored, shipped and/or injected into localized volumes, for example, an annular volume defined by concentric well casing strings.

42 ENGINEERING↗

Secondary air injection system and method

According to one embodiment of the invention, a secondary air injection system includes a first conduit in fluid communication with at least one first exhaust passage of the internal combustion engine and a second conduit in fluid communication with at least one second exhaust passage of the internal combustion engine, wherein the at least one first and second exhaust passages are in fluid communication with a turbocharger. The system also includes an air supply in fluid communication with the first and second conduits and a flow control device that controls fluid communication between the air supply and the first conduit and the second conduit and thereby controls fluid communication to the first and second exhaust passages of the internal combustion engine.

42 ENGINEERING↗

A coupled thermo-hydro-mechanical model for simulating leakoff-dominated hydraulic fracturing with application to geologic carbon storage

A potential risk of injecting CO2 into storage reservoirs with marginal permeability (≲ 10 mD (1 mD = 10 –15 m 2 )) is that commercial injection rates could induce fracturing of the reservoir and/or the caprock. Such fracturing is essentially fluid-driven fracturing in the leakoff-dominated regime. Recent studies suggested that fracturing, if contained within the lower portion of the caprock complex, could substantially improve the injectivity without compromising the overall seal integrity. Modeling this phenomenon entails complex coupled interactions among the fluids, the fracture, the reservoir, and the caprock. Here, we develop a simple method to capture all these interplays in high fidelity by sequentially coupling a hydraulic fracturing module with a coupled thermal-hydrological-mechanical (THM) model for nonisothermal multiphase flow. The model was made numerically tractable by taking advantage of self-stabilizing features of leakoff-dominated fracturing. The model is validated against the PKN solution in the leakoff-dominated regime. Moreover, we employ the model to study thermo-poromechanical responses of a fluid-driven fracture in a field-scale carbon storage reservoir that is loosely based on the In Salah project's Krechba reservoir. The model reveals complex yet intriguing behaviors of the reservoir-caprock-fluid system with fracturing induced by cold CO 2 injection. We also study the effects of the in situ stress contrast between the reservoir and caprock and thermal contraction on the vertical containment of the fracture. The proposed model proves effective in simulating practical problems on length and time scales relevant to geological carbon storage.

58 GEOSCIENCES↗

NRAP-Open-IAM Multisegmented Wellbore Reduced-Order Model

Geologic carbon storage is one of the promising strategies to mitigate climate change by reducing the emission of carbon dioxide to the atmosphere. As part of the National Risk Assessment Partnership (NRAP), a systems-level stochastic analysis tool called the open source integrated assessment model, NRAP-Open-IAM, has been developed to estimate and manage the risk of containment loss at a geological carbon sequestration site. NRAP-Open-IAM contains several wellbore leakage model components that estimate the fluid leak rate that may occur through compromised legacy wells due to the increase in pressure resulting from CO 2 injection activities. Coupled to a reservoir component model, these components estimate the leakage of CO 2 and/or brine from a storage reservoir to overlying aquifer layers and the atmosphere through legacy wells. This report presents the theoretical framework and quality testing of the multisegmented wellbore reduced-order model. The model allows for segmenting of the legacy wells passing through the overlying stratigraphy into several intervals to simulate a site’s specific stratigraphic and hydrogeologic properties. For quality assurance, the analytical model is validated against numerical reservoir flow simulations for single and multiple aquifer(s) models. The results indicate that the model accurately predicts the transport of two-phase fluids (brine and injected CO 2 ) through the well over time. A detailed description of the model helps users to understand the model and provides a basis for future improvements.

58 GEOSCIENCES↗

Development of an analytical solution for thermal single-well injection-withdrawal tests in horizontally fractured reservoirs

In this study, we have developed an analytical solution for thermal single-well injection-withdrawal tests in horizontally fractured reservoirs where fluid flow through the fracture is radial. The dimensionless forms of the governing equations and the initial and boundary conditions in the radial flow system can be written in a form identical to those in the linear flow system developed by Jung and Pruess [Jung, Y., and K. Pruess (2012), A Closed-Form Analytical Solution for Thermal Single-Well Injection-Withdrawal Tests, Water Resour. Res., 48, W03504, doi:10.1029/2011WR010979], and therefore the analytical solutions developed in Jung and Pruess (2012) can be applied to compute the time dependence of temperature recovery at the injection/withdrawal well in a horizontally oriented fracture with radial flow.

