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DOE OSTI2021

Alkylation of monomeric, dimeric, and polymeric lignin models through carbon-hydrogen activation using Ru-catalyzed Murai reaction

In this study, we have assessed directed carbon-hydrogen activation (CHA) for alkylation of monomeric, dimeric, and polymeric lignin models using Murai's catalyst [RuH 2 (CO)(PPh 3 ) 3 ]. Based on related work from our laboratory showing that isolated organosolv lignin bears benzylic directing groups ideal for CHA reactions, this approach could offer new methodology for the valorization of biorefinery lignin. Monomeric and dimeric models bearing a keto group at the benzylic position undergo Ru-catalyzed alkylation in good to excellent yield. Similarly, models bearing a benzylic OH group also undergo alkylation via a tandem oxidation/alkylation process enabled by the Ru catalyst. Polymeric models show low levels of functionalization as a result of the poor solubility of the starting polymer. With unsymmetrical models, functionalization occurs first at the least sterically hindered ortho-site, but a subsequent alkylation, leading to disubstituted products can occur at the more sterically hindered site, leading to hexasubstituted arenes. The reaction shows sensitivity to free phenolic OH groups, which appears to reduce the yield in some reactions, and is also a contributing factor to the low yields observed with polymeric lignin models. Finally, combining CHA methodology with lignin isolation technology able to introduce appropriate directing groups for catalytic functionalization will form the basis for improved conversion of lignin to high value chemical products.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS2019

A Comprehensive Chandra Study of the Disk Wind in the Black Hole Candidate 4U 1630-472

The mechanisms that drive disk winds are a window into the physical processes that underlie the disk. Stellar-mass black holes are an ideal setting in which to explore these mechanisms, in part because their outbursts span a broad range in mass accretion rate. We performed a spectral analysis of the disk wind found in six Chandra/HETG observations of the black hole candidate 4U 1630−472, covering a range of luminosities over two distinct spectral states. We modeled both wind absorption and extended wind re-emission components using PION, a selfconsistent photoionized absorption model. In all but one case, two photoionization zones were required in order to obtain acceptable fits. Two independent constraints on launching radii, obtained via the ionization parameter formalism and the dynamical broadening of the re-emission, helped characterize the geometry of the wind. The innermost wind components (r ≃ 10(sup 2-3)GM/c(exp 2)) tend toward small volume filling factors, high ionization, densities up to n ≃ 10(sup 15-16) cm(exp -3), and outflow velocities of ∼0.003c. These small launching radii and large densities require magnetic driving, as they are inconsistent with numerical and analytical treatments of thermally driven winds. Outer wind components (r ≃ 10(exp 5)GM/c(exp 2)) are significantly less ionized and have filling factors near unity. Their larger launching radii, lower densities (n ≃ 10(exp 12) cm(exp -3)), and outflow velocities (∼0.0007c) are nominally consistent with thermally driven winds. The overall wind structure suggests that these components may also be part of a broader MHD outflow and perhaps better described as magneto-thermal hybrid winds.

Black hole physics↗

NASA NTRS1972

Wind-tunnel simulation of store jettison with the aid of magnetic artificial gravity

A method employed in the simulation of jettison of stores from aircraft involving small scale wind-tunnel drop tests from a model of the parent aircraft is described. Proper scaling of such experiments generally dictates that the gravitational acceleration should ideally be a test variable. A method of introducing a controllable artificial component of gravity by magnetic means has been proposed. The use of a magnetic artificial gravity facility based upon this idea, in conjunction with small scale wind-tunnel drop tests, would improve the accuracy of simulation. A review of the scaling laws as they apply to the design of such a facility is presented. The design constraints involved in the integration of such a facility with a wind tunnel are defined. A detailed performance analysis procedure applicable to such a facility is developed. A practical magnet configuration is defined which is capable of controlling the strength and orientation of the magnetic artificial gravity field in the vertical plane, thereby allowing simulation of store jettison from a diving or climbing aircraft. The factors involved in the choice between continuous or intermittent operation of the facility, and the use of normal or superconducting magnets, are defined.

Stephens, T.↗

NASA NTRSDate not supplied

Alternative Treatment of Crew Wastewater Using a Hybrid Membrane Technology

Environmental Control and Life Support Systems (ECLSS) of future long-duration, deep-space human exploration missions should treat all “waste” streams for recovery and ideally by near closed-loop. Onboard the International Space Station (ISS), the Water Recovery System (WRS) does not treat urine and gray water to recover elements beyond water and utilizes physical-chemical technologies that operate with single-use and hazardous consumables. Urine offers a renewable source of nitrogen and other trace elements that can support sustainable crop production. In response to the lack of flight ready technologies capable of treating urine and gray water for water and nutrient recovery, a Suspended Aerobic Membrane Bioreactor (SAMBR) is under development between the University of South Florida and Kennedy Space Center. SAMBR is optimized for an early planetary base/partial gravity habitat and serves as a hybrid alternative to currently utilized urine treatment technologies and support closing the resource recovery loop. With its ECLSS minded form factor and modular design, SAMBR’s operation can be customized to suit the treatment objectives (i.e., nitrogen conversion) at that time. This proceeding presents preliminary research pertaining to: 1) design challenges in maximizing hydraulic throughput while minimizing mass and volume of the assembly; 2) capabilities for treating high nitrogen waste under steady and non-steady state conditions; and 3) measured performance parameters such chemical oxygen demand (COD), nitrogen conversion, nutrients, turbidity, and system throughput. Future research and development pertaining to further optimization on system safety, reliability, and expanded treatment capabilities will also be presented.

Membrane Filtration↗

NASA NTRS2001

Warm-Core Intensification Through Horizontal Eddy Heat Transports into the Eye

A simulation of Hurricane Bob (1991) using the PSU/NCAR MM5 mesoscale model with a finest mesh spacing of 1.3 km is used to diagnose the heat budget of the hurricane. Heat budget terms, including latent and radiative heating, boundary layer forcing, and advection terms were output directly from the model for a 6-h period with 2-min frequency. Previous studies of warm core formation have emphasized the warming associated with gentle subsidence within the eye. The simulation of Hurricane Bob confirms subsidence warming as a major factor for eye warming, but also shows a significant contribution from horizontal advective terms. When averaged over the area of the eye, subsidence is found to strongly warm the mid-troposphere (2-9 km) while horizontal advection warms the mid to upper troposphere (5-13 km) with about equal magnitude. Partitioning of the horizontal advective terms into azimuthal mean and eddy components shows that the mean radial circulation does not, as expected, generally contribute to this warming, but that it is produced almost entirely by the horizontal eddy transport of heat into the eye. A further breakdown of the eddy components into azimuthal wave numbers 1, 2, and higher indicates that the warming is dominated by wave number 1 asymmetries, with smaller coming from higher wave numbers. Warming by horizontal eddy transport is consistent with idealized modeling of vortex Rossby waves and work is in progress to identify and clarify the role of vortex Rossby waves in warm-core intensification in both the full-physics model and idealized models.

Braun, Scott A.↗

DOE OSTI2023

Mitigation of nitrogen vacancy photoluminescence quenching from material integration for quantum sensing

The nitrogen-vacancy (NV) color center in diamond has demonstrated great promise in a wide range of quantum sensing. Recently, there have been a series of proposals and experiments using NV centers to detect spin noise of quantum materials near the diamond surface. This is a rich complex area of study with novel nano-magnetism and electronic behavior, that the NV center would be ideal for sensing. However, due to the electronic properties of the NV itself and its host material, getting high quality NV centers within nanometers of such systems is challenging. Band bending caused by space charges formed at the metal-semiconductor interface force the NV center into its insensitive charge states. Here, we investigate optimizing this interface by depositing thin metal films and thin insulating layers on a series of NV ensembles at different depths to characterize the impact of metal films on different ensemble depths. We find an improvement of coherence and dephasing times we attribute to ionization of other paramagnetic defects. The insulating layer of alumina between the metal and diamond provide improved photoluminescence and higher sensitivity in all modes of sensing as compared to direct contact with the metal, providing as much as a factor of 2 increase in sensitivity, decrease of integration time by a factor of 4, for NV T 1 relaxometry measurements.

