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NASA NTRS1993

X ray emission from Wolf-Rayet stars with recurrent dust formation

We were granted a ROSAT observation of the Wolf-Rayet star WR 137 (equals HD 192641) to test a proposed mechanism for producing the infrared variability reported by Williams et al. (1987). These studies showed one clear infrared outburst preceded by what may be the dimming of a previous outburst. The recurrent dust formation model was put forward by Williams et al. (1990) to account for similar variability seen in WR 140, which varies in both the infrared and X-ray bands. The detected X-ray flux from WR 140 was observed to decrease from its normally high (for Wolf-Rayet stars) level as the infrared flux increased. Observation of two apparently-periodic infrared outbursts led to the hypothesis that WR 140 had an O star companion in an eccentric orbit, and that the increase in infrared flux came from a dust formation episode triggered by the compression of the O star and Wolf-Rayet star winds. The absorption of the X-rays by the increased material explained the decrease in flux at those wavelengths. If the infrared variability in WR 137 were caused by a similar interaction of the Wolf-Rayet star with a companion, we might expect that WR 137 would show corresponding X-ray variability and an X-ray luminosity somewhat higher than typical WC stars, as well as a phase-dependent non-thermal X-ray spectrum. Our goals in this study were to obtain luminosity estimates from our counting rates for comparison with previous observations of WR 137 and other WC class stars, especially WR 140; to compare the luminosity with the IR lightcurve; and to characterize the spectral shape of the X-ray emission, including the column density.

Rawley, Gayle L.↗

NASA NTRS2005

Novel Applications of Magnetic Fields for Fluid Flow Control and for Simulating Variable Gravity Conditions

Static and dynamic magnetic fields have been used to control convection in many materials processing applications. In most of the applications, convection control (damping or enhancement) is achieved through the Lorentz force that can be tailored to counteract/assist dominant system flows. This technique has been successfully applied to liquids that are electrically conducting, such as high temperature melts of semiconductors, metals and alloys, etc. In liquids with low electrical conductivity such as ionic solutions of salts in water, the Lorentz force is weak and hence not very effective and alternate ways of flow control are necessary. If the salt in solution is paramagnetic then the variation of magnetic susceptibility with temperature and/or concentration can be used for flow control. For thermal buoyancy driven flows this can be accomplished in a temperature range below the Curie point of the salt. The magnetic force is proportional to the magnetic susceptibility and the product of the magnetic field and its gradient. By suitably positioning the experiment cell in the magnet, system flows can be assisted or countered, as desired. A similar approach can be extended to diamagnetic substances and fluids but the required magnetic force is considerably larger than that required for paramagnetic substances. The presentation will provide an overview of work to date on a NASA fluid physics sponsored project that aims to test the hypothesis of convective flow control using strong magnetic fields in protein crystal growth. The objective is to understand the nature of the various forces that come into play, delineate causative factors for fluid flow and to quantify them through experiments, analysis, and numerical modeling. The seminar will report specifically on the experimental results using paramagnetic salts and solutions in magnetic fields and compare them to analytical predictions. Applications of the concept to protein crystallization studies will be discussed. The use of strong magnetic fields for terrestrially simulating variable gravity environments and applications supporting the NASA Exploration Initiative will also be briefly discussed.

Ramachandran, N.↗

NASA NTRS1995

Reflectance spectroscopy of ferric sulfate-bearing montmorillonites as Mars soil analog materials