54 ENVIRONMENTAL SCIENCES↗

Highly resolved Eulerian simulations of fuel spray transients in single and multi-hole injectors: Nozzle flow and near-exit dynamics

In high pressure fuel injectors, needle opening and closing transients cause complex off-design fluid dynamics behaviors that profoundly impact the spray and mixture formation processes. These dynamics are completely different from what is known to occur in steady state conditions. In this study, diesel spray transients have been investigated in single-hole and 3-hole nozzles, encompassing internal and external nozzle flow and including needle motion, performing highly resolved (2.5 μm) computational fluid dynamics (CFD) simulations. We focused on end-of-injection (EOI) and start-of-injection (SOI) processes, in order to provide insights in to the physics. The liquid fuel, vapor and gas species are modeled with a single-fluid multiphase mixture approach, with diffuse interface, and with large eddy simulations (LES) of the turbulence. Occurrence of phase change due to cavitation is accounted for, and the spray dispersion is described with a turbulent dispersion model. Detailed needle motion data and orifice internal surface are available from xray synchrotron source measurements carried out at Argonne National Laboratory, and shared through the Engine Combustion Network (ECN) community. Simulations are compared against x-ray phase contrast imaging and radiography of the internal and near-exit flow, in addition to optical microscopy data of the near-exit sprays. Simulation results are found to agree well with available experimental data, and are able to realistically capture local and global features. The simulations allow to gain insight into the physics of gas ingestion and dribbles at EOI, for different hole diameters, operating conditions and number of holes. At SOI, timing of liquid appearance out of the injector and spray tip penetration are adequately predicted, by using the EOI flow field as in-nozzle initialization, and by prescribing the measured tip needle displacement with an informed effective valve opening point inferred from the x-ray observations. Lastly, the variation of spreading angle over time is also discussed in detail for the multi-hole case, including hole-to-hole variations. Due to real geometry features and asymmetric needle motion with eccentric components, it is found that the three holes exhibit swirling flows of increasing intensity as the lift decreases, causing the near cone angle to open and spread, in a quasi-hollow cone structure. These features are not observed in axial single-hole injectors because of their relative simplicity and intrinsic symmetry.

42 ENGINEERING↗

Performance, Fuel Economy, and Economic Assessment of a Combustion Concept Employing In-Cylinder Gasoline/Natural Gas Blending for Light-Duty Vehicle Applications

In current production natural gas/gasoline bi-fuel vehicles, fuels are supplied via port fuel injection (PFI). Injecting a gaseous fuel in the intake port significantly reduces the volumetric efficiency and consequently torque as compared to gasoline. In addition to eliminating the volumetric efficiency challenge, direct injection (DI) of natural gas (NG) can enhance the in-cylinder flow, mixing, and combustion process resulting in improved efficiency and performance. A computational fluid dynamics (CFD) approach to model high-pressure gaseous injection was developed and validated against X-ray data from Argonne’s Advanced Photon Source. NG side and central DI of various designs and injection strategies were assessed experimentally along with CFD correlation. Significant effects on combustion metrics were quantified and explained via improved understanding of the in-cylinder flow effects due to NG injection. On-demand in-cylinder blending using E10 PFI and NG DI provides an additional lever to adjust in-cylinder turbulence as well as knock resistance across the engine speed and load range. NG DI improves part-load dilution tolerance due to higher in-cylinder turbulence and the high knock resistance of NG compared to E10 improves wide open throttle (WOT) performance while enabling increased compression ratios (CR). Vehicle level simulations suggest that implementing this strategy on a ½ ton pick-up truck with a naturally aspirated engine at 12.5:1 CR improves energy consumption on the aggressive US06 drive cycle by 15.5% compared to E10 operation, and gives a petroleum reduction of 78% over the blended range. There are challenges regarding market acceptance and widespread adoption of dual-fuel NG-gasoline vehicle applications beyond the performance degradation when the vehicle runs out of natural gas. Furthermore, those challenges include practical concerns such as loss of cargo volume and payload due to the NG storage tank, extended NG refueling times, fueling convenience due to gasoline and NG fuel tanks, and limited NG fueling infrastructure.

