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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Probabilistic estimation of depth-resolved profiles of soil thermal diffusivity from temperature time series

Abstract. Improving the quantification of soil thermal and physical properties is key to achieving a better understanding and prediction of soil hydro-biogeochemical processes and their responses to changes in atmospheric forcing. Obtaining such information at numerous locations and/or over time with conventional soil sampling is challenging. The increasing availability of low-cost, vertically resolved temperature sensor arrays offers promise for improving the estimation of soil thermal properties from temperature time series, and the possible indirect estimation of physical properties. Still, the reliability and limitations of such an approach need to be assessed. In the present study, we develop a parameter estimation approach based on a combination of thermal modeling, sliding time windows, Bayesian inference, and Markov chain Monte Carlo simulation to estimate thermal diffusivity and its uncertainty over time, at numerous locations and at an unprecedented vertical spatial resolution (i.e., down to 5 to 10 cm vertical resolution) from soil temperature time series. We provide the necessary framework to assess under which environmental conditions (soil temperature gradient, fluctuations, and trend), temperature sensor characteristics (bias and level of noise), and deployment geometries (sensor number and position) soil thermal diffusivity can be reliably inferred. We validate the method with synthetic experiments and field studies. The synthetic experiments show that in the presence of median diurnal fluctuations ≥ 1.5 ∘C at 5 cm below the ground surface, temperature gradients > 2 ∘C m−1, and a sliding time window of at least 4 d the proposed method provides reliable depth-resolved thermal diffusivity estimates with percentage errors ≤ 10 % and posterior relative standard deviations ≤ 5 % up to 1 m depth. Reliable thermal diffusivity under such environmental conditions also requires temperature sensors to be spaced precisely (with accuracy to a few millimeters), with a level of noise ≤ 0.02 ∘C, and with a bias defined by a standard deviation ≤ 0.01 ∘C. Finally, the application of the developed approach to field data indicates significant repeatability in results and similarity with independent measurements, as well as promise in using a sliding time window to estimate temporal changes in soil thermal diffusivity, as needed to potentially capture changes in bulk density or water content.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2022

Probabilistic estimation of depth-resolved profiles of soil thermal diffusivity from temperature time series: Supporting Data

This dataset consists of soil temperature time series that were used to estimate soil thermal diffusivity and its uncertainty trough the probabilistic modelling approach developed and presented in the article named "Probabilistic estimation of depth-resolved profiles of soil thermal diffusivity from temperature time series" and published in Earth Surface Dynamics. There are two compressed (.zip) files that contains synthetic (Synthetic_soiltemp_Teller.zip) and field (Field_soiltemp_Teller.zip) data. There is one MATLAB file that requires MATLAB to execute but any text editor can open it. The Synthetic_soiltemp_Teller.zip file includes 5 comma-delimited data files (.csv) each of which contains soil temperature time series generated through forward modeling (i.e., heat-conduction process in a heterogeneous medium using an explicit finite difference method) to mimic various types of temperature gradients, trend and fluctuations. These synthetic soil temperatures were used to investigate the impact of different environmental conditions on the uncertainty of thermal diffusivity estimates. The Field_soiltemp_Teller.zip file contains 28 comma-delimited data files (.csv) out of which (a) 27 files includes soil temperature time series recorded from 27 temperature probes located in a site along Teller Road about 40 km northwest of Nome, Alaska (64.72°N, 165.94°W), (b) one includes the name and coordinates of the 27 probes. These field soil temperatures were used to infer soil thermal diffusivity at numerous locations and depths in a discontinuous permafrost environment, and to evaluate the links between the estimated soil thermal diffusivity values and soil physical properties. The comma-delimited data files (.csv) of the synthetic and field soil temperature time series includes date and time (UTC) in the first column and soil temperature from 5 cm below the ground surface to 1.05 m depth (with 5 or 10 cm spacing between sensors) in the other columns. The measurements were acquired every 15 minutes. The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1971

Development of lithium diffused radiation resistant solar cells, part 2

The work performed to investigate the effect of various process parameters on the performance of lithium doped P/N solar cells is described. Effort was concentrated in four main areas: (1) the starting material, (2) the boron diffusion, (3) the lithium diffusion, and (4) the contact system. Investigation of starting material primarily involved comparison of crucible grown silicon (high oxygen content) and Lopex silicon (low oxygen content). In addition, the effect of varying growing parameters of crucible grown silicon on lithium cell output was also examined. The objective of the boron diffusion studies was to obtain a diffusion process which produced high efficiency cells with minimal silicon stressing and could be scaled up to process 100 or more cells per diffusion. Contact studies included investigating sintering of the TiAg contacts and evaluation of the contact integrity.

