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AVIRIS calibration and application in coastal oceanic environments

The Airborne Visible-Infrared Imaging Spectrometer (AVIRIS) is a test-bed for future spacecraft sensors such as the High-Resolution Imaging Spectrometer and the Moderate-Resolution Imaging Spectrometers planned for the Earth Observing System. To use this sensor for ocean applications, S/N was increased by spatial averaging of images. Post-flight recalibration was accomplished by measuring in situ the water-leaving radiance at flight time, modeling its transmission to the aircraft, and adding modeled atmospheric radiance to that value. The preflight calibration curve was then adjusted until aircraft and modeled total radiance values matched. Water-leaving radiance values from the recalibrated AVIRIS imagery were consistent with in situ data supporting the validity of the approach. Imagery of the absorption coefficient at 415 nm and backscattering coefficient at 671 nm were used to depict the dissolved and particulate constituents of the Tampa Bay plume during late, ebb-tidal conditions.

Carder, Kendall L.↗

Concept for a high-resolution thermometer utilizing the temperature dependence of the magnetic penetration depth

A thermometer using the temperature dependence of the magnetic penetration depth in superconductors is described which has the potential for temperature resolution, when using a dc SQUID readout, on the order of 1 pK. One such device has been fabricated and characterized to demonstrate proof of concept. It consists of primary and secondary coils of NbTi wire wound on a copper toroidal core on which a thin layer of In (Tc = 3.4 K) has been deposited. The temperature dependence of the mutual inductance, M(T), or self-inductance, is used to detect changes in temperature. Measurements of M(T) have been made with an ac excitation of the primary for various frequencies and peak magnetic field strengths. Estimates of ultimate temperature resolution are given.

Shirron, P. J.↗

Isotopic composition and concentration of sulfur in carbonaceous chondrites

New sulfur isotopic ratio measurements are reported for seven carbonaceous chondrites. Newly developed procedures permit measurement of delta S-33, delta S-34, and delta S-36 at precisions significantly greater than previously reported. A search for S-36 nucleosynthetic anomalies coproduced with anomalies in, for example, Ti-50 and Ca-48 was negative. The high endemic sulfur concentration probably dilutes any S-36 anomaly, and separation of individual sulfur phases may be needed to identify S-36 carrier phases. Large internal isotopic variations are observed, deriving from parent body and possibly nebular processes. Chondrule separates from Allende demonstrate isotopic compositions which vary as a function of diameter. High-temperature gas-solid exchange and a two-component mixing model may account for the observations. High-resolution isotopic data and structural information are reported for organic sulfur compounds separated by chemical extractions. The insoluble organics appear to be of either aliphatic or alicyclic structure and are dominant phases.

Gao, Xia↗

Optical studies of interstellar material in low density regions of the Galaxy. I - A survey of interstellar Na I and Ca II absorption toward 57 distant stars

We present high-resolution spectra of the Na I D and Ca II K lines toward 57 late-O and early-B stars along extended (d greater than 1 kpc) low-density paths through the Milky Way disk and halo. The sight lines preferentially sample diffuse gas in the interstellar medium (ISM) along interarm, Galactic center, and high latitude directions. We measure equivalent widths, apparent column densities, and absorption component structure. The Ca II to Na I ratios presented as a function of velocity for each sight line exhibit variations due to elemental depletion, ionization, and density enhancements. Absorption along high latitude sight lines is kinematically simpler than it is along interarm and Galactic center sight lines. Galactic rotation noticeably broadens the absorption profiles of distant stars located in these latter directions. Along several sight lines, we see Ca II absorption at velocities corresponding to large distances (/z/ about 1 kpc) from the Galactic plane. The effects of differences in the Ca II and Na I scale heights and nonzero velocity dispersions are readily apparent in the data. Brief notes are given for several sight lines with interesting absorption properties.