33 ADVANCED PROPULSION SYSTEMS↗

Gulf of Mexico miocene CO₂ site characterization mega transect

This project characterized the Miocene-age sub-seafloor stratigraphy in the near-offshore portion of the Gulf of Mexico adjacent to the Texas coast. The large number of industrial sources of carbon dioxide (CO₂) in coastal counties and the high density of onshore urbanization and environmentally sensitive areas make this offshore region extremely attractive for long-term storage of carbon dioxide emissions from industrial sources (CCS). The study leverages dense existing geologic data from decades of hydrocarbon exploration in and around the study area to characterize the regional geology for suitability and storage capacity. Primary products of the study include: regional static storage capacity estimates, sequestration “leads” and prospects with associated dynamic capacity estimates, experimental studies of CO₂-brine-rock interaction, best practices for site characterization, a large-format ‘Atlas’ of sequestration for the study area, and characterization of potential fluid migration pathways for reducing storage risks utilizing novel high-resolution 3D (HR3D) seismic surveys. In addition, three subcontracted studies address source-to-sink matching optimization, offshore well bore management and environmental aspects. The various geologic data and interpretations are integrated and summarized in a series of cross-sections and maps, which represent a primary resource for any near-term commercial deployment of CCS in the area. The regional study characterized and mapped important geologic features (e.g., Clemente-Tomas fault zone, the regionally extensive Marginulina A and Amphistegina B confining systems, etc.) that provided an important context for regional static capacity estimates and specific sequestration prospects of the study. A static capacity estimate of the majority of the Study area (14,467 mi 2 ) was estimated at 86 metric Gigatonnes. While local capacity estimates are likely to be lower due to reservoir-scale characteristics, the offshore Miocene interval is a storage resource of National interest for providing CO₂ storage as an atmospheric emissions abatement strategy. The natural petroleum system was used as an analog to infer seal quality and predict possible migration pathways of fluids in an engineered system of anthropogenic CO₂ injection and storage. The regional structural features (e.g., Clemente-Tomas fault zone) that exert primary control on the trapping and distribution of Miocene hydrocarbons are expected to perform similarly for CCS. Industrial-scale CCS will require storage capacity utilizing well-documented Miocene hydrocarbon (dominantly depleted gas) fields and their larger structural closures, as well as barren (unproductive, brine-filled) closures. No assessment was made of potential for CO₂ utilization for enhanced oil and gas recovery. The use of 3D numerical fluid flow simulations have been used in the study to greatly assist in characterizing the potential storage capacity of a specific reservoir. Due to the complexity of geologic systems (stratigraphic heterogeneity) and inherent limitations on producing a 3D geologic model, these simulations are typically simplified scenarios that explore the influence of model property variability (sensitivity study). A specific site offshore San Luis Pass (southern Galveston Island) was undertaken successfully, indicating stacked storage potential. Downscaling regional capacity estimates to the local scale (and the inverse) has proven challenging, and remains an outstanding gap in capacity assessments. In order to characterize regional seal performance and identify potential brine and CO₂ leakage pathways, results from three high-resolution 3D (HR3D) seismic datasets acquired by the study using novel HR3D (P-Cable) acquisition system showed steady and significant improvements in data quality because of improved acquisition and processing technique. Finely detailed faults and stratigraphy in the shallowest 1000 milliseconds (~800 m) of data allowed for the identification and mapping of unconformable surfaces including what is probably a surface associated with the last Pleistocene glacial lowstand. The identification of a previously unrecognized (in commercial seismic data) gas chimney that was clearly defined in the 2013 HR3D survey, indicates that HR3D surveys may be useful as both a characterization tool for the overburden of a potential carbon sequestration site and as an additional monitoring tool for future engineered injection sites. Geochemical modeling indicated that injection of CO₂ would result in minor dissolution of calcite, K-feldspar and albite. In addition, modeling of typical brines in Miocene age rocks indicate that approximately 5% of injection capacity would result from CO₂ dissolution into the brine. After extensive searches, no rock samples of the Marginulina A and Amphistegina B seals (“caprocks”) were obtained, but analyses of available core samples of other Miocene age mudrocks (seals or caprocks) indicate that they have sealing ability sufficient for potential CO 2 storage in underlying sandstone units.

