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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
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DOE OSTI2018

Molecular Models and Wave Function Definitions for Models A-G of the [2Fe]F Cluster in FeFe-hydrogenase Maturase Enzyme HydF

The dataset contains all relevant atomic positional coordinates for 2Fe-cluster models, and electronic wave function data (using formatted Gaussian checkpoint files) as described in the related publication (see citation below). The version 2.0 contains additional models for [2Fe-2S] cluster linked [2Fe]F constructs. The top folder contains "analysis.xlsx" electronic spreadsheet that summarizes all the numerical results for absolute and relative electronic energy values, internal coordinates, calculated and scaled vibrational frequencies for diatomic stretching modes. The details of developing scaled quantum forcefields as a function of level of theory and model composition are also given. The schematic structural definitions are given in the "models.pdf" file and keys for abbreviations are provided in "symbols.txt" file.

carbonyl stretching frequencies↗
NASA NTRS1968

Geochemistry of andesites.

Trace element geochemistry of calc-alkaline andesites, discussing crustal composition models and trace elements distribution

Taylor, S. R.↗
NASA NTRS1973

Iron abundance in the moon from magnetometer measurements

Apollo 12 and 15 lunar surface magnetometer data with simultaneous lunar orbiting Explorer 35 data are used to plot hysteresis curves for the whole moon. From these curves a whole-moon permeability mu = 1.029 + 0.024 or - 0.019 is calculated. This result implies that the moon is not composed entirely of paramagnetic material, but that ferromagnetic material such as free iron exists in sufficient amounts to dominate the bulk lunar susceptibility. From the magnetic data the ferromagnetic free iron abundance is calculated. Then for assumed compositional models of the moon the additional paramagnetic iron is determined, yielding total lunar iron content. The calculated abundances are as follows: ferromagnetic free iron = 5 + or - 4 wt. percent, and total iron in the moon = 9 + or - 4 wt. percent.

Parkin, C. W.↗
NASA NTRS1972

Thermal expansion compatibility of ceramic chip capacitors mounted on alumina substrates.

The thermal expansion coefficients of a representative sample of BaTiO3 and TiO2 ceramic chip capacitors and alumina substrates have been examined. These data have revealed large potential mechanical stresses under thermal cycling. A mathematical analysis of a composite model of the capacitor to predict the thermal expansion and modulus of elasticity and an analysis of the capacitor-substrate system to predict the magnitude of thermally induced stresses have been conducted. In all cases studied, thermally induced stresses great enough to cause capacitor body rupture or termination failure was predicted.

Allen, R. V.↗
NASA NTRS1974

Lunar electrical conductivity, permeability,and temperature from Apollo magnetometer experiments

Magnetometers were deployed at four Apollo sites on the moon to measure remanent and induced lunar magnetic fields. Measurements from this network of instruments were used to calculate the electrical conductivity, temperature, magnetic permeability, and iron abundance of the lunar interior. Global lunar fields due to eddy currents, induced in the lunar interior by magnetic transients, were analyzed to calculate and electrical conductivity profile for the moon, and those profiles were used to calculate the lunar temperature for an assumed lunar material of olivine. Simultaneous measurements by magnetometers on the lunar surface and in orbit around the moon were use to construct a whole-moon hysteresis curve, from which the global lunar magnetic permeability is determined. Total iron abundance (sum of iron in the ferromagnetic and paramagnetic states) was calculated for two assumed compositional models of the lunar interior. Other lunar models with an iron core and with a shallow iron-rich layer also discussed in light of the measured global lunar permeability. Simultaneous magnetic field and solar plasma pressure measurements show that the remanent fields at the Apollo 12 and 16 sites interact with, and are compressed by, the solar wind. Velocities and thicknesses of the earth's magnetopause and bow shock were also estimated from simultaneous magnetometer measurements.

Dyal, P.↗
NASA NTRS1973

Iron abundance in the moon from magnetometer measurements

Apollo 12 and 15 lunar surface magnetometer data with simultaneous lunar orbiting Explorer 35 data are used to plot hysteresis curves for the whole moon. From these curves a whole-moon permeability of 1.029 (+0.024 or -0.019) is calculated. This result implies that the moon is not composed entirely of paramagnetic material, but that ferromagnetic material such as free iron exists in sufficient amounts to dominate the bulk lunar susceptibility. From the magnetic data the ferromagnetic free iron abundance is calculated. Then for assumed compositional models of the moon the additional paramagnetic iron is determined, yielding total lunar iron content. The calculated abundances are as follows: ferromagnetic free iron, 5 plus or minus 4 wt %; total iron in the moon, 9 plus or minus 4 wt %.

Parkin, C. W.↗
NASA NTRS1974

An interpretation of the carbon-oxygen to iron ratio

Data from recent measurements on the composition of primary cosmic rays above 1 GeV/nucleon are critically reviewed for information pertaining to selection of suitable energy-dependent composition models. Areas where crucial experimental information may result in selection of a suitable model are pointed out. In particular, the study of the energy distribution of VVH nuclei, and the derivation of more accurate energy spectra of 10 less than or equal to Z less than or equal to 14, 15 less than or equal to Z less than or equal to 23 and Z greater than 24 would contribute to discriminate between models which rely on interstellar propagation and those that ascribe a different source mechanism for Fe group nuclei.