Sembach, K. R.↗

High-resolution X-ray spectroscopy of the supernova remnant N132D

A joint nonequilibrium ionization analysis of spectral data from the Einstein Observatory of the SNR N132D in the LMC is presented on the basis of data from the Focal Plane Crystal Spectrometer (FPCS) and the Solid State Spectrometer (SSS), and lower spectral resolution data from the IPC and the Monitor Proportional Counter (MPC). The FPCS detected individual emission lines of O VII, O VIII, Ne IX, Ne X, Fe XVII, and possibly Fe XX. Measured line widths for the oxygen lines suggest Doppler broadening that is roughly consistent with optically measured expansion velocities of 2250 km/s. At the SSS/IPC temperature, FPCS flux ratios constrain the O/Fe abundance to be at least 1.9 times its solar value and the O/Ne abundance to be 0.2-1.0 times its solar value. Models for remnants with progenitor masses of 20 and 25 solar masses are completely consistent with the data, while remnants with progenitor masses of 13 and 15 solar masses can be made consistent if the progenitors are required to eject a large fraction of their iron cores.

Hwang, Una↗

Multi-beam laser altimeter

Laser altimetry provides a high-resolution, high-accuracy method for measurement of the elevation and horizontal variability of Earth-surface topography. The basis of the measurement is the timing of the round-trip propagation of short-duration pulses of laser radiation between a spacecraft and the Earth's surface. Vertical resolution of the altimetry measurement is determined primarily by laser pulsewidth, surface-induced spreading in time of the reflected pulse, and the timing precision of the altimeter electronics. With conventional gain-switched pulses from solid-state lasers and sub-nsec resolution electronics, sub-meter vertical range resolution is possible from orbital attitudes of several hundred kilometers. Horizontal resolution is a function of laser beam footprint size at the surface and the spacing between successive laser pulses. Laser divergence angle and altimeter platform height above the surface determine the laser footprint size at the surface, while laser pulse repetition-rate, laser transmitter beam configuration, and altimeter platform velocity determine the space between successive laser pulses. Multiple laser transitters in a singlaltimeter instrument provide across-track and along-track coverage that can be used to construct a range image of the Earth's surface. Other aspects of the multi-beam laser altimeter are discussed.

Bufton, Jack L.↗

AVIRIS calibration and application in coastal oceanic environments

The Airborne Visible-Infrared Imaging Spectrometer (AVIRIS) is a test-bed for future spacecraft sensors such as the High-Resolution Imaging Spectrometer and the Moderate-Resolution Imaging Spectrometers planned for the Earth Observing System. To use this sensor for ocean applications, S/N was increased by spatial averaging of images. Post-flight recalibration was accomplished using in situ the water-leaving radiance measured at flight time, modeling radiance transmission to the aircraft, and adding modeled atmospheric radiance to that value. The preflight calibration curve was then adjusted until aircraft and modeled total radiance values matched. Water-leaving radiance values from the recalibrated AVIRIS imagery were consistent with in situ data supporting the validity of the approach. Imagery of the absorption coefficient at 415 nm and backscattering coefficient at 671 nm were used to depict the dissolved and particulate constituents of an ebb-tidal esturance plume on the East coast of Florida.

