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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS2020

Measuring Multiple Cosmogenic Nuclides in Glacial Cobbles Sheds Light on Greenland Ice Sheet Processes

The extent and erosivity of the Greenland Ice Sheet during the Pleistocene remain uncertain due to the paucity of evidence predating the Last Glacial Maximum. Here, we employ a novel approach, cosmogenic nuclide analysis of individual subglacial cobbles, which allows us to infer the behavior of the ice sheet over time and space. From three locations in western Greenland, we collected 86 cobbles from the current ice sheet margin and nine cobbles exposed on the modern proglacial land surface. We measured the concentration of in situ 10Be in all cobbles (n= 95) and 26Al and 14C in a subset (n= 14). Cobbles deposited during Holocene retreat have 10Be exposure ages generally consistent with the timing of ice retreat determined by other means. Conversely, most of the 86 subglacial cobbles contain very low concentrations of 10Be (median 1.0 x 10^3 atoms g-1), although several have ~10^4 and one has ~10^5 atoms g-1. The low concentrations of 10Be in most subglacial cobbles imply that their source areas under the Greenland Ice Sheet are deeply eroded, preserving minimal evidence of surface or near-surface exposure. The presence of measurable 14C in ten of the cobbles requires that they experienced cosmogenic nuclide production within the past ~30 ka; however, 14C/10Be ratios of ~6 suggest that production occurred beneath thin overlying rock, sediment, and/or ice, where the muon component of 14C production dominates. Only two of the 86 subglacial cobbles definitively have cosmogenic nuclide concentrations consistent with prior surface exposure during times of reduced ice extent. Overall, isotopic analysis of subglacial cobbles indicates that western Greenland's subglacial landscape is characterized by deep erosion and minimal subaerial exposure.

Pliocene↗
NASA NTRS2014

Design, Analysis, and On-Sun Evaluation of Reflective Strips Under Controlled Buckling

Solar concentrators are envisioned for use in a variety of space-based applications, including applications involving in situ resource utilization. Identifying solar concentrators that minimize mass and cost are of great interest, especially since launch cost is driven in part by the mass of the payload. Concentrators must also be able to survive the wide temperature excursions on the lunar surface. Identifying smart structures which compensate for changes in concentrator geometry brought about by temperature extremes are of interest. Some applications may benefit from the ability to change the concentrators focal pattern at will. This paper addresses a method of designing a single reflective strip to produce a desired focal pattern through the use of controlled buckling. Small variations in the cross section over the length of the reflective strip influence the distribution of light in the focal region. A finite element method of analysis is utilized here which calculates the curve produced for a given strip cross section and axial load. Varying axial force and strip cross section over the length of the reflective strip provide a means of optimizing ray convergence in the focal region. Careful selection of a tapered cross section yields a reflective strip that approximates a parabola. An array of reflective strips under controlled buckling produces a light weight concentrator and adjustments in the compression of individual strips provide a means of compensating for temperature excursions or changing the focal pattern at will.

solar collectors↗
NASA NTRS2014

Design, Analysis, and On-Sun Evaluation of Reflective Strips Under Controlled Buckling

Solar concentrators are envisioned for use in a variety of space-based applications, including applications involving in situ resource utilization. Identifying solar concentrators that minimize mