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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Absolute rate of the reaction of bromine atoms with ozone from 200-360 K

The rate constant for the reaction Br + O3 yields BrO + O2 was measured from 200 to 360 K by the technique of flash photolysis coupled to time resolved detection of bromine atoms by resonance fluorescence (FP-RF). Br atoms were produced by the flash photolysis of CH3Br at lambda 165nm.O3 was monitored continuously under reaction conditions by absorption at 253.7 nm. At each of five temperatures the results were independent of substantial variations in O3, total pressure and limited variations in flash intensity. The measured rate constants obeyed the Arrhenius expression, where the error quoted is two standard deviations. Results are compared with previous determinations which employed the discharge flow-mass spectrometric technique.

Michael, J. V.↗
NASA NTRS1978

Absolute flux density calibrations: Receiver saturation effects

The effect of receiver saturation was examined for a total power radiometer which uses an ambient load for calibration. Extension to other calibration schemes is indicated. The analysis shows that a monotonic receiver saturation characteristic could cause either positive or negative measurement errors, with polarity depending upon operating conditions. A realistic model of the receiver was made by using a linear-cubic voltage transfer characteristic. The evaluation of measurement error for this model provided a means for correcting radio source measurements.

Freiley, A. J.↗
NASA NTRS1977

Silicon vidicon imaging of Jupiter - 4100- to 8300-A absolute reflectivities and limb darkening of spatially resolved regions

Jupiter was observed in six continuum wavelength channels in the region 4100-8300 A, using a silicon vidicon imaging photometer. Spectral reflectivities and high spatial resolution limb-darkening curves for several belts and zones have been extracted from the data. Simple model fits to the data yield information regarding spectral and spatial variations in single-scattering albedos and shape of particle single-scattering phase functions. Belts appear to be more backscattering than zones, particularly in the blue. The data are in moderate agreement with limb-darkening predicted by models derived from the center-to-limb variation in equivalent width of the H2 4-0 S(1) quadrupole line (Cochran, 1976) in the South Tropical Zone, but strongly disagree with the results of such models for the North Equatorial Belt.

Diner, D. J.↗
NASA NTRS1978

Absolute rate of the reaction of bromine atoms with ozone from 200 to 360 K

The rate constant for the reaction Br + O3 yields BrO + O2 has been measured from 200 to 360 K by the technique of flash photolysis coupled to time resolved detection of bromine atoms by resonance fluorescence (FP-RF). Br atoms were produced by the flash photolysis of CH3Br at a wavelength of 165 nm. O3 concentration was monitored continuously under reaction conditions by absorption at 253.7 nm. At each of five temperatures the results were independent of substantial variations in O3 concentration, total pressure (Ar), and limited variations in flash intensity (i.e., initial Br concentration). The measured rate constants obey the Arrhenius expression, k = (7.74 plus or minus 0.50) x 10 to the -12th exp(-603 plus or minus 16/T) cu cm/molecule/sec, where the error quoted is two standard deviations.

Michael, J. V.↗
NASA NTRS1978

Measurement at different temperatures of absolute intensities, line half-widths, and broadening by Ar and N2 for the 30 0 1 II--00 0 0 band of CO2

Vibration-rotation line intensities, self-broadening coefficients, and foreign-gas-broadening (Ar and N2) coefficients were measured at 197, 233, and 294 K for the 30 0 1 II--00 0 0 band of CO2 at 6348/cm. Values for the total band intensity, purely vibrational transition moment, and vibration-rotation interaction factor were deduced from the measurements.

Valero, F. P. J.↗
NASA NTRS1978

Absolute rate of the reaction of atomic hydrogen with ethylene from 198 to 320 K at high pressure

The rate constant for the H+C2H4 reaction has been measured as a function of temperature. Experiments were performed with high pressures of Ar heat bath gas at seven temperatures from 198 to 320 K with the flash photolysis-resonance fluorescence (FP-RF) technique. Pressures were chosen so as to isolate the addition rate constant k1. The results are well represented by an Arrhenius expression. The results are compared with other studies and are theoretically discussed.

