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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Visible-to-THz near-field nanoscopy

Optical microscopy has a key role in research, development and quality control across a wide range of scientific, technological and medical fields. However, diffraction limits the spatial resolution of conventional optical instruments to about half the illumination wavelength. A technique that surpasses the diffraction limit in the wide spectral range between visible and terahertz frequencies is scattering-type scanning near-field optical microscopy (s-SNOM). The basis of s-SNOM is an atomic force microscope in which the tip is illuminated with light from the visible to the terahertz spectral range. By recording the elastically tip-scattered light while scanning the sample below the tip, s-SNOM yields near-field optical images with a remarkable resolution of 10 nm, simultaneously with the standard atomic force microscopic topography image. This resolution is independent of the illumination wavelength, rendering s-SNOM a versatile nanoimaging and nanospectroscopy technique for fundamental and applied studies of materials, structures and phenomena. This Review presents an overview of the fundamental principles governing the measurement and interpretation of near-field contrasts and discusses key applications of s-SNOM. We also showcase emerging developments that enable s-SNOM to operate under various environmental conditions, including cryogenic temperatures, electric and magnetic fields, electrical currents, strain and liquid environments. Furthermore, all these recent developments broaden the applicability of s-SNOMs for exploring fundamental solid-state and quantum phenomena, biological matter, catalytic reactions and more.

Hillenbrand, Rainer [CIC nanoGUNE BRTA and Departm↗
DOE OSTI2024

Quantification of the Crack Evolution Process by Extracting Relevant Signal Components from Wave Propagation and Diffusive Transport Front Measurements

Wave propagation and diffusive transport phenomena in a geological rock sample undergoing crack evolution process are expected to interact with the mechanical discontinuities in the medium. The measurements of the signals associated with these phenomena can be used to assess and monitor the crack-driven micromechanical alterations in the rock. Different wave/diffusion phenomena, such as sonic propagation, pressure diffusion, and acoustic emission (AE), are sensitive to different elements of the mechanical discontinuities generated during the evolution of the crack clusters from initiation to coalescence. Sonic propagation, AE, and pressure diffusion monitoring have the potential to map the crack evolution because the transmitter-receiver arrays can be designed, arranged and tuned to (1) achieve maximum recovery of the scattered waveforms and travel times, (2) capture the later arrivals and multiple reflections, and (3) illuminate large rock volume. However, the structural/topological complexities of the mechanical discontinuities, complex distribution of the stress fields, complex mechanical alterations in media, and fluid redistribution in the crack system pose serious challenges for the detection and modeling of the crack evolution process (from here on, we will use the term ‘crack evolution process’ to mean that the crack evolution occurred under shallow crustal conditions). For purposes of accurately accounting such complexities and heterogeneities in the absence of reliable physical laws, simulation methods, and signal processing techniques, my early-career research proposal will develop and apply novel data-driven machine learning methods to: (1) extract signal components relevant to the various phases of crack evolution and (2) generate a 2D visual map of the crack evolution process.

58 GEOSCIENCES↗
DOE OSTI2020

Photoelectrochemical Nitrogen Reduction to Ammonia on Cupric and Cuprous Oxide Photocathodes

Photoelectrochemical N 2 reduction enables the production of NH 3 under ambient conditions using water as the hydrogen source. Furthermore, by utilizing solar energy, photoelectrochemical N 2 reduction can significantly reduce the energy input required for N 2 reduction. In this study, photoelectrochemical N 2 production was investigated using CuO and Cu 2 O photocathodes that are known to be poorly catalytic for water reduction, the major reaction competing with N 2 reduction. When tested under simulated solar illumination with isotopically labeled 15 N 2 in 0.1 M KOH solution, the CuO and Cu 2 O photocathodes produced 15 NH 3 with a Faradaic efficiency of 17% and 20% at 0.6 V and 0.4 V vs. RHE, respectively. These potentials are significantly more positive than the thermodynamic reduction potential of N 2 , which demonstrates how the use of photoexcited electrons in the CuO and Cu 2 O photocathodes can reduce the energy input required for NH 3 production. Here, the use of photoexcited electrons in these photocathodes for N 2 reduction, water reduction, and photocorrosion was carefully examined.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS2017

High-Resolution OH and CH2O Visualization in a Premixed Cavity-Anchored Ethylene-Air Flame in a M = 0.6 Flowfield

