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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 577 records · Page 32
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

The chemistry and mineralogy of Mars soil and dust

A single geological unit consisting of fine, apparently weathered soil material is covering large portions of the surface of Mars. This soil material has been thoroughly homogenized by global dust storms and it is plausible to assume that Mars dust is strongly correlated with it. The chemical-elemental composition of the soil was directly measured by the Viking Landers. Positive detection of Si, Al, Fe, Mg, Ca, Ti, S, Cl, and Br was achieved. Analyses of the SNC meteorites, a group of meteorites that has been suggested to be ejected Martian rocks, supply additional elemental-concentration data, broadening considerably the chemical data-base on the surface materials. A composition model for Mars soil, giving selected average elemental concentrations of major and trace elements, was recently suggested. It was constructed by combining the Viking Lander data, the SNC meteorite analyses, and other analyses. The mineralogy of the surface materials on Mars has not been directly measured yet. By use of various indirect approaches, including chemical correspondence to the surface analyses, spectral analogies, simulations of Viking Lander experiments, analyses of the SNC meteorites and various modeling efforts, the mineralogical composition was constrained to some extent. No direct analyses of soil reactivity have been done yet. Indirect evidence, mostly from the Viking biology experimental results, suggests that the soil probably has a slightly acidic reaction and is generally oxidized. Unambiguous identification of the Mars soil minerals by direct mineralogical analyses, and non-disturbed or in-situ measurements of the soil's reactivity, are of primary importance in future Mars research.

Banin, A.↗
NASA NTRS1992

Surface chemistry and mineralogy

The accumulated knowledge on the chemistry and mineralogy of Martian surface materials is reviewed. Pertinent information obtained by direct analyses of the soil on Mars by the Viking Landers, by remote sensing of Mars from flyby and orbiting spacecraft, by telescopic observations from earth, and through detailed analyses of the SNC meteorites presumed to be Martian rocks are summarized and analyzed. A compositional model for Mars soil, giving selected average elemental concentrations of major and trace elements, is suggested. It is proposed that the fine surface materials on Mars are a multicomponent mixture of weathered and nonweathered minerals. Smectite clays, silicate mineraloids similar to palagonite, and scapolite are suggested as possible major candidate components among the weathered minerals.

Banin, A.↗
NASA NTRS1994

Coincidence in Time of the Imbrium Basin Impact and Apollo 15 KREEP Volcanic Flows: The Case for Impact-Induced Melting

On the Earth there is no firm evidence that impacts can induce volcanic activity. However, the Moon does provide a very likely example of volcanism induced by an immense impact: the Imbrium basin-forming event was immediately succeeded by a crustal partial melting event that released basalt flows characterized by K, rare-earth elements (REE), P, and other trace elements (KREEP) over a wide area creating the Apennine Bench Formation. Impact total melting is inconsistent with the chemistry and petrography of these Apollo 15 KREEP basalts, which are quite unlike the impact melts recognized at Taurus-Littrow as the products of the Serenitatis impact. The Imbrium impact and the KREEP volcanic events are indistinguishable in radiometric age, and thus the volcanism occurred less than about 20 Ma later than the impact (less than about 0.5% of lunar history). The sample record indicates that such KREEP volcanism had not occurred in the region prior to that time, and demonstrates that it never occurred again. Such coincidence in time implies a genetic relationship between the two events, and impact-induced partial melting or release appears to be the only feasible process. Nonetheless, the characteristics of the Apollo 15 KREEP basalts suggest large-degree crustal melting that is not easy to reconcile with the inability of lunar pressure release alone to induce partial melting unless the source was already almost at its melting point. The earliest history of the surface of the Earth, at a time of greater internal heat production and basin-forming impacts, could have been greatly influenced by impact-induced melting.

