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At least 577 records · Page 32

Final Report for Electro-oxidative valorization of biomass: design strategies for selective and stable catalysis

This project aimed to develop a fundamental understanding of the factors that dictate activity and selectivity during electrochemical partial oxidation of multi-carbon organic molecules derived from biomass. Value-adding selective conversions of alcohols to aldehydes, and aldehydes to carboxylic acids were considered, with the ultimate goal to establish general principles for controlling selectivity in organic oxidations. Specific aims involved the use of furfural (FF) and 5-hydoxymethyfurfural (HMF) as model systems and seek to develop knowledge for control of mechanisms that permit selective conversions between oxygenate functional groups with prevention or control of C-C cleavage steps. Another major focus of the work was in achieving these transformations in acidic conditions, which contrasts most existing work (done in base), but is crucial toward compatibility with common pretreatments used to generate small molecules from lignocellulose (e.g. acid hydrolysis or pyrolysis). The work involved well-defined catalyst material synthesis, comparative kinetics, and operando spectroscopies (PI Holewinski), supported by quantum chemical simulations (PI Janik), enabling progress toward efficient, acid-stable oxidation catalysis for biomass upgrading.

Holewinski, Adam [University of Colorado Boulder] ↗

ELVES-Field: Isolated Dwarf Galaxy Quenched Fractions Rise below M ∗ ≈ 10 7 M ⊙

We use a new sample of low-mass (M * < 10 9 M ⊙ ) isolated galaxies from the Exploration of Local VolumE Survey-Field (ELVES-Field) to examine the star formation properties and sizes of field dwarf galaxies in the Local Volume (LV; D < 10 Mpc). This volume-limited sample was selected from nearly 3000 deg 2 of imaging, relying on surface brightness fluctuations to determine distances to the majority of the systems and is complete to M * ≈ 10 6 M ⊙ . Across the surveyed area, we catalog over 2300 candidate LV dwarfs, of which we confirm 95 as genuine LV members and reject over 1600 as background contaminants, with the remaining 600 candidates still requiring a distance measurement. Of the confirmed LV dwarfs, 46 are either new discoveries or confirmed via a distance measurement for the first time here. We explore different environmental criteria to select isolated dwarfs but primarily focus on dwarfs that are >2 × R vir in projection from any known group with M ⋆ > 10 9 M ⊙ . We find that, at higher dwarf masses (M ⋆ ≳ 10 7 M ⊙ ), essentially all field dwarfs are star forming as has been found before. In contrast, at M ⋆ ≲ 10 7 M ⊙ , ∼30% of field dwarfs appear to be quenched. Finally, we find that isolated dwarfs are noticeably smaller (∼20%) than satellite dwarfs of the same stellar mass, regardless of quenched status.

Carlsten, Scott G. [Princeton Univ., NJ (United St↗

Functional colloidal particles for immunoresearch

The paper deals with the development of a new class of immunological reagents consisting of antibodies covalently bonded to polymeric microspheres to serve as convenient markers for detection of cell surface antigens by scanning electron and light microscopy. Attention is focused on the design and synthesis of spherical particles containing hydroxyl and carboxyl groups on their surface in a wide range of sizes (30-340 nm diam) by emulsion copolymerization, the preparation of spherical particles ranging from 300 nm to 3 microns and containing a variety of functional groups by means of ionizing radiation, and the experimental conditions for the covalent bonding of fluorescent molecules and antibodies to the spheres by means of the cyanogen bromide, carbodiimide and glutaraldehyde methods. These reagents are used to locate antigens on red blood cells, on mouse and human lymphocytes, and on the surface of photoreceptors. They offer a number of advantages and applications for the study of cell surfaces for immunodiagnosis.