OH and CH2O were imaged in a premixed, cavity-anchored, ethylene-air turbulent flame using a high resolution planar laser-induced fluorescence (PLIF) system. The electrically-heated, continuous flow facility (UVa Supersonic Combustion Facility, Configuration E) consisted of a Mach 2 nozzle, an isolator with fuel injectors, a test section with a cavity flame holder and optical access, and an extender. Standard test conditions comprised total temperature 1200 K, total pressure 300 kPa, local equivalence ratio near 0.4, and local Mach number near 0.6. OH PLIF data was also collected for a case with reduced total temperature and another with reduced equivalence ratio. OH and CH2O were excited in separate experiments with light sheets at 283.55 nm and 352.48 nm, respectively. A light sheet of approximate thickness 25 ?m illuminated the stream-wise midplane. This plane was imaged for 120 mm downstream of the backward-facing step. The intensified camera system imaged OH with magnification 1.97, a square 6.67 mm field of view, and in-plane resolution of 39 ?m. The smallest observed OH structures observed were approximately 100 ?m wide. The CH2O PLIF image signal was much weaker; the smallest observed structures were approximately 200 ?m wide. Composite fluorescence images were computed for the observed area.

Geipel, Clayton M.↗
NASA NTRS2018

The Laser Enhanced Arc-Jet Facility (LEAF-Lite): Simulating Convective and Radiative Heating with Arc-Jets and Multiple 50-KW CW Lasers

LEAF-Lite (Laser Enhanced Arc-Jet Facility) is a radiative laser heating facility that has been added to the 60 MW Interaction Heating Facility (IHF) convective plasma arc-jet located at NASA Ames Research Center. Together, these two systems can simulate both convective and radiative heating at heat fluxes reaching 551 W/cm2 by simultaneously combining a highest measured heat flux of 160 W/cm2 convective and 391 W/cm2 radiative heating on a 152-mm x 152-mm wedge model configuration. Adding radiant heating to an existing convective facility better simulates Earth atmospheric entry from hyperbolic lunarreturn speeds. The radiative heat is provided by multiple 50-kW CW IR lasers, which is nearly uniform across the illuminated surface with a total variation less than 6%, while the convective heat is provided by a high enthalpy plasma arc-jet. In a later phase, the facility will expand to test panel test articles of 432-mm x 432-mm and provide 100 W/cm2 of radiative heating in a plasma convective flow environment. The paper describes this new combined heating capability, its current testing conditions, and the unique application of the laser system with respect to the Orion test flight lunar orbits.

Cushman, Geoff↗
DOE OSTI2021

Development of High-Efficiency GaAs Solar Cells Grown on Nanopatterned GaAs Substrates

One approach to reducing the cost of high-efficiency III–V devices involves adding patterned layers to heteroepitaxial or homoepitaxial substrates to facilitate substrate removal and reuse. However, few studies have focused explicitly on high-quality devices grown over patterned substrates, which is required for any cost saving to be beneficial. In this work, we demonstrate the growth of high-efficiency GaAs solar cells on GaAs substrates patterned with an array of nanoscale SiOX mask stripes. We show that reducing the pattern dimensions to submicron length scales with nanoimprint lithography enables defect-free coalescence. By varying the growth conditions, faceting of the epilayer material during overgrowth of the patterned mask was also controlled. A V/III ratio of 200 during MOVPE overgrowth produced smooth coalesced epilayers, which is desirable for the growth of subsequent device layers. Inverted GaAs front homojunction devices grown on patterned GaAs(001) substrates achieved threading dislocation densities below 5 × 10 5 cm –2 and maintained >23% solar cell efficiencies at one sun illumination, equivalent to control devices grown on unpatterned epi-ready substrates.

14 SOLAR ENERGY↗
DOE OSTI2024

A platform for non-local thermodynamic equilibrium atomic physics research using the buried layer target approach at a kJ level laser facility

Here we present a design and first use of a kJ level laser facility for research of non-local thermodynamic equilibrium atomic physics using the buried layer target method. The target design included a metal layer buried inside a plastic tamper with thicknesses tailored to the expected laser intensities. The target was illuminated from each side by two laser beams with intensities of 0.5–5 × 10 14 W/cm 2 . The advanced diagnostic suite included static and time-resolved imagers and spectrometers with various spectral resolutions. A 3D printed dual elliptically curved spectrometer is presented, and its results are compared to a traditional crystal spectrometer. Experimental results and radiation hydrodynamic simulations demonstrate that the target achieved the desired thermodynamic conditions of n e ≈ 10 21 –10 22 cm -3 and T e ≈ 1–2 keV.