Carder, Kendall L.↗

Direct numerical simulations and modeling of a spatially-evolving turbulent wake

Understanding of turbulent free shear flows (wakes, jets, and mixing layers) is important, not only for scientific interest, but also because of their appearance in numerous practical applications. Turbulent wakes, in particular, have recently received increased attention by researchers at NASA Langley. The turbulent wake generated by a two-dimensional airfoil has been selected as the test-case for detailed high-resolution particle image velocimetry (PIV) experiments. This same wake has also been chosen to enhance NASA's turbulence modeling efforts. Over the past year, the author has completed several wake computations, while visiting NASA through the 1993 and 1994 ASEE summer programs, and also while on sabbatical leave during the 1993-94 academic year. These calculations have included two-equation (K-omega and K-epsilon) models, algebraic stress models (ASM), full Reynolds stress closure models, and direct numerical simulations (DNS). Recently, there has been mutually beneficial collaboration of the experimental and computational efforts. In fact, these projects have been chosen for joint presentation at the NASA Turbulence Peer Review, scheduled for September 1994. DNS calculations are presently underway for a turbulent wake at Re(sub theta) = 1000 and at a Mach number of 0.20. (Theta is the momentum thickness, which remains constant in the wake of a two dimensional body.) These calculations utilize a compressible DNS code written by M. M. Rai of NASA Ames, and modified for the wake by J. Cimbala. The code employs fifth-order accurate upwind-biased finite differencing for the convective terms, fourth-order accurate central differencing for the viscous terms, and an iterative-implicit time-integration scheme. The computational domain for these calculations starts at x/theta = 10, and extends to x/theta = 610. Fully developed turbulent wake profiles, obtained from experimental data from several wake generators, are supplied at the computational inlet, along with appropriate noise. After some adjustment period, the flow downstream of the inlet develops into a fully three-dimensional turbulent wake. Of particular interest in the present study is the far wake spreading rate and the self-similar mean and turbulence profiles. At the time of this writing, grid resolution studies are underway, and a code is being written to calculate turbulence statistics from these wake calculations; the statistics will be compared to those from the ongoing PIV wake measurements, those of previous experiments, and those predicted by the various turbulence models. These calculations will lead to significant long-term benefits for the turbulence modeling effort. In particular, quantities such as the pressure-strain correlation and the dissipation rate tensor can be easily calculated from the DNS results, whereas these quantities are nearly impossible to measure experimentally. Improvements to existing turbulence models (and development of new models) require knowledge about flow quantities such as these. Present turbulence models do a very good job at prediction of the shape of the mean velocity and Reynolds stress profiles in a turbulent wake, but significantly underpredict the magnitude of the stresses and the spreading rate of the wake. Thus, the turbulent wake is an ideal flow for turbulence modeling research. By careful comparison and analysis of each term in the modeled Reynolds stress equations, the DNS data can show where deficiencies in the models exist; improvements to the models can then be attempted.

Cimbala, John M.↗

Hubble Space Telescope Goddard high-resolution spectrograph H2 rotational spectra of Jupiter's aurora

We have observed the emission spectrum from Jupiter's north auroral atmosphere with 0.57 A spectral resolution over 1204-1241 A. Bright emissions have been detected from 50 deg to 60 deg latitude at locations consistent with 6 to 30 R (sub J) auroral ovals, with much fainter emissions away form the auroral ovals. The emission spectrum is well fitted by both laboratory spectra and theoretical models of optically thin electron excited H2, with added Doppler-broadened Lyman Alpha emission. The observed Lyman Alpha emission wings extend more than 1 A from line center and appear correlated in strength with the H2 brightness. Individual rotational lines in the H2 Werner band system are resolved, allowing a determination of the H2 rotational temperature at the altitude of the emission. We derive best-fit temperatures from 400-450 to 700-750 K, with the auroral emission layer temperature changing either across the auroral oval or over several days' time. These observations demonstrate for the first time the ability to measure the observed rapid H2 temperature variations across Jupiter's auroral atmosphere.

Clarke, John T.↗

Secular evolution of the vertical column abundances of CHClF2 (HCFC-22) in the Earth's atmosphere inferred from ground-based IR solar observations at the Jungfraujoch and at Kitt Peak, and comparison with model calculations

Series of high-resolution infrared solar spectra recorded at the International Scientific Station of the Jungfraujoch, Switzerland, between 06/1986 and 11/1992, and at Kitt Peak National Observatory, Tucson, Arizona (U.S.A.), from 12/1980 to 04/1992, have been analyzed to provide a comprehensive ensemble of vertical column abundances of CHClF2 (HCFC-22; Freon-22) above the European and the North American continents. The columns were derived from nonlinear least-squares curve fittings between synthetic spectra and the observations containing the unresolved 2 nu(sub 6) Q-branch absorption of CHClF2 at 829.05/cm. The changes versus time observed in these columns were modeled assuming both an exponential and a linear increase with time. The exponential rates of increase at one-sigma uncertainties were found equal to (7.0 +/- 0.35)%/yr for the Junfraujoch data and (7.0 +/- 0.23)%/yr for the Kitt Peak data. The exponential trend of 7.0%/yr found at both stations widely separated in location can be considered as representative of the global increase of the CHClF2 burden in the Earth's atmosphere during the period 1980 to 1992. When assuming two realistic vertical volume mixing ratio profiles for CHClF2 in the troposphere, one quasi constant and the other decreasing by about 13% from the ground to the tropopause, the concentrations for mid-1990 were found to lie between 97 and 111 pptv (parts per trillion by volume) at the 3.58 km altitude of the Jungfraujoch and between 97 and 103 pptv at Kitt Peak, 2.09 km above sea level. Corresponding values derived from calculations using a high vertical resolution-2D model and recently compiled HCFC-22 releases to the atmosphere, were equal to 107 and 105 pptv, respectively, in excellent agreement with the measurements. The model calculated lifetime of CHClF2 was found equal to 15.6 years. The present results are compared critically with similar data found in the literature. On average, the concentrations found here are lower by 15-20% than those derived from in situ investigations; this difference cannot be explained by the absolute uncertainty of +/- 11% assigned presently to the infrared remote measurements.

