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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS2008

Using Wind and Temperature Fields to Study Dehydration Mechanisms in the Tropical Tropopause Layer

The tropics are the main region for troposphere-to-stratosphere transport (TST) of air. One of the dominant mechanisms that control tropical TST of water vapor is freeze-drying by the cold tropical tropopause. This mechanism is supported by evidence from satellite observations of the "tape recorder", where seasonal changes in stratospheric water vapor are in phase with seasonal changes in tropopause temperatures in the tropics. Over the last few years, however, the concept of the tropical tropopause has evolved from a single material surface to a layer called the Tropical Tropopause Layer (TTL). A recent hypothesis on dehydration mechanisms suggests that dehydration and entry point into the stratosphere are not always co-located (Holton and Gettelman, 2001). Instead, dehydration can occur during horizontal advection through Lagrangian 'cold pools', or coldest regions along a parcel's trajectory, as air ascends within the TTL while the entry point into the stratosphere occurs at a different geographical location. In this study, we investigate the impact that these Lagrangian cold pools have on TTL moisture. For this purpose, we use in situ measurements of TTL water vapor obtained aboard NASA's WB-57 aircraft over the Eastern Tropical Pacific, and we compare these measurements to minimum saturation water vapor mixing ratios obtained from three-dimensional backward trajectory calculations. Aircraft measurements show frequent unsaturated conditions, which suggest that the entry value of stratospheric water vapor in this region was not set by local saturation conditions. Trajectory calculations, driven by both ECMWF operational analysis and reanalysis winds and temperature fields, are used to explore the impact (e.g., geographical location, timing, dehydration magnitude) of the Lagrangian cold pools intercepted by the parcels sampled by the aircraft. We find noteworthy differences in the location of the Lagrangian cold pools using the two ECMWF data sets, namely influence of the Western Tropical Pacific region when using operational analysis fields versus influence of the Eastern Tropical Pacific and South America regions when using reanalysis fields. These results have a significant impact on our scientific conclusions on dehydration mechanisms affecting the air sampled by the aircraft, given that these regions have different thermodynamic and convective properties.

Pittman, Jasna↗
NASA NTRS2005

A Multi-Sensor Approach To Estimation of Tropospheric Delays

We will discuss techniques for optima1 integration of atmospheric measurements from collocated GPS receiver, pointed WVR, and a barometer, capitalizing on the unique strength of each sensor, and minimizing the impact of the sensor's weaknesses. The goal is to improve our ability to estimate line of sight (LOS) total atmospheric delay, which is required in support of certain high precision applications, such as radio science, and deep space navigation. The benefits from improved atmospheric sensing extend to many other applications such as geodesy and time transfer.

optical integration↗
NASA NTRS2010

TERRA Battery Thermal Control Anomaly - Simulation and Corrective Actions

The TERRA spacecraft was launched in December 1999 from Vandenberg Air Force Base, becoming the flagship of NASA's Earth Observing System program to gather data on how the planet's processes create climate. Originally planned as a 5 year mission, it still provides valuable science data after nearly 10 years on orbit. On October 13th, 2009 at 16:23z following a routine inclination maneuver, TERRA experienced a battery cell failure and a simultaneous failure of several battery heater control circuits used to maintain cell temperatures and gradients within the battery. With several cells nearing the minimum survival temperature, preventing the electrolyte from freezing was the first priority. After several reset attempts and power cycling of the control electronics failed to reestablish control authority on the primary side of the controller, it was switched to the redundant side, but anomalous performance again prevented full heater control of the battery cells. As the investigation into the cause of the anomaly and corrective action continued, a battery thermal model was developed to be used in determining the control ability remaining and to simulate and assess corrective actions. Although no thermal model or detailed reference data of the battery was available, sufficient information was found to allow a simplified model to be constructed, correlated against pre-anomaly telemetry, and used to simulate the thermal behavior at several points after the anomaly. It was then used to simulate subsequent corrective actions to assess their impact on cell temperatures. This paper describes the rapid development of this thermal model, including correlation to flight data before and after the anomaly., along with a comparative assessment of the analysis results used to interpret the telemetry to determine the extent of damage to the thermal control hardware, with near-term corrective actions and long-term operations plan to overcome the anomaly.