3D printing↗
NASA NTRS2020

Automated Identification and Differentiation of Spectrally Similar Hydrothermal Minerals on Mars

Early telescopic observations corroborated hydration related absorptions on Mars in the infrared. Images from the Viking missions led to speculation of hydrothermal alteration and were followed by two missions which mapped the spatial variability of the ~ 3 μm hydration feature. Since then, the Compact Reconnaissance Imager for Mars (CRISM) has provided high spatial resolution (up to 18m) spectral identification of a suite of hydrothermal and diagenetic minerals which have illuminated a range of formation mechanisms. Presence/absence and spatial segregation or mixing of minerals like prehnite, epidote, chlorite amphiboles, and mixed-layer Fe/Mg smectite-chlorite provide valuable evidence for the geologic setting of deposits on Earth, and these phases are often used as temperature and aqueous chemistry indicators in terrestrial systems. Mapping the distribution of these phases will help to answer whether Mars had widespread conditions favorable for low-grade metamorphism and diagenesis, or only focused hydrothermal systems in areas of high heat flow. Further characterizing the chemistry and structure of these phases will then help to answer how most of the widespread Fe/Mg phyllosilicates formed, further defining early geochemical cycling and climate. A fully automated approach for accurate mapping of important hydrothermal mineral phases on Mars has been a challenge. Due to overlapping features in the M-OH region (~2.2-2.4 μm), the strongest absorption features of chlorite, prehnite, and epidote in the short-wave infrared are difficult to distinguish from one another and from the most commonly occurring hydrated silicates on Mars, Fe/Mg smectites. Weaker absorptions are present in both prehnite and epidote which help to distinguish them from chlorite and smectites, but their relative strength in the presence of noise and spatial mixing is often too low to confidently identify them without the noise suppression and feature enhancement methods described here. The spectral signatures of mixed-layer Fe/Mg smectite-chlorite and partially chloritized Fe/Mg smectites have not yet been adequately assessed. Here we evaluate the effectiveness of two empirical and statistical methods for identifying and differentiating these phases using CRISM data.

Rasmussen, B. P.↗
DOE OSTI2020

Alternating Current Photovoltaic Effect

It is well known that the photovoltaic effect produces a direct current (DC) under solar illumination owing to the directional separation of light-excited charge carriers at the p–n junction, with holes flowing to the p-side and electrons flowing to the n-side. In this study, we found that apart from the DC generated by the conventional p–n photovoltaic effect, there is another new type of photovoltaic effect that generates alternating current (AC) in the nonequilibrium states when the illumination light periodically shines at the junction/interface of materials. The peak current of AC at high switching frequency can be much higher than that from DC. The AC cannot be explained by the established mechanisms for conventional photovoltaics; instead, it is suggested to be a result of the relative shift and realignment between the quasi-Fermi levels of the semiconductors adjacent to the junction/interface under the nonequilibrium conditions, which results in electron flow in the external circuit back and forth to balance the potential difference between two electrodes. By virtue of this effect, the device can work as a high-performance broadband photodetector with extremely high sensitivity under zero bias; it can also work as a remote power source providing extra power output in addition to the conventional photovoltaic effect.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Cavity molecular dynamics simulations of vibrational polariton-enhanced molecular nonlinear absorption

We report recent experiments have observed that the chemical and photophysical properties of molecules can be modified inside an optical Fabry– Pérot microcavity under collective vibrational strong coupling (VSC) conditions, and such modification is currently not well understood by theory. In an effort to understand the origin of such cavity-induced phenomena, some recent studies have focused on the effect of the cavity environment on the nonlinear optical response of the molecular subsystem. Here, we use a recently proposed protocol for classical cavity molecular dynamics simulations to numerically investigate the linear and the nonlinear response of liquid carbon dioxide under such VSC conditions following an optical pulse excitation. We find that applying a strong pulse of excitation to the lower hybrid light–matter state, i.e., the lower polariton (LP), can lead to an overall molecular nonlinear absorption that is enhanced by up to two orders of magnitude relative to the excitation outside the cavity. This polariton-enhanced multiphoton absorption also causes an ultrashort LP lifetime (0.2 ps) under strong illumination. Unlike usual polariton relaxation processes—whereby polaritonic energy transfers directly to the manifold of singly excited vibrational dark states—under the present mechanism, the LP transfers energy directly to the manifold of higher vibrationally excited dark states; these highly excited dark states subsequently relax to the manifold of singly excited states with a lifetime of tens of ps. Because the present mechanism is generic in nature, we expect these numerical predictions to be experimentally observed in different molecular systems and in cavities with different volumes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

