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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Selective Oxidative Coupling of Amines Using Mesoporous MoO x Catalysts

In this paper, we report a synthesis method for highly porous molybdenum oxide via molybdenum-oxo cluster formation under acidic conditions providing extraordinary stability. Synthesized materials indicate higher valences of molybdenum as compared to the commercial standards as verified through X-ray photoelectron spectroscopy, electron paramagnetic resonance spectroscopy, and ultraviolet–visible spectroscopy. The formation of a 91% orthorhombic molybdenum oxide bulk structure was verified through powder X-ray diffraction analysis. The effect of the hydrogen peroxide solvent system was optimized to obtain pore diameters as big as 17.4 nm and pore volumes as high as 0.168 cm 3 /g. These materials serve as great catalysts providing excellent yields of imine via amine coupling, having first-order kinetics with a turnover number as good as 27.93 with a slight decrease to 22.04 even after the fourth cycles. Surface hydroxyl species on the catalyst aid in the solid acid catalysis to jump-start the reaction.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Pangenomics reveals alternative environmental lifestyles among chlamydiae

Chlamydiae are highly successful strictly intracellular bacteria associated with diverse eukaryotic hosts. Here we analyzed metagenome-assembled genomes of the “Genomes from Earth’s Microbiomes” initiative from diverse environmental samples, which almost double the known phylogenetic diversity of the phylum and facilitate a highly resolved view at the chlamydial pangenome. Chlamydiae are defined by a relatively large core genome indicative of an intracellular lifestyle, and a highly dynamic accessory genome of environmental lineages. We observe chlamydial lineages that encode enzymes of the reductive tricarboxylic acid cycle and for light-driven ATP synthesis. We show a widespread potential for anaerobic energy generation through pyruvate fermentation or the arginine deiminase pathway, and we add lineages capable of molecular hydrogen production. Genome-informed analysis of environmental distribution revealed lineage-specific niches and a high abundance of chlamydiae in some habitats. Together, our data provide an extended perspective of the variability of chlamydial biology and the ecology of this phylum of intracellular microbes.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2020

The rupture mechanism of rubredoxin is more complex than previously thought

The surprisingly low rupture force and remarkable mechanical anisotropy of rubredoxin have been known for several years. Exploiting the first combination of steered molecular dynamics and the quantum chemical Judgement of Energy DIstribution (JEDI) analysis, the common belief that hydrogen bonds between neighboring amino acid backbones and the sulfur atoms of the central FeS 4 unit in rubredoxin determine the low mechanical resistance of the protein is invalidated. The distribution of strain energy in the central part of rubredoxin is elucidated in real-time with unprecedented detail, giving important insights into the mechanical unfolding pathway of rubredoxin. While structural anisotropy as well as the contribution of angle bendings in the FeS 4 unit have a significant influence on the mechanical properties of rubredoxin, these factors are insufficient to explain the experimentally observed low rupture force. Instead, the rupture mechanism of rubredoxin is far more complex than previously thought and requires more than just a hydrogen bond network.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Effect of outer divertor leg detachment on the high field side scrape-off layer in DIII-D and ASDEX Upgrade

In this work, evidence is presented that detachment of the outer divertor leg leads to a reduction of electron density and neutral pressure in the high-field side (HFS) scrape-off layer (SOL) of the ASDEX Upgrade (AUG) and DIII-D tokamaks with ion $B$ x $∇B$ drift directed toward the X-point (favorable configuration). These results are observed across multiple diagnostics and without the use of impurity seeding to reach detachment. In AUG, outer divertor leg detachment correlates with a decrease in electron density near the separatrix at the inner midplane, measured with HFS reflectometry. A concurrent reduction in inner divertor density and neutral pressure at the inner target is observed using divertor Thomson scattering and neutral pressure gauges. These effects are present in both L- and H-mode plasmas. In DIII-D, a similar reduction is detected through analysis of line-integrated hydrogenic emission measured by multiple diagnostics in the HFS SOL close to the separatrix. The consistent trends in both devices indicate that high electron density and strong hydrogenic emissivity in the HFS SOL are common features of H-mode plasmas in the favorable configuration, independent of wall material and divertor geometry. In L-mode plasmas, the reduction in electron density and neutral pressure is not observed in DIII-D, possibly due to differences in wall material. These results emphasize the importance of the divertor state in determining the two-dimensional neutral distribution and edge fueling.