Zander, R.↗

Four micron high-resolution spectra of Jupiter in the North Equatorial Belt: H3(+) emissions and the C-12/C-13 ratio

Spectra of the North Equatorial Belt of Jupiter were obtained in March 1992 at an unapodized resolution of 0.1/cm between 2450 and 2600/cm with the Fourier Transform Spectrometer at the 3.6 m Canada-France-Hawaii Telescope (CFHT) on Mauna Kea. Several emissions from the nu(sub 2) band of H3(+) were detected. The excitation temperature derived from the relative intensities of these emissions averaged over a wide range of longitudes is 800 +/- 100 K, and the H3(+) column density is 1.56(sup +1.0)(sub -0.5) x 10(exp 11)/sq. cm. In addition, several strong absorption features due to (13)CH4 were observed. A comparison between (12)CH4 and (13)CH4 absorptions allowed us to obtain a new measurement of the C-12/C-13 ratio. We found that this ratio, estimated for the first time in this spectral range, is 89 (+/- 25), in agreement with the terrestrial value.

Marten, A.↗

Al III, Si IV, and C IV absorption toward zeta Ophiuchi: Evidence for photionized and collisionally ionized gas

We present Goddard High-Resolution Spectrograph observations at 3.5 km/s resolution and signal-to-noise ratios of 30 to 60 for the Al III, Si IV, and N V absorption lines in the far-ultraviolet spectrum of the O9.5 V star zeat Ophiuchi. The measurement reveal three types of highly ionized gas along the 140 pc line of sight. (1) Narrow components of Al III (b = 4.3 km/s, the mean value of (v(helio)) = -7.8 km/s; b = 3.2 km/s, the mean value of (v(sub helio)) = -14.4 km/s) and Si IV (b = 5.3 km/s, the mean value of (v(sub helio)) = -15.0 km/s) trace photionized gas in the expanding H II region surrounding zeta Oph. The observed magnitude and direction of the velocity offset between the Al III and Si IV profiles can be explained by models of H II regions that incorporate expansion. Narrow C IV absorption associated with the H II region is not detected. Predictions of the expected amounts of Si IV and C IV overestimate the column densities of these ions by factors of 30 and more than 10, respectively. The discrepancy may be due to the effects of elemental depletions in the gas and/or to the interaction of the stellar wind with surrounding matter. (2) Broad (b = 15 to 18 km/s) and weak Si IV and C IV absorption components are detected near the mean value of (v(sub helio)) = -26 km/s. The high-ionization species associated with these absorption components are probably produced by electron collisional ionization in a heated gas. This absorption may be physically related to the zeta Oph bow shock ot to a cloud complex situated within the local interstellar medium at d less than 60 pc. The C IV to Si IV column density ratio in this gas is 8, a factor of 6 less than conductive interface models predict, but this discrepancy may be removed by considering the effects of self-photoionization within the cooling gas in the model calculations. (3) A broad (b = 13 km/s) and weak C IV absorption feature detected at the mean value of (v(sub helio)) = -61 km/s is not seen in other species. We tentatively ascribe this absorption to gas in a postshock ragion of an optically thin shock in the zeta Oph stellar wind.