CdSeTe solar-cell performance with different dopant types

Four doping conditions were explored for CdTe-based solar cells: p-type As and P, n-type Al, and no intentional doping. In each case, the CdTe absorber was alloyed with Se, but only near the normal front-side, light entry for the cells, while the dopants were added from the back. Cells with p-dopants showed efficiencies up to 20% with front-side illumination, but the n-doped and undoped ones were close to zero. With back-side illumination, this was reversed with undoped up to 8% and p-doped ones only about 2%. These results are explained by Kelvin-probe measurements of electric-field profiles, which showed that the diode field was near the front for the higher-efficiency p-doping, but near the back for undoped and n-doped.

14 SOLAR ENERGY↗
DOE OSTI2021

Barcoded reciprocal hemizygosity analysis via sequencing illuminates the complex genetic basis of yeast thermotolerance

Decades of successes in statistical genetics have revealed the molecular underpinnings of traits as they vary across individuals of a given species. But standard methods in the field cannot be applied to divergences between reproductively isolated taxa. Genome-wide reciprocal hemizygosity mapping (RH-seq), a mutagenesis screen in an interspecies hybrid background, holds promise as a method to accelerate the progress of interspecies genetics research. Here, we describe an improvement to RH-seq in which mutants harbor barcodes for cheap and straightforward sequencing after selection in a condition of interest. As a proof of concept for the new tool, we carried out genetic dissection of the difference in thermotolerance between two reproductively isolated budding yeast species. Experimental screening identified dozens of candidate loci at which variation between the species contributed to the thermotolerance trait. Hits were enriched for mitosis genes and other housekeeping factors, and among them were multiple loci with robust sequence signatures of positive selection. Together, these results shed new light on the mechanisms by which evolution solved the problems of cell survival and division at high temperature in the yeast clade, and they illustrate the power of the barcoded RH-seq approach.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Cone beam neutron interferometry: From modeling to applications

Phase-grating moiré interferometers (PGMIs) have emerged as promising candidates for the next generation of neutron interferometry, enabling the use of a polychromatic beam and manifesting interference patterns that can be directly imaged by existing neutron cameras. However, the modeling of the various PGMI configurations is limited to cumbersome numerical calculations and backward propagation models which often do not enable one to explore the setup parameters. Here we generalize the Fresnel scaling theorem to introduce a k -space model for PGMI setups illuminated by a cone beam, thus enabling an intuitive forward propagation model for a wide range of parameters and experimental setups. The interference manifested by a PGMI is shown to be a special case of the Talbot effect, and the optimal fringe visibility is shown to occur at the moiré location of the Talbot distances. We derive analytical expressions for the contrast and the propagating intensity profiles in various conditions and provide the first analysis of the PGMI dark-field imaging signal when considering sample characterization. The model's predictions are compared to experimental measurements and good agreement is found between them. Last, we propose and experimentally verify a method to recover contrast at typically inaccessible PGMI autocorrelation lengths. The presented work provides a toolbox for analyzing and understanding existing PGMI setups and their future applications, for example extensions to two-dimensional PGMIs and characterization of samples with nontrivial structures. Published by the American Physical Society 2024

Sarenac, D. (ORCID:0000000185753367)↗
DOE OSTI2023

Speckle contrast of interfering fluorescence X-rays

With the development of X-ray free-electron lasers (XFELs), producing pulses of femtosecond durations comparable with the coherence times of X-ray fluorescence, it has become possible to observe intensity–intensity correlations due to the interference of emission from independent atoms. This has been used to compare durations of X-ray pulses and to measure the size of a focused X-ray beam, for example. Here it is shown that it is also possible to observe the interference of fluorescence photons through the measurement of the speckle contrast of angle-resolved fluorescence patterns. Speckle contrast is often used as a measure of the degree of coherence of the incident beam or the fluctuations of the illuminated sample as determined from X-ray diffraction patterns formed by elastic scattering, rather than from fluorescence patterns as addressed here. Commonly used approaches to estimate speckle contrast were found to suffer when applied to XFEL-generated fluorescence patterns due to low photon counts and a significant variation of the excitation pulse energy from shot to shot. A new method to reliably estimate speckle contrast under such conditions, using a weighting scheme, is introduced. The method is demonstrated by comparing the speckle contrast of fluorescence observed with pulses of 3 fs to 15 fs duration.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
NASA NTRS1978