Yen, S. P. S.↗

An Overview of the NOAA Drought Task Force

The charge of the NOAA Drought Task Force is to coordinate and facilitate the various MAPP-funded research efforts with the overall goal of achieving significant advances in understanding and in the ability to monitor and predict drought over North America. In order to achieve this, the task force has developed a Drought Test-bed that individual research groups can use to test/evaluate methods and ideas. Central to this is a focus on three high profile North American droughts (1998-2004 western US drought, 2006-2007 SE US drought, 2011- current Tex-Mex drought) to facilitate collaboration among projects, including the development of metrics to assess the quality of monitoring and prediction products, and the development of an experimental drought monitoring and prediction system that incorporates and assesses recent advances. This talk will review the progress and plans of the task force, including efforts to help advance official national drought products, and the development of early warning systems by the National Integrated Drought Information System (NIDIS). Coordination with other relevant national and international efforts such as the emerging NMME capabilities and the international effort to develop a Global Drought Information System (GDIS) will be discussed.

Schubert, S.↗

Evolution of International Space Station Program Safety Review Processes and Tools

The International Space Station Program at NASA is constantly seeking to improve the processes and systems that support safe space operations. To that end, the ISS Program decided to upgrade their Safety and Hazard data systems with 3 goals: make safety and hazard data more accessible; better support the interconnection of different types of safety data; and increase the efficiency (and compliance) of safety-related processes. These goals are accomplished by moving data into a web-based structured data system that includes strong process support and supports integration with other information systems. Along with the data systems, ISS is evolving its submission requirements and safety process requirements to support the improved model. In contrast to existing operations (where paper processes and electronic file repositories are used for safety data management) the web-based solution provides the program with dramatically faster access to records, the ability to search for and reference specific data within records, reduced workload for hazard updates and approval, and process support including digital signatures and controlled record workflow. In addition, integration with other key data systems provides assistance with assessments of flight readiness, more efficient review and approval of operational controls and better tracking of international safety certifications. This approach will also provide new opportunities to streamline the sharing of data with ISS international partners while maintaining compliance with applicable laws and respecting restrictions on proprietary data. One goal of this paper is to outline the approach taken by the ISS Progrm to determine requirements for the new system and to devise a practical and efficient implementation strategy. From conception through implementation, ISS and NASA partners utilized a user-centered software development approach focused on user research and iterative design methods. The user-centered approach used on the new ISS hazard system utilized focused user research and iterative design methods employed by the Human Computer Interaction Group at NASA Ames Research Center. Particularly, the approach emphasized the reduction of workload associated with document and data management activities so more resources can be allocated to the operational use of data in problem solving, safety analysis, and recurrence control. The methods and techniques used to understand existing processes and systems, to recognize opportunities for improvement, and to design and review improvements are described with the intent that similar techniques can be employed elsewhere in safety operations. A second goal of this paper is to provide and overview of the web-based data system implemented by ISS. The software selected for the ISS hazard systemMission Assurance System (MAS)is a NASA-customized vairant of the open source software project Bugzilla. The origin and history of MAS as a NASA software project and the rationale for (and advantages of) using open-source software are documented elsewhere (Green, et al., 2009).

Ratterman, Christian D.↗

GCR Environmental Models I: Sensitivity Analysis for GCR Environments

Accurate galactic cosmic ray (GCR) models are required to assess crew exposure during long-duration missions to the Moon or Mars. Many of these models have been developed and compared to available measurements, with uncertainty estimates usually stated to be less than 15%. However, when the models are evaluated over a common epoch and propagated through to effective dose, relative differences exceeding 50% are observed. This indicates that the metrics used to communicate GCR model uncertainty can be better tied to exposure quantities of interest for shielding applications. This is the first of three papers focused on addressing this need. In this work, the focus is on quantifying the extent to which each GCR ion and energy group, prior to entering any shielding material or body tissue, contributes to effective dose behind shielding. Results can be used to more accurately calibrate model-free parameters and provide a mechanism for refocusing validation efforts on measurements taken over important energy regions. Results can also be used as references to guide future nuclear cross-section measurements and radiobiology experiments. It is found that GCR with Z>2 and boundary energies below 500 MeV/n induce less than 5% of the total effective dose behind shielding. This finding is important given that most of the GCR models are developed and validated against Advanced Composition Explorer/Cosmic Ray Isotope Spectrometer (ACE/CRIS) measurements taken below 500 MeV/n. It is therefore possible for two models to very accurately reproduce the ACE/CRIS data while inducing very different effective dose values behind shielding.

