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NASA NTRS1992

Electrons in the ionosphere of Titan

A theoretical model of the spatial and energy distribution of electrons in the ionosphere of Titan has been constructed using the two-stream electron transport method and the electron energy equation. The calculated electron spectra show abrupt decreases that can contribute to the 'bite-out' signature observed by the Voyager 1 plasma science instrument. Energy deposition rates in the exosphere of Titan by photoelectrons and magnetospheric electrons are calculated. Calculated N2 EUV airglow emission rates lead to the conclusion that airglow emission due to photoelectron impact is much more important than airglow emission due to magnetospheric electron interactions. Thermal electron temperatures at Titan are calculated for the first time. The electron gas remains well thermalized with the neutral atmosphere for radial distances from the center of Titan less than 3500 km. For radial distances beyond about 4000 km, energy transport dominates the energetics, and the electrons are almost isothermal along magnetic field lines.

Gan, L.↗
NASA NTRS1992

Upstream waves at Mars

Weak, about 0.15 nT, narrow band emissions at the proton gyro frequency are observed by the Phobos magnetometer MAGMA, upstream from the bow shock of Mars. These waves are left-hand elliptically polarized. They may be associated with the pick up of protons from the Martian hydrogen exosphere. Strong turbulence, similar to that observed at the terrestrial bow shock, is found on occasion in the upstream region when the IMF connects to the bow shock. On two occasions this turbulence occurred when the spacecraft crossed the orbit of Phobos. This coincidence raises the possibility that material in the orbits of Phobos interacts with the solar wind in such a way to either affect the direction of the IMF or to cause instabilities in the solar wind plasma. However, since on a third occasion these waves did not occur, these waves may be shock associated rather than Phobos associated.

Russell, C. T.↗
NASA NTRS1992

Lunar base activities and the lunar environment

The Moon is an attractive site for astronomical observatories and other facilities because of the absence of a substantial lunar atmosphere and the stability of the lunar surface. The present lunar atmosphere is sufficiently transparent that there is no significant image distortion due to absorption or refraction. This thin atmosphere results from a combination of small sources and prompt losses. The major source that has been identified is the solar wind, whose total mass input into the lunar atmosphere is approximately 50 gm/sec. The major components of the solar wind are light elements (H and He) that promptly escape from the lunar surface by exospheric evaporation (Jeans' escape). The principal atmospheric loss mechanism for heavier gases is photoionization within a period of weeks to months, followed by immediate loss to the solar wind. Lunar base activities will modify the lunar atmosphere if gas is released at a larger rate than that now occurring naturally. Possible gas sources are rocket exhaust, processing of lunar materials, venting of pressurized volumes, and astronaut life support systems. For even modest lunar base activity, such sources will substantially exceed natural sources, although effects are expected to be localized and transient. The Apollo database serves as a useful reference for both measurements of the natural lunar environment and its modification by lunar base activities.

Vondrak, Richard R.↗
NASA NTRS1992

Stellar lyman alpha emission and the local interstellar medium

Under the auspices of this ADP program, a systematic study was made of IUE archival images in order to extract spectra of the Lyman alpha region and to measure the stellar Lyman alpha flux for as many late-type stars as possible. The Lyman alpha resonance line is a powerful cooling channel for the hot chromospheres of solar-type stars, but has not been studied before in any systematic fashion across the H-R diagram. A major deterrent which has limited the use of Lyman alpha in the study of stellar chromospheres is the contamination of this spectral feature caused by the scattering of solar Lyman alpha photons in the Earth's exosphere. This scattered light is monochromatically imaged through the entrance slot of the IUE telescope and is superposed onto the stellar spectrum. In all but the shortest exposures with IUE, this 'geocoronal emission' overwhelms the stellar flux and makes it impossible to directly measure the strength of the stellar chromospheric feature. The IUESIPS processing contains no provision for correcting standard G.O. output products for this contamination. The first task was to develop a scheme for removing the geocoronal flux, specifically from low-dispersion spectra taken with the Short-Wavelength Camera of IUE. The strategy adopted was to fit a 'sky model' to the spatially-resolved geocoronal emission observed through the large science aperture of the telescope, using the spectral orders on either side of the central ones where the stellar emission is concentrated. The model emission was then subtracted from the observed image, leaving behind the corrected stellar Lyman alpha emission. The details of this fitting procedure are described. Having devised a successful method for removing the unwanted geocoronal emission, the correction procedure was applied to 366 archival images which, from inspection of the photowrites in the IUE browse file, seemed especially promising. In this survey, Lyman alpha emission were eventually detected in the spectra of 227 stars representing a wide range in age, temperature, and luminosity throughout the cool half of the H-R diagram. Previously fewer than 30 such stars had been measured, and an order of magnitude increase in the numbers of stars having Lyman alpha flux measurements is provided. Multiple measurements were made for 52 stars and upper limits on chromospheric flux were derived for another 48 stars.