36 MATERIALS SCIENCE↗

NASA NTRS1990

Experimental observations and finite element analysis of the initiation of fiber microbuckling in notched composite laminates

A better understanding of the factors that affect the semi-circular edge-notched compressive strength is developed, and the associated failure mode(s) of thermoplastic composite laminates with multidirectional stacking sequences are identified. The primary variables in this investigation are the resin nonlinear shear constitutive behavior, stacking sequence (orientation of plies adjacent to the 0 degree plies), resin-rich regions between the 0 degree plies and the off-axis supporting plies, fiber/matrix interfacial bond strength, and initial fiber waviness. Two thermoplastic composite material systems are used in this investigation. The materials are the commercial APC-2 (AS4/PEEK) and a poor interface experimental material, AU4U/PEEK, designed for this investigation. Notched compression specimens are studied at 21, 77, and 132 C. Geometric and material nonlinear two-dimensional finite element analysis is used to model the initiation of fiber microbuckling of both the ideal straight fiber and the more realistic initially wavy fiber. The effects of free surface, fiber constitutive properties, matrix constitutive behavior, initial fiber curvature, and fiber/matrix interfacial bond strength on fiber microbuckling initiation strain levels are considered.

Guynn, E. Gail↗

DOE OSTI2024

DCMIP2016: the tropical cyclone test case

This paper describes and analyzes the Reed–Jablonowski (RJ) tropical cyclone (TC) test case used in the 2016 Dynamical Core Model Intercomparison Project (DCMIP2016). This intermediate-complexity test case analyzes the evolution of a weak vortex into a TC in an idealized tropical environment. Reference solutions from nine general circulation models (GCMs) with identical simplified physics parameterization packages that participated in DCMIP2016 are analyzed in this study at 50 km horizontal grid spacing, with five of these models also providing solutions at 25 km grid spacing. Evolution of minimum surface pressure (MSP) and maximum 1 km azimuthally averaged wind speed (MWS), the wind–pressure relationship, radial profiles of wind speed and surface pressure, and wind composites are presented for all participating GCMs at both horizontal grid spacings. While all TCs undergo a similar evolution process, some reach significantly higher intensities than others, ultimately impacting their horizontal and vertical structures. TCs simulated at 25 km grid spacings retain these differences but reach higher intensities and are more compact than their 50 km counterparts. These results indicate that dynamical core choice is an essential factor in GCM development, and future work should be conducted to explore how specific differences within the dynamical core affect TC behavior in GCMs.

Willson, Justin L.↗

NASA NTRS1993

Barotropic simulation of large-scale mixing in the Antarctic polar vortex

Theory and observations suggest that the Antarctic polar vortex is relatively isolated from midlatitudes, although others have interpreted the observations to indicate that there is substantial mixing from the interior of the vortex into middle latitudes. The equivalent barotropic model of Salby et al. is used to study quasi-horizontal mixing by the large-scale flow in the lower stratosphere during Southern Hemisphere spring, which is when the Antarctic ozone hole appears and disappears. The model is forced by relaxation to observed climatological monthly mean zonal-mean winds and by an idealized wave 1 or 2 forcing at the lower boundary. Mixing and transport are diagnosed primarily through Lagrangian tracer trajectories. For September, October, and November basic states, there is little or no mixing in the interior of the vortex. Mixing occurs near the critical lines for the waves: in the tropics and subtropics for a stationary wave 1, and in midlatitudes on the equatorial flank of the jet for an eastward-moving wave 2. For the December basic state, the wave 2 forcing rapidly mixes the interior of the vortex. Mixing of Lagrangian tracer particles can be significant even when the waves do not `break', as evidenced by the potential vorticity field. In the model there does not appear to be any significant transport of air out of the interior of the polar vortex prior to the vortex breakdown. The principal factor that leads to the vortex breakdown and mixing of the vortex interior is the deceleration of the jet to the point where winds in the interior of the vortex are close to the phase velocity of the wavenumber 2 forcing. The tracer transport is very similar to many aspects of the behavior of the total ozone field during the spring season.