Sembach, Kenneth R.↗

Highly ionized gas absorption in the disk and halo toward HD 167756 at 3.5 kilometers per second resolution

High-resolution spectra of interstellar Si IV, C IV, and N V absorption lines along the 4 kpc path to the inner Galaxy star HD 167756 at z = -0.85 kpc are presented. The spectra were obtained with the echelle mode of Goddard High Resolution Spectrograph (GHRS) aboard the Hubble Space Telescope (HST) and have signal-to-noise ratios ranging from 23 to 38. The high resolution of the measurements full width at half maximum (FWHM = 3.5 km/s) results in fully resolved line profiles for the highly ionized gas absorption. The measurements provide information on the column density per unit velocity, N(v), as a function of velocity for Si IV, C IV, and N V. The C IV and N V profiles extend from -70 to +70 km/s, while the Si IV profiles extend from -40 to +70 km/s. The integrated logarithmic column densities are long N(Si IV) = 13.09 +/- 0.02, log N(C IV) = 13.83 +/- 0.02, and log N(N V) = 13.56 +/- 0.03. The N V profile is broad, asymmetric, and featureless, while the Si IV profile contains narrow absorption components near V(sub LSR) = -19, 0, +20, and +52 km/s with Doppler spread parameters, b about = 10-12 km/s. The C IV profile contains both broad and narrow structure. The high ion feature near +52 km/s is also detected in the low-ionization lines of Ca II, O I, Si II, and Fe II. The other narrow Si IV and C IV components occur within several km/s of components seen in low-ionization species. The sight line contains at least two types of highly ionized gas. One type gives rise to a broad N V profile, and the other results in the more structured Si IV profile. The C IV profile contains contributions from both types of highly ionized gas. The broad but asymmetric N V profile is well represented by a large Galactic scale height gas which is participating in Galactic rotation and has a combination of thermal and turbulent broadening with b(sub tot) about = 42 km/s. The C IV to N V abundance ratio of 1.0 +/- 0.3 for the gas implies T about 1.6 x 10(exp 5) K or about 8 x 10(exp 5) K if the gas is in collisional ionization equilibrium and has a solar carbon to nitrogen abundance ratio. This absorption may be associated with cooling hot gas situated in Galactic shells and supershells along the sight line. The gas producing the narrow Si IV and C IV absorption components has line widths that are compatible with origins in conductive interfaces between the warm and hot interstellar medium. Kinematic flows associated with the photoionized edges of clouds might also produce Si IV and C IV lines with Doppler spread parameters similar to those observed, but the C IV to Si IV ratio in this gas is 3.5, which leads us to favor the conductive interface interpretation.

Savage, Blair D.↗

A statistical equilibrium analysis of interstellar CO toward zeta Ophiuchi as recorded by the Goddard High Resolution Spectrograph

High-resolution and high signal-to-noise ratio echelle observations made by the Goddard High Resolution Spectrograph (GHRS), aboard the Hubble Space Telescope, of molecular (12)C(16)O and (13)C(16)O in the absorbing gas toward zeta Oph are reported. A statistical equilibrium model, incorporating a different way of dealing with the radiation field in the interstellar clouds, is presented. Based upon previous observations, two velocity components of the gas at V(sub LSR) = - 0.79 and 0.39 km/s, corresponding to solar velocity = -14.6 and -13.4 km/s, together with three different sets of velocity dispersions are adopted in our models. The ratios of the computed emergent intensities (I(sub em)) resulting from the emission lines in the lowest transitions (J = 1 goes to 0, 2 goes to 1, 3 goes to 2) of ground state of CO are presented. The ratios for the two velocity components, (I(sub em)(1 goes to 0)(sub 1))/(I(sub em)(1 goes to 0)(sub 2)), and (I(sub em)(2 goes to 1)(sub 1))/I(sub em)(1 goes to 0)(sub 1)) are comparable to the observed corrected antenna temperature ratios. From the solutions to the statistical equilibrium equations including the six lowest rotational transitions of CO and from multiple Voigt profile fits, the observed (12)CO and (13)CO UV abroption features are successfully reproduced. Profile fitting and double cloud curve-of-growth analysis using the GHRS and Copernicus data indicate that the abundance of CO is (1.8 +/- 0.2) x 10(exp 15)/sq cm. The most recently measured wavelength of the (6 goes to 0) (13)CO band by Haridass & Huber (R(0) = 1370.616 A) shows that the tentative (13)CO features in the GHRS data are unquestionably identified. If there is no blending from any other unknown interstellar species, the isotope ratio of (12)CO/(13)CO is approximately 82 +/- 25. This result is close to the terrestrial value of 90 and implies that the CO is not substantially fractionated, and (12)C(16)O experiences little preferential self-shielding through the selective isotopic photodissociation process. This conclusion differs strongly with that of Sheffer et al. Other implications of the results are discussed.

