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At least 577 records · Page 32

Petrography, mineral chemistry and origin of Type I enstatite chondrites

The petrography and mineralogy of four Type I enstatite chondrites were examined by optical and cathololuminescent and electron microprobe means to discern particular chemical and mechanical processes present during solar system condensation. The specimens examined included sections of the Indarch, Abee, Kota-Kota, and Adhi-Kot chondrites. Textural interpretations were performed, as well as chemical analyses of the degree of similarity of the clinoenstatite, olivine, accessory silicates, metal, schreibersite, troilite, oldhamite, and niningerite grains in each sample. Simple models of progressive condensation either at equilibrium or with mechanical removal of early condensates were ruled out due to the occurrence of both blue and red enstatite crystals in metal clasts. A need for sequential processes of mixing, melting, crystallization, condensation, fracturing, and mechanical aggregation are suggested as necessary to model the formation mechanisms of the mineral aggregates.

Leitch, C. A.↗

A semiempirical method for analysis of the reflectance spectra of binary mineral mixtures

A simple semiempirical method is presented for determination of the spectral reflectance of a powdered binary mineral mixture. This technique uses a two-stream radiative transfer model (a modified Kubelka-Munk model) on a particulate medium of isotroic scatterers The particles are assumed to be much larger than the wavelength of light under consideration. This same method can be used to determine the relative proportion of components in a mixture for which the spectral reflectance is known. Binary mixtures of olivine, two pyroxenes, and magnetite are used to test this model. The theoretical and empirical results agree approximately within experimental errors.

Johnson, P. E.↗

Use of MAGSAT anomaly data for crustal structure and mineral resources in the US midcontinent

Magnetic field data acquired by NASA's MAGSAT satellite is used to construct a long-wavelength magnetic anomaly map for the U.S. midcontinent. This aids in interpretation of gross crustal geology (structure, lithologic composition, resource potential) of the region. Magnetic properties of minerals and rocks are investigated and assessed, to help in evaluation and modelling of crustal magnetization sources and depth to the Curie-temperature isotherm.

Carmichael, R. S.↗

Characterization of erosion of metallic materials under cavitation attack in a mineral oil

Cavitation erosion and erosion rates of eight metallic materials representing three crystal structures were studied using a 20-kHz ultrasonic magnetostrictive oscillator in viscous mineral oil. The erosion rates of the metals with an fcc matrix were 10 to 100 times higher than that of an hcp-matrix titanium alloy. The erosion rates of iron and molybdenum, with bcc matrices, were higher than that of the titanium alloy but lower than those of the fcc metals. Scanning electron microscopy indicates that the cavitation pits are initially formed at the grain boundaries and precipitates and that the pits that formed at the triple points grew faster than the others. Transcrystalline craters formed by cavitation attack over the surface of grains and roughened the surfaces by multiple slip and twinning. Surface roughness measurements show that the pits that formed over the grain boundaries deepended faster than other pits. Computer analysis revealed that a geometric expression describes the nondimensional erosion curves during the time period 0.5 t(0) t 2.5 t(0), where t(0) is the incubation period. The fcc metals had very short incubation periods; the titanium alloy had the longest incubation period.

Rao, B. C. S.↗

Mineral chemistry of the shergottites, nakhlites, Chassigny, Brachina, pallasites and urelites

The mineral chemistry is compared for selected achondrites. Olivine in the ALHA 77005 and EETA 79001 shergottites, olivine-rich Chassigny and Brachina, and the nakhlites, contains Ni indicative of oxidizing conditions, whereas pallasitic and ureilitic olivines contain much lower Ni due to reducing conditions. The Brachina olivine and pyroxene have distinctively higher Fe/Mn than the shergottites and Chassigny, further indicating that Brachina is unique. The Chassigny and 77005 olivines contain lower Cr2O3 (0.03 wt. pct) than the Brachina and 79001 olivines. Values of Fe/Mn for cumulus augites in nakhlites are higher than for the shergottites, whereas those for ferropigeonites are not. The 77005 shergottite contains troilite FeS in contrast to 79001, Shergotty, Zagami, and Chassigny, which contain pyrrhotite. Further analyses are needed, but the present survey indicates that at least Brachina is not chemically cogenetic with the other 'oxidized achondrites', and that the Fe/Mn ratio of the cumulus augites in nakhlites is a problem for the assignment of the nakhlites, shergottites, and Chassigny to a single genetic group.