Bowman, Kenneth P.↗

NASA NTRS2005

Neptune Polar Orbiter with Probes

The giant planets of the outer solar system divide into two distinct classes: the gas giants Jupiter and Saturn, which consist mainly of hydrogen and helium; and the ice giants Uranus and Neptune, which are believed to contain significant amounts of the heavier elements oxygen, nitrogen, and carbon and sulfur. Detailed comparisons of the internal structures and compositions of the gas giants with those of the ice giants will yield valuable insights into the processes that formed the solar system and, perhaps, other planetary systems. By 2012, Galileo, Cassini and possibly a Jupiter Orbiter mission with microwave radiometers, Juno, in the New Frontiers program, will have yielded significant information on the chemical and physical properties of Jupiter and Saturn. A Neptune Orbiter with Probes (NOP) mission would deliver the corresponding key data for an ice giant planet. Such a mission would ideally study the deep Neptune atmosphere to pressures approaching and possibly exceeding 1000 bars, as well as the rings, Triton, Nereid, and Neptune s other icy satellites. A potential source of power would be nuclear electric propulsion (NEP). Such an ambitious mission requires that a number of technical issues be investigated, however, including: (1) atmospheric entry probe thermal protection system (TPS) design, (2) probe structural design including seals, windows, penetrations and pressure vessel, (3) digital, RF subsystem, and overall communication link design for long term operation in the very extreme environment of Neptune's deep atmosphere, (4) trajectory design allowing probe release on a trajectory to impact Neptune while allowing the spacecraft to achieve a polar orbit of Neptune, (5) and finally the suite of science instruments enabled by the probe technology to explore the depths of the Neptune atmosphere. Another driving factor in the design of the Orbiter and Probes is the necessity to maintain a fully operational flight system during the lengthy transit time from launch through Neptune encounter, and throughout the mission. Following our response to the recent NASA Research Announcement (NRA) for Space Science Vision Missions for mission studies by NASA for implementation in the 2013 or later time frame, our team has been selected to explore the feasibility of such a Neptune mission.

