Investigation of material properties of thermoplastic and thermoset polymer materials at cryogenic temperatures using molecular dynamics
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The NASA's Advanced Composites Technologies (ACT) Project has the potential to develop composite materials and structures technologies for the largest composite aerospace structures ever made. The objective the ACT Project of is to develop mid-technology readiness level (TRL) composite materials and structures technologies to TRL 6 for specific heavy lift Ares V launch vehicle and Altair lunar lander applications. To accomplish this objective, the ACT Project has four major technical elements: materials and manufacturing; structural concepts development and assessment of lightweight components; testing and evaluation; and highly loaded composite struts. The Project uses capabilities from across NASA to form multi-disciplinary, cross-center teams to meet the milestones of these technical elements. This presentation will describe the activities and plans for the ACT Project. Studies from the first execution year of the project will be summarized including results from materials selection and structural concept evaluation studies. Plans for continuing activities include studies for nondestructive evaluation/structural health monitoring, damage tolerance, joints, and material and structural testing, and these studies will be described. A major emphasis this fiscal year is the start of work for a manufacturing demonstration barrel. This structure will be composed of six, 5-m-diameter, 3-m-long curved panels that when assembled, result in a 10-m-diameter barrel. Activities related to the development of this structure will also be described.
A summary of the ATS battery design which is onboard the Applications Technology Satellite (ATS) is provided. The 15 ampere hour nickel cadmium cells were manufactured by Gulton, 19 series connected cells per battery, and there are two batteries in each spacecraft. The operating design life was two years in a synchronous orbit, and a maximum depth of discharge of 50 percent. The design temperature for the batteries in the spacecraft was 0 to 25 C, and the charge control consisted of 1 volt versus temperature on a constant percentage voltage. Also, C/10 current limit, and a commandable trickle charge rate, using C/20 or C/60. The undervoltage was sent across a 9 cell and a 10 cell group, and it was set at one volt average per group on either group.
As the U.S. government and the aviation industry strive to achieve net-zero carbon emissions by 2050, the Sustainable Manufacturing of Aircraft (SUMAC) project, supported by the Convergent Aeronautics Solutions (CAS) program of the National Aeronautics and Space Administration (NASA), aims to develop sustainably derived thermoplastic composites and manufacturing technologies for future aviation. A multidisciplinary team of experts drives this initiative through a collective effort. The team’s key focus areas are sustainably derived thermoplastic resins, natural fiber reinforcement, composite manufacturing, structural health monitoring, computational materials modeling, and systems analysis. This presentation will give an overview of the SUMAC project. Fiber-scale microscopy analysis characterized fiber cross sections finding that hemp and flax fibers are very deformable and non-circular (circularities of 0.2 were observed), and diameters range from submicron to 20 μm. Fiber shapes range from flattened, with aspect ratios Rlong/Rshort up to 5, to round, Rlong/Rshort =1. And Fiber core perimeters, which likely drives deformability, were calculated Pcore=7 μm. Explicit-fiber yarn simulations, parameterized from single-fiber measurements, resolved and identified slack as a cause for yarn strain-hardening tensile behavior. The bonded network model of PLA, PHA and PA11 resins captures tensile behavior, and can model an infused weave. Computational models of the weave unit cells matched the pattern (including plain, twill and triaxial braid), yarn ply (1to 2), and yarn twist from optical microscopy.
As the U.S. government and the aviation industry strive to achieve net-zero carbon emissions by 2050, the Sustainable Manufacturing of Aircraft (SUMAC) project, supported by the Convergent Aeronautics Solutions (CAS) program of the National Aeronautics and Space Administration (NASA), aims to develop sustainably derived thermoplastic composites and manufacturing technologies for future aviation. A multidisciplinary team of experts drives this initiative through a collective effort. The team’s key focus areas are sustainably derived thermoplastic resins, natural fiber reinforcement, composite manufacturing, structural health monitoring, computational materials modeling, and systems analysis. This presentation will give an overview of the SUMAC project. Fiber-scale microscopy analysis characterized fiber cross sections finding that hemp and flax fibers are very deformable and non-circular (circularities of 0.2 were observed), and diameters range from submicron to 20 μm. Fiber shapes range from flattened, with aspect ratios Rlong/Rshort up to 5, to round, Rlong/Rshort =1. And Fiber core perimeters, which likely drives deformability, were calculated Pcore=7 μm. Explicit-fiber yarn simulations, parameterized from single-fiber measurements, resolved and identified slack as a cause for yarn strain-hardening tensile behavior. The bonded network model of PLA, PHA and PA11 resins captures tensile behavior, and can model an infused weave. Computational models of the weave unit cells matched the pattern (including plain, twill and triaxial braid), yarn ply (1to 2), and yarn twist from optical microscopy.