Spectroscopic analyses have shown that smectites enhanced in the laboratory with additional ferric species exhibit important similarities to those of the soils on Mars. Ferrihydrite in these chemically treated smectites has features in the visible to near-infrared region that resemble the energies and band strengths of features in reflectance spectra observed for several bright regions on Mars. New samples have been prepared with sulfate as well, because S was found by Viking to be a major component in the surface material on Mars. A suite of ferrihydrite-bearing and ferric sulfate-bearing montmorillonites, prepared with variable Fe3+ and S concentrations and variable pH conditions, has been analyzed using reflectance spectroscopy in the visible and infrared regions, Mossbauer spectroscopy at room temperature and 4 K, differential thermal analysis, and X-ray diffraction. These analyses support the formation of ferrihydrite of variable crystallinity in the ferrihydrite-bearing montmorillonites and a combination of schwertmannite and ferrihydrite in the ferric sulfate-bearing montmorillonites. Small quantities of poorly crystalline or nanophase forms of other ferric materials may also be present in these samples. The chemical formation conditions of the ferrihydrite-bearing and ferric sulfate-bearing montmorillonites influence the character of the low temperature Mossbauer sextets and the visible reflectance spectra. An absorption minimum is observed at 0.88-0.89 micrometers in spectra of the ferric sulfate-bearing samples, and at 0.89-0.92 micrometers in spectra of the ferrihydrate-bearing montmorillonites. Mossbauer spectra of the ferric sulfate-bearing montmorillonites indicate variable concentrations of ferrihydrite and schwertmannite in the interlaminar spaces and along grain surfaces. Dehydration under reduced atmospheric pressure conditions induces a greater effect on the adsorbed and interlayer water in ferrihydrite-bearing montmorillonite than on the water in ferric sulfate-bearing montmorillonite. Reflectance spectra of ferric sulfate-bearing montmorillonite include a strong 3-micrometers band that is more resistant to dry atmospheric conditions than the 3-micrometers band in spectra of similarly prepared ferrihydrite-bearing montmorillonites.

NASA Discipline Exobiology↗

NASA NTRS1986

Effects of state recovery on creep buckling under variable loading

Structural alloys embody internal mechanisms that allow recovery of state with varying stress and elevated temperature, i.e., they can return to a softer state following periods of hardening. Such material behavior is known to strongly influence structural response under some important thermomechanical loadings, for example, that involving thermal ratchetting. The influence of dynamic and thermal recovery on the creep buckling of a column under variable loading is investigated. The column is taken as the idealized (Shanley) sandwich column. The constitutive model, unlike the commonly employed Norton creep model, incorporates a representation of both dynamic and thermal (state) recovery. The material parameters of the constitutive model are chosen to characterize Narloy Z, a representative copper alloy used in thrust nozzle liners of reusable rocket engines. Variable loading histories include rapid cyclic unloading/reloading sequences and intermittent reductions of load for extended periods of time; these are superimposed on a constant load. The calculated results show that state recovery significantly affects creep buckling under variable loading. Structural alloys embody internal mechanisms that allow recovery of state with varying stress and time.

Robinson, D. N.↗

NASA NTRS1988

Effects of state recovery on creep buckling under variable loading

Robinson, D. N.↗

NASA NTRS1990

Effects of state recovery on creep buckling under variable loading

Robinson, D. N.↗

NASA NTRS2001

Optimal Design of Grid-Stiffened Panels and Shells With Variable Curvature

A design strategy for optimal design of composite grid-stiffened structures with variable curvature subjected to global and local buckling constraints is developed using a discrete optimizer. An improved smeared stiffener theory is used for the global buckling analysis. Local buckling of skin segments is assessed using a Rayleigh-Ritz method that accounts for material anisotropy and transverse shear flexibility. The local buckling of stiffener segments is also assessed. Design variables are the axial and transverse stiffener spacing, stiffener height and thickness, skin laminate, and stiffening configuration. Stiffening configuration is herein defined as a design variable that indicates the combination of axial, transverse and diagonal stiffeners in the stiffened panel. The design optimization process is adapted to identify the lightest-weight stiffening configuration and stiffener spacing for grid-stiffened composite panels given the overall panel dimensions. in-plane design loads, material properties. and boundary conditions of the grid-stiffened panel or shell.

Ambur, Damodar R.↗

NASA NTRS1973

Space shuttle GN and C equation document: Entry and transition guidance

The entry-guidance routine presented is designed to take the orbiter vehicle from entry interface through the critical heating phase of entry down to the start of the approach phase. The material includes: (1) a functional flow diagram, (2) input and output variables, (3) a description of equations, and (4) detailed flow diagrams.