Simon, Theodore↗
NASA NTRS1992

The Coronal Ultraviolet Berkeley Spectrometer (CUBS)

We describe an instrument package to remotely measure thermospheric, exospheric, and plasmaspheric structure and composition. This instrument was flown aboard the second test flight of the Black Brant XII sounding rocket on December 5, 1989, which attained an apogee of 1460 km. The experiment package consisted of a spectrophotometer to measure He I 584 A, O II 834 A, O I 989 A, hydrogen Lyman beta (1025 A), hydrogen Lyman alpha (1216 A), and O I 1304 A transitions, and a photometer to measure the He II 304 A emission. The optical design of the spectrophotometer was identical to that of the Berkeley Extreme Ultraviolet (EUV) Airglow Rocket Spectrometer payload, flown on September 30, 1988 aboard the maiden flight of the Black Brant XII rocket. We present the initial data analysis and describe directions we will go toward the completion of our study.

Bush, Brett C.↗
NASA NTRS1993

Maintaining the Na atmosphere of Mercury

The possible sources of the Na atmosphere of Mercury are calculatively studied. The likely structure, composition, and temperature of the planet's upper crust is examined along with the probable flux of Na from depth by grain boundary diffusion and by Knudsen flow. The creation of fresh regolith is considered along with mechanisms for supplying Na from the surface to the exosphere. The implications of the calculations for the probable abundances in the regolith are discussed.

Killen, Rosemary M.↗
NASA NTRS1993

Light ion flow in the nightside ionosphere of Venus

The flow characteristics of the light ions H(+) and He(+) have been studied in the midnight region of the ionosphere of Venus. Measurements of ion composition, electron and ion temperatures and magnetic fields by instruments onboard the Pioneer Venus Orbiter have been used in rite electron and ion equations of conservation of mass and momentum to derive the vertical flow velocities of H(+) and He(+). When average height profiles of the measured quantities were used, H(+) was found to flow upward, accelerating to speeds of almost 1 km/s at the ion-exobase. In a similar fashion, He(+) was found to flow downward into the neutral atmosphere where it is readily quenched by charge transfer reactions. The polarization electric field played an important role in forcing H(+) upward, but did not contribute enough to the He(+) force balance to produce upward flow. At the ion-exobase, the outward electric polarization force on H(+) was shown to be five times the gravitational force. Using an analogy with the terrestrial ion-exosphere, H(+) was inferred to flow upward into the ionotail of Venus and accelerate to escape speeds. A planet averaged escape flux of 1.4 x 10 exp 7/sq cm/s was calculated, which is comparable to hydrogen loss rates estimated by other investigators.

Hartle, R. E.↗
NASA NTRS1977

Mariner 9 Ultraviolet Spectrometer Experiment: Mars Atomic Oxygen 1304-A Emission

Selected results are presented for an analysis of Mariner 9 1304-A data from the first 100 passes. Based on a comparison of limb data, the exospheric temperature appears lower on several Mariner 9 passes than when Mariner 6 and 7 encountered the planet in 1969. Temperatures of 300 and 350 K are considered in the atmospheric modeling. At 300 K, derived values of the atomic oxygen concentration are typically between 0.5 and 1 percent of the total density at 135 km, based on fitting theoretical intensities to limb data from several passes. Structure in the limb data below 200 km suggests the possibility that approximately 0.2 kR of the observed approximately 0.8 kR near 150 km is due to dissociative excitation of CO2. There is variability in limb profiles indicating changes in the O distribution with time. The variability does not appear to follow a recognizable pattern. Interpretation of the 1304-A disc data shows a correlation in intensity with the 10.7 cm solar flux and larger O concentrations in the afternoon than in the morning. The correlation in intensity with the 10.7 cm flux is probably due largely to variation in the solar 1304-A fluxes. Selected disc data show localized and random enhancements in the intensity.