Lyu, Cheng-Hsuan↗

High-resolution observations of the polar magnetic fields of the sun

High-resolution magnetograms of the solar polar region were used for the study of the polar magnetic field. In contrast to low-resolution magnetograph observations which measure the polar magnetic field averaged over a large area, we focused our efforts on the properties of the small magnetic elements in the polar region. Evolution of the filling factor (the ratio of the area occupied by the magnetic elements to the total area) of these magnetic elements, as well as the average magnetic field strength, were studied during the maximum and declining phase of solar cycle 22, from early 1991 to mid-1993. We found that during the sunspot maximum period, the polar regions were occupied by about equal numbers of positive and negative magnetic elements, with equal average field strength. As the solar cycle progresses toward sunspot minimum, the magnetic field elements in the polar region become predominantly of one polarity. The average magnetic field of the dominant polarity elements also increases with the filling factor. In the meanwhile, both the filling factor and the average field strength of the non-dominant polarity elements decrease. The combined effects of the changing filling factors and average field strength produce the observed evolution of the integrated polar flux over the solar cycle. We compared the evolutionary histories of both filling factor and average field strength, for regions of high (70-80 deg) and low (60-70 deg) latitudes. For the south pole, we found no significant evidence of difference in the time of reversal. However, the low-latitude region of the north pole did reverse polarity much earlier than the high-latitude region. It later showed an oscillatory behavior. We suggest this may be caused by the poleward migration of flux from a large active region in 1989 with highly imbalanced flux.

Lin, H.↗

Variability of (O I) 6300-A emission near Io

Observations of (O I) 6300-A emission near Io have been obtained in 1990, 1991, and 1992 by the National Solar Observatory staff using the solar-stellar spectrography on the McMath-Pierce telescope at Kitt Peak. High-resolution spectra with a resolving power of about 1.2 x 10(exp 5) were obtained with an integration time of 10-15 min each. The viewing aperture for the observations was 5.2 arc sec x 5.2 arc sec centered on Io, with spatial resolution limited within this area by seeing conditions. Observations thus far have been reduced to obtain average brightness values over the aperture which range from approximately 200 to 1000 R for a number of different Io phase angles and Io system III longitudes. The (O I) 6300-A emission brightness exhibits an east-west asymmetry, where the average intensity for Io phase angles in the west (receding ansa) is 1.5 times brighter than in the east (approaching ansa). Similar east-west intensity ratios have also been observed for neutrals near Io and ions in the plasma torus for a number of other optical and ultraviolet emission lines which are excited by electron impact. In addition to the east-west asymmetry, the (O I) 6300-A emission brightness exhibits a strong dependence on the Io system III longitude angle, with a maximum value occurring in the range 200 deg +/- 50 deg. Earlier IUE observations of ultraviolet emission lines of O and S near Io obtained over a number of years have measured the east-west asymmetry, but the long IUE integration times of approximately 7-14 hours masked any detection of system III variability. For the (O I) 6300-A emission, the O(1D) state may be excited by electron impact of atomic oxygen and by electron impact dissociation of SO. The molecule SO may be present at the exobase or may be produced above the exobase as the dominant product of SO2 dissociation by electron impact. Preliminary assessment indicates that production of O(1D) by molecular dissociation may be more important. The (O I) 6300-A emission may therefore provide a remote signature for monitoring (1) the upward transport rates of molecular species in Io's atmosphere, (2) the relative abundance and time-variable dissociation of SO2 and/or SO at the exobase and in the corona of Io, and (3) the spatial distribution of these escaping molecular and atomic species and their ion production rates in the planetary magnetosphere.

