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At least 595 records · Page 33

Growth Orientation of Carbon Nanotubes by Thermal CVD

Carbon nanotubes with a few shells are synthesized using thermal chemical vapor depositions. The sizes of these carbon nanotubes (CNT) are quite uniform and the length is up to several tens of micrometers. With the particular substrate location for which the substrate surface is normal along or against the gravity vector, different growth orientations of CNT are observed by scanning electron microscopy, though the Raman spectra for samples at different locations are similar to each other. The results suggest the gravitation effects in growth of the long and small diameter CNT.

Zhu, S.↗

Gravity Effects in Carbon Nanotube Growth by Thermal Chemical Vapor Deposition

Carbon nanotubes are synthesized using thermal chemical vapor deposition. The sizes of these carbon nanotubes (CNT) are quite uniform and the length of the tube is up to several tens of micrometers. With the substrate surface normal either along or against the gravity vector, different growth orientations of CNT are observed by scanning electron microscopy although the Raman spectra are similar for samples synthesized at different locations. These results suggest the gravitation effects in the growth of long and small diameter CNT.

Zhu, S.↗

Orientational Growth of Carbon Nanotube for Applications

Since the superior properties of multi-wall carbon nanotubes (MWCNT) could improve numerous devices such as electronics and sensors, many efforts have been made in investigating the growth mechanism of MWCNT to synthesize high quality MWCNT. Most applications require uniform aligned CNT. In this presentation, a directional growth of CNT will be reported. Carbon nanotubes are synthesized using thermal chemical vapor deposition. Temperature and pressure are two important growth parameters for fabricating carbon nanotubes. It is found that the nanotube diameter distribution mainly depends on the growth-temperature. With the substrate surface normal either along or against the gravity vector, different growth orientations of MWCNT are observed by scanning electron microscopy although the Raman spectra are similar for samples synthesized at different locations. The sizes of these carbon nanotubes in each sample are quite uniform and the length of the tube is up to several tens of micrometers. These results suggest the gravitation effects in the growth of long and small diameter CNT.

Zhu, Shen↗

Status of the GAMMA-400 Project

The preliminary design of the new space gamma-ray telescope GAMMA-400 for the energy range 100 MeV-3 TeV is presented. The angular resolution of the instrument, 1-2 deg at E(gamma) approximately 100 MeV and approximately 0.01 at E(gamma) greater than 100 GeV, its energy resolution is approximately 1% at E(gamma) greater than 100 GeV, and the proton rejection factor is approximately 10(exp 6) are optimized to address a broad range of science topics, such as search for signatures of dark matter, studies of Galactic and extragalactic gamma-ray sources, Galactic and extragalactic diffuse emission, gamma-ray bursts, as well as high-precision measurements of spectra of cosmic-ray electrons, positrons, and nuclei.

Galper, A. M.↗

Experiment M409: Bremsstrahlung spectrometer

Spectrometric data were used to gain information for computation of the flux-energy spectra of bremsstrahlung inside the Gemini spacecraft and to determine if energetic electrons are able to penetrate the vehicle walls. The spectra were compared with computer predicted bremsstrahlung spectra by the use of data from beta spectrometers flown on Gemini 10 and 12 missions. The calculations of bremsstrahlung radiation involved uncertainties because of the small amount of information available on cross-section interaction and because of the complex, heterogeneous composition of the spacecraft. The bremsstrahlung detector was designed for time-differentiated measurement of the electron-induced gamma rays over a large section of the vehicle. Preliminary analysis of the data obtained during the missions was indicative that electrons did penetrate the spacecraft wall.

Lindsey, R. S., Jr.↗

Electron-impact excitation of UF6 at an electron energy of 20 eV in the energy-loss range of 0-10 eV

A technique combining electron impact excitation and optical absorption spectroscopy was applied to UF6. The crucial features of the experiment were that: (1) the electron optics was differentially pumped relative to the scattering chamber and (2) the target UF6 beam was condensed on a liquid nitrogen cold trap placed immediately above the scattering center. Energy loss spectra are presented at an incident electron energy of 20 eV and at scattering angles between 20 and 135 degrees. It is shown that no transitions are found below the first-detected feature at 3.0 eV and an optically forbidden excitation is found at 4.2 eV. A fairly strong optical absorption at 4.8 eV is observed to 'fill-in' at a scattering angle of 20 degrees but is practically absent at higher angles.