Strickland, D. J.↗
NASA NTRS1993

Nitrates in SNCs: Implications for the nitrogen cycle on Mars

Nitrogen is the second most abundant constituent of the Martian atmosphere, after CO2, present at a level of ca. 2.7 percent. Several authors have hypothesized that earlier in the planet's history, nitrogen was more abundant, but has been removed by processes such as exospheric loss from the atmosphere. However, an alternative sink for atmospheric nitrogen is the regolith; model calculations have predicted that, via the formation of NOx, HNO2 and HNO3 in the lower layers of the Martian atmosphere, the regolith might trap nitrite and nitrate anions, leading to the build-up of involatile nitrates. Integrated over 4.5 x 10(exp 9) yr, such a mechanism would contribute the equivalent of a layer of nitrates up to 0.3 cm thick distributed across the Martian surface. Features in thermal emission spectra of the surface of Mars have been interpreted tentatively as emanating from various anions (carbonates, bicarbonates, sulphates, etc.), and the presence of nitrates has also been addressed as a possibility. The identification of carbonates in SCN meteorites has allowed inferences to be drawn concerning the composition and evolution of the Martian atmosphere in terms of its carbon isotope systematics; if nitrites, nitrates, or other nitrogen-bearing salts could be isolated from SNC's, similar conclusions might be possible for an analogous nitrogen cycle. Nitrates are unstable, being readily soluble in water, and decomposed at temperatures between 50 C and 600 C, depending on composition. Any nitrates present in SNC's might be removed during ejection from the planet's surface, passage to Earth, or during the sample's terrestrial history, by weathering etc. The same might have been said for carbonates, but pockets of shock-produced glass (lithology C) from within the EET A79001 shergottite and bulk samples of other SNC contain this mineral, which did apparently survive. Nitrates occurring within the glassy melt pockets of lithology C in EET A79001 might likewise be protected. Lithology C glass was therefore selected for nitrate analysis, first by non-destructive infra red spectroscopy, and then by stepped combustion.

Grady, Monica M.↗
NASA NTRS1994

First measurement of helium on Mars: Implications for the problem of radiogenic gases on the terrestrial planets

The 108 photons of the Martian He 584 A airglow detected by the Extreme Ultraviolet Explorer satellite during a two-day exposure (22-23 Jan. 1993) correspond to the effective disk average intensity of 43 (+/-) 10 Rayleigh. Radiative transfer calculations, using a model atmosphere appropriate to the conditions of the observation and having an exospheric temperature of 210 (+/-) 20 K, result in an He mixing ratio of 1.1 (+/-) 0.4 ppm in the lower atmosphere. Nonthermal escape of helium is due to the following: electron impact ionization and pickup of He(+) by the solar wind; collisions with hot oxygen atoms; and charge exchange with molecular species with corresponding column loss rates of 1.4 x 10(exp 5), 3 x 10(exp 4), and 7 x 10(exp 3) cm(exp -2)s(exp -1), respectively. The lifetime of helium on Mars is 5 x 10(exp 4) yr. The He outgassing rate, coupled with the Ar-40 atmospheric abundance and with the K:U:Th ratio measured in the surface rocks, is used as input to a simple two-reservoir degassing model which presumes the loss of all argon accumulated in the atmosphere during the first Byr by large-scale impacts. The model results in total planet mass ratios of 10(exp -5) g/g for K, 2.3 x 10(exp -9) g/g for U, 8.5 x 10(exp -9) g/g for Th, 4 x 10(exp -10) g/g for He, and 1.5 x 10(exp -9) g/g for Ar-40. The predicted radiogenic heat flux is 2 erg cm(exp -2)s(exp -1). Similar modeling for Venus results in total plant mass ratios of 4.7 x 10(exp -5) g/g for K, 6.7 x 10(exp -9) g/g for U, 2.2 x 10(exp -8) g/g for Th, 1.3 x 10(exp -9) for He, 6.7 x 10(exp -9) g/g for Ar-40, and a radiogenic heat flux of 15 erg cm(exp -2)s(exp -1). The implications of these results are discussed. The modeling shows that the radioactive elements were not distributed uniformly in the protoplanetary nebula, and their relative abundances differ very much in the terrestrial planets.