Bienstock, Bernard↗

NASA NTRS1998

Acquisition and Early Losses of Rare Gases from the Deep Earth

Direct observations show that the deep Earth contains rare gases of solar composition distinct from those in the atmosphere. We examine the implications of mantle rare gas characteristics on acquisition of rare gases from the solar nebula and subsequent losses due to a large impact. Deep mantle rare gas concentrations and isotopic compositions can be obtained from a model of transport and distribution of mantle rare gases. This model assumes the lower mantle closed early, while the upper mantle is open to subduction from the atmosphere and mass transfer from the lower mantle. Constraints are derived that can be incorporated into models for terrestrial volatile acquisition: (1) Calculated lower-mantle Xe-isotopic ratios indicate that the fraction of radiogenic Xe produced by I-129 and Pu-244 during the first about 10(exp 8) yr was lost, a conclusion also drawn for atmospheric Xe. Thus, either the Earth was made from materials that had lost >99% of rare gases about (0.7-2) x 10(exp 8) yr after the solar system formed, or gases were then lost from the fully formed Earth. (2) Concentrations of 3He and 20Ne in the lower mantle were established after these losses. (3) Neon-isotopic data indicates that mantle Ne has solar composition. The model allows for solar Ar/Ne and Xe/Ne in the lower mantle if a dominant fraction of upper mantle Ar and Xe are subduction-derived. If Earth formed in the presence of the solar nebula, it could have been melted by accretional energy and the blanketing effect of a massive, nebula-derived atmosphere. Gases from this atmosphere would have been sequestered within the molten Earth by dissolution at the surface and downward mixing. It was found that too much Ne would be dissolved in the Earth unless the atmosphere began to escape when the Earth was only partially assembled. Here we consider conditions required to initially dissolve sufficient rare gases to account for the present lower mantle concentrations after subsequent losses at 10(exp 8) yr. It is assumed that equilibration of the atmosphere with a thoroughly molten mantle was rapid, so that initial abundances of gases retained in any mantle layer reflected surface conditions when the layer solidified. For subsequent gas loss of 99.5% and typical solubility coefficients, a total pressure of 100 atm was required for an atmosphere of solar composition. Calculations of the pressure at the base of a primordial atmosphere indicate that this value might be exceeded by an order of magnitude or more for an atmosphere supported by accretional energy. Surface temperatures of about 4000 K would have been produced, probably high enough to melt the deep mantle. Initial distributions of retained rare gases would then be determined by the history of surface pressure and temperature during mantle cooling and solidification, i.e., the coupled cooling of Earth and atmosphere. The Earth's thermal state was determined by its surface temperature and the efficiency of convection in the molten mantle, estimated to be sufficient to maintain an adiabatic gradient. Because the melting curve is steeper than the adiabat, solidification of the mantle proceeded outward from the interior. Incorporation of atmospheric gases in the mantle therefore occurred over a range in surface temperature of a few thousand degrees Kelvin. The thermal state of the atmosphere was controlled by total luminosity of the Earth (energy) released by accreting planetesimals and the cooling Earth), nebular temperature and pressure, and atmospheric opacity. The energy released by accretion declined with time as did nebular pressure. Analytical solutions for an idealized (constant opacity radiative atmosphere show that declining energy sources under constant nebular conditions result in slowly diminishing surface temperature but dramatically increasing surface pressure. For such an atmosphere with declining nebular pressure but constant total luminosity, surface pressure decreases gradually with decreasing temperaure. A decline in accretion luminosity might be compensated by energy released as the mantle cools for about 10(exp 5) year, after which luminosity must decline. The total complement of dissolved rare gases will depend on the particular evolutionary path determined by the declining accretional luminosity, the Earth thermal history, removal of the nebula, and opacity variations of the atmosphere. Models for these coupled evolutionary histories for Earth's acquisition of nebular-derived noble gases are in progress. The later losses required at about 10(exp 8) yr (depleting the interior concentrations of the sequestered solar gases by a factor of > 100) were presumably related to the major impact in which the Moon formed.

Porcelli, D.↗

DOE OSTI2020

Validation of a Generalized Formulation for Load-Sharing Behavior in Epicyclic Gears for Wind Turbines: Preprint

In an ideal epicyclic gear set every parallel gear path transmits the same amount of torque. However, it is well known that certain manufacturing variations result in unequal load sharing between the parallel gear paths. Previous works have developed and validated a general closed-form analytical model of this phenomenon that describes the load sharing characteristics of epicyclic gear sets from three to six planets at any torque level. More recently, this analytical model has been reformulated to include the effects of gravity, carrier bearing clearance, and external applied moments, all of which are relevant to most gearboxes and their mounting configuration in horizontal-axis wind turbines. In this paper, the reformulated model is compared to load measurements collected from two similar wind turbine gearboxes with three-planet epicyclic gear sets. The resulting load sharing values are also compared to the mesh load factor requirements in the AGMA 6006 and IEC 61400-4 wind turbine gearbox design standards. Load sharing factors as high as 1.16 at extreme rotor moments and 1.08 with no moment were measured for the gearbox with cylindrical roller bearings, but the load sharing factor remained below 1.10 for the gearbox with tapered roller bearings The results show that in the wind turbine application, load sharing is not equal - even for three-planet systems with a floating central member because of the effects of gravity, rotor moments, and the resulting relative motions among the epicyclic gear components within the carrier bearing clearance.