Grob, Eric W.↗
NASA NTRS2012

Space Telescope Sensitivity and Controls for Exoplanet Imaging

Herein we address design considerations and outline requirements for space telescopes with capabilities for high contrast imaging of exoplanets. The approach taken is to identify the span of potentially detectable Earth-sized terrestrial planets in the habitable zone of the nearest stars within 30 parsecs and estimate their inner working angles, flux ratios, SNR, sensitivities, wavefront error requirements and sensing and control times parametrically versus aperture size. We consider 1, 2, 4, 8 and 16-meter diameter telescope apertures. The achievable science, range of telescope architectures, and the coronagraphic approach are all active areas of research and are all subject to change in a rapidly evolving field. Thus, presented is a snapshot of our current understanding with the goal of limiting the choices to those that appear currently technically feasible. We describe the top-level metrics of inner working angle, contrast and photometric throughput and explore how they are related to the range of target stars. A critical point is that for each telescope architecture and coronagraphic choice the telescope stability requirements have differing impacts on the design for open versus closed-loop sensing and control.

Wavefront control↗
NASA NTRS2013

Advanced UVOIR Mirror Technology Development (AMTD) for Very Large Space Telescopes

ASTRO2010 Decadal Survey stated that an advanced large-aperture ultraviolet, optical, near-infrared (UVOIR) telescope is required to enable the next generation of compelling astrophysics and exoplanet science; and, that present technology is not mature enough to affordably build and launch any potential UVOIR mission concept. AMTD is the start of a multiyear effort to develop, demonstrate and mature critical technologies to TRL-6 by 2018 so that a viable flight mission can be proposed to the 2020 Decadal Review. AMTD builds on the state of art (SOA) defined by over 30 years of monolithic & segmented ground & space-telescope mirror technology to mature six key technologies: (1) Large-Aperture, Low Areal Density, High Stiffness Mirror Substrates: Both (4 to 8 m) monolithic and (8 to 16 m) segmented primary mirrors require larger, thicker, and stiffer substrates. (2) Support System: Large-aperture mirrors require large support systems to ensure that they survive launch and deploy on orbit in a stress-free and undistorted shape. (3) Mid/High Spatial Frequency Figure Error: Very smooth mirror is critical for producing high-quality point spread function (PSF) for high contrast imaging. (4) Segment Edges: The quality of segment edges impacts PSF for high-contrast imaging applications, contributes to stray light noise, and affects total collecting aperture. (5) Segment to Segment Gap Phasing: Segment phasing is critical for producing high-quality temporally-stable PSF. (6) Integrated Model Validation: On-orbit performance is driven by mechanical & thermal stability. Compliance cannot be 100% tested, but relies on modeling. AMTD is pursuing multiple design paths to provide the science community with options to enable either large aperture monolithic or segmented mirrors with clear engineering metrics traceable to science requirements.

Postman, Marc↗
NASA NTRS2014

Overview and Summary of Advanced UVOIR Mirror Technology Development (AMTD) Project