Smith, J. V.↗

Spectral properties of mixtures of montmorillonite and dark grains - Implications for remote sensing minerals containing chemically and physically adsorbed water

The spectral properties from 0.4 to 3 microns of montmorillonite plus dark carbon grains (called opaques) of various sizes are studied as a function of the weight fraction of opaques present. The reflectance level and band depths of the 1.4-, 1.9-, 2.2-, and 2.8-micron water and/or OH absorption features are analyzed using derived empirical relationships and scattering theory. It is found that the absorption band depths and reflectance level are a very nonlinear function of the weight fraction of opaques present but can be predicted in many cases by simple scattering theory. The 2.8-micron bound water fundamental band is the most difficult absorption feature to suppress. The overtone absorptions are suppressed a greater amount than the fundamental but are still apparent even when 10-20 wt pct opaques are present. The relationships observed and the simple scattering theory presented show that quantitative compositional remote sensing studies are feasible for surfaces containing complex mineral mixtures.

Clark, R. N.↗

Landsat mapping of rocks associated with copper mineralization, northern Bahia State, Brazil

This project has applied Landsat digital data to a study of the geology of a mineralized zone in northern Bahia State, Brazil. The study accomplished two tasks: (1) production of a 1:100,000 geologic map of approximately 3300 sq km and (2) development of a two tiered geobotanical index that exploits increased vegetation density and decreased soil brightness on the mafic rock units.

Stone, T. A.↗

Surface roughness effects with solid lubricants dispersed in mineral oils

The lubricating effectiveness of solid-lubricant dispersions are investigated in both point and line contacts using surfaces with both random and directional roughness characteristics. Friction and wear data obtained at relatively low speeds and at room temperature, indicate that the existence of solid lubricants such as graphite, MoS2, and PTFE in a plain mineral oil generally will not improve the effectiveness of the oil as a lubricant for such surfaces. Under boundary lubrication conditions, the friction force, as a function of time, initially depends upon the directional roughness properties of the contacting surfaces irrespective of whether the base oil or dispersions are used as lubricants.

Cusano, C.↗

Measurement of spine and total body mineral by dual-photon absorptiometry

The use of Gd-153 dual-photon absorptiometry at 43 and 100 keV to measure individual-bone and total-body bone minerals is discussed in a survey of recent studies on humans, phantoms, and monkeys. Precision errors of as low as 1 percent have been achieved in vivo, suggesting the use of sequential measurements in studies of immobilization and space-flight effects.

Mazess, R. B.↗

The microstructure of minerals in coarse-grained Ca-Al-rich inclusions from the Allende meteorite

Transmission electron microscopy (TEM) is used to investigate the microstructure and microchemistry of minerals in Ca-Al-rich, coarse-grained inclusions (CAI) from the meteorite. The spinels contain only low to moderate dislocation densities and are characterized by a ubiquitous, fine black spotty texture that is thought to originate from a slightly nonstoichiometric composition. Whereas the Ti-Al-pyroxenes are relatively devoid of features, they contain veins of secondary phases apparently deposited in unhealed cracks. Chromite is identified in the veins, indicating transport of oxidized iron during alteration. The melilites show the greatest variety of microstructures and are the most heavily altered phase in CAI. High dislocation densities are common and the crystals exhibit considerable internal strain, suggesting that they have not been annealed.

Barber, D. J.↗

Clays and other minerals in prebiotic processes

Clays and other minerals have been investigated in context with prebiotic processes, mainly in polymerization of amino acids. It was found that peptides adsorbed on the clay, prior to polymerization, influence the reaction. The ratio between the amount of the peptides adsorbed and that of the clay is important for the yield as well as for the degrees of polymerization obtained. Adsorption prior to reaction produces a certain order in the aggregates of the clay particles which might induce better reaction results. Excess of added peptides disturbs this order and causes lesser degrees of polymerization. In addition to adsorption, clays are also able to occlude between their layers substances out of the environment, up to very high concentrations.

Paecht-Horowitz, M.↗

Characterization of erosion of metallic materials under cavitation attack in a mineral oil

Cavitation erosion and erosion rates of eight metallic materials representing three crystal structures were studied. The erosion experiments were conducted with a 20-kHz ultrasonic magnetostrictive oscillator in a viscous mineral oil. The erosion rates of the metals with an fcc matrix were 10 to 100 times higher than that of an hop-matrix titanium alloy. The erosion rates of iron and molybdenum, with bcc matrices, were higher than that of the titanium alloy but lower than those of those of the fcc materials. Studies with scanning electron microscopy indicated that the cavitation pits were initially formed at the grain boundaries and precipitates and that the pits formed at the junction of grain boundaries grew faster than the others. Transcrystalline craters formed by cavitation attack over the surface of grains and roughened the surfaces by multiple slip and twinning. Surface roughness measurements showed that the pits that formed over the grain boundaries deepened faster than pits. Computer analysis revealed that a geometric expression describes the nondimensional erosion curves during the time period 0.5 t (sub 0) t 2.5 t (sub 0), where t (sub 0) is the incubation period. The fcc metals had very short incubation periods; the titanium alloy had the longest incubation period.