Bowyer, S.↗
NASA NTRS1994

Quantitative understanding of the cycles of oxidized and reduced sulfur on Venus

The evolution of the Venus atmosphere is determined by the supply of gases from the interior of the planet and outer space, and by the loss of particles to space over time. In particular, questions pertaining to the initial inventory of water and the current and past rates of outgassing can be addressed by studying the loss rates of H, D, He3 and He4. The photochemistry of the H2SO4 clouds may also have played an important role in regulating the amount of water above the cloud tops, and hence limit the rate of escape of hydrogen from the planet. Thus the problems of evolution and chemistry are intimately related. In our proposal the principal tasks we undertook to advance our understanding of the origin and evolution of water on Venus included: (1) escape of light atoms from Venus and (2) develop a photochemical model of sulfate formation. In the last two years we have made progress on Task 1 regarding how light atoms can escape from the exosphere of Venus with the development of a Monte Carlo program and in Task 2 have developed a thorough update on the SO2 photochemistry that had been previously carried out.

Yung, Yuk L.↗
NASA NTRS1994

Scientific objectives of the primitive body sample return missions: An approach from the light-induced effect on water vapor

Water is undoubtedly one of the most crucial components of the solar nebula for determining planetary composition: planets were formed from the accretion of the dust particles in the nebula, and the redox state of Fe in the particles can be determined by the reaction of Fe with water vapor diffused into the interior of the particle in the early stage of solar system formation. It has been discussed from various observations that the cores of Mercury, Venus, and the Earth might be metallic Fe, although the core of the Earth may be somewhat oxidized by the high pressure and temperature reaction of liquid Fe with perovskite at the boundary of the mantle and the core, whereas the core of Mars may be highly oxidized, as suggested by its low density. Isotopic anomalies of various elements have frequently been observed in the solar system (in planetary atmospheres and in meteorites) and some of them can be attributed to the injection of exotic particles formed in other stars into the solar nebula. Hydrogen and D anomalies in planetary atmospheres were frequently believed to correlate with the differential escape of H and D from the exospheres of Venus and Mars, although no one knows the primordial D/H ratios before thermal escape. This paper explains the decrease of the observed D/H ratios with distance from the sun by considering the light-induced drift effect to displace H2(16)O alone to the outside in the solar nebula.

Shimizu, Mikio↗
NASA NTRS1994

Nitrogen isotopic components in the early solar system

It is quite common to take the terrestrial atmospheric value of (15)N/(14)N (0.00366) as typical of nitrogen in the early solar system, but in fact there is little reason to suppose that this value had a nebula-wide significance. Indeed, it is not clear that there was a unique solar-system-wide (15)N/(14)N ratio, of whatever value. Here we review what is known about the distribution of the nitrogen isotopes among those solar-system objects that have been sampled so far and conclude that those isotopes reveal widespread inhomogeneity in the early solar system. Whether the isotopically distinct primordial components implied by this analysis were solid or gaseous or a mixture of both is not known. The isotopic composition of N in the Earth's mantle is controversial: estimates range from a 1.1 percent depletion in (15)N to a 1.4 percent enrichment. (Isotopic compositions will be expressed throughout as percent deviations from the terrestrial atmospheric value.) The present-day Martian atmosphere is characterized by a value of plus 62 percent but this enrichment in (15)N is attributed to selective loss of (14)N from the Martian exosphere. Modelling of this fractionation leads to an estimated primordial composition similar to the terrestrial atmospheric value, through the precision of this model-dependent result is unclear.