detachment↗
DOE OSTI2024

Assessment of Potential Failure Modes and Effects for On-Board Components for Hydrogen-Powered Locomotives

Hydrogen fuel sources offer alternatives to conventional fuels in the rail transportation industry. Hydrogen powered locomotive designs utilizing either a fuel cell or an internal combustion engine can make migration to alternative fuels possible for rail transportation. Codes and standards are still in development for rail application of hydrogen and safety risks must be assessed for hydrogen locomotive applications. This report utilizes a failure mode & effects analysis framework to help qualitatively understand possible risks from a hydrogen locomotive system. Findings illustrate how a combination of three mitigations greatly reduces the risks from a hydrogen locomotive system.

08 HYDROGEN↗
DOE OSTI2025

Feasibility and Qualitative Risk Assessment of Fuel Cell Electric Bus Use for Emergency Backup Power for Airport Applications

Airports rely on robust backup power systems to maintain critical operations during emergencies. This paper investigates the feasibility of using hydrogen fuel cell electric buses (FCEBs) as emergency backup power sources, focusing on their technical specifications, operational challenges, and associated risks. Using Portland International Airport as a case study, the analysis evaluates the power output and hydrogen consumption of New Flyer’s 40’ Xcelsior Charge fuel cell buses, to provide power for key airport systems. Additionally, the paper explores the design and layout of how FCEBs can be connected to airport facilities, and addresses safety considerations, hydrogen supply logistics, and electrical compatibility. While FCEBs present significant advantages in terms of sustainability and resilience, their implementation requires careful planning, infrastructure investment, and adherence to safety standards. This research provides actionable insights for airport stakeholders seeking to transition to hydrogen-based backup power system.

08 HYDROGEN↗
DOE OSTI2023

Chemical Vapor Deposition of Zirconium Compounds: A Review

Coatings of zirconium compounds are used in a wide variety of fields, yet an understanding and descriptions of deposition mechanisms are scant in the public literature. The mechanisms of deposition for metallic zirconium, ZrC, ZrN, ZrO 2 , ZrB 2 , and zirconium silicides are discussed based on the direct vapor deposition research of those compounds where possible or compared to complementary titanium systems when direct research is lacking. Both inorganic and organometallic deposition systems are discussed. As a class of compounds, an understanding of the vapor deposition mechanisms can be significantly improved by investigations on metallic zirconium deposition by zirconium halides and hydrogen and by in situ analysis techniques such as Fourier-transform infrared (FTIR) spectroscopy or x-ray photoelectron spectroscopy (XPS).

organometallic↗
DOE OSTI2020

Predictions of the glass transition temperature and viscosity of organic aerosols from volatility distributions

Abstract. Volatility and viscosity are important properties of organic aerosols (OA), affecting aerosol processes such as formation, evolution, and partitioning of OA. Volatility distributions of ambient OA particles have often been measured, while viscosity measurements are scarce. We have previously developed a method to estimate the glass transition temperature (Tg) of an organic compound containing carbon, hydrogen, and oxygen. Based on analysis of over 2400 organic compounds including oxygenated organic compounds, as well as nitrogen- and sulfur-containing organic compounds, we extend this method to include nitrogen- and sulfur-containing compounds based on elemental composition. In addition, parameterizations are developed to predict Tg as a function of volatility and the atomic oxygen-to-carbon ratio based on a negative correlation between Tg and volatility. This prediction method of Tg is applied to ambient observations of volatility distributions at 11 field sites. The predicted Tg values of OA under dry conditions vary mainly from 290 to 339 K and the predicted viscosities are consistent with the results of ambient particle-phase-state measurements in the southeastern US and the Amazonian rain forest. Reducing the uncertainties in measured volatility distributions would improve predictions of viscosity, especially at low relative humidity. We also predict the Tg of OA components identified via positive matrix factorization of aerosol mass spectrometer (AMS) data. The predicted viscosity of oxidized OA is consistent with previously reported viscosity of secondary organic aerosols (SOA) derived from α-pinene, toluene, isoprene epoxydiol (IEPOX), and diesel fuel. Comparison of the predicted viscosity based on the observed volatility distributions with the viscosity simulated by a chemical transport model implies that missing low volatility compounds in a global model can lead to underestimation of OA viscosity at some sites. The relation between volatility and viscosity can be applied in the molecular corridor or volatility basis set approaches to improve OA simulations in chemical transport models by consideration of effects of particle viscosity in OA formation and evolution.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1969

The 2.8-14-micron spectrum of Jupiter.