Chutjian, A.↗

Cross Sections for Electron Impact Excitation of Ions Relevant to Planetary Atmospheres Observation

The goal of this research grant was to calculate accurate oscillator strengths and electron collisional excitation strengths for inelastic transitions in atomic species of relevance to Planetary Atmospheres. Large scale configuration-interaction atomic structure calculations have been performed to obtain oscillator strengths and transition probabilities for transitions among the fine-structure levels and R-matrix method has been used in the calculations of electron-ion collision cross sections of C II, S I, S II, S III, and Ar II. A number of strong features due to ions of sulfur have been detected in the spectra of Jupiter satellite Io. The electron excitation cross sections for the C II and S II transitions are studied in collaboration with the experimental atomic physics group at the Jet Propulsion Laboratory. There is excellent agreement between experiment and theory which provide an accurate and broad-base test of the ability of theoretical methods used in the calculation of atomic processes. Specifically, research problems have been investigated for: electron impact excitation cross sections of C II: electron impact excitation cross sections of S III; energy levels and oscillator strengths for transitions in S III; collision strengths for electron collisional excitation of S II; electron impact excitation of inelastic transitions in Ar II; oscillator strengths of fine-structure transitions in neutral sulfur; cross sections for inelastic scattering of electrons from atomic nitrogen; and excitation of atomic ions by electron impact.

Tayal, Swaraj S.↗

Understanding Breaks in Flare X-Ray Spectra: Evaluation of a Cospatial Collisional Return-Current Model

Hard X-ray (HXR) spectral breaks are explained in terms of a one-dimensional model with a cospatial return current. We study 19 flares observed by the Ramaty High Energy Solar Spectroscopic Imager with strong spectral breaks at energies around a few deka-keV, which cannot be explained by isotropic albedo or non-uniform ionization alone. We identify these breaks at the HXR peak time, but we obtain 8 s cadence spectra of the entire impulsive phase. Electrons with an initially power-law distribution and a sharp low-energy cutoff lose energy through return-current losses until they reach the thick target, where they lose their remaining energy through collisions. Our main results are as follows. (1) The return-current collisional thick-target model provides acceptable fits for spectra with strong breaks. (2) Limits on the plasma resistivity are derived from the fitted potential drop and deduced electron-beam flux density, assuming the return current is a drift current in the ambient plasma. These resistivities are typically 2-3 orders of magnitude higher than the Spitzer resistivity at the fitted temperature, and provide a test for the adequacy of classical resistivity and the stability of the return current. (3) Using the upper limit of the low-energy cutoff, the return current is always stable to the generation of ion-acoustic and electrostatic ion-cyclotron instabilities when the electron temperature is nine times lower than the ion temperature. (4) In most cases, the return current is most likely primarily carried by runaway electrons from the tail of the thermal distribution rather than by the bulk drifting thermal electrons. For these cases, anomalous resistivity is not required.

Alaoui, Meriem↗

Electron impact excitation of autoionising states of krypton

Energy-loss spectra of krypton in the region between 21 and 29 eV have been obtained at electron impact energies of 30, 60 and 100 eV. For each energy, the angular distribution of intensities has been measured at 5, 10 and 15 deg scattering angles. Assignments of spectral features found in this region are suggested and a comparison is made with previous measurements.

Srivastava, S. K.↗

Negative-ion formation in the explosives RDX, PETN, and TNT by using the reversal electron attachment detection technique

First results of a beam-beam, single-collision study of negative-ion mass spectra produced by attachment of zero-energy electrons to the molecules of the explosives RDX, PETN, and TNT are presented. The technique used is reversal electron attachment detection (READ) wherein the zero-energy electrons are produced by focusing an intense electron beam into a shaped electrostatic field which reverses the trajectory of electrons. The target beam is introduced at the reversal point, and attachment occurs because the electrons have essentially zero longitudinal and radial velocity. The READ technique is used to obtain the 'signature' of molecular ion formation and/or fragmentation for each explosive. Present data are compared with results from atmospheric-pressure ionization and negative-ion chemical ionization methods.

Boumsellek, S.↗

Spectrum of a fast sporadic meteor

The spectrum of a fast (63 km/s) sporadic meteor for which altitude and orbit data are available is reported. The -6 mag meteor occurred on January 5, 1976, over southern New Mexico. Fifty features have been identified in the spectrum. The spectrum is essentially identical to that of Perseid meteors of similar brightness. It is shown that heavy-particle collisions do not dominate bright meteor spectra lacking time resolution. Low-energy electron excitation of Ca II is strongly indicated in the wake to such an extent as to strongly affect spectra of this type lacking time resolution.