Ryder, Graham↗
NASA NTRS1994

The Large Impact Process Inferred from the Geology of Lunar Multiring Basins

The study of the geology of multiring impact basins on the Moon over the past ten years has given us a rudimentary understanding of how these large structures have formed and evolved on the Moon and other bodies. Two-ring basins on the Moon begin to form at diameters of about 300 km; the transition diameter at which more than two rings appear is uncertain, but it appears to be between 400 and 500 km in diameter. Inner rings tend to be made up of clusters or aligned segments of massifs and are arranged into a crudely concentric pattern; scarp-like elements may or may not be present. Outer rings are much more scarp-like and massifs are rare to absent. Basins display textured deposits, interpreted as ejecta, extending roughly an apparent basin radius exterior to the main topographic rim. Ejecta may have various morphologies, ranging from wormy and hummocky deposits to knobby surfaces; the causes of these variations are not known, but may be related to the energy regime in which the ejecta are deposited. Outside the limits of the textured ejecta are found both fields of satellitic craters (secondaries) and light plains deposits. Impact melt sheets are observed on the floors of relatively unflooded basins. Samples of impact melts from lunar basins have basaltic major-element chemistry, characterized by K, rare-earth elements (REE), P, and other trace elements of varying concentration (KREEP); ages are between 3.8 and 3.9 Ga. These lithologies cannot be produced through the fusion of known pristine (plutonic) rock types, suggesting the occurrence of unknown lithologies within the Moon. These melts were probably generated at middle to lower crustal levels. Ejecta compositions, preservation of pre-basin topography, and deposit morphologies all indicate that the excavation cavity of multiring basins is between about 0.4 and 0.6 times the diameter of the apparent crater diameter. Basin depths of excavation can be inferred from the composition of basin ejecta. A variety of mechanisms has been proposed to account for the formation of basin rings but none of them are entirely plausible. Mechanisms can be divided into two broad groups: (1) forcible uplift due to fluidization of the target; (2) concentric, brittle, fracturing and failure of the target, on regional (megaterraces) to global scales (lithospheric fracturing). Most basin rings are spaced at a constant factor on all planets. Evidence supports divergent ringforming models, so it may be that the ring-locating mechanism differs from the ring-forming mechanism. Thus, large-scale crustal foundering (megaterracing) could occur along concentric zones of weakness created by some type of resonant wave mechanism (fluidization and uplift); such immediate crustal adjustment could then be followed by long-term adjustment of the fractured lithosphere.

Spudis, Paul D.↗
NASA NTRS2011

Lunar Volatiles: An Earth-Moon Perspective

It has generally been accepted that the Moon is depleted in volatile elements. However, the recent discovery of measurable water in lunar glasses and apatites suggests that volatiles are not as depleted as was once thought. And, in fact, some authors have claimed that water contents of the lunar and terrestrial mantles are similar. Moderately volatile alkali elements may have a bearing on this issue. In general, bulk Moon alkalis are depleted relative to the bulk silicate Earth. Although the bulk lunar chemical composition is difficult to reconstruct, good correlations of alkali elements with refractory lithophile incompatible trace elements make this conclusion robust. These observations have been taken to mean that the Moon overall is depleted in volatiles relative to the Earth. Since water is more volatile than any of the alkali elements, presumably this conclusion is true for water, or even more so.

Jones, John H.↗
DOE OSTI2019

Additive manufacturing of platinum group element (PGE) reference materials with a silica matrix

The microanalytical community has an outstanding need for platinum group element (PGE) reference materials, particularly for trace element analysis by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). National Institute of Standards and Technology (NIST) glasses contain Rh, Pd, and Pt, but lack Ru, Os, and Ir. Synthesis of silicate PGE standards has proven difficult due the tendency of PGEs to form metallic nuggets. Additive manufacturing methods were used to produce PGE standards with a silica matrix. Monodispersed submicron PGE-doped Stöber particles were used as feedstock materials for electrophoretic deposition (EPD). Two-cm-sized samples produced by EPD were subsequently densified by thermal processing. The homogeneity of PGEs was tested using LA-ICPMS and concentrations were measured by laser ablation and solution ICPMS. The PGE concentrations ranged from 0.5 to 3 μg/g. The inhomogeneity was at the 3% RSD level for Ru, Rh, Ir, and Os throughout and 5% for Pt and Pd in the interior of the samples. Based on LA-ICPMS analyses, the interiors of the two samples have near identical concentrations in PGEs. The samples fabricated in this study represent the most complete and homogeneous PGE standards produced with a silicate matrix. The ability to produce multiple samples with the same composition provides opportunities for validating methods, monitoring long-term reproducibility, and facilitating interlaboratory comparisons.

36 MATERIALS SCIENCE↗
DOE OSTI2024

The importance of accounting for landscape position when investigating grasslands: A multidisciplinary characterisation of a Californian coastal grassland