01 COAL, LIGNITE, AND PEAT↗

Systems and methods for preventing flashback in a combustor assembly

Embodiments of the present application include a combustor assembly. The combustor assembly may include a combustion chamber, a first plenum, a second plenum, and one or more elongate air/fuel premixing injection tubes. Each of the elongate air/fuel premixing injection tubes may include a first length at least partially disposed within the first plenum and configured to receive a first fluid from the first plenum. Moreover, each of the elongate air/fuel premixing injection tubes may include a second length disposed downstream of the first length and at least partially disposed within the second plenum. The second length may be formed of a porous wall configured to allow a second fluid from the second plenum to enter the second length and create a boundary layer about the porous wall.

33 ADVANCED PROPULSION SYSTEMS↗

Compositional simulation of hydrocarbon recovery from oil shale reservoirs with diverse initial saturations of fluid phases by various thermal processes

We have studied the hydrocarbon production from oil shale reservoirs filled with diverse initial saturations of fluid phases by implementing numerical simulations of various thermal in-situ upgrading processes. We use our in-house fully functional, fully implicit, and non-isothermal simulator, which describes the in-situ upgrading processes and hydrocarbon recovery by multiphase-multicomponent systems. We have conducted two sets of simulation cases—five-spot well pattern problems and Shell In-situ Conversion Process (ICP) problems. In the five-spot well pattern problems, we have analyzed the effects of initial fluid phase that fills the single-phase reservoir and thermal processes by four cases—electrical heating in the single-phase-aqueous reservoir, electrical heating in the single-phase-gaseous reservoir, hot water injection in the single-phase-aqueous reservoir, and hot CO 2 -injection in the single-phase-gaseous reservoir. In the ICP problems, we have analyzed the effects of initial saturations of fluid phases that fill two-phase-aqueous-and-gaseous reservoir by three cases—initial aqueous phase saturations of 0.16, 0.44, and 0.72. Through the simulation cases, system response and production behavior including temperature profile, kerogen fraction profile, evolution of effective porosity and absolute permeability, phase production, and product selectivity are analyzed. In the five-spot well pattern problems, it is found that the hot water injection in the aqueous phase reservoir shows the highest total hydrocarbon production, but also shows the highest water-oil-mass-ratio. Productions of phases and components show very different behavior in the cases of electrical heating in the aqueous phase reservoir and the gaseous phase reservoir. In the ICP problems, it is found that the speed of kerogen decomposition is almost identical in the cases, but the production behavior of phases and components is very different. It is found that more liquid organic phase has been produced in the case with the higher initial saturation of aqueous phase by the less production of gaseous phase.

04 OIL SHALES AND TAR SANDS↗

Heavy Oil Polymer EOR in the Challenging Alaskan Arctic - It Works!