Jupiter spectrum observations in 2.8-14 micron range, describing absorption strength and brightness temperature, basing analysis on ammonia, methane and hydrogen absorption

Gillett, F. C.↗
NASA NTRS1981

Creep-rupture behavior of iron superalloys in high pressure hydrogen

Two cast alloys (CRM-6D and XF-818) and four sheet alloys (A-26, Incoloy 800H, N-155, and 19-9DL) in the thickness range of 0.79 to 0.99 mm were evaluated for use in the Stirling engine. The creep rupture behavior of these iron base high temperature alloys is being determined in air for 10 hr to 3,00 hr, and in 20.7 MPa (3,000 psi) H2 for 10 to 300 hr at temperatures of 650 deg to 925 deg. Material procurement, preparation and air creep rupture testing are described and existing data is analyzed. Systems for the high pressure hydrogen testing are discussed. Statistical analysis of temperature-compensated rupture data for each alloy is included.

Bhattacharyya, S.↗
NASA NTRS1982

The Venus environment; Proceedings of the International Conference, Palo Alto, CA, November 1-6, 1981

Attention is given to noble gases in planetary atmospheres, the photochemistry of the stratosphere of Venus, the chemistry of metastable species in the Venusian ionosphere, the Venus ionosphere at grazing incidence of solar radiation, disappearing ionospheres on the nightside of Venus, and the observed composition of the ionosphere of Venus. Other investigations considered are concerned with the predicted electrical conductivity between 0 and 80 km in the Venusian atmosphere, sulfuric acid vapor and other cloud-related gases in the Venus atmosphere, the composition and vertical structure of the lower cloud deck on Venus, amorphous sulfur as the ultraviolet absorber on Venus, and polarization studies of the Venus UV contrasts. A description is provided of topics related to temporal variability of ultraviolet cloud features in the Venus stratosphere, zonal mean circulation at the cloud level on Venus, the influence of thermospheric winds on exospheric hydrogen on Venus, and an analysis of Venus gravity data.

Source record↗
NASA NTRS1985

Lunar bases and space activities of the 21st century

The present conference gives attention to such major aspects of lunar colonization as lunar base concepts, lunar transportation, lunar science research activities, moon-based astronomical researches, lunar architectural construction, lunar materials and processes, lunar oxygen production, life support and health maintenance in lunar bases, societal aspects of lunar colonization, and the prospects for Mars colonization. Specific discussions are presented concerning the role of nuclear energy in lunar development, achromatic trajectories and the industrial scale transport of lunar resources, advanced geologic exploration from a lunar base, geophysical investigations of the moon, moon-based astronomical interferometry, the irradiation of the moon by particles, cement-based composites for lunar base construction, electrostatic concentration of lunar soil minerals, microwave processing of lunar materials, a parametric analysis of lunar oxygen production, hydrogen from lunar regolith fines, metabolic support for a lunar base, past and future Soviet lunar exploration, and the use of the moons of Mars as sources of water for lunar bases.

Mendell, W. W.↗
NASA NTRS1986

Electron-impact excitation of the a3Sigma(+)g, B1Sigma(+)u, c3Pi u, and C1Pi u states of H2

Normilized differential and integral cross sections for electron-impact excitation of the dipole-allowed B1Sigma(+)u, C1Pi u and dipole-forbidden a3Sigma(+)g, c3Pi u states of molecular hydrogen have been determined by analysis of energy-loss spectra obtained with a crossed-beam apparatus at electron-impact energies of 20, 30, 40 and 60 eV and scattering angles ranging from 10 to 120 degrees. Normalization of the data was achieved by utilizing elastic differential cross sections measured previously by (Khakoo and Trajmar, 1986). The cross sections are compared with other available theoretical and experimental data.