Marcus, F. J.↗

NASA NTRS1974

Some practical examples of cavitation erosion and their prevention

The problem of failures caused by cavitation erosion are discussed. The concepts of intensity of erosion, erosion strength, and the time dependence of erosion rate are analyzed. The relation of these parameters to system variables such as pressure and velocity, and to the properties of materials are investigated. Using several examples of actual cavitation erosion, methods of prevention and their limitations are examined.

Conn, A. F.↗

NASA NTRS1976

Spectrophotometry and UBVRI photometry of Eros

Spectrophotometric and broad-band photoelectric observations of Eros are reported. No existing meteorite spectrum matches the asteroid data directly. Assemblages of iron or stony-iron with ordinary-chondrite material generate the best match for the reflectivity curve of Eros. Variability was found in the 0.6 micron band and V-R and V-I colors.

Wisniewski, W. Z.↗

NASA NTRS1979

Path dependence of J in three numerical examples

Three cracked geometries are studied with the aid of a new finite element model. The procedure employs a variable singularity at the crack tip that tracks changes in the material response during the loading process. Two of the problems are tension-loaded center-crack panels and the other is a three-point bend specimen. Results usually agree with other numerical and analytical analyses, except the finding that J is path dependent as a substantial plastic zone develops. Credible J values are obtained near the crack tip and J shows a significant increase as the radius of J path increases over two orders of magnitude. Incremental and deformation theories are identical provided the stresses exhibit proportionality found in the far field stresses but not near the tip.

Karabin, M. E., Jr.↗

NASA NTRS1983

Stratigraphy and structural evolution of southern Mare Serenitatis - A reinterpretation based on Apollo Lunar Sounder Experiment data

Two subsurface reflecting horizons have been detected by the Apollo Lunar Sounder Experiment (ALSE) in the southern Mare Serenitatis which appear to be regolith layers more than 2 m thick, and are correlated with major stratigraphic boundaries in the southeastern Mare Serenitatis. The present stratigraphic boundaries in the southeastern Mare Serenitatis. The present analysis implies that the lower horizon represents the interface between the earliest mare unit and the modified Serenitatis basin material below. The depth of volcanic fill within Serenitatis is highly variable, with an average thickness of mare basalts under the ALSE ground track of 1.6 km. Comparisons with the Orientale basin topography suggests that a major increaae in load thickness could occur a few km basinward of the innermost extent of the traverse. The history of volcanic infilling of Mare Serenitatis was characterized by three major episodes of volcanism.

Sharpton, V. L.↗

NASA NTRS1983

NASA mechanical impact testing in high-pressure oxygen

Three independently developed high-pressure gaseous oxygen mechanical impact testers have been used to evaluate materials for the Space Shuttle Program. A test program evaluating the performance of these test systems is described. The gaseous and liquid oxygen test procedures and equipment are considered along with the material selection procedures. The results of the NASA mechanical impact tester variability study are presented, including penetration function curves and curve parameters and equivalent energies and comparisons of high-pressure testers at ambient pressure and temperature, ambient temperature and 34 MPa, and cryogenic temperature and 34 MPa. Finally, a summary of NASA mechanical impact test data is presented.

Bryan, C. J.↗

NASA NTRS1989

Static aeroelastic analysis and tailoring of missile control fins

A concept for enhancing the design of control fins for supersonic tactical missiles is described. The concept makes use of aeroelastic tailoring to create fin designs (for given planforms) that limit the variations in hinge moments that can occur during maneuvers involving high load factors and high angles of attack. It combines supersonic nonlinear aerodynamic load calculations with finite-element structural modeling, static and dynamic structural analysis, and optimization. The problem definition is illustrated. The fin is at least partly made up of a composite material. The layup is fixed, and the orientations of the material principal axes are allowed to vary; these are the design variables. The objective is the magnitude of the difference between the chordwise location of the center of pressure and its desired location, calculated for a given flight condition. Three types of constraints can be imposed: upper bounds on static displacements for a given set of load conditions, lower bounds on specified natural frequencies, and upper bounds on the critical flutter damping parameter at a given set of flight speeds and altitudes. The idea is to seek designs that reduce variations in hinge moments that would otherwise occur. The block diagram describes the operation of the computer program that accomplishes these tasks. There is an option for a single analysis in addition to the optimization.