Under co-sponsorship of the US Department of Energy and Hilcorp Alaska LLC the first ever polymer field pilot commenced on 8/28/2018 in the Schrader Bluff heavy oil reservoir at the Milne Point Field on Alaska North Slope (ANS). The primary objective of the pilot is to prove the efficacy of polymer Enhanced Oil Recovery (EOR) to unlock the vast heavy oil resources on ANS. More than two and half years after startup, the polymer injection, supporting laboratory experiments and simulation studies steadily continue. The pilot started injecting hydrolyzed polyacrylamide (HPAM), at a concentration of 1,750 ppm to achieve a target viscosity of 45 cP, into the two horizontal injectors in the flood pattern. Production is monitored in the two horizontal producers. Based on laboratory measurements of polymer viscosity at reservoir conditions, the team decided to reduce polymer concentration to 1,200 ppm since July 2020 in an effort to control injection pressure and optimize polymer utilization. Quality control (QC) on the field ensures uniform polymer solution properties. Representative rock and fluid systems and test conditions are utilized in the corefloods on polymer retention, effect of injection water salinity, polymer loading, and their combinations on oil recovery. A history matched reservoir simulation model for forecasting oil recovery was developed on the basis of all the available field data. Field concerns related to the post-polymer breakthrough impact on flow assurance is addressed via specialized laboratory tests. Notwithstanding early operational disruptions and hydration issues, continuous polymer injection in both injectors has been achieved. To date, 950,000 lbs of polymer or 2 million barrels of polymer solution, equating to 13% of total pore volume (PV), has been placed in the flood pattern, serving as an effective indicator of adequate polymer injectivity. So far, the success of polymer EOR is evident from drastically reduced water cut in the producers, an estimated incremental 1,000 bopd over waterflood, and a favorable polymer utilization of 1.7 lbs/barrel of incremental oil. Polymer breakthrough was observed 26 months after the start of polymer injection. Main observations from corefloods are unusually high polymer retention values in some cases and a positive response to low salinity water. Although the heterogeneity in the flood pattern and exceptionally low water cut pose some challenges, persistent novel and justifiable simulation approaches have resulted in a robust history matched model. Experimental results on produced fluids treatment provide operational guidance for improved oil-water separation and mitigation of heater tube fouling. The ongoing success of the pilot is a key indicator of bringing the team ever closer to meeting the project’s primary objective. The encouraging results of the pilot is one of the drivers that has provided the impetus to apply polymer EOR throughout the Milne Point Field, which would increase oil recovery and extend the economic life of the Trans Alaska Pipeline System. The scientific knowledge, including the many lessons learned from this pilot also has referential value for other potential heavy oil EOR projects throughout the world. The collected data, operational lessons learned, and the overall success of the pilot are summarized in the paper.

None, None↗

Small Scale Field Test Demonstrating CO 2 Sequestration In Arbuckle Saline Aquifer And By CO 2 -Eor At Wellington Field, Sumner County, Kansas