Selection of a seventh spectral band for the LANDSAT-D thematic mapper

The author has identified the following significant results. Each of the candidate bands were examined in terms of the feasibility of gathering high quality imagery from space while taking into account solar illumination, atmospheric attenuation, and the signal/noise ratio achievable within the TM sensor constraints. For the 2.2 micron region and the thermal IR region, inband signal values were calculated from representative spectral reflectance/emittance curves and a linear discriminant analysis was employed to predict classification accuracies. Based upon the substantial improvement (from 78 t0 92%) in discriminating zones of hydrothermally altered rocks from unaltered zones, over a broad range of observation conditions, a 2.08-2.35 micron spectral band having a ground resolution of 30 meters was recommended.

Holmes, Q. A.↗
NASA NTRS1994

Dunes and microdunes on Venus: Why were so few found in the Magellan data?

A search through cycle 1, 2, and 3 Magellan radar data covering 98% of the surface of Venus revealed very few dunes. Only two possible dune fields and several areas that may contain microdunes smaller than the resolution of the images (75 m) were identified. The Aglaonice dune field was identified in the cycle 1 images by the specular returns characteristic of dune faces oriented perpendicular to the radar illumination. Cycle 1 and 2 data of the Fortuna-Meshkenet dune field indicate that there has been no noticeable movement of the dunes over an 8-month period. The dunes, which are oriented both parallel and perpendicular to the radar illumination, appear to be dark features on a brighter substrate. Bright and dark patches that were visible in either cycle 1 or 2 data, but not both, allowed identification of several regions in the southern part of Venus that may contain microdunes. The microdunes are associated with several parabolic crater deposits in the region and are probably similar to those formed in wind tunnel experiments under Venus-like conditions. Bragg scattering and/or subpixel relfections from the near-normal face on asymmetric microdunes may account for these bright and dark patches. Look-angle effects and the lack of sufficient sand-size particles seem to be most likely reasons so few dunes were identified in Magellan data. Insufficient wind speeds, thinness of sand cover, and difficulty in identifying isolated dunes may also be contributors to the scarcity of dunes.

Weitz, Catherine M.↗
NASA NTRS1994

Dunes and Microdunes on Venus: Why Were So Few Found in the Magellan Data?

A search through cycle 1, 2, and 3 Magellan radar data covering 98% of the surface of Venus revealed very few dunes. Only two possible dune fields and several areas that may contain microdunes smaller than the resolution of the images (75 m) were identified. The Aglaonice dune field was identified in the cycle I images by the specular returns characteristic of dune faces oriented perpendicular to the radar illumination. Cycle 1 and 2 data of the Fortuna-Meshkenet dune field indicate that there has been no noticeable movement of the dunes over an 8-month period. The dunes, which are oriented both parallel and perpendicular to the radar illumination, appear to be dark features on a brighter substrate. Bright and dark patches that were visible in either cycle 1 or 2 data, but not both, allowed identification of several regions in the southern part of Venus that may contain microdunes. The microdunes are associated with several parabolic crater deposits in the region and are probably similar to those formed in wind tunnel experiments under Venus-like conditions. Bragg scattering and/or subpixel reflections from the near-normal face on asymmetric microdunes may account for these bright and dark patches. Look-angle effects and the lack of sufficient sand-size particles seem to be the most likely reasons so few dunes were identified in Magellan data. Insufficient wind speeds, thinness of sand cover, and difficulty in identifying isolated dunes may also be contributors to the scarcity of dunes.

Weitz, Catherine M.↗
DOE OSTI2023

Combined Stress Testing of Perovskite Solar Cells for Stable Operation in Space

Perovskite solar cells (PSCs) could provide new low-cost opportunities for powering spacecraft. Here we are designing a PSC resilient to lunar surface conditions, focusing on contact/barrier layers combinations that maximize stability. Thermal vacuum stress shows cells with gold back-contacts and SiOx protection retain >90% of initial efficiency and indium tin oxide (ITO)-contacted cells retain ~100% of initial efficiency after five months of stress. SiO x mitigates mechanical aspects of contact stress, retaining 99% of initial efficiency, whereas cells with silicone/cover glass decreased 27%. We further exposed cells to combined illumination, 75 °C heat, and 10 -6 Torr vacuum for 24 h and found that ITO-contacted cells outperformed Au-contacted cells.

14 SOLAR ENERGY↗