Data from the characterisation of the Point Reyes Field Site, published in AGU Earth's Future under the title: The importance of accounting for landscape position when investigating grasslands: A multidisciplinary characterisation of a Californian coastal grassland. This paper explored the effect of landscape position on the response of a Californian grassland to seasonal changes. All files are csv files. The EMI data contains 8 csv files with a metadata csv explaining the columns. The dataset also includes soil variables including total concentrations calculated from fused samples, then dissolved and measured on ICP-AES for whole-rock elements and ICP-MS for trace elements. Mineral composition was attained using X-ray diffraction at BL 11-3 at SSRL . Data was then run through the High Score database to characterise different mineral phases. total It also includes a table with bulk soil characteristics such as soil pH, cation exchange capacity, and soil textural data. Data from Teros 12 Meter soil moisture, electrical conductivity and temperature sensors are presented in SMS Csv file. While the WL bottom and top files contain data from Piezometers measuring the ground water table. We have included a csv file that contains soil CO2 efflux data from Feb 2021-Oct 2021 in the Point Reyes Grassland Experiment We have included the spatially orientated (easting northing) remotely sensed datasets that were used in the K-means clustering analysis conducted on our site with electrical conductivity, normalised difference vegetation index, elevation, slope, solar radiation, topographic position and wetness index, and a clustering score. Finally there is a list of all the identified grassland species at the site.For more information on flux data, please contact the corresponding author.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1979

Petrogenetic relationship between Allan Hills 77005 and other achondrites

The paper presents chemical and petrologic data relating the Allan Hills (ALHA) 77005 achondrite from Antarctica and explores their petrogenetic relationship with the shergottites. Petrologic similarities with the latter in terms of mineralogy, oxidation state, inferred source region composition, and shock ages suggest a genetic relationship, also indicated by volatile to involatile element ratios and abundances of other trace elements. ALHA 77005 may be a cumulate crystallized from a liquid parental to materials from which the shergottites crystallized or a sample of peridotite from which shergottite parent liquids were derived. Chemical similarities with terrestrial ultramafic rocks suggest that it provides an additional sample of the only other solar system body with basalt source origins chemically similar to the upper earth mantle.

Mcsween, H. Y., Jr.↗
NASA NTRS1974

Elemental abundances in meteoritic and terrestrial matter

Major and trace element analyses of over 180 individual chondrules from 12 carbonaceous chondrites are reported, including individual analyses of 60 chondrules from Pueblito de Allende. Siderophile elements in most chondrules are depleted, compared to the whole chondrite. Correlations of Al-Ir and Ir-Sc among chondrules high in Ca and Al were observed. A Cu-Mn correlation was also found for chondrules from some meteorites. No correlation was observed between Au and other siderophile elements (Fe, Ni, Co and Ir). It is suggested that these elemental associations were present in the material from which the chondrules formed. Compositionally, chondrules appear to be a multicomponent mixture of remelted dust. One component displaying an Al-Ir correlation is identified as Allende-type white aggregates. The other components are a material chemically similar to the present matrix and sulfides-plus-metal material. Abundances of the REE (rare earth elements) were measured in ordinary Allende chondrules and were 50% higher than REE abundances in Mokoia chondrules; REE abundances in Ca-Al rich chondrules were similar to REE abundances in Ca-rich white aggregates.

Schmitt, R. A.↗
NASA NTRS1974

Labile and nonlabile element relationships among Apollo 17 samples

Volatile and nonvolatile trace element contents in a suite of Apollo 17 soils and rocks are studied. It is found that the halogens exhibit a remarkable degree of coherence because of their apparent diverse geochemistry, that the F-Cl-P2O5 coherence previously noted persists among Apollo 17 samples, that both U and Ru-Os support lateral mixing of regolith on a local scale, and that the meteoritic Ru/Os ratios found in a few samples are attributed to primitive lunar material that has not been extensively recycled.

Jovanovic, S.↗
DOE OSTI2025

Effect of seasonal anoxia on geochemical cycling in a stratified pond: Comparison to cooler pond conditions 40 years ago

Seasonal stratification in temperate lakes deeper than a few meters creates favorable conditions for pronounced vertical redox zones, often resulting in anaerobic hypolimnions and significant geochemical changes. Here, this study examined thermocline formation and trace element behavior in a seasonally stratified pond amid rising air temperatures. Over two years, data were collected from Pond B at the US Department of Energy Savannah River Site in Aiken, South Carolina. Pond B, a man-made monomictic reservoir, received cooling water from a nuclear reactor from 1961 to 1964. Strong thermal stratification forms a distinct thermocline in May and progresses downward until November. Compared to the 1980s, this study shows a delayed onset and extended duration of stratification. The prolonged summer stratification reduces deep water oxygen replenishment, extending hypoxic conditions. Trace and major elements sampled in the water column revealed strong correlations between As, Fe, and Mn profiles, with concentrations increasing by 1–2 orders of magnitude in the anaerobic hypolimnion. This period captured the seasonal transition from winter mixing to summer stratification to fall overturn. Under anoxic conditions, Fe(III) reduces to Fe(II) in the sediment, releasing dissolved iron into the water column. The extended anoxic periods likely promoted arsenic release from sediments. Prolonged anoxia may enhance arsenic mobilization and solubility in the lake. This study illustrates how climate-induced changes in seasonal stratification of contaminated waters can convert contaminant sinks into sources, offering insights into the cycling of arsenic and other dissolved ions in stratified lakes and their implications for water quality management.

