<study of isothermal and adiabatic calorimetry of alkaline cells< semiannual status report, 1 oct. 1964 - 1 apr. 1965
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Bruins, P. F.↗
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Development of cathodic electrocatalysts for use in low temperature H2/O2 fuel cells with an alkaline electrolyte First quarterly report, Jul. 1 - Sep. 30, 1965
Potentiostatic and corrosion resistance tests for metallic ingots prepared as rotating disk electrodes - cathodic electrocatalysts for use in low temperature hydrogen-oxygen fuel cells
ROTATING DISK↗
Oxygen reduction on titanium nitride in alkaline electrolyte.
Oxygen reduction on titanium nitride noting rate of electrochemical oxidation in fuel cell studies
ELECTROCHEMICAL OXIDATION↗
Development of cathodic electrocatalysts for use in low temperature H2/O2 fuel cells with an alkaline electrolyte Quarterly report 1 Oct. - 31 Dec. 1966
Carbides, nitrides, nitrocarbides, and carbonitrides of iron examined for catalytic activity in oxygen reduction reaction in potassium hydroxide - peroxide fuel cells
CATALYTIC ACTIVITY↗
Studies of reaction geometry in oxidation and reduction of the alkaline silver electrode Quarterly report
Polarization curve of silver anode in ammoniacal electrolyte - Effective electrolytic surface area of sintered silver electrodes - Ultrasonic vibration effects on oxidation of electrode
ELECTROCHEMICAL OXIDATION↗
Separator for alkaline batteries
Separator compositions have been tested as components of three-plate silver-zinc oxide cells in a standard cycling test. Six materials meet imposed requirements, giving cycling performance superior to cellophane.
Hoyt, H. W.↗
Development of an improved oxygen electrode for use in alkaline H2-O2 fuel cells Quarterly report, Apr. 1 - Jun. 30, 1967
Preparation of institial compounds of transition metals for hydrogen oxygen fuel cell cathodes
Akhtar, S.↗
Studies of reaction geometry in oxidation and reduction of the alkaline silver electrode Quarterly report
Determination of effective electrolytic surface area of sintered and foil silver electrodes subjected to oxidation at various current densities in ammoniacal medium
Blackham, A. U.↗
Studies of reaction geometry in oxidation and reduction of the alkaline silver electrode Final report
Reaction of sintered silver electrode to oxidation and reduction
Blackham, A. U.↗
Development of an improved oxygen electrode for use in alkaline h2-o2 fuel cells quarterly report, 1 jul. - 30 sep. 1967
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Development of cathodic electrocatalysts for use in low temperature h2/02 fuel cells with an alkaline electrolyte
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Giner, J.↗
Primary radical yields in pulse irradiated alkaline aqueous solution
Primary radical yields of hydrated electrons, H atoms, and OH radicals are determined by measuring hydrated electron formation following a 4 microsecond pulse of X rays. The pH dependence of free radical yields beyond pH 12 is determined by observation of the hydrated electrons.
Fielden, E. M.↗
Improved alkaline electrochemical cell
Addition of lead ions to electrolyte suppresses zinc dendrite formation during charging cycle. A soluble lead salt can be added directly or metallic lead can be incorporated in the zinc electrode and allowed to dissolve into the electrolyte.
Fleischmann, C. W.↗
Electrodeposited inorganic separators for alkaline batteries
Coating electrodes of silver-cadmium cells with thermostable electrodeposits of calcium hydroxide or magnesium hydroxide reduces silver migration and increases cell life. Absence of organic matter enables assembled cells to be sterilized without oxidation of the material of the separators.
Carson, W. N., Jr.↗
Investigation of electrode materials for alkaline batteries Quarterly report, no. 7
Silver oxides for use as amalgam electrodes and their thermal decomposition
Arcand, G. M.↗
Alkaline battery separators characterization studies Quarterly report
Separator materials characterization tests for silver-zinc batteries
Source record↗
Oxygen reduction on gold alloys in alkaline electrolyte
Gold alloys electrocatalytic activity in cathodic reduction of oxygen in potassium hydroxide
Giner, J.↗
Investigation of electrode materials for alkaline batteries
A number of amalgam electrode systems were investigated for possible use as high rate anodes and cathodes. The systems examined include: lithium, sodium, and potassium in Group 1, magnesium, calcium, and barium in Group 2, aluminum in Group 3, lead in Group 4, copper in Group 1b, and zinc and cadmium in Group 2b. The K(Hg) and Na(Hg) anodes in 10 VF and 15 VF (an unambiguous expression of concentration that indicates the number of formula weights of solute dissolved in a liter of solution) hydroxide solutions have proven satisfactory; some of these have produced current densities of more than 8 A/sq cm. None of the amalgam cathodes have approached this performance although the TI(Hg) has delivered 1 A/sq cm. Se(Hg) and Te(Hg) cathodes have given very stable discharges. Zn(Hg) and Cd(Hg) electrodes did not show good high rate characteristics, 200 to 300 mA/sq cm being about the maximum current densities obtainable. Both anodes are charged through a two-step process in which M(Hg) is first formed electrochemically and subsequently reduces Zn(II or Cd(II) to form the corresponding amalgam. The second step is extremely rapid for zinc and very slow for cadmium.
Arcand, G. M.↗