Lee, J. H.↗
NASA NTRS1979

Absolute spectral energy distribution of quasi-stellar objects from 0.3 to 10 microns

Energy distributions of 24 quasrs have been measured from 0.3 to 10 microns. In addition, optical emission-line strengths have been obtained for 35 quasars. The sample includes quasars discovered from both radio and optical surveys. Over the observed range of wavelengths the energy distributions are roughly characterized by a power law of slope -1, but there are vast differences in the shapes of individual spectra. In the rest frame the average slope between 1 and 3 microns is significantly steeper than the average slope between 0.3 and 1 micron; the power emitted at 0.3 and 3 microns is significantly greater than that emitted around 1 micron. On the basis of arguments of variability and the shape of the energy distribution between optical and radio wavelengths, it is concluded that the bulk of the radiation in the observed range results from nonthermal processes. Some contribution from thermal emission from dust cannot be ruled out and may explain the break in the spectra at 1 micron seen in many quasars.

Neugebauer, G.↗
NASA NTRS1979

Absolute rate constants for the reaction of atomic hydrogen with ketene from 298 to 500 K

Rate constants for the reaction of atomic hydrogen with ketene have been measured at room temperature by two techniques, flash photolysis-resonance fluorescence and discharge flow-resonance fluorescence. The measured values are (6.19 + or - 1.68) x 10 to the -14th and (7.3 + or - 1.3) x 10 to the -14th cu cm/molecule/s, respectively. In addition, rate constants as a function of temperature have been measured over the range 298-500 K using the FP-RF technique. The results are best represented by the Arrhenius expression k = (1.88 + or - 1.12) x 10 to the -11th exp(-1725 + or - 190/T) cu cm/molecule/s, where the indicated errors are at the two standard deviation level.

Michael, J. V.↗
NASA NTRS1978

Absolute elastic differential electron scattering cross sections in the intermediate energy region. IV - CO

Using a crossed electron beam-molecular beam scattering geometry and a relative-flow technique, ratios of elastic differential cross sections of CO to those of He have been measured at electron impact energies of 3, 5, 7.5, 9.9, 15, 20, 30, 50, 75, and 100 eV. At each energy, an angular range of 15 to 130 deg has been covered. These ratios have been multiplied by previously known He elastic differential cross sections to obtain elastic differential cross sections for CO. Since pure rotational excitations were not resolved, the elastic differential cross sections are a sum of elastic and pure rotational excitations at room temperature. From a knowledge of differential cross sections (DCS), integral and momentum transfer cross sections have been calculated. Both the DCS and integral cross sections are compared at 50, 75, and 100 eV to a recent two-potential theory of e-molecule scattering. Present results show that the isoelectronic molecules CO and N2 have very similar magnitudes and shapes of their differential cross sections.

Tanaka, H.↗
NASA NTRS1980

Results of a Loran-C flight test using an absolute data reference

A closed circuit flight test was conducted in the Boston area using VOR's and NDB's as reference points. The Loran-C data collected during the flight was then compared against a reference provided by the Discrete Address Beacon System (DABS) facility at Lincoln Laboratories. A MIT crew used a commercial receiver and recorded Loran-C time differences which would also be compared with the data provided by the DABS facility and eventually with the data collected by Ohio University. The Ohio University low-cost receiver was used for this test which was conducted in the Ohio University DC-3 flying laboratory. The Loran-C time-difference data was recorded with a microcomputer data collection system and stored on magnetic tape for subsequent analysis. The MIT receiver was also on board the DC-3, and recorded its data on a cassette tape which was later used by the MIT crew for data analysis. The equipment configuration in the aircraft, the flight procedure and the results obtained from the data collected with Ohio University's receiver and recording system are described.

Fischer, J. P.↗