The objectives of this project are to understand the processes that occur when a maximum of 70,000 metric tonnes of CO 2 are injected into two different formations to evaluate the response in different lithofacies and depositional environments. The evaluation will be accomplished through the use of both in situ and indirect MVA (monitoring, verification, and accounting) technologies. The project will optimize for carbon storage accounting for 99% of the CO 2 using lab and field testing and comprehensive characterization and modeling techniques. Site characterization and CO 2 injection should demonstrate state-of-the-art MVA tools and techniques to monitor and visualize the injected CO 2 plume and to refine geomodels developed using nearly continuous core, exhaustive wireline logs, and well tests and a multi-component 3-D seismic survey. Reservoir simulation studies will map the injected CO 2 plume and estimate tonnage of CO 2 stored in solution, as residual gas, and by mineralization and integrate MVA results and reservoir models shall be used to evaluate CO 2 leakage. A rapid-response mitigation plan was developed to minimize CO 2 leakage and provide a comprehensive risk management strategy. The CO 2 was intended to be supplied from a reliable facility and have an adequate delivery and quality of CO 2 . However, several unforeseen circumstances complicated this plan: (1) the initially negotiated CO 2 supply facility went offline and contracts associated with CO 2 supply had to be renegotiated, (2) a UIC Class VI permit proved to be difficult to obtain due to the experimental nature of the project. Both subjects are detailed in separate deliverables attached to this report. The CO 2 enhanced oil recovery (EOR) and geologic storage in Mississippian carbonate reservoir was sucessully deployed. Approximately 20,000 metric tons of CO 2 was injected in the upper part of the Mississippian reservoir to verify CO 2 EOR viability in carbonate reservoirs and evaluate a potential of transitioning to geologic CO 2 storage through EOR. A total of 1,101 truckloads, 19,803 metric tons—an average of 120 tonnes per day—were delivered over the course of injection that lasted from January 9 to June 21, 2016. After cessation of CO 2 injection, the KGS 2-32 well was converted to water injector and continues to operate. CO 2 EOR progression in the field was monitored weekly with fluid level, temperature, and production recording and formation fluid composition sampling. It is important to note that normally, CO 2 EOR pilots are less efficient than commercial operations due to lack of directional and precise well control, lack of surface facilities for CO 2 recycling, and other factors. As a result of this pilot CO 2 injection, the observed incremental average oil production increase was ~68% with only ~18% of injected CO 2 produced back. Decline curve analysis forecasts of additional cumulative oil produced were 32.44M STB to the end of 2027. Wellington Mississippian pilot efficiency by the end of forecast calculations is 11 MCF per barrel of produced oil. Using 32M STB oil production and $1,964,063 cost of CO 2 , CO 2 EOR cost per barrel of oil production is ~$60. Simple but robust monitoring technologies proved to be very efficient in detecting and locating CO 2 . High CO 2 reservoir retentions with low yields within an actively producing field could help to estimate real-world risks of CO 2 geological storage for future projects. The Wellington Field CO 2 EOR was executed in a controlled environment with high efficiency. This case study proves that CO 2 EOR could be successfully applied in Kansas carbonate reservoirs if CO 2 sources and associated infrastructure are available. Recent developments in unconventional resources development in Mid-Continent USA and associated large volume disposal of backflow water and the resulting seismic activity have brought more focus and attention to the Arbuckle Group in southern Kansas. Despite the commercial interest, limited essential information about reservoir properties and structural elements has impeded the management and regulation of disposal, an issue brought to the forefront by recent seismicity in and near areas of large volumes and rates of brine disposal. The Kansas Geological Survey (KGS) collected, compiled, and analyzed available data, including well logs, core data, step rate tests, drill stem tests, 2-D and 3-D seismic data, water level measurements, and others types of data. Several exploratory wells were drilled and core was collected and modern suites of logs were analyzed. Reservoir properties were populated into several site-specific geological models. The geological models illustrate the highly heterogeneous nature of the Arbuckle Group. Vertical and horizontal variability results in several distinct hydro-stratigraphic units that are the result of both depositional and diagenetic processes. During the course of this project, it has been demonstrated that advanced seismic interpretation methods can be used successfully for characterization of the Mississippian reservoir and Arbuckle saline aquifer. Analysis of post-stack 3-D seismic data at the Mississippian reservoir showed the response of a gradational velocity transition. Pre-stack gather analysis showed that porosity zones of the Mississippian and Arbuckle reservoirs exhibit characteristic amplitude versus offset (AVO) response. Simultaneous AVO inversion estimated P- and S-impedances. The 3-D survey gather azimuthal anisotropy analysis (AVAZ) provided information about the fault and fracture network and showed good agreement to the regional stress field and well data. Mississippian reservoir porosity and fracture predictions agreed well with the observed mobility of injected CO 2 in KGS well 2-32. Fluid substitution modeling predicted acoustic impedance reduction in the Mississippian carbonate reservoir introduced by the presence of CO 2 . Seismicity in the United States midcontinent has increased by orders of magnitude over the past decade. Spatiotemporal correlations of seismicity to wastewater injection operations have suggested that injection-related pore fluid pressure increases are inducing the earthquakes. In this investigation, we examine earthquake occurrence in southern Kansas and northern Oklahoma and its relation to the change in pore pressure. The main source of data comes from the Wellington Array in the Wellington oil field, in Sumner County, Kansas, which has monitored for earthquakes in central Sumner County, Kansas, since early 2015. The seismometer array was established to monitor CO 2 injection operations at Wellington Field. Although no seismicity was detected in association with the spring 2016 Mississippian CO 2 injection, the array has recorded more than 2,500 earthquakes in the region and is providing valuable understanding to induced seismicity. A catalog of earthquakes was built from this data and was analyzed for spatial and temporal changes, stress information, and anisotropy information. The region of seismic concern has been shown to be expanding through use of the Wellington earthquake catalog, which has revealed a northward progression of earthquake activity reaching the metropolitan area of Wichita. The stress orientation was also calculated from this earthquake catalog through focal mechanism inversion. The calculated stress orientation was confirmed through comparison to other stress measurements from well data and previous earthquake studies in the region. With this knowledge of the stress orientation, the anisotropy in the basement could be understood. This allowed for the anisotropy measurements to be correlated to pore pressure increases. The increase in pore pressure was monitored through time-lapse shear-wave anisotropy analysis. Since the onset of the observation period in 2010, the orientation of the fast shear wave has rotated 90°, indicating a change associated with critical pore pressure build up. The time delay between fast and slow shear wave arrivals has increased, indicating a corresponding increase in anisotropy induced by pore pressure rise. In-situ near-basement fluid pressure measurements corroborate the continuous pore pressure increase revealed by the shear-wave anisotropy analysis over the earthquake monitoring period. This research is the first to identify a change in pore fluid pressure in the basement using seismological data and it was recently published in the AAAS journal Science Advances (Nolte et al., 2017). The shear-wave splitting analysis is a novel application of the technique, which can be used in other regions to identify an increase in pore pressure. This increasing pore fluid pressure has become more regionally extensive as earthquakes are occurring in southern Kansas, where they previously were absent. These monitoring techniques and analyses provide new insight into mitigating induced seismicity’s impact on society.