Rao, B. C. S.↗

Active airborne infrared laser system for identification of surface rock and minerals

Emissivity and reflectivity in the thermal infrared spectral region (8-13 microns) may be used to discriminate among rocks and minerals. Although considerable success has been achieved in remote sensing classification of rock types based on emissivity measurements made with NASA's Thermal Infreared Multispectral Scanner (TIMS), classification based on reflectivity offers several advantages: much narrower bandwidths are used, higher signal to noise ratios are possible, and measurements are little affected by surface temperature. As a demonstration, an airborne CO2 laser instrument was flown along the margin of Death Valley, California. Measurements of spectral reflectance collected with this device were compared with emissivity measurements made with the TIMS. Data from either instrument provided the means for recognizing boundaries between geologic units including different rock types and fan surfaces of different ages.

Kahle, A. B.↗

Identification of hydrothermal mineralization in Baja California, Mexico from orbit using the Shuttle multispectral infrared radiometer

Data from the Space Shuttle Multispectral IR Radiometer (SMIRR), which is a 10-channel remote sensor designed to record narrow band spectral data in the 0.5-2.4 micron wavelength range, were used to identify and study a previously unreported area of hydrothermal alteration on the Baja California peninsula. Absorption at 2.17 microns, which is diagnostic of the minerals pyrophyllite, dickite, and alunite, was observed in many spectra and the presence of pyrophyllite and dickite was confirmed by X-ray diffraction analysis of field samples. Anomalously high Mo, B, Sn, Zr, and Ag were found in three samples.

Rowan, L. C.↗

Soluble minerals in chemical evolution. I - Adsorption of 5-prime-AMP on CaSO4 - A model system

The adsorption of 5-prime-AMP onto solid CaSO4-2H2O was studied in a saturated suspension as a function of pH and electrolyte concentration. The adsorption is pH-dependent and is directly correlated with the charge on the 5-prime-AMP molecule which is determined by the state of protonation of the N-1 nitrogen of the purine ring and the phosphate oxygens. It is proposed that the binding that occurs between the nucleotide and the salt is electrostatic in nature. The adsorption decreases with increasing ionic strength of the solution which means that in a fluctuating environment of wetting and drying cycles, a biomolecule similar to 5-prime-AMP could be expected to desorb during the drying phase. The results indicate that CaSO4-2H2O can serve as a concentrating surface for biomolecules. The significance of this is discussed with regard to the possible role of soluble minerals and their surfaces in a geochemical model consistent with the evolution of the earth and the origin of life.

Orenberg, J. B.↗

Mineral chemistry and origin of spinel-rich inclusions in the Allende CV3 chondrite

The present electron probe microanalysis of 20 spinel-rich inclusions in Allende indicates that the mineralogy of spinel-rich Allende inclusions is similar to that of fine grained Ca, Al-rich inclusions (CAIs) in ALH-77003 and rims on coarse grained CAIs in Allende. The mineralogy, mineral chemistry, and bulk chemistry of the inclusions indicate that they are not primitive aggregates of crystalline nebular condensates, but rather aggregates of minute concentric objects that are presently interpreted to be a fractionated distillation residue that lost Ca, Si-rich partial melt. It is suggested that interstellar dust aggregates were melted or distilled into Allende inclusions by aerodynamic drag heating, in regions of the nebula where the dust/gas ratio was so enhanced that the local oxygen fugacity was raised by several order of magnitude and liquids became thermodynamically stable.

Kornacki, A. S.↗

Template-directed polynucleotide synthesis on mineral surfaces

Ferric hydroxide, a plausible prebiotic material, strongly adsorbs polynucleotides. It is shown that adsorption on ferric hydroxide and on several other minerals has no effect, under the conditions studied, on the template-directed oligomerization of guanylic acid on polycytidylic acid.

Schwartz, A. W.↗

Erosion of phosphor bronze under cavitation attack in a mineral oil

Experimental investigations on erosion of a copper alloy, phosphor bronze, under cavitation attack in a viscous mineral oil are presented. The details of pit formation and erosion were studied using scanning electron microscopy. The mean depth of penetration, the variations in surface roughness, and the changes in erosion pit size were studied. Cavitation pits formed initially over the grain boundaries while the surface grains were plastically deformed. Erosion of surface grains occurred largely by ductile fracture involving microcracking and removal in layers. The ratio h/a of the depth h to half width a of cavitation pits increased with test duration from 0.047 to 0.55.

Rao, B. C. S.↗