Payne, P. R.↗
NASA NTRS1971

Electron pitch-angle diffusion driven by oblique whistler-mode turbulence.

A general description of cyclotron harmonic resonant pitch-angle scattering is presented. Quasi-linear diffusion coefficients are prescribed in terms of the wave normal distribution of plasma wave energy. Numerical computations are performed for the specific case of relativistic electrons interacting with a band of low frequency whistler-mode turbulence. A parametric treatment of the wave energy distribution permits normalized diffusion coefficients to be presented graphically solely as a function of the electron pitch-angle. The diffusion coefficients generally decrease with increasing cyclotron harmonic number. Higher harmonic diffusion is insignificant at very small electron pitch-angles, but becomes increasingly important as the pitch-angle increases. One thus expected the rate of pitch-angle scattering to decrease with increasing electron energy, since the resonant value of the latter varies proportionately with harmonic number. This indicates that, in mirror-type magnet field geometrics, such as the earth's radiation belts, the diffusion losses of high energy electrons are likely to be appreciably slower than those at low energy.

Lyons, L. R.↗
NASA NTRS1972

Inner-zone energetic-electron repopulation by radial diffusion.

Quantitative study of the intrusion of natural electrons into the inner radiation zone during and after the geomagnetic storm of Sept. 2, 1966. It is shown that the transport is consistent with a radial-diffusion mechanism in which the first two invariants are conserved. Except for the three-day period of the storm main phase when data were missing, the radial-diffusion coefficient is found to have a value which could be produced by a variation of a large-scale electric field across the magnetosphere having an amplitude of 0.28 mV/m and a period of 1600 sec. Electric fields having approximately these characteristics have been inferred from previous observations of the motion of whistler ducts within the plasmapause. If fields of this amplitude and period exist throughout the magnetosphere, the radial diffusion of all geomagnetically trapped particles except the high-energy inner-zone protons is strongly influenced by electric-field variations. A comprehensive review of previously reported radial-diffusion coefficients shows reasonable agreement for L less than about 3.0, but serious discrepancies among reported values exist for determinations made in the outer zone. These discrepancies cannot be explained by the simple theory of radial diffusion due to variation of large-scale electric or magnetic fields.

Tomassian, A. D.↗
NASA NTRS1972

Resonant diffusion in the presence of strong plasma turbulence.

The diffusion equation which describes the evolution of the average one-particle distribution function for an ensemble of strongly turbulent plasmas is derived. The diffusion tensor is a time integral of the autocorrelation tensor of the fluctuations as observed by particles moving along statistically distributed orbits. These orbits contain the effects of fluctuations and thus differ from those encountered in weak turbulence theory. Two statistical orbit effects quadratic in the strength of the fluctuations affect the magnitude of the diffusion: (a) modification of the ensemble average orbits by the fluctuations, and (b) statistical dispersion in particle orbits about the average. The plasma trajectory equations are used to relate each to the diffusion tensor itself when the turbulence is electrostatic. The diffusion tensor is explicitly evaluated for a strongly turbulent unmagnetized plasma.

Birmingham, T. J.↗
NASA NTRS1973

Diffusion across the modified polyethylene separator GX in the heat-sterilizable AgO-Zn battery

Models of diffusion across an inert membrane have been studied using the computer program CINDA. The models were constructed to simulate various conditions obtained in the consideration of the diffusion of Ag (OH)2 ions in the AgO-Zn battery. The effects on concentrations across the membrane at the steady state and on the fluxout as a function of time were used to examine the consequences of stepwise reducing the number of sources of ions, of stepwise blocking the source and sink surfaces, of varying the magnitude of the diffusion coefficient for a uniform membrane, of varying the diffusion coefficient across the membrane, and of excluding volumes to diffusion.