Harvey, G. A.↗

The contribution of electron collisions to rotational excitations of cometary water

The e-H2O collisional rate for exciting rotational transitions in cometary water is evaluated for conditions found in comet Halley during the Giotto spacecraft encounter. In the case of the O(sub 00) yields 1(sub 11) rotational transition, the e-H2O collisional rate exceeds that for excitation by neutral-neutral collisions at distances exceeding 3000 km from the cometary nucleus. Thus, the rotational temperature of the water molecule in the intermediate coma may be controlled by collisions with electrons rather than with neutral collisions, and the rotational temperature retrieved from high resolution infrared spectra of water in comet Halley may reflect electron temperatures rather than neutral gas temperature in the intermediate coma.

Xie, Xingfa↗

Electron-impact excitation of the low-lying electronic states of HCN

The first study of the low-energy electron-impact excitation of low-lying electronic transitions in the HCN molecule is reported. Measurements were made at incident electron energies of 11.6 and 21.6 eV in the energy-loss range of 3-10 eV, and at scattering angles of 20-130 deg. Inelastic scattering spectra were placed on the absolute cross-section scale by determining first the ratio of inelastic-to-elastic scattering cross sections, and then separately measuring the absolute elastic scattering cross section. Several new electronic transitions are observed which are intrinsically overlapped in the molecule itself. Assignments of these electronic transitions are suggested. These assignments are based on present spectroscopic and cross-sections measurements, high-energy electron scattering spectra, optical absorption spectra, and ab initio molecular orbital calculations.

Chutjian, A.↗

New electronic states of NH and ND observed by resonance enhanced multiphoton ionization spectroscopy

Resonance Enhanced MultiPhoton Ionization (REMPI) spectra of NH and ND, which reveal four new electronic states are presented. Transitions from NH a 1 delta to 3s and 3p Rydberg states in both NH and ND have been observed and rotationally analyzed. The transitions were observed in the wavelength range of 258 to 288 nm. The state assignments are: e 1 pi (3s sigma) at 82857/cm, f 1 pi (3p sigma) at 86378/cm, g 1 delta (3p pi) at 88141/cm and h 1 sigma (3p pi) at 89151/cm.

Johnson, Russell D., III↗

The Focusing Optics X-Ray Solar Imager: FOXSI

The Focusing Optics x-ray Solar Imager (FOXSI) is a sounding rocket payload funded under the NASA Low Cost Access to Space program to test hard x-ray (HXR) focusing optics and position-sensitive solid state detectors for solar observations. Today's leading solar HXR instrument, the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) provides excellent spatial (2 arcseconds) and spectral (1 keV) resolution. Yet, due to its use of an indirect imaging system, the derived images have a low dynamic range (typically <10) and sensitivity. These limitations make it difficult to study faint x-ray sources in the solar corona which are crucial for understanding the particle acceleration processes which occur there. Grazing-incidence x-ray focusing optics combined with position-sensitive solid state detectors can overcome both of these limitations enabling the next breakthrough in understanding impulsive energy release on the Sun. The FOXSI project is led by the Space Sciences Laboratory at the University of California, Berkeley. The NASA Marshall Space Flight Center is responsible for the grazing-incidence optics, while the Astro-H team at JAXA/ISAS has provided double-sided silicon strip detectors. FOXSI is a pathfinder for the next generation of solar hard x-ray spectroscopic imagers. Such observatories will be able to image the non-thermal electrons within the solar flare acceleration region, trace their paths through the corona, and provide essential quantitative measurements such as energy spectra, density, and energy content in accelerated electrons.

Krucker, Saem↗

Auger Spectroscopy of Hydrogenated Diamond Surfaces

An energy shift and a change of the line shape of the carbon core-valence-valence Auger spectra are observed for diamond surfaces after their exposure to an electron beam, or annealing at temperatures higher then 950 C. The effect is studied for both natural diamond crystals and chemical-vapor-deposited diamond films. A theoretical model is proposed for Auger spectra of hydrogenated diamond surfaces. The observed changes of the carbon Auger line shape are shown to be related to the redistribution of the valence-band local density of states caused by the hydrogen desorption from the surface. One-electron calculation of Auger spectra of diamond surfaces with various hydrogen coverages are presented. They are based on self-consistent wave functions and matrix elements calculated in the framework of the local-density approximation and the self-consistent linear muffin-tin orbital method with static core-hole effects taken into account. The major features of experimental spectra are explained.

Krainsky, I. L.↗