Slaba, Tony C.↗

Principles of Sociology in Systems Engineering

Systems engineering involves both the integration of the system and the integration of the disciplines which develop and operate the system. Integrating the disciplines is a sociological effort to bring together different groups, often with different terminology, to achieve a common goal, the system. The focus for the systems engineer is information flow through the organization, between the disciplines, to ensure the system is developed and operated with all relevant information informing system decisions. Robert K. Merton studied the sociological principles of the sciences and the sociological principles he developed apply to systems engineering. Concepts such as specification of ignorance, common terminology, opportunity structures, role-sets, and the reclama (reconsideration) process are all important sociological approaches that should be employed by the systems engineer. In bringing the disciplines together, the systems engineer must also be wary of social ambivalence, social anomie, social dysfunction, insider-outsider behavior, unintended consequences, and the self-fulfilling prophecy. These sociological principles provide the systems engineer with key approaches to manage the information flow through the organization as the disciplines are integrated and share their information. This also helps identify key sociological barriers to information flow through the organization. This paper will discuss this theoretical basis for the application of sociological principles to systems engineering.

Watson, Michael D.↗

NASA's Megawatt Electric Aircraft Propulsion Research and Development

Electric aircraft propulsion (EAP) has become a major thrust in NASA’s aeronautics programs. The EAP is a NASA technology used to fulfill NASA’s role in its Sustainable Flight National Partnership, which has a goal of net-zero carbon emissions by 2050. Three of NASA’s four aeronautics programs have one or more projects that support EAP technology development and target technologies for wide body (> 10 megawatts) aircraft to urban air mobility (100s of kilowatts). The effort includes megawatt-scale flight demonstration, systems studies, electric machine and drive development, thermal management, and materials development. The Glenn Research Center (GRC) in Cleveland is intensely involved in much of this research. Specifically, GRC has material development groups working to develop materials that will help enable EAP. This presentation will focus on selected NASA megawatt-scale EAP technology efforts that span several NASA projects and programs and will highlight material development in this area.

Electric Aircraft Propulsion↗

Sulfidization Contemporaneous with Oxidation and Metamorphism in CK6 Chondrites

As the most oxidized chondrites and a group of carbonaceous chondrites spanning the range of petrologic types, CK chondrites occupy an extreme in our understanding of the origin and evolution of chondritic parent bodies. With the proposed linkage of CV and CK chondrites and the suggestion that differentiation of a postulated CV-CK asteroid could have differentiated to form a core and established a magnetic dynamo, CK chondrites are receiving considerable attention. Most of this attention has focused on the similarities between CK3 and CV3 chondrites and the origin of each. We have previously argued that melting of an oxidized core could produce a magnetite-sulfide core, rather than the more conventional metal-sulfide core. In this work, we focus on CK6 chondrites to understand the origin of the most highly metamorphosed members of the group as representative of the material that might differentiate to form such an oxidized core.

McCoy, T. J.↗

Proceedings of the Workshop for Applied Nuclear Data Activities WANDA 2022

On February 28 – March 4, 2022, the Nuclear Data Interagency Working Group (NDIAWG) hosted the 5-day virtual Workshop for Applied Nuclear Data (WANDA2022) to facilitate interagency collaboration on nuclear data for applications. This year’s focus was nuclear data for space applications, but also included photon reactions and transport, reactions on unstable nuclei, and data adjustment topics. The annual WANDA workshops are planned by the Nuclear Data Working Group (NDWG) with the goal of assembling users and producers of nuclear data to provide input to identify and prioritize nuclear data needs and to suggest solutions to address those needs. The workshop consisted of talks by agency program managers, six topic focused road mapping sessions and a review of NDIAWG-funded projects. More than 350 attendees represented national laboratories, universities, and federal agencies, as well as international organizations and industry. The proceedings presented herein summarize the workshop’s content, highlight important outcomes, and document attendees’ recommendations.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Design and Development of Functionally Effective Human-Machine Interfaces for Firing Room Displays