Mcintosh, S. C., Jr.↗

NASA NTRS1989

Characterization of ceramics and intermetallics fabricated by self-propagating high-temperature synthesis

Three efforts aimed at investigating the process of self-propagating high temperature synthesis (SHS) for the fabrication of structural ceramics and intermetallics are summarized. Of special interest was the influence of processing variables such as exothermic dopants, gravity, and green state morphology in materials produced by SHS. In the first effort directed toward the fabrication of SiC, exothermic dopants of yttrium and zirconium were added to SiO2 or SiO2 + NiO plus carbon powder mix and processed by SHS. This approach was unsuccessful since it did not produce the desired product of crystalline SiC. In the second effort, the influence of gravity was investigated by examining Ni-Al microstructures which were produced by SHS combustion waves traveling with and opposite the gravity direction. Although final composition and total porosities of the combusted Ni-Al compounds were found to be gravity independent, larger pores were created in those specimens which were combusted opposite to the gravity force direction. Finally, it was found that green microstructure has a significant effect on the appearance of the combusted piece. Severe pressing laminations were observed to arrest the combustion front for TiC samples.

Hurst, Janet B.↗

NASA NTRS1989

Refinements in a viscoplastic model

A thermodynamically admissible theory of viscoplasticity with two internal variables (a back stress and a drag strength) is presented. Six material functions characterize a specific viscoplastic model. In the pursuit of compromise between accuracy and simplicity, a model is developed that is a hybrid of two existing viscoplastic models. A limited number of applications of the model to Al, Cu, and Ni are presented. A novel implicit integration method is also discussed. Applications are made to obtain solutions using this viscoplastic model.

Freed, A. D.↗

NASA NTRS1988

Robotic and automatic welding development at the Marshall Space Flight Center

Welding automation is the key to two major development programs to improve quality and reduce the cost of manufacturing space hardware currently undertaken by the Materials and Processes Laboratory of the NASA Marshall Space Flight Center. Variable polarity plasma arc welding has demonstrated its effectiveness on class 1 aluminum welding in external tank production. More than three miles of welds were completed without an internal defect. Much of this success can be credited to automation developments which stabilize the process. Robotic manipulation technology is under development for automation of welds on the Space Shuttle's main engines utilizing pathfinder systems in development of tooling and sensors for the production applications. The overall approach to welding automation development undertaken is outlined. Advanced sensors and control systems methodologies are described that combine to make aerospace quality welds with a minimum of dependence on operator skill.

Jones, C. S.↗

NASA NTRS2005

Crosslinking Amine-Modified Silica Aerogels with Epoxies: Mechanically Strong Lightweight Porous Materials

The mesoporous surfaces of TMOS-derived silica aerogels have been modified with amines by co-polymerization of TMOS with APTES. The amine sites have become anchors for crosslinking the nanoparticles of the skeletal backbone of the aerogel by attachment of di-, tri and tetra-functional epoxies. The resulting conformal coatings increase the density of the native aerogels by a factor of 2-3 but the strength of the resulting materials may increase by more than two orders of magnitude. Processing variables such as amount of APTES used to make the gels, the epoxy type and concentration used for crosslinking, as well as the crosslinking temperature and time were varied according to a multivariable design-of-experiments (DOE) model. It was found that while elastic modulus follows a similar trend with density, maximum strength is attained neither at the maximum density nor at the highest concentration of -NH2 groups, suggesting surface saturation effects. Aerogels crosslinked with the tri-functional epoxide always show improved strength compared with aerogels crosslinked with the other two epoxides under identical conditions. Solid C-13 NMR studies show residual unreacted epoxides, which condense with ne another by heating crosslinked aerogels at 150 C.

Meador, Mary Ann B.↗