Kerridge, J. F.↗
NASA NTRS1995

Surface conversion techniques for low energy neutral atom imagers

This investigation has focused on development of key technology elements for low energy neutral atom imaging. More specifically, we have investigated the conversion of low energy neutral atoms to negatively charged ions upon reflection from specially prepared surfaces. This 'surface conversion' technique appears to offer a unique capability of detecting, and thus imaging, neutral atoms at energies of 0.01 - 1 keV with high enough efficiencies to make practical its application to low energy neutral atom imaging in space. Such imaging offers the opportunity to obtain the first instantaneous global maps of macroscopic plasma features and their temporal variation. Through previous in situ plasma measurements, we have a statistical picture of large scale morphology and local measurements of dynamic processes. However, with in situ techniques it is impossible to characterize or understand many of the global plasma transport and energization processes. A series of global plasma images would greatly advance our understanding of these processes and would provide the context for interpreting previous and future in situ measurements. Fast neutral atoms, created from ions that are neutralized in collisions with exospheric neutrals, offer the means for remotely imaging plasma populations. Energy and mass analysis of these neutrals provides critical information about the source plasma distribution. The flux of neutral atoms available for imaging depends upon a convolution of the ambient plasma distribution with the charge exchange cross section for the background neutral population. Some of the highest signals are at relatively low energies (well below 1 keV). This energy range also includes some of the most important plasma populations to be imaged, for example the base of the cleft ion fountain.

Quinn, J. M.↗
NASA NTRS1994

First measurement of helium on Mars: Implications for the problem of radiogenic gases on the terrestrial planets

108 +/- 11 photons of the martian He 584-A airglow detected by the Extreme Ultraviolet Explorer (EUVE) satellite during a 2-day exposure (January 22-23, 1993) correspond to the effective disk average intensity of 43 +/- 10 Rayleigh (Ra). Radiative transfer calculations, using a model atmosphere appropriate to the conditions of the observation and having an exospheric temperature of 210 +/- 20 K, result in a He mixing ratio of 1.1 +/- 0.4 ppm in the lower atmosphere. Nonthermal escape of helium is due to electron impact ionization and pickup of He(+) by the solar wind, to collisions with hot oxygen atoms, and to charge exchange with molecular species with corresponding column loss rates of 1.4 x 10(exp 5), 3 x 10(exp 4), and 7 x 10(exp 3)/sq cm/s, respectively. The lifetime of helium on Mars is 5 x 10(exp 4) years. the He outgassing rate, coupled with the Ar-40 atmospheric abundance and with the K:U:Th ratio measured in the surface rocks, is used as input to a single two-reservoir degassing model which is applied to Mars and then to Venus. A similar model with known abundances if K, U, and Th is applied to Earth. The models for Earth and Mars presume loss of all argon accumulated in the atmospheres during the first billion years by large-scale meteorite and planetesimal impacts. The models show that the degassing coefficients for all three planets may be approximated by function delta = delta(sub 0) x (t(sub 0)/t)(exp 1/2) with delta(sub 0) = 0.1, 0.04, and 0.0125 Byr for Earth, Venus, and Mars, respectively. After a R(exp 2) correction this means that outgassing processes on Venus and Mars are weaker than on Earth by factors of 3 and 30, respectively. Mass ratios of U and Th are almost the same for all three planets, while potassiumis depleted by a factor of 2 in Venus and Mars. Mass ratio of helium and argon are close to 5 x 10(exp -9) and 2 x 10(exp -8) g/g in the interiors of all three planets. The implications of these results are discussed.