closed-form analytical model↗

DOE OSTI2020

Validation of a Generalized Formulation for Load Sharing Behavior in Epicyclic Gears for Wind Turbines

closed-form analytical model↗

DOE OSTI2021

Muon flux measurement at China Jinping Underground Laboratory

China Jinping Underground Laboratory (CJPL) is ideal for studying solar, geo-, and supernova neutrinos. A precise measurement of the cosmic-ray background is essential in proceeding with R&D research for these MeV-scale neutrino experiments. Using a 1-ton prototype detector for the Jinping Neutrino Experiment (JNE), we detected 264 high-energy muon events from a 645.2-day dataset from the first phase of CJPL (CJPL-I), reconstructed their directions, and measured the cosmic-ray muon flux to be $(3.53\pm0.22_{\rm{stat.}}\pm0.07_{\rm{sys.}})\times10^{-10}$ cm $^{-2}$s $^{-1}$. The observed angular distributions indicate the leakage of cosmic-ray muon background and agree with simulation data accounting for Jinping mountain's terrain. A survey of muon fluxes at different laboratory locations, considering both those situated under mountains and those down mine shafts, indicates that the flux at the former is generally a factor of $(4\pm2)$ larger than at the latter, with the same vertical overburden. In conclusion, this study provides a convenient back-of-the-envelope estimation for the muon flux of an underground experiment.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

NASA NTRS2001

Warm-Core Intensification of a Hurricane Through Horizontal Eddy Heat Transports Inside the Eye

A simulation of Hurricane Bob (1991) using the PSU/NCAR MM5 mesoscale model with a finest mesh spacing of 1.3 km is used to diagnose the heat budget of the hurricane. Heat budget terms, including latent and radiative heating, boundary layer forcing, and advection terms were output directly from the model for a 6-h period with 2-min frequency. Previous studies of warm core formation have emphasized the warming associated with gentle subsidence within the eye. The simulation of Hurricane Bob also identifies subsidence warming as a major factor for eye warming, but also shows a significant contribution from horizontal advective terms. When averaged over the area of the eye, excluding the eyewall (at least in an azimuthal mean sense), subsidence is found to strongly warm the mid-troposphere (2-9 km) while horizontal advection warms the mid to upper troposphere (5-13 km) with about equal magnitude. Partitioning of the horizontal advective terms into azimuthal mean and eddy components shows that the mean radial circulation cannot, as expected, generally contribute to this warming, but that it is produced almost entirely by the horizontal eddy transport of heat into the eye. A further breakdown of the eddy components into azimuthal wave numbers 1, 2, and higher indicates that the warming is dominated by wave number 1 asymmetries, with smaller contributions coming from higher wave numbers. Warming by horizontal eddy transport is consistent with idealized modeling of vortex Rossby waves and work is in progress to identify and clarify the role of vortex Rossby waves in warm-core intensification in both the full-physics model and idealized models.

Braun, Scott A.↗

NASA NTRS2024

Premature Deaths Due to Heat Exposure: the Potential Effects of Neighborhood-Level Versus City-Level Acclimatization Within Us Cities

For the population of a given US city, the risk of premature death associated with heat exposure increases as temperatures rise, but risks in hotter cities are generally lower than in cooler cities at equivalent temperatures due to factors such as acclimatization. Those living in especially hot neighborhoods within cities might therefore suffer much more than average if such adaptation is only at the city-wide level, whereas they might not experience greatly increased risk if adjustment is at the neighborhood level. To compare these possibilities, we use high spatial resolution temperature data to evaluated heat-related deaths assuming either adjustment at the city-wide or at the neighborhood scale in 10 large US cities. On average, we find that if inhabitants are adjusted to their local conditions, a neighborhood that was 10°C hotter than a cooler one would experience only about 1.0–1.5 excess heat deaths per year per 100,000 persons. By contrast, if inhabitants are acclimatized to city-wide temperatures, the hotter neighborhood would experience about 15 excess deaths per year per 100,000 persons. Using idealized analyses, we demonstrate that current city-wide epidemiological data do not differentiate between these differing adjustments. Given the very large effects of assumptions about neighborhood-level acclimatization found here, as well as the fact that current literature is conflicting on the spatial scale of acclimatization, more neighborhood-level epidemiological data are urgently needed to determine the health impacts of variations in heat exposure within urban areas, better constrain projected changes, and inform mitigation efforts.