Lutwack, R.↗
NASA NTRS1973

Effects of diffusion on aluminum depletion and degradation of NiAl coatings

Experiments were performed to critically demonstrate the effects of diffusion on the aluminum depletion and degradation of NiAl coatings on superalloys. Pack aluminized IN 100 and Mar-M200 were diffusion annealed in 0.0005 torr vacuum at 1100 C for 300 hours. Aluminum losses due to oxidation and vaporization were minimal. Metallographic and electron microprobe analyses showed considerable interdiffusion of the coating with the substrate, which caused a large decrease in the original aluminum level of the coating. Subsequent cyclic furnace oxidation tests were performed at 1100 C using 1 hour cycles on pre-diffused and as-coated specimens. The pre-diffusion treatment decreased the oxidation protection for both alloys, but more dramatically for IN 100. Identical oxidation tests of bulk NiAl, where such diffusion effects are precluded, showed no signs of degradation at twice the time needed to degrade the coated superalloys.

Smialek, J. L.↗
NASA NTRS1974

The diffusive idealization of charged particle transport in random magnetic fields

The transport of charged particles diffusing in a random magnetic field parallel to a relatively large guiding field is presented. The same coefficient of diffusion is obtained by three methods. Two corrections must be added to the expression in which the diffusive flux is proportional to the gradient of the density. Explicit expressions are given for a characteristic time and a characteristic length which describe the corrections. The well known divergence of the coefficient of diffusion, which is implied by the quasilinear analysis of pitch angle scattering, does not occur if the scattering rate is finite at 90 deg pitch angle. This effect is illustrated by formulas which give the coefficient of diffusion when the quasilinear expression is perturbed by a variable amount of isotropic scattering.

Earl, J. A.↗
NASA NTRS1974

The electron diffusion coefficient in Jupiter's magnetosphere

A steady-state model of Jupiter's electron radiation belt is developed. The model includes injection from the solar wind, radial diffusion, energy degradation by synchrotron radiation, and absorption at Jupiter's surface. A diffusion coefficient of the form D sub RR/R sub J squared = k times R to the m-th power is assumed, and then observed data on synchrotron radiation are used to fit the model. The free parameters determined from this fit are m = 1.95 plus or minus 0.5, k = 1.7 plus or minus 0.5 x 10 to the 9th power per sec, and the magnetic moment of injected particles equals 770 plus or minus 300 MeV/G. The value of m shows quite clearly that the diffusion is not caused by magnetic pumping by a variable solar wind or by a fluctuating convection electric field. The process might be field line exchange driven by atmospheric-ionospheric winds; our diffusion coefficient has roughly the same radial dependence but is considerably smaller in magnitude than the upper bound diffusion coefficients recently suggested for this process by Brice and McDonough (1973) and Jacques and Davis (1972).

Birmingham, T.↗
NASA NTRS1975

Better vacuum by removal of diffusion-pump-oil contaminants

The complex problem of why large space simulation chambers do not realize true ultimate vacuum was investigated. Some contaminating factors affecting diffusion pump performance were identified, and some advances in vacuum distillation-fractionation technology were achieved which resulted in a two-decade-or-more lower ultimate pressure. Data are presented to show the overall or individual contaminating effects of commonly used phthalate ester plasticizers of 390 to 530 molecular weight on diffusion pump performance. Methods for removing contaminants from diffusion pump silicone oil during operation and for reclaiming contaminated oil by high-vacuum molecular distillation are described. Conceptual self-cleansing designs and operating procedures are proposed for modifying large diffusion pumps into high-efficiency distillation devices. The potential exists for application of these technological advancements to other disciplines, such as medicine, biomedical materials, metallurgy, refining, and chemical (diffusion-enrichment) processing.

Buggele, A. E.↗
NASA NTRS1975

On upstream blocking in a viscous diffusive stratified flow

The effect of diffusion of specie upon the flow about a transverse flat plate moving horizontally in a viscous stratified medium is considered. Asymptotic expansions are used to define a parameter regime where a viscous-diffusive-buoyancy balance is dominant. The solution, expressed in terms of an inverse Fourier transform, is numerically integrated. The results show that, as in the non-diffusive problem, a region of closed streamlines exists ahead of the body. However, unlike the case where diffusion is neglected, the density field within this recirculating region is uniquely determined and found to be statically stable. It is also found that varying the relative amount of diffusion affects not only the density distribution, but the velocity profile as well, indicating a strong coupling between the vorticity and specie equation.