Khakoo, M. A.↗
NASA NTRS1992

An Alpha-p-x Analytical Instrument for Lunar Resource Investigations

An instrument using alpha backscattering, alpha-proton nuclear reactions, and x-ray production by alpha particles and other auxiliary sources can be used on lunar landers to provide detailed analytical information concerning the lunar surface material. This information is important scientifically and can be the basis for utilizing efficiently lunar resources to build lunar colonies in the future. This alpha particle instrument uses radioactive isotopes, silicon detectors for the alpha and proton modes, and mercuric iodide detectors operating at room temperature for the x-ray mode. The alpha and proton modes of the instrument can provide an analysis for all elements (except hydrogen) present in amounts greater than about 1 percent by atom. These modes have excellent sensitivity and accuracy for the lighter elements, in particular, directly determining the amount of oxygen in the lunar soil. This is an element of paramount significance for the lunar resource mission. The x-ray mode makes possible a determination of Ti, Fe, and other important metals with even greater accuracy. In general, the x-ray mode provides increased sensitivity for heavier elements, in many cases achieving a sensitivity of several hundred ppm.

Economou, T. E.↗
NASA NTRS1992

Controlled Ecological Life Support System (CELSS) modeling

Attention is given to CELSS, a critical technology for the Space Exploration Initiative. OCAM (object-oriented CELSS analysis and modeling) models carbon, hydrogen, and oxygen recycling. Multiple crops and plant types can be simulated. Resource recovery options from inedible biomass include leaching, enzyme treatment, aerobic digestion, and mushroom and fish growth. The benefit of using many small crops overlapping in time, instead of a single large crop, is demonstrated. Unanticipated results include startup transients which reduce the benefit of multiple small crops. The relative contributions of mass, energy, and manpower to system cost are analyzed in order to determine appropriate research directions.

Drysdale, Alan↗
NASA NTRS2002

Hydrogen Storage for Aircraft Applications Overview

Advances in fuel cell technology have brought about their consideration as sources of power for aircraft. This power can be utilized to run aircraft systems or even provide propulsion power. One of the key obstacles to utilizing fuel cells on aircraft is the storage of hydrogen. An overview of the potential methods of hydrogen storage was compiled. This overview identifies various methods of hydrogen storage and points out their advantages and disadvantages relative to aircraft applications. Minimizing weight and volume are the key aspects to storing hydrogen within an aircraft. An analysis was performed to show how changes in certain parameters of a given storage system affect its mass and volume.

Colozza, Anthony J.↗
DOE OSTI2021

Nuclear Transparency from Quasi-elastic ¹²C(e, e'p) scattering reaction up to Q2 = 14.2 (GeV/c)2 in Hall C at Jefferson Lab

Color Transparency (CT) is a unique prediction of Quantum Chromodynamics (QCD) where the final (and/or initial) state interactions of hadrons with the nuclear medium are suppressed for exclusive processes at high momentum transfers. While this phenomenon has been observed for mesons, there has never been a conclusive observation for baryons. A clear signal of CT for baryons would be the first evidence of baryons fluctuating to a small size in the nucleus, and the onset would show the transition from nucleon-meson picture to quark-gluon degrees of freedom. The experiment E1206107, searching for the onset of CT in protons was completed in Hall C at Jefferson Laboratory (JLab) using the upgraded 12 GeV e- beam. It used the High Momentum Spectrometer (HMS) and the new Super High Momentum spectrometer (SHMS) in coincidence to measure the e- + ¹²C ? e-' + p + X reaction in quasi-elastic kinematics. Data were collected on a ¹²C target over the range of Q2 = 8 - 14.3 (GeV/c)2, covering the region where a previous p + A ? p' + p + X experiment at Brookhaven National Laboratory (BNL) had observed an enhancement. Proton Transparency (PT) was extracted from these data. A rise in the PT as a function of Q2 (defined as the square of the negative of the 4-momentum transfer by the scattered electron) is predicted to be a signature of the onset of CT. Our data showed no significant increase and consistent with the traditional nuclear physics calculation. This dissertation discusses the theory and implementation of the CT experiment, summarizes the data analysis and presents results on hydrogen normalization and nuclear transparency.

Bhetuwal, Deepak↗