This project involves creating software for support equipment used on the Space l aunch System (SLS). The goal is to create applications and displays that will be used to remotely operate equipment from the firing room and will continue to support the SLS launch vehicle to the extent of its program. These displays include design practices that help to convey information effectively, such as minimizing distractions at normal operating state and displaying intentional distractions during a warning or alarm state. The general practice for creating an operator display is to reduce the detail of unimportant aspects of the display and promote focus on data and dynamic information. These practices include using minimalist design, using muted tones for background colors, using a standard font at a readable text size, displaying alarms visible for Immediate attention, grouping data logically, and displaying data appropriately varying on the type of data. Users of these displays are more likely to stay focused on operating for longer periods by using design practices that reduce eye strain and fatigue. Effective operator displays will improve safety by reducing human errors during operation, which will help prevent catastrophic accidents. This report entails the details of my work on developing remote displays for the Hypergolics ground system. Before developing a prototype display, the design and requirements of the system are outlined and compiled into a document. Then each subsystem has schematic representations drawn tha.t meet the specifications detailed in the document. The schematics are then used as the outline to create display representations of each subsystem. Each display is first tested individually. Then the displays are integrated with a prototype of the master system, and they are tested in a simulated environment then retested in the real environment. Extensive testing is important to ensure the displays function reliably as intended.

Cho, Henry↗

Design and Development of Functionally Effective Human-Machine Interfaces for Firing Room Displays

This project involves creating software for support equipment used on the Space Launch System (SLS). The goal is to create applications and displays that will be used to remotely operate equipment from the firing room and will continue to support the SLS launch vehicle to the extent of its program. These displays include design practices that help to convey information effectively, such as minimizing distractions at normal operating state and displaying intentional distractions during a warning or alarm state. The general practice for creating an operator display is to reduce the detail of unimportant aspects of the display and promote focus on data and dynamic information. These practices include using minimalist design, using muted tones for background colors, using a standard font at a readable text size, displaying alarms visible for immediate attention, grouping data logically, and displaying data appropriately varying on the type of data. Users of these displays are more likely to stay focused on operating for longer periods by using design practices that reduce eye strain and fatigue. Effective operator displays will improve safety by reducing human errors during operation, which will help prevent catastrophic accidents. This report entails the details of my work on developing remote displays for the Hypergolic fuel servicing system. Before developing a prototype display, the design and requirements of the system are outlined and compiled into a document. Then each subsystem has schematic representations drawn that meet the specifications detailed in the document. The schematics are then used as the outline to create display representations of each subsystem. Each display is first tested individually. Then the displays are integrated with a prototype of the master system, and they are tested in a simulated environment then retested in the real environment. Extensive testing is important to ensure the displays function reliably as intended.

displays↗

Non-coding RNAs: update on mechanisms and therapeutic targets from the ESC Working Groups of Myocardial Function and Cellular Biology of the Heart

Abstract Vast parts of mammalian genomes are actively transcribed, predominantly giving rise to non-coding RNA (ncRNA) transcripts including microRNAs, long ncRNAs, and circular RNAs among others. Contrary to previous opinions that most of these RNAs are non-functional molecules, they are now recognized as critical regulators of many physiological and pathological processes including those of the cardiovascular system. The discovery of functional ncRNAs has opened up new research avenues aiming at understanding ncRNA-related disease mechanisms as well as exploiting them as novel therapeutics in cardiovascular therapy. In this review, we give an update on the current progress in ncRNA research, particularly focusing on cardiovascular physiological and disease processes, which are under current investigation at the ESC Working Groups of Myocardial Function and Cellular Biology of the Heart. This includes a range of topics such as extracellular vesicle-mediated communication, neurohormonal regulation, inflammation, cardiac remodelling, cardio-oncology as well as cardiac development and regeneration, collectively highlighting the wide-spread involvement and importance of ncRNAs in the cardiovascular system.