Koop, C. G.↗
NASA NTRS1975

An experimental and analytical investigation of axisymmetric diffusers

A finite difference computer program for turbulent compressible flow was used to establish the performance of several diffuser shapes for experimental testing. The diffusers were designed to have a linear change in Mach number, a linear change in pressure, or a curvature fitted by a quadratic equation. Testing was performed with M = 0.1 to 0.9 with and without boundary layer bleed. Above M = 0.6, data were obtained with a normal shock upstream of the diffuser entrance. Peak static pressure recovery occurred with a diffuser inlet M0.75. The quadratic diffuser yielded the highest total pressure recovery.

Povinelli, L. A.↗
NASA NTRS1975

An experimental and analytical investigation of axisymmetric diffusers

A finite difference computer program for turbulent compressible flow was used to establish the performance of several diffuser shapes for experimental testing. The diffusers were designed to have a linear change in Mach number, a linear change in pressure or a curvature fitted by a quadratic equation. Testing was performed with M = 0.1 to 0.9 with and without boundary layer bleed. Above M = 0.6, data were obtained with a normal shock upstream of the diffuser entrance. Peak static pressure recovery occurred with a diffuser inlet M-0.75. The quadratic diffuser yielded the highest total pressure recovery.

Povinelli, L. A.↗
NASA NTRS1976

Diffused waveguiding capillary tube with distributed feedback for a gas laser

For use in a waveguide gas laser, a capillary tube of glass or ceramic has an inner surface defining a longitudinal capillary opening through which the laser gas flows. At least a portion of the inner surface is corrugated with corrugations or channels with a periodicity Lambda where Lambda = 1/2 Lambda, Lambda being the laser gas wavelength. The tube includes a diffused region extending outwardly from the opening. The diffused region of a depth d on the order of 1 Lambda to 3 Lambda acts as a waveguide for the waves, with the corrugations producing distributed feedback. The evanescent component of the waves traveling in the diffused region interact with the laser gas in the opening, gaining energy, and thereby amplifying the waves travelling in the diffused region, which exit the diffused region, surrounding the opening, as a beam of wavelength Lambda.

Elachi, C.↗
NASA NTRS1977

Two-dimensional hygrothermal diffusions into a finite width composite laminate

Two dimensional hygroscopic diffusion into composite laminates with free edges was obtained through the use of a second order finite difference scheme. A computer program was developed for the transient nonlinear coupled hygrothermal diffusion into finite width laminates with varying surface conditions along two edges. The formulation permits the diffusion coefficient to be a function of temperature, moisture concentration, and fiber orientation. The moisture distributions thus obtained are necessary for analysis of the moisture induced interlaminar stresses in the vicinity of free edges. It is shown that large diffusion times tend to eliminate the significance of stacking sequence, but gradients within and between layers are significant for all diffusion times.

Farley, G. L.↗
NASA NTRS1977

Some basic mathematical methods of diffusion theory

An introductory treatment of the fundamentals of diffusion theory is presented, starting with molecular diffusion and leading up to the statistical methods of turbulent diffusion. A multilayer diffusion model, designed to permit concentration and dosage calculations downwind of toxic clouds from rocket vehicles, is described. The concepts and equations of diffusion are developed on an elementary level, with emphasis on atmospheric applications.

Giere, A. C.↗
NASA NTRS1977

The velocity correlation function in cosmic-ray diffusion theory

It is shown that Earl's (1973) eigenvalue sum for the cosmic-ray spatial diffusion coefficient parallel to the mean magnetic field is precisely equivalent to the time integral of the particle-velocity correlation function parallel to the mean field. A derivation due to Kubo (1957) is applied to cosmic-ray pitch-angle scattering, and it is proven that all nine components of the cosmic-ray diffusion tensor can be expressed as integrals over the velocity correlation function. A pitch-angle correlation function is derived, and the effect of long-wavelength turbulence on the velocity correlation function and spatial diffusion coefficients is examined. Application of the velocity-correlation method to a realistic case involving both pitch-angle scattering and appreciable fluctuation in the direction of the local field indicates that long-wavelength turbulence in the local field reduces the parallel diffusion coefficient and places an upper limit on the ratio of the perpendicular to parallel diffusion coefficients.

Forman, M. A.↗