ASTRO2010 Decadal Survey stated that an advanced large-aperture ultraviolet, optical, near-infrared (UVOIR) telescope is required to enable the next generation of compelling astrophysics and exoplanet science; and, that present technology is not mature enough to affordably build and launch any potential UVOIR mission concept. AMTD is a multiyear effort to develop, demonstrate and mature critical technologies to TRL-6 by 2018 so that a viable flight mission can be proposed to the 2020 Decadal Review. AMTD builds on the state of art (SOA) defined by over 30 years of monolithic & segmented ground & space-telescope mirror technology to mature six key technologies: center dotLarge-Aperture, Low Areal Density, High Stiffness Mirror Substrates: Both (4 to 8 m) monolithic and (8 to 16 m) segmented telescopes require larger and stiffer mirrors. center dotSupport System: Large-aperture mirrors require large support systems to ensure that they survive launch, deploy on orbit, and maintain a stable, undistorted shape. center dotMid/High Spatial Frequency Figure Error: Very smooth mirror is critical for producing high-quality point spread function (PSF) for high contrast imaging. center dotSegment Edges: The quality of segment edges impacts PSF for high-contrast imaging applications, contributes to stray light noise, and affects total collecting aperture. center dotSegment to Segment Gap Phasing: Segment phasing is critical for producing high-quality temporally-stable PSF. center dotIntegrated Model Validation: On-orbit performance is driven by mechanical & thermal stability. Compliance cannot be 100% tested, but relies on modeling. Because we cannot predict the future, AMTD is pursuing multiple design paths to provide the science community with options to enable either large aperture monolithic or segmented mirrors with clear engineering metrics traceable to science requirements

Stahl, H. Philip↗
NASA NTRS2018

Surprising Results from Large Crowds Using Micro-Purchase Challenges - Using Contests on Freelancing Communities to Source Innovative, Impactful and Cost-Effective Solutions

Our world is more connected than ever before. The new digital economy is empowering platforms and crowds to become a progressively strategic way for organizations to innovate ahead of their competition. Existing research shows the effectiveness and quality of solutions crowdsourcing yields, yet few organizations genuinely understand it nor are leveraging those solutions to unlock the full range of benefits. Moreover, early adopters often face structural and financial barriers towards evangelizing digital platforms at scale within their organizations. NASA is an exception - being an advocate of the field since 2010, it has paved the path for large organizations to follow. An empirical analysis is conducted on NASA's Center of Excellence for Collaborative Innovation (CoECI) micro-purchase challenges on a crowd-based platform to assess the cost-savings, quality of work, time for work turnaround and brand effects of using this problem-solving mechanism. The results proved to provide a tangible impact on all four parameters. As such, micro-purchases could become a compelling entry-point for organizations who are willing to experiment and subsequently build a convincing business case to present to stakeholders. The paper concludes with NASA's learnings, supplemented by literature, on how to redesign business processes, change conventional thinking and create an organization that will transform its future with crowds.

Tang, Sarah↗
NASA NTRS2022

The Development of a Real-Time Optical Angle-of-Attack Measurement Capability at the NASA Ames Unitary Plan Wind Tunnel

The following details the implementation of a real-time optical angle-of-attack capability under development at the NASA Ames Unitary Plan Wind Tunnel (UPWT). Recent advancements in the integration of high bandwidth imaging systems at the Ames UPWT has laid the groundwork for the deployment of a calibrated, imaging based measurement capability. Some of the measurement goals of this data system include: an estimation of the orientation of a wind tunnel model to six degrees of freedom, measurements made at framerates high enough to time resolve model dynamics, triangulate corresponding points of interest from multiple camera views in three-dimensional space, acquire imagery with no impact to the productivity of the test matrix, provide results in real-time, and finally compute an estimation of the errors associated with the measurement. The following will outline the imaging hardware and data systems architecture, describe the data flow and image processing routines currently implemented, and explore example data and results from previous wind tunnel test entries.