Scherb, F.↗

Long-Term Trends in the Concentrations of SF6, CHClF2, and COF2 in the Lower Stratosphere from Analysis of High-Resolution Infrared Solar Occultation Spectra

Long-term trends in the concentrations of SF6, CHClF2 (CFC-22), and COF2 in the lower stratosphere have been derived from analysis of ca. 1980 and more recent infrared solar occultation spectra recorded near 32 deg N latitude at approx. 0.02/ cm resolution. Consistent sets of line parameters and spectral calibration methods have been used in the retrievals to minimize systematic error effects. Quoted error limits are 1 sigma estimated precisions. The SF6 and CHClF2 results are based on spectra recorded by balloon-borne interferometers in March 1981 and June 1988 and a comparison of these results with the Atmospheric Trace Molecule Spectroscopy (ATMOS) Experiment/Spacelab 3 measurements obtained in May 1985 near 30 deg N latitude. In the 13-18 km altitude range the mean measured SF6 mixing ratio in parts per trillion by volume (pptv) increased from 1.17 +/- 0.21 in March 1981 to 2.02 +/- 0.20 pptv in June 1988, and the CHClF2 mixing ratio below 15 km altitude increased from 51 +/- 8 pptv in March 1981 to 102 +/- 10 pptv in June 1988. The CHClF2 retrievals used new empirical CHClF2 line parameters derived from 0.03/cm resolution laboratory spectra recorded at six temperatures between 203 and 293 K; the derived mixing ratios are approx. 30% higher than obtained with earlier sets of line parameters, thereby removing a large discrepancy noted previously between IR and in situ measurements of CHClF2. Assuming an exponential growth model for fitting the trends, SF6 and CHClF2 mean increase rates of 7.4% +/- 1.9% and 9.4% +/- 1.3% /year, are obtained, respectively, which correspond to cumulative increases by factors of approx. 1.7 and -2.0 in the concentrations of these gases over the 7.2-year measurement period. Analysis of spectra recorded in October 1979 and April 1989 yields COF2 volume mixing ratios that are respectively 0.44 +/- 0.17 and 1.21 +/- 0.24 times the ATMOS/Spacelab 3 values, from which an average COF2 increase rate of 10.3 +/- 1.8%/ year over this time period has been estimated. The present results are compared with previously reported observations and trends and with one-dimensional model calculations. The model calculated trends are in reasonably good agreement with the observations.

Rinsland, C. P.↗

Far Outer Galaxy H II Regions

We have made a multifrequency (6, 3.6, and 2 cm), high-resolution (3"-6"), radio continuum survey of IRAS selected sources from the catalogue of Wouterloot & Brand (1989) to search for and study H II regions in the far outer Galaxy. We identified 31 sources in this catalog with well determined galactocentric distances, and with R approx.. greater than 15 kpc and L(sub FIR) approx.greater than 10(exp 4) solar luminosity, indicating the presence of high-mass star-formation. We have observed 11 of these sources with the Very Large Array (VLA). We observed the sources at 6 and 2 cm using "scaled arrays", making possible a direct and reliable comparison of the data at these two wavelengths for the determination of spectral indices. We detected a total of 12 radio sources, of which 10 have spectral indices consistent with optically-thin free-free emission from H II regions. Combined with previous VLA observations by other investigators, we have data on a total of 15 H II regions at galactocentric distances of 15 to 18.2kpc, among the most remote H II regions found in our Galaxy. The sizes of the H II regions range from approx. less than 0.10 to 2.3 pc. Using the measured fluxes and sizes, we determine the electron densities, emission measures, and excitation parameters of the H II regions, as well as the fluxes of Lyman continuum photons needed to keep the nebulae ionized. The sizes and electron densities are consistent with most of the sources detected in this survey being compact or ultracompact H II regions. Seven of the fifteen H II regions have sizes approx. less than 0.20 pc. Assuming simple pressure-driven expansion of the H II regions, these sizes indicate ages approx. less than 5 x 10(exp 4) yr, or only 1% of the lifetime of an O star, which implies an unlikely overabundance of O stars in the outer Galaxy. Thus, the large number of compact H II regions suggests that the time these regions spend in a compact phase must be much longer than their dynamical expansion times. Five of the fifteen H II regions have cometary shapes; the remainder are spherical or unresolved. Comparison of the radio continuum data with molecular line maps suggests that the cometary shape of the two H II regions in S 127 may be due to pressure confinement of the expanding ionized gas, as in the "blister" or "champagne flow" models of H II regions. Comparison of the radio continuum data with the IRAS far-infrared data indicates that the five most luminous H II regions are consistent with a single 0 or B star exciting a dust-free H II region. Subject headings: stars: formation - ISM: H II regions - ISM: individual objects: S 127 radio continuum: interstellar

Rudolph, A. L.↗