heat island↗

DOE OSTI2022

Local structure elucidation of tungsten-substituted vanadium dioxide (V$$_{1-x}$$W$$_x$$O$$_2$$)

Abstract Initially, vanadium dioxide seems to be an ideal first-order phase transition case study due to its deceptively simple structure and composition, but upon closer inspection there are nuances to the driving mechanism of the metal-insulator transition (MIT) that are still unexplained. In this study, a local structure analysis across a bulk powder tungsten-substitution series is utilized to tease out the nuances of this first-order phase transition. A comparison of the average structure to the local structure using synchrotron x-ray diffraction and total scattering pair-distribution function methods, respectively, is discussed as well as comparison to bright field transmission electron microscopy imaging through a similar temperature-series as the local structure characterization. Extended x-ray absorption fine structure fitting of thin film data across the substitution-series is also presented and compared to bulk. Machine learning technique, non-negative matrix factorization, is applied to analyze the total scattering data. The bulk MIT is probed through magnetic susceptibility as well as differential scanning calorimetry. The findings indicate the local transition temperature ( $$T_c$$ T c ) is less than the average $$T_c$$ T c supporting the Peierls-Mott MIT mechanism, and demonstrate that in bulk powder and thin-films, increasing tungsten-substitution instigates local V-oxidation through the phase pathway VO $$_2\, \rightarrow$$ 2 → V $$_6$$ 6 O $$_{13} \, \rightarrow$$ 13 → V $$_2$$ 2 O $$_5$$ 5 .

Wilson, Catrina E. (ORCID:0000000173397318)↗

NASA NTRS2017

Building Better Biosensors for Exploration into Deep-Space, Using Humanized Yeast

1.BioSentinel is 1 of 13 secondary payloads hitching a ride beyond Low Earth Orbit on Exploration Mission 1 (EM-1), set to launch from NASAs Space Launch System in 2019. EM-1 is our first opportunity to investigate the effects of the deep space environment on a eukaryotic biological system, the budding yeast S. cerevisiae. Though separated by a billion years of evolution we share hundreds of genes important for basic cell function, including responses to DNA damage. Thus, yeast is an ideal biosensor for detecting typesextent of damage induced by deep-space radiation.We will fly desiccated cells, then rehydrate to wake them up when the automated payload is ready to initiate the experiment. Rehydration solution contains SC (Synthetic Complete) media and alamarBlue, an indicator for changes in growth and metabolism. Telemetry of LED readings will then allow us to detect how cells respond throughout the mission. The desiccation-rehydration process can be extremely damaging to cells, and can severely diminish our ability to accurately measure and model cellular responses to deep-space radiation. The aim of this study is to develop a better biosensor: yeast strains that are more resistant to desiccation stress. We will over-express known cellular protectants, including hydrophilin Sip18, the protein disaggregase Hsp104, and thioredoxin Trx2, a responder to oxidative stress, then measure cell viability after desiccation to determine which factors improve stress tolerance. Over-expression of SIP18 in wine yeast starter cultures was previously reported to increase viability following desiccation stress by up to 70. Thus, we expect similar improvements in our space-yeast strains. By designing better yeast biosensors we can better prepare for and mitigate the potential dangers of deep-space radiation for future missions.This work is funded by NASAs AES program.

biosensor↗