Ground Testing↗
NASA NTRS2021

Late Glacial and Holocene Environmental Variability, Lago Trasimeno, Italy

Lago Trasimeno (central Italy), 10 km wide and < 6m deep, fills a basin of tectonic origin, and is one of Europe's few endorheic lakes. We report on a multidisciplinary stratigraphic study based on seismic reflection profiles and two sediment cores, aimed at providing information on the vegetational, lithological, and climate history of this area. Trace elements, palynology, macrofossils, organic carbon, and C isotopes, coupled with AMS C-14 dating, describe environmental changes from Late-Glacial to present. The base of the cores records a Late-Glacial steppic vegetation (Poaceae, Artemisia, Amaranthaceae), with dry and cold conditions and a high charcoal/pollen ratio. An ensuing shift to a warmer and moister climate is shown by the rise of Pinus and Quercus, and shallow water aquatics such as Nitella. Early Holocene warming, indicated by Quercus, Oleaceae, Corylus, and Betula, is followed by a hiatus suggesting one or more severe drought events between 9000 and 3000 yr BP. Late Holocene presence of Alnus and Fagus indicates increased moisture, probably in winter, which would have increased lake level. Heavy metal pollution indicators (Pb, Cu, Zn) in the upper portion of the cores imply industrialization. Due to its location, to intensive and uninterrupted anthropogenic impacts since proto historical times, and to its shallow depths, Lago Trasimeno provides an important observation point for climate and environmental changes in the central Mediterranean region during and before Holocene times.

Lago trasimeno↗
NASA NTRS2017

Computational Modeling to Limit the Impact Displays and Indicator Lights Have on Habitable Volume Operational Lighting Constraints

NASA has demonstrated an interest in improving astronaut health and performance through the installment of a new lighting countermeasure on the International Space Station. The Solid State Lighting Assembly (SSLA) system is designed to positively influence astronaut health by providing a daily change to light spectrum to improve circadian entrainment. Unfortunately, existing NASA standards and requirements define ambient light level requirements for crew sleep and other tasks, yet the number of light-emitting diode (LED) indicators and displays within a habitable volume is currently uncontrolled. Because each of these light sources has its own unique spectral properties, the additive lighting environment ends up becoming something different from what was planned or researched. Restricting the use of displays and indicators is not a solution because these systems provide beneficial feedback to the crew. The research team for this grant used computer-based computational modeling and real-world lighting mockups to document the impact that light sources other than the ambient lighting system contribute to the ambient spectral lighting environment. In particular, the team was focused on understanding the impacts of long-term tasks located in front of avionics or computer displays. The team also wanted to understand options for mitigating the changes to the ambient light spectrum in the interest of maintaining the performance of a lighting countermeasure. The project utilized a variety of physical and computer-based simulations to determine direct relationships between system implementation and light spectrum. Using real-world data, computer models were built in the commercially available optics analysis software Zemax Optics Studio(c). The team also built a mockup test facility that had the same volume and configuration as one of the Zemax models. The team collected over 1200 spectral irradiance measurements, each representing a different configuration of the mockup. Analysis of the data showed a measurable impact on ambient light spectrum. This data showed that obvious design techniques exist that can be used to bind the ambient light spectrum closer to the planned spectral operating environment for the observer's eye point. The following observations should be considered when designing an operational environment that is dominated by computer displays. When more light is directed into the field of view of the observer, the greater the impact it will make on various human factors issues that depend on spectral shape and intensity. Because viewing angle has a large part to play in the amount of light flux on the crewmember's retina, beam shape, combined with light source location is an important factor for determining percent probable incident flux on the observer from any combination of light sources. Computer graphics design and display lumen output are major factors influencing the amount of spectrally intense light projected into the environment and in the viewer's direction. Use of adjustable white point display software was useful only if the predominant background color was white and if it matched the ambient light system's color. Display graphics that used a predominantly black background had the least influence on unplanned spectral energy projected into the environment. Percent reflectance makes a difference in total energy reflected back into an environment, and within certain architectural geometries, reflectance can be used to control the amount of a light spectrum that is allowed to perpetuate in the environment. Data showed that room volume and distance from significant light sources influence the total spectrum in a room. Smaller environments had a homogenizing effect on total light spectrum, whereas light from multiple sources in larger environments was less mixed. The findings indicated above should be considered when making recommendations for practice or standards for architectural systems. The ambient lighting system, surface reflectance, and display and indicator implementation all factor into the users' spectral environment. A variety of low-cost solutions exist to mitigate the impact of light from non-architectural lighting systems, and much potential for system automation and integration of display systems with the ambient environment. This team believes that proper planning can be used to avoid integration problems and also believes that human-in-the-loop evaluations, real-world test and measurement, and computer modeling can be used to determine how changes to a process, display graphics, and architecture will help maintain the planned spectral operating lighting environment.