Anoxic conditions↗
DOE OSTI2021

Unraveling the advances of trace doping engineering for potassium ion battery anodes via tomography

Doping have been considered as a prominent strategy to stabilize crystal structure of battery materials during the insertion and removal of alkali ions. The instructive knowledge and experience acquired from doping strategies predominate in cathode materials, but doping principle in anodes remains unclear. Here, we demonstrate that trace element doping enables stable conversion-reaction and ensures structural integrity for potassium ion battery (PIB) anodes. With a synergistic combination of X-ray tomography, structural probes, and charge reconfiguration, we encode the physical origins and structural evolution of electro-chemo-mechanical degradation in PIB anodes. By the multiple ion transport pathways created by the orderly hierarchical pores from “surface to bulk” and the homogeneous charge distribution governed in doped nanodomains, the anisotropic expansion can be significantly relieved with trace isoelectronic element doping into the host lattice, maintaining particle mechanical integrity. Our work presents a close relationship between doping chemistry and mechanical reliability, projecting a new pathway to reengineering electrode materials for next-generation energy storage.

25 ENERGY STORAGE↗
DOE OSTI2021

Total metals & anion concentration data; Slate River floodplain, Crested Butte, CO; May 2020-September 2020

This data package includes processed and undiluted measurements for metal and anion concentrations from pore water (groundwater) samples from the Slate River floodplain of Crested Butte, CO, a focus field site for the SLAC Floodplain Hydro-Biogeochemistry SFA. The data was generated as part of the work targeting the overarching research question for the SLAC SFA: How do ubiquitous subsurface interfaces mediate molecular-scale biogeochemical processes and groundwater quality in floodplains and watersheds? Samples were collected between May and September of 2020. These measurements were all recorded at the Arizona Laboratory for Emerging Contaminants (ALEC) at the University of Arizona located in Tucson, AZ. Groundwater samples were extracted from a network of installed rhizon (Rhizosphere Research Products, part no. 19.60.21F, 0.6 micrometer mesh size) and piezometer wells within the river floodplain. All water samples were shaded from sun exposure during extraction from the subsurface and preserved at 4C until measured at ALEC.Analysis by ICP-MS:Measurements for total metals were made on the Agilent 7700x ICP-MS (for total metals) – Agilent Technologies, Santa Clara, CA.The analytical QA/QC protocol was adapted from US EPA Method 200.8 for analysis by ICP-MS. Calibration standards were prepared from multi-element stock solution (Sigma-Aldrich Multielement standard solution for ICP, St. Louis, MO) using matrix matched to sample solutions (either 2% HCl or HNO3 from AriStar Plus,grade acids from VWR Scientific). Calibration curves include at least 7 points with correlation coefficients > 0.995. The QC protocol includes a continuing calibration blank (CCB), a continuing calibration verification (CCV) solution and at least one quality control sample (QCS) to be analyzed just after calibration and again after every 12 samples and at the completion of the run. The QCS solutions are from an independent source, such as NIST SRM 1643e - Trace Elements in Water, or QCS solutions from High Purity Standards (Charleston, SC). Acceptable QC responses must be between 90 and 110% of the certified value. An internal standard (Rh) is added via on-line addition into the sample line using a mixing tee.Analysis by Ion Chromatography (Anions):The protocol follows Method 4110 in Standard Methods for Examination of Water and Wastewater.The instrument used is the Thermo Scientific Dionex ICS-6000 using AS+AG22 column set for anion analysis with isocratic method using sodium carbonate eluent. Detection is by chemical suppression of eluent conductivity. Quality control solutions and mixed analyte standards purchased from Inorganic Ventures, Christiansburg, VA.All files are in csv format.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Analysis of liquid petroleum using a laser-induced breakdown spectroscopy instrument