Krasnopolsky, V. A.↗
NASA NTRS1995

Theoretical overview and modeling of the sodium and potassium atmospheres of mercury

A general theoretical overview for the sources, sinks, gas-surface interactions, and transport dynamics of sodium and potassium in the exospheric atmsophere of Mercury is given. Information for these four factors, which control the spatial distribution of these two alkali-group gases about the planet, is incorporated in numerical models. The spatial nature and relative importance of the initial source atom atmosphere and the ambient (ballistic hopping) atom atmosphere are then examined and are shown to be controlled and coupled to a great extent by the extremely large and variable solar radiation acceleration experienced by sodium and potassium as they resonantly scatter solar photons. The lateral (antisunward) transport rate of thermally accommodated sodium and potassium ambient atoms is shown to be driven by the solar radiation acceleration and, over a significant portion of Mercury's orbit about the Sun, is sufficiently rapid to be competitive with the short photoionization lifetimes for these atoms when they are located on the summit surface near or within about 30 deg of the terminator. The lateral transport rate is characterized by a migration time determined by model calculations for an ensemble of atoms initially starting at a point source on the surface (i.e., a numerical spacetime dependent Green's function). Four animations for the spacetime evolution of the sodium (or potassium) atmosphere produced by a point source on the surface are presented on a videotape format. For extended surface sources for sodium and potassium, the local column density is determined by competition between the photoionization lifetimes and the lateral transport times of atoms originating from different surface source locations. Sodium surface source fluxes (referenced to Mercury at perihelion) that are required on the sunlit hemisphere to reproduce the typically observed several megarayleighs of D2 emission-line brightness and the inferred column densities of 1-2 x 10(exp 11) atoms per sq cm range from approximately 2-5 x 10(exp 7) atoms/sq cm/sec. The sodium model is applied to study observational data that document an anticorrelation in the average sodium column density and solar radiation acceleration. Lateral transport driven by the solar radiation acceleration is shown to produce this behavior for combinations of different sources and surface accomodation coefficients. The best fit model fits to the observational data require a significant degree of thermal accommodation of the ambient sodium atoms to the surface and a source rate that decreases as an inverse power of 1.5 to 2 in heliocentric distance.

Smyth, William H.↗
NASA NTRS1995

Planetary loss from light ion escape on Venus

Using Pioneer Venus data, hydrogen and deuterium ions are shown to escape from the hydrogen bulge region in the nightside ionosphere. The polarization electric field propels these light ions upward through the ionosphere and into the ion-exosphere, where H(+) and D(+) continue to be accelerated away from Venus and move into the ionotail and beyond. The vertical flow speeds of H(+) and D(+) are found to be about the same; therefore, selective escape between H(+) and D(+) is negligible for this mechanism. Present day planetary loss rates of about 8.6 x 10(exp 25)/s and 3.2 X 10(exp 23)/s were obtained for H(+) and D(+), respectively. Such rates, persisting over a few billion years, should have significantly affected the planetary water budget.

Hartle, R. E.↗
NASA NTRS1995

Theoretical overview and modeling of the sodium and potassium atmospheres of the moon

A general theoretical overview for the sources, sinks, gas-surface interactions, and transport dynamics of sodium and potassium in the exospheric atmosphere of the Moon is given. These four factors, which control the spatial distribution of these two alkali-group gases about the Moon, are incorporated in numerical models. The spatial nature and relative importance of the initial source atoms atmosphere (which must be nonthermal to explain observational data) and the ambient (ballistic hopping) atom atmosphere are examined. The transport dynamics, atmospheric structure, and lunar escape of the nonthermal source atoms are time variable with season of the year and lunar phase because of their dependence on the radiation acceleration experienced by sodium and potassium atoms as they resonantly scatter solar photons. The dynamic transport time of fully thermally accomodated ambient atoms along the surface because of solar radiation acceleration (only several percent of surface gravity) is larger than the photoionization lifetimes and hence unimportant in determining the local density, although for potassium the situation is borderline. The sodium model was applied to analyze sodium observations of the sunward brightness profiles acquired near last quarter by Potter & Morgan (1988b) extending from the surface to an altitude of 1200 km, and near first quarter by Mendillo, Baumgardner, & Flynn (1991), extending in altitude from approximately 1430 to approximately 7000 km. The observations at larger altitudes could be fitted only for source atoms having a velocity distribution with a tail that is mildly nonthermal (like an approximately 1000 K Maxwell-Boltzmann distribution). Solar wind sputtering appears to a be a viable source atom mechanism for the sodium observations with photon-simulated desorption also possible but highly uncertain, although micrometeoroid impact vaporization appears to have a source that is too small and too hot, with likely an incorrect angular distribution about the Moon.

Smyth, William H.↗