Clark, T. A.↗
NASA NTRS2011

How WISE Points to Future Far-Infrared Missions

Based on the tantalizing science that is emerging from the first WISE discoveries, we consider the impact that the future will bring to far-infrared mission concepts. What we've learned from WISE gives us new investigations for missions like SPICA and SPIRIT. We highlight the new results from WISE and incorporate that into the context of the Far-Infrared Community Plan and the recent New Worlds, New Horizons documents. Plain-Language Abstract: Based on tantalizing science emerging from the first WISE discoveries, what we've learned gives us new investigations for missions like SPICA and SPIRIT. We highlight the new results from WISE and incorporate that into the context of the Far-Infrared Community Plan and the recent New Worlds, New Horizons documents.

Benford, Dominic J.↗
NASA NTRS1999

Validation of Landsat-7 ETM+ MEM Thermal Improvement in Thermal Vacuum Tests and in Flight Due to Lower Louver Set Points

The Enhanced Thematic Mapper Plus (ETM+) Main Electronics Module (MEM) power supply heat sink temperature is critical to the Landsat-7 mission. It is strongly dependent on the thermal louver design. A lower power supply heat sink temperature increases the reliability of the MEM, and reduces the risk of over heating and thermal shut-down. After the power supply failures in ETM+ instrument thermal vacuum tests #1 and #2, the author performed detailed thermal analyses of the MEM, and proposed to reduce the louver set-points by 7C. At the 1998 Intersociety Energy Conversion Engineering Conference (IECEC), the author presented a paper that included results of thermal analysis of the MEM. It showed that a 70C reduction of the louver set points could reduce the maximum power supply heat sink temperature in thermal vacuum test and in flight to below 20"C in the cooler outgas mode and in the nominal imaging mode, and has no significant impact on the standby heater duty cycle. It also showed that the effect of Earth infrared and albedo on the power supply heat sink temperature is small. The louver set point reduction was implemented in June 1998, just prior to ETM+ thermal vacuum test #3. Results of the thermal vacuum tests, and temperature data in flight validate the MEM thermal performance improvement due to the 70C reduction of the louver set points.

Choi, Michael K.↗
NASA NTRS2022

LECTURE 8: Understanding Global Cloud Radiative Impacts

The influence of clouds on the radiation budget is one of the most important facets of the Earth’s climate. Satellite observations in the last 35 years have helped us understand the bulk radiative effects of different classes of clouds. Bill Rossow has spearheaded efforts in that direction, demonstrating the value of the International Satellite Cloud Climatology Project (ISCCP) cloud retrievals as a foundation for the full reconstruction of Earth’s Radiation Budget components. This main aim of this document is to provide an overview of the global radiative impacts of clouds at annual time scales. While geographical and seasonal aspects receive some attention, it is cloud radiative effect decomposition by cloud category (or“class” ) that is the main focal point. Furthermore, this document addresses the large-scale radiative behavior of clouds only for the current climate, with no further discussion of how this behavior may change in the future and what its climatic impact may be [please refer to Del Genio (2018) for an excellent overview of this topic]. Cloud classes can be defined in many ways, and are often referred to with terms such as “cloud type”and “cloud regime”. Some of the definitions are more meaningful at the level of individual instrument footprints (“pixels” for passive or “rays” for active satellite observations) while others for larger areas (e.g., “mesoscale”).This distinction will become apparent below.