Balasubrahmanyan, V. K.↗
NASA NTRS1975

The relationship between reliability and bonding techniques in hybrid microcircuits

Differential thermal expansion was shown to be responsible for many observed failures in ceramic chip capacitors mounted on alumina substrates. It is shown that the mounting techniques used in bonding the capacitors have a marked effect upon the thermally induced mechanical stress and thus the failure rate. A mathematical analysis was conducted of a composite model of the capacitor-substrate system to predict the magnitude of thermally induced stresses. It was experimentally observed that the stresses in more compliant bonding systems such as soft lead tin and indium solders are significantly lower than those in hard solder and epoxy systems. The marked dependence upon heating and cooling rate was proven to be a determining factor in the prediction of failure solder systems. It was found that the harder or higher melting solders are less susceptible to thermal cycling effects but that they are more likely to fail during initial processing operations. Strain gage techniques were used to determine thermally induced expansion stresses of the capacitors and the alumina substrates. The compliance of the different bonding mediums was determined. From the data obtained, several recommendations are made concerning the optimum bonding system for the achievement of maximum reliability.

Caruso, S. V.↗
NASA NTRS1975

The peculiar object HD 44179 /'The red rectangle'/

A strong infrared source detected in the AFCRL sky survey is confirmed, and is identified with the binary star HD 44179, embedded in a peculiar nebula. UBVRI and broad-band photometry between 2.2 and 27 microns are combined with blue, red, and near-infrared spectra, polarimetry and spectrophotometry of the star, and a range of direct and image-tube photographs of the nebula, to suggest a composite model of the system. In this model, the infrared radiation derives from thermal emission by dust grains contained in a disklike geometry about the central object, which appears to be of spectral type B9-A0 III and which may be in pre-main-sequence evolution. Two infrared emission features are found, peaking at 8.7 and 11.3 microns, the latter corresponding to the feature seen in the spectrum of the planetary nebula NGC 7027. The complex nebular structure is discussed on the basis of photographs through narrow-band continuum and emission-line filters. The polarization data support the suggestion of a disk containing some large particles. No radio continuum emission is detected.

Cohen, M.↗
NASA NTRS1974

A meteorite that got away

The mass and brightness are estimated for a meteorite which passed through the atmosphere without touching the ground and was observed over the northwestern part of North America. It is noted that the ultimate mass of a meteorite should be derived from its deceleration and that the ablated mass must also be calculated in order to obtain the initial mass. The deceleration, ablation, and brightness are calculated for the present meteorite on the basis of two composition models: a stony meteorite and a hard cometary dustball. The results suggest that this object probably was a hard cometary dustball.

Opik, E. J.↗
NASA NTRS1975

The relationship between reliability and bonding techniques in hybrid systems

Differential thermal expansion has been shown to be responsible for many observed failures in ceramic chip capacitors mounted on alumina substrates. The present work has shown that the mounting techniques used in bonding the capacitors have a marked effect upon the thermally induced mechanical stress and thus the failure rate. A mathematical analysis of a composite model of the capacitor-substrate system to predict the magnitude of thermally induced stresses have been conducted. It has been experimentally observed that the stresses in more compliant bonding systems such as soft lead/tin and indium solders are significantly lower than those in hard solder and epoxy systems. From the data obtained, several recommendations are made concerning the optimum bonding system for the achievement of maximum reliability.

Kinser, D. L.↗
NASA NTRS1976

Satellite measurements of ion composition and temperatures in the topside ionosphere during medium solar activity

Information on both ion density and temperature is obtained from analysis of Retarding Potential Analyzer data from the OGO-4 and Explorer-31 satellites. Results obtained from data in the altitude range of 700-2000 km during medium solar activity are presented. An attempt is made to describe the major altitude variations of ion densities and temperatures at middle and low latitudes. The transition heights, where the heavier and lighter ions are equal, are found to be about 1600 and 1300 km at middle and low latitudes, respectively, for daytime and 700 km at night for middle latitudes. Based on the observed data and using diffusive equilibrium as a first-order approximation, topside ionospheric composition models are given for medium solar activity.

Goel, M. K.↗
NASA NTRS1975

The relationship between reliability and bonding techniques in hybrid systems

Differential thermal expansion has been shown to be responsible for many observed failures in ceramic chip capacitors mounted on alumina substrates. The present work has shown that the mounting techniques used in bonding the capacitors have a marked effect upon the thermally induced mechanical stress and thus the failure rate. A mathematical analysis of a composite model of the capacitor-substrate system to predict the magnitude of thermally induced stresses has been conducted. It has been observed that the stresses in more compliant bonding systems such as soft lead/tin and indium solders are significantly lower than those in hard solder and epoxy systems. The marked dependence upon heating and cooling rate has proven to be a determining factor in the prediction of failure in both the indium and tin/lead solder systems. This study has shown that the harder or higher melting solders are less susceptible to thermal cycling effects but that they are more likely to fail during initial processing operations. Recommendations are made concerning the optimum bonding system for the achievement of maximum reliability.

Kinser, D. L.↗