02 PETROLEUM↗

Panel fuel injector

The present disclosure is directed to a panel fuel injector having a first side wall that defines a plurality of first side injection outlets and a second side wall that defines a plurality of second side injection outlets. A premix air plenum, a fuel plenum, a plurality of first side premixing channels and a plurality of second side premixing channels are defined between the first side wall and the second side wall. Each first side premixing channel is in fluid communication with the premix air plenum, the fuel plenum and a respective first side injection outlet of the plurality of first side injection outlets. Each second side premixing channel is in fluid communication with the premix air plenum, the fuel plenum and a respective second side injection outlet of the plurality of second side injection outlets.

42 ENGINEERING↗

Data supporting the article titled "Heterogeneous Multiphase Flow Properties of Volcanic Rocks and Implications for Noble Gas Transport from Underground Nuclear Explosions"

The submission is a Reproducible Research (RR) data archive that contains the supporting multiphase fluid flow and curve fitting results of the Vadose Zone Journal article titled: "Heterogeneous Multiphase Flow Properties of Volcanic Rocks and Implications for Noble Gas Transport from Underground Nuclear Explosions." The article's DOI number is the following: https://doi.org/10.1002/vzj2.20123. Please see the "Methods and Materials" section of the journal article and the ReadMe.txt in the RR_ARCHIVE folder for further details. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525. SAND Number: SAND2021-3407 O.

mercury injection capillary pressure↗

A unified non-equilibrium phase change model for injection flow modeling

The homogenous relaxation model (HRM) is one of the most widely used models to describe the liquid- gas phase transition. However, in its original formulation, it is unable to handle multispecies vapor-liquid equilibrium (VLE), which limits its applicability to single-component fluids. In this work, a unified non-equilibrium phase change model that considers the VLE of multicomponent mixtures is proposed building upon the HRM's structure. A time factor is introduced to mimic the effect of different phase change timescales due to different mechanisms, e.g., cavitation, flash-boiling, and evaporation. Here to assess the model's performance, computational fluid dynamics simulations of the internal and near-nozzle injection flow of the Engine Combustion Network's Spray G injector were performed using the nine-component PACE-20 fuel with both the unified model and the original HRM. The predicted fuel density in the near-nozzle region matched well with X-ray tomography measurements. The simulation results indicated that, whereas the HRM failed to capture the vaporization due to convective mixing between the fuel and ambient gas, the unified model performed well in predicting the mixing-driven vaporization and the corresponding evaporative cooling. Further comparisons using the nine-component fuel formula and a single-component fuel surrogate demonstrated the unified model's ability to predict preferential vaporization, which affects the predictions of local mixture composition and rate of vaporization. Finally, it is shown that the unified model is capable of representing multiple phase change mechanisms, and the relaxation time factor plays an important role in determining the degree of phase change due to the different mechanisms.