Lazaros Oreopoulos↗
NASA NTRS2019

Impact of Assimilating Adaptively Thinned AIRS Cloud-Cleared Radiances in the GEOS

This work examines the assimilation of AIRS (Atmospheric Infrared Sounder) radiances from two points of view: the thinning strategy and the use of cloud-cleared radiances as opposed to clear-sky. Previous published work by this team, based on a very large set of Observing System Experiments performed with a 2014 3DVAR version of the GEOS (Goddard Earth Observing System), has shown that the assimilation of adaptively thinned AIRS cloud-cleared radiances (CCRs) improves the representation of tropical cyclones (TCs) without damaging the global forecast skill. The simple adaptive methodology is based on denser AIRS coverage in moving domains centered on TCs, and sparser coverage everywhere else. Subsequent experiments showed that the adaptive methodology produces good results also when applied to clear-sky CrIS (Cross-track Infrared Sounder) and IASI (Infrared Atmospheric Sounding Interferometer) radiances. In addition, the results indicate that the density of all hyperspectral data assimilated over meteorologically inactive areas is excessive, probably because of horizontal error correlation, suggesting that the global thinning should be more aggressive. More recent work focused on the polar regions has shown another positive impact of assimilating cloud-cleared AIRS radiances instead of clear-sky. The results show that high latitude atmospheric dynamics is very sensitive to the representation of the lower tropospheric temperature structure over the Arctic region. Specifically, assimilation of CCRs over areas that are data poor and also affected by broken stratus clouds, and as such minimally observed by AIRS clear-sky radiances, changes substantially the temperature structure over the Arctic low troposphere. Ingestion of CCRs over the region propagates, through hydrostatic adjustments, to mid-tropospheric geopotential height, allowing for better prediction of mid-latitude waves. In addition, adaptively thinned CCRs also improve the representation of mesoscale convective cyclones at high latitudes. An example of an Antarctic low is provided. Finally, recent ongoing work with the hybrid 4DenVAR GEOS, investigating the 2017 boreal TC season, has confirmed the previous results: namely that aggressively thinned cloud-cleared radiances improve TC structure with no loss of global skill.

CCR↗
NASA NTRS1973

Conical scan impact study. Volume 1: General central data processing facility

The impact of a conical scan versus a linear scan multispectral scanner (MSS) instrument was studied in terms of: (1) design modifications required in framing and continuous image recording devices; and (2) changes in configurations of an all-digital precision image processor. A baseline system was defined to provide the framework for comparison, and included pertinent spacecraft parameters, a conical MSS, a linear MSS, an image recording system, and an all-digital precision processor. Lateral offset pointing of the sensors over a range of plus or minus 20 deg was considered. The study addressed the conical scan impact on geometric, radiometric, and aperture correction of MSS data in terms of hardware and software considerations, system complexity, quality of corrections, throughput, and cost of implementation. It was concluded that: (1) if the MSS data are to be only film recorded, then there is only a nomial concial scan impact on the ground data processing system; and (2) if digital data are to be provided to users on computer compatible tapes in rectilinear format, then there is a significant conical scan impact on the ground data processing system.

Ebert, D. H.↗
NASA NTRS1994

Heat capacity and thermal relaxation of bulk helium very near the lambda point

In October 1992 a low temperature experiment was flown on the Space Shuttle in low Earth orbit. The objective of the mission was to measure the heat capacity and thermal conductivity of helium very close to the lambda point with the smearing effect of gravity removed. We report preliminary results from the experiment, and compare them with related measurements performed on the ground. The sample was s sphere of helium 3.5 cm in diameter contained within a copper calorimeter of vey high thermal conductivity. The calorimeter was attached to a pair of high resolution paramagnetic salt thermometers with noise levels in the 10(exp -10) K range and suspended from a high stability thermal isolation system. During the mission we found that the resolution of the thermometers was degraded somewhat due to the impact of charged particles. This effect limited the useful resolution of the measurements to about two nanokelvins from the lambda point. The results reported here are limited to about ten nanokelvins from the transition.