Bär, Christian↗

New Laboratory and Astrophysical Probes of Physics Beyond the Standard Model (Final Technical Report)

The first of these directions centers on new ideas in dark matter detection. As experimental scrutiny narrows the window for new physics at the weak scale, it has become apparent that the solution to the dark matter mystery may not reside there. Theoretical developments such as the hidden sector/valley paradigm have, at the same time, shown that compelling theories of dark matter reside below the weak scale. Searching for dark matter at lower mass scales requires looking beyond the current paradigm of dark matter direct detection based on nuclear recoils. It is the goal of this project to provide new ideas to guide the experimental program looking for light dark matter. I am actively proposing ideas for detecting dark matter as light as a meV, well beyond the current focus of GeV-TeV scale dark matter. Some of the ideas I have proposed, such as superconducting, superfluid, and polar material targets, are actively being developed into experiments. My group will provide the relevant calculations to determine dark matter reach, providing crucial input to experiment on which targets should be developed. We will also provide an effective field theory framework to understand which types of experiments are most sensitive to each interaction type. The second of these directions is on probes of dark matter substructure as a mean to constrain, or observe, models of dark matter. The standard ΛCDM paradigm assumes that the dark matter density perturbations are adiabatic, scale invariant, and produced during inflation. However, many standard models of dark matter will produce modifications of this prediction, such as axion models with symmetry broken below the inflationary scale. Remarkably, we have limited direct measurements of the dark matter clumpiness at mass scales below dwarf galaxies. This allows for the possibility of observing modifications from vanilla ΛCDM due to particle dynamics. In many cases, simulations of dark matter structure in the presence of non-scale invariant fluctu- ations are understudied or completely lacking. I plan to develop both theoretical predictions for small scale structure in models with additional matter power on small scales, as well as observa- tional probes of small scale halos or clumps. One idea I have been recently focused on is pulsar timing, though my group will pursue a variety of lensing and astrometric probes. Lastly, the most risky direction involves spacetime fluctuations from quantum gravity. I showed that if one assumes that metric fluctuations in the Minkowski vacuum, at a surface separating a region in and out of causal contact (which we call a “horizon”), are determined by standard thermodynamic considerations at horizon, these metric fluctuations are large enough to observe in an interferometer with similar sensitivity to LIGO. In a follow-up paper we showed that these assumption holds for the vacuum in AdS/CFT. In future work, I plan to connect this work to recent soft graviton results, to frame this work in a concrete Randall-Sundrum model, and to work out concrete phenomenological predictions from the model. This work unquestionably takes a less trodden path, and works well as part of a well-rounded portfolio of less and more risky ideas. Particle physics is currently at a juncture which requires bold exploration of qualitatively new directions. This proposal outlines some of my plans over the coming years in these directions, leaving room also for surprises.

79 ASTRONOMY AND ASTROPHYSICS↗

Meeting Report: Long Term Monitoring of Global Vegetation using Moderate Resolution Satellites