Here, a prototype analyzer for the direct LIBS analysis of nebulized liquid samples was developed and tested, particularly for the analysis of petroleum, organic solvents and aqueous solutions. The LIBS analyzer requires about 750 µl of liquid sample, 1 liter of N 2 gas, and 10 s of the analysis time to record 100 spectra. The limits of detection in oil and solvent are as low as 0.01–0.04 ppm for Li, Mg, and Cu. They increase for the difficult elements, such as Pb and Hg (7-10 ppm), Cl (250 ppm), and S (~0.7%). The relative standard deviation of measuring 100 ppm vanadium in oil and solvent was 1.5%. The LIBS detection limits and repeatability are better than required by the standard method ASTM D5185 for the analysis of lubricating oils in ICP-OES. Several petroleum samples were analyzed by LIBS and the quantitative results for V, Ni, and Fe compared to the ICP-OES data. Light crude oils can be nebulized and analyzed directly. Medium crude oils require minimal dilution at least 1:1, otherwise errors of determination become large. Presumably, utilization of the internal standard and chemometrics can be useful to correct for the matrix effects. In addition to the trace element analysis, the LIBS prototype demonstrated ability to measure the hydrogen-to-carbon ratio in organic liquid samples. Several unidentified features were observed in the carbon spectrum. Their possible origin is discussed.

02 PETROLEUM↗
DOE OSTI2018

Quaternary tephra from the Valles caldera in the volcanic field of the Jemez Mountains of New Mexico identified in western Canada

A fine-grained, up to 3-m-thick tephra bed in southwestern Saskatchewan, herein named Duncairn tephra (Dt), is derived from an early Pleistocene eruption in the Jemez Mountains volcanic field of New Mexico, requiring a trajectory of northward tephra dispersal of ~1500 km. An unusually low CaO content in its glass shards denies a source in the closer Yellowstone and Heise volcanic fields, whereas a Pleistocene tephra bed (LSMt) in the La Sal Mountains of Utah has a very similar glass chemistry to that of the Dt, supporting a more southerly source. Comprehensive characterization of these two distal tephra beds along with samples collected near the Valles caldera in New Mexico, including grain size, mineral assemblage, major- and trace-element composition of glass and minerals, paleomagnetism, and fission-track dating, justify this correlation. Two glass populations each exist in the Dt and LSMt. The proximal correlative of Dt1 is the plinian Tsankawi Pumice and co-ignimbritic ash of the first ignimbrite (Qbt1g) of the 1.24 Ma Tshirege Member of the Bandelier Tuff. Finally, the correlative of Dt2 and LSMt is the co-ignimbritic ash of Qbt2. Mixing of Dt1 and Dt2 probably occurred during northward transport in a jet stream.

58 GEOSCIENCES↗
NASA NTRS2006

Removal and Replacement of Primary Metal in Ferroan Lodranite MAC 88177

Collectively, acapulcoites and lodranites form a clan of primitive achondrites generally thought to have originated from the same parent body on the basis of similarities in petrology, mineral compositions, bulk compositions, cosmic ray exposure ages and oxygen isotope compositions, although considerable variation in some of these parameters has shown that the parent body was not entirely uniform. The presence of relict chondrules in several acapulcoites indicates that all were likely derived from chondrite-like precursor materials. The transition from acapulcoite to lodranite is gradual and corresponds to increasing metamorphic grade. Lodranites are generally coarser grained, but petrographic distinction between the two groups can also be made by modal abundances of troilite and plagioclase. Depletion of both these phases and incompatible lithophile trace elements in lodranites is consistent with their restitic origin formed by greater than 10% extraction of basaltic melt. Magnesian lodranites (e.g. Gibson, GRA 95209, Y-75274, Y-8002), some of which might also be considered transitional acapulcoites, have mineral and chemical compositions consistent with derivation by thermal metamorphism and partial melt extraction from acapulcoites, as would seem logical if samples represented different grades of metamorphism along a linear evolution trend. Ferromagnesian silicates in these lodranites tend to be displaced toward lower fe# (opx fe# 4-6) than the distribution observed in acapulcoites (opx fe# 6-11). A subset of lodranites, termed ferroan lodranites (e.g. FRO 90011, LEW 88280, Lodran, MAC 88177, Y-74357, Y- 791491/Y-791493), have ferromagnesian silicate minerals that are too Fe-rich (fe#>10) to have formed as simple restites from any known acapulcoite. Like silicates, metal-sulfide systematics of the ferroan lodranites are also inconsistent with a simple restitic origin. Logically, restitic lodranites should have been depleted in FeS during extraction of partial melts, since melting of the metal-sulfide system initiates at lower temperatures than melting of silicates. Yet, puzzingly, ferroan lodranites contain significant quantities (1.9-5.3 modal%) of troilite, indicating either (1) metal sulfide partial melts were retained during basaltic melt extraction or (2) later infusion of metal sulfide melts has occurred. In this study, we use trace siderophile elements in metals to assess the relative importance of each in creating the observed troilite enrichment.

Herrin, J. S.↗