Lipa, John A.↗
NASA NTRS2010

Evaluation of Enhanced High Resolution MODIS/AMSR-E SSTs and the Impact on Regional Weather Forecast

Over the last few years, the NASA Short-term Prediction Research and Transition (SPoRT) Center has been generating a 1-km sea surface temperature (SST) composite derived from retrievals of the Moderate Resolution Imaging Spectroradiometer (MODIS) for use in operational diagnostics and regional model initialization. With the assumption that the day-to-day variation in the SST is nominal, individual MODIS passes aboard the Earth Observing System (EOS) Aqua and Terra satellites are used to create and update four composite SST products each day at 0400, 0700, 1600, and 1900 UTC, valid over the western Atlantic and Caribbean waters. A six month study from February to August 2007 over the marine areas surrounding southern Florida was conducted to compare the use of the MODIS SST composite versus the Real-Time Global SST analysis to initialize the Weather Research and Forecasting (WRF) model. Substantial changes in the forecast heat fluxes were seen at times in the marine boundary layer, but relatively little overall improvement was measured in the sensible weather elements. The limited improvement in the WRF model forecasts could be attributed to the diurnal changes in SST seen in the MODIS SST composites but not accounted for by the model. Furthermore, cloud contamination caused extended periods when individual passes of MODIS were unable to update the SSTs, leading to substantial SST latency and a cool bias during the early summer months. In order to alleviate the latency problems, the SPoRT Center recently enhanced its MODIS SST composite by incorporating information from the Advanced Microwave Scanning Radiometer-EOS (AMSR-E) instruments as well as the Operational Sea Surface Temperature and Sea Ice Analysis. These enhancements substantially decreased the latency due to cloud cover and improved the bias and correlation of the composites at available marine point observations. While these enhancements improved upon the modeled cold bias using the original MODIS SSTs, the discernable impacts on the WRF model were still somewhat limited. This paper explores several factors that may have contributed to this result. First, the original methodology to initialize the model used the most recent SST composite available in a hypothetical real ]time configuration, often matching the forecast initial time with an SST field that was 5-8 hours offset. To minimize the differences that result from the diurnal variations in SST, the previous day fs SST composite is incorporated at a time closest to the model initialization hour (e.g. 1600 UTC composite at 1500 UTC model initialization). Second, the diurnal change seen in the MODIS SST composites was not represented by the WRF model in previous simulations, since the SSTs were held constant throughout the model integration. To address this issue, we explore the use of a water skin-temperature diurnal cycle prediction capability within v3.1 of the WRF model to better represent fluctuations in marine surface forcing. Finally, the verification of the WRF model is limited to very few over-water sites, many of which are located near the coastlines. In order to measure the open ocean improvements from the AMSR-E, we could use an independent 2-dimensional, satellite-derived data set to validate the forecast model by applying an object-based verification method. Such a validation technique could aid in better understanding the benefits of the mesoscale SST spatial structure to regional models applications.

Schiferl, Luke D.↗
DOE OSTI2025

Global Impacts of Marine Methanethiol Emissions and Chemistry in the Atmosphere

Oceanic emissions of dimethyl sulfide (DMS) have long been known to influence aerosol particle composition, cloud condensation nuclei (CCN) concentration, and Earth’s radiative budget. However, the impact of oceanic emissions of methanethiol (MeSH), a sulfur compound produced by the same oceanic precursor as DMS, has been relatively less explored. The gas-phase oxidation of MeSH has a higher effective yield of SO 2 and a shorter oxidative lifetime compared to DMS, highlighting the relevance of this pathway for the modeled representation of particle formation, growth, and CCN abundance in the marine atmosphere. Here, we use the global chemical transport model GEOS-Chem to explore possible scenarios representative of specific environmental conditions and MeSH emission schemes based on previous experimental studies. We further implement and test previously reported chemical mechanisms for MeSH oxidation, along with additional improvements, highlighting key uncertainties and sensitivities for regional and global sulfur budgets. We place our results in the context of recent modeling updates to DMS chemistry and cloud processing, which further impact SO 2 production in the marine atmosphere in parallel with MeSH oxidation. Within the overall marine sulfur budget, our findings highlight that MeSH plays a significant role in SO 2 production in the marine atmosphere, contributing to regional surface layer concentration increases of up to 40–60%. These results point to the importance of MeSH for efforts aimed at improving the modeled representation of sulfur spatiotemporal patterns relevant to air quality predictions and climate impact assessments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