Ultrahigh temperature shape memory alloys (UHT-SMAs) have transition temperatures above 600 C, and they have found applications for sensing and actuating devices in aerospace industry. Among very few such UHT-SMAs currently known are Ru-based alloys such as RuNb and RuTa, whose martensite structures and phase transitions are totally different from those of NiTi-based SMAs and were poorly understood. In this work, we carried out a systematical study of RuNb using first-principles total energy calculations and molecular dynamics (MD) simulations. The transition paths and mechanisms in cubic → tetragonal →monoclinic transitions are revealed. and the transition sequence and martensitic transition temperatures are determined (MTTs) by evaluating the Gibbs free energies using thermodynamic integration. The calculated MTTs are in very good agreement with the experimental data. We found that the monoclinic phase at the second transition has the 𝑃21/m symmetry instead of experimentally identified 𝑃2/m. Our calculations demonstrate that RuTa has very similar phase transitions to those of RuTa. Furthermore, we studied the Ru0.5Nb0.25Ta0.25 ternary. Our results can explain the measured significant drop of MTT (~ 200 C) in the second transition for Ru0.5Nb0.25Ta0.25 compared with those of RuNb and RuTa, while in the first transition its MTT is between MTTs of RuNb and RuTa. The insights gained by this study and the verified ab initio methods for accurate MTT calculations can be applied to fast screen and quantitatively design novel UHT-SMAs having similar properties with desirable MTTs and much reduced cost.
Future NASA missions require high specific energy battery technologies, greater than 400 Wh/kg. Current NASA missions are using "state-of-the-art" (SOA) Li-ion batteries (LIB), which consist of a metal oxide cathode, a graphite anode and an organic electrolyte. NASA Glenn Research Center is currently studying the physical and electrochemical properties of the anode-electrolyte interface for ionic liquid based Li-air batteries. The voltage-time profiles for Pyr13FSI and Pyr14TFSI ionic liquids electrolytes studies on symmetric cells show low over-potentials and no dendritic lithium morphology. Cyclic voltammetry measurements indicate that these ionic liquids have a wide electrochemical window. As a continuation of this work, sp2 carbon cathode and these low flammability electrolytes were paired and the physical and electrochemical properties were studied in a Li-air battery system under an oxygen environment.
A phase change material heat capacitor prototype, designed and built under a NASA Small Business Innovation Research grant by Mezzo Technologies, was tested through coolant thermal cycling within the expected flow rates and temperature range of the Orion spacecraft’s propylene glycol-water mixture coolant system. Testing was performed with the phase change material contained under sealed conditions after a degassing procedure and exposed to atmosphere without prior degassing. The useful heat storage capacitance was measured and compared to Orion spacecraft requirements and theoretical N-Pentadecane storage capacity.
We present preliminary results on the development of a fire detection system for partial and low gravity environments. A significant challenge is the design of a system with a low false alarm rate. The detection system therefore has to discriminate between combustion particles, cabin, and lunar dust. Aerosol properties are measured and cross referenced to the target detectors at the Gases and Aerosols from Smoldering Polymers (GASP) Laboratory located at the NASA Glenn Research Center. A computational fluid dynamics plume model is also employed to determine the smoke transport properties of the targeted habitats.
A document discusses the use of saturating transformers in a matrix arrangement to address individual cells in a high voltage battery. This arrangement is able to monitor and charge individual cells while limiting the complexity of circuitry in the battery. The arrangement has inherent galvanic isolation, low cell leakage currents, and allows a single bad cell in a battery of several hundred cells to be easily spotted.
The longevity of tribological components in extraterrestrial environments is challenged by abrasive regolith, extreme temperatures, and ionizing radiation. This study evaluates the performance of vacuum plasma sprayed (VPS) Ti-2vol.% hexagonal boron nitride (hBN) coatings applied to joint mechanisms such as rod and slot, ball and socket, and hinge assemblies, fabricated from Al6061 and Ti6Al4V for planetary structures. Coated and uncoated samples were tested under vacuum with lunar regolith simulant (JSC-1A), followed by environmental exposures including electron radiation and thermal cycling. Results show that coated samples consistently outperformed uncoated counterparts across all configurations. Wear depth in coated components was reduced by over 80%, as confirmed by 3D profilometry and surface imaging. SEM analysis revealed severe abrasion and localized plastic deformation in uncoated surfaces, while coated samples retained structural integrity due to synergy of hard protective phases formed during deposition and retained hBN providing solid lubrication in the sliding surface. Coated and exposed samples exhibited smoother actuation profiles and reduced friction, indicating a beneficial "conditioning" effect from environmental exposure. The coatings-maintained performance even on complex geometries with minimal delamination. These findings demonstrate the potential of VPS Ti-hBN coatings to extend the operational life of lunar mechanisms, bridging laboratory-scale tribology with flight-relevant mechanical applications.