33 ADVANCED PROPULSION SYSTEMS↗

Benefits and Costs of Brine Extraction for Increasing Injection Efficiency In geologic CO2 Sequestration

Pressure increases attendant with CO2 injection into the subsurface drive many of the risk factors associated with commercial-scale CCS projects, impacting project costs and liabilities in a number of ways. The area of elevated pressure defines the area that must be characterized and monitored; pressure drives fluid flow out of the storage reservoir along higher-permeability pathways that might exist through the caprock into overlying aquifers or hydrocarbon reservoirs; and pressure drives geomechanical changes that could potentially impact subsurface infrastructure or the integrity of the storage system itself. Pressure also limits injectivity, which can increase capital costs associated with installing additional wells to meet a given target injection rate. The ability to mitigate pressure increases in storage reservoirs could have significant value to a CCS project, but these benefits are offset by the costs of the pressure mitigation technique itself. Of particular interest for CO2 storage operators is the lifetime cost of implementing brine extraction at a CCS project site, and the relative value of benefits derived from the extraction process. This is expected to vary from site to site and from one implementation scenario to the next. Indeed, quantifying benefits against costs could allow operators to optimize their return on project investment by calculating the most effective scenario for pressure mitigation. This work builds on research recently submitted for publication by the authors examining the costs and benefits of brine extraction across operational scenarios to evaluate the effects of fluid extraction on injection rate to assess the cost effectiveness of several options for reducing the number of injection wells required. Modeling suggests that extracting at 90% of the volumetric equivalent of injection rate resulted in a 1.8% improvement in rate over a non-extraction base case; a four-fold increase in extraction rate results in a 7.6% increase in injection rate over the no-extraction base case. However, the practical impacts on capital costs suggest that this strategy is fiscally ineffective when evaluated solely on this metric, with extraction reducing injection well needs by only one per 56 (1x case) or one per 13 (4x case).

54 ENVIRONMENTAL SCIENCES↗

Feasibility of a Deep Direct-Use Geothermal System at the University of Illinois Urbana-Champaign

This study assesses the feasibility of using deep direct-use (DDU) geothermal energy in agricultural research facilities on the University of Illinois at Urbana-Champaign campus to exploit low-temperature sedimentary basins, such as the Illinois Basin. Subsurface components of the system include extraction and injection wells and downhole pumps. Surface equipment includes heat pumps/exchangers, and fluid transport and monitoring systems. Two geologic formations in the region exhibit a potential as sources for geothermal energy, based on pre initial temperatures and flow rates of fluids. The St. Peter and Mt. Simon Sandstones lie at depths of 634 and 1,280 m, respectively. Geocellular modeling is used to characterize the reservoirs. A St. Peter Sandstone model was made for an area south of the campus. Petrophysical and geothermal properties used are based on data from the closest wells penetrating the formations. Characterization of the Mt. Simon Sandstone is in progress and is not discussed here. Extraction and injection flows simulated with different wellbore configurations provide estimates of fluid flow out of and into the reservoir. The models are used to optimize flow rates, bottomhole pressure, and temperature of the produced fluid. Individual wellbore models simulate subsurface heat loss and gain, providing guidance on the optimal type and amount of insulation in the wellbore. Design of the surface facilities will address aspects of fluid delivery, heat exchange, capital operating costs, heat loss, and corrosion. Heat capacity and flow rates are assessed to estimate life-cycle costs and benefits, including the environmental benefits of reducing greenhouse gases and water use and increased energy efficiency. A preliminary analysis of surface configurations for the DDU system (including cascading applications) based on building heat loads is being conducted to identify multiple system designs that will maximize performance, energy efficiency, and cost recovery.

15 GEOTHERMAL ENERGY↗

Multichannel pumps and applications of same

A push-pull micropump includes one or more pairs of channels configured to transfer one or more fluids, each channel pair having an aspiration channel and an injection channel; and an actuator configured to engage the one or more pairs of channels, wherein the actuator comprises a plurality of rolling members and a driving member configured such that when the driving member rotates, the plurality of rolling members rolls along the one or more pairs of channels to cause individually the one or more fluids to transfer through each channel pair simultaneously at different flowrates or the same flowrate, depending upon actuated lengths of the aspiration and injection channels of each channel pair, wherein an actuated length of a channel is defined by a length of the channel along which the plurality of rolling members rolls during a full rotation of the driving member.

Wikswo, John P.↗