The international community has long recognized the need to coordinate observations of Earth from space. In 1984, this situation provided the impetus for creating the Committee on Earth Observation Satellites (CEOS), an international coordinating mechanism charged with coordinating international civil spaceborne missions designed to observe and study planet Earth. Within CEOS, its Working Group on Calibration and Validation (WGCV) is tasked with coordinating satellite-based global observations of vegetation. Currently, several international organizations are focusing on the requirements for Earth observation from space to address key science questions and societal benefits related to our terrestrial environment. The Global Vegetation Workshop, sponsored by the WGCV and held in Missoula, Montana, 7-10 August, 2006, was organized to establish a framework to understand the inter-relationships among multiple, global vegetation products and identify opportunities for: 1) Increasing knowledge through combined products, 2) Realizing efficiency by avoiding redundancy, and 3) Developing near- and long-term plans to avoid gaps in our understanding of critical global vegetation information. The Global Vegetation Workshop brought together 135 researchers from 25 states and 14 countries to advance these themes and formulate recommendations for CEOS members and the Global Earth Observation System of Systems (GEOSS). The eighteen oral presentations and most of the 74 posters presented at the meeting can be downloaded from the meeting website (www.ntsg.umt.edu/VEGMTG/). Meeting attendees were given a copy of the July 2006 IEEE Transactions on Geoscience and Remote Sensing Special Issue on Global Land Product Validation, coordinated by the CEOS Working Group on Calibration and Validation (WGCV). This issue contains 29 articles focusing on validation products from several of the sensors discussed during the workshop.

Morisette, Jeffrey↗

Sensitivity Analysis Comparisons on Geologic Case Studies: An International Collaboration

Over the past four years, an informal working group has developed to investigate existing sensitivity analysis methods, examine new methods, and identify best practices. The focus is on the use of sensitivity analysis in case studies involving geologic disposal of spent nuclear fuel or nuclear waste. To examine ideas and have applicable test cases for comparison purposes, we have developed multiple case studies. Four of these case studies are presented in this report: the GRS clay case, the SNL shale case, the Dessel case, and the IBRAE groundwater case. We present the different sensitivity analysis methods investigated by various groups, the results obtained by different groups and different implementations, and summarize our findings.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Virtual Power Plants and Energy Justice

The Federal Energy Regulatory Commission's (FERC) Order 2222, issued in September 2020, removes barriers for distributed energy resources (DERs) to participate in wholesale energy markets by allowing DERs to aggregate and participate in wholesale markets as a single entity, known as a virtual power plant (VPP). VPPs can provide balancing, reliability, and resiliency grid services and can participate in capacity, energy and ancillary services markets. They can also increase customer energy access and lower electricity bills. This report focuses on VPP business models, including considerations of energy justice (EJ). Through an analysis of the VPP value chain, business models, programs, and pilots, several VPP applications are identified and grouped by their ability to have quantitatively measurable or monetized benefits. Benefits and barriers specific to underserved communities are outlined, and VPP programs with an intentional focus on underserved communities are compared to those without such a focus.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

FY24 – FY25 Efforts to Revive the ANS-54.8 Liquid Metal Fire Protection in LMR Plants Standard

The current multi-year effort seeks to utilize national laboratory support from Argonne to expedite revival of the ANS-54.8 standard titled “Liquid Metal Fire Protection in LMR Plants.” To achieve that objective, the following tasks were identified: Task 1 involves working directly with ANS to revive the ANS-54.8 Working Group. This was to be accomplished by completing necessary paperwork, submitting that paperwork to ANS for approval, enlisting potential working group members from industry, the NRC, national laboratories, and universities, and organizing and leading Working Group activities. The overall purpose of the Working Group is to develop an updated draft of ANS-54.8 for review and approval by ANS consensus committees, the ANS Standards Board, and certification from ANSI. Task 2 focuses on leveraging historical information and expertise at Argonne related to sodium fire protection systems and strategies. For more than a decade, Argonne has worked on both international and domestic projects related to sodium fire protection system development and evaluation. The goal of this task is to utilize that experience to help inform the ANS-54.8 Working Group on important considerations that may be addressed in an updated draft of ANS-54.8. Task 3 focuses on leveraging Argonne experience in the development of and use of analysis methods and tools for the simulation of sodium fire scenarios and evaluation of the effectiveness of sodium fire protection systems and strategies. For more than a decade, Argonne has recovered, modified, and utilized several historical sodium fire analysis software tools. The goal of this task is to utilize that experience to help inform the ANS-54.8 Working Group of best practices for sodium fire progression analysis that may be addressed in an updated draft of ANS-54.8.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