The Galileo Optical Experiment (GOPEX) has demonstrated the first laser communications uplink to a deep space vehicle. This article describes the optical design and validation tests performed at the Table Mountain Facility (TMF) transmitter site. The system used a 0.6-m telescope and an optical system at coude focus to produce the uplink beam. The optical system used a pulsed neodymium:yttrium-aluminum-garnet (Nd:Yag) laser and beam diverger optics to produce the required optical output. In order to validate the optical design, a number of uplinks were performed on Earth-orbiting satellites (e.g., Lageos 1 and 2).
The Long Life (Lithium Ion) Battery is designed to replace the current Extravehicular Mobility Unit Silver/Zinc Increased Capacity Battery, which is used to provide power to the Primary Life Support Subsystem during Extravehicular Activities. The Charger is designed to charge, discharge, and condition the battery either in a charger-strapped configuration or in a suit-mounted configuration. This paper will provide an overview of the capabilities and systems engineering development approach for both the battery and the charger
The Fast Auroral Snapshot (FAST) Explorer spacecraft is to study the physical processes that produce the aurora borealis and aurora australis. It is a unique plasma physics experiment that will take fundamental measurements of the magnetic and electrical fields. This investigation will add significantly to our understanding of the near-earth space environments and its effect. The FAST has a 1 year requirement and 3-year goal for its mission life in low earth orbit. The FAST power power system topology is a Direct Energy Transfer (DET) system based on the SAMPEX design. The FAST flight battery supplies power to the satellite during pre-launch operations, the launch phase, the eclipse periods for all mission phases, and when the load is about 50 watts.
Studies of many objects in petrographic thin section, such as melt inclusions in igneous rocks, chondrules and Ca-Al rich inclusions in chondritic meteorites, or clasts in lunar and other breccias, require or can benefit from knowledge of their bulk compositions. Given the scarcity of these materials, the reluctance of curators to provide more abundant material, and the extreme difficulty of cleanly separating such objects from their rock matrices, geochemical and cosmochemical studies need the ability to determine their bulk compositions from in situ methods, such as defocused beam analysis, or quantitative chemical mapping by electron beam methods.
The Helicopter and Urban Air Mobility (UAM) Laboratory Comparison (HULC) psychoacoustic test was conducted in July 2025 to compare human annoyance responses to noise from UAM vehicles and helicopters. This document provides a literature review, describes the HULC test methodology including stimuli selection and test administration procedures, and presents results from an initial analysis using multilevel statistical modeling. The test utilized 123 sound stimuli from four helicopters and six UAM vehicles across three flight phases (departure, cruise, and approach), presented to 40 subjects in the Exterior Effects Room (EER) at NASA's Langley Research Center. Subjects rated their annoyance on a 0 to 10 scale while imagining hearing these sounds multiple times daily near their homes. Key findings revealed that, at the same A-weighted sound exposure levels, UAM vehicles and helicopters produced similar annoyance responses across all flight phases, with mean differences of only approximately 1 dB and overlapping confidence intervals. However, at equivalent observer distances, UAM vehicles had inherently quieter operations and lower mean annoyance ratings. These results suggest that UAM vehicles and helicopters may be assessed in a similar manner for community noise impact. The quieter noise characteristics of UAM vehicles may provide advantages for operating in communities and integrating into urban environments.
With today's analysis tools, large, complex thermal radiation problems are easily solved; But, as with any analytical tool, lack of an understanding of the fundamental equations and technique limitations may leave you with the wrong answer; Whether you are a new engineer or a seasoned veteran, an understanding of the techniques employed by these powerful analysis tools is crucial.
Atmospheric Plasma Spray (APS) and Vacuum Plasma Spray (VPS) techniques were used to develop Ti/2 vol.% hBN coatings, for extreme space environments and tested aboard the International Space Station as part of the MISSE-17 (Materials International Space Station Experiments) program. The coatings were exposed to atomic oxygen, space radiation, and low-orbit thermal cycling. VPS coatings showed a 56% increase in microhardness, a 26% rise in elastic modulus, minimal porosity and crack density changes compared to APS coatings. The change in mechanical properties is attributed to the formation of TiO, TiO₂ and TiN from nitrogen retention, alongside radiation-induced dislocations, which enhanced surface hardening. The oxidation of titanium led to the formation of TiO and TiO₂, while boron nitride was retained and underwent transmutation in VPS coatings. XPS and EDS analyses confirmed the enhanced space-environment resistance of VPS coatings, making them ideal for long-term spacecraft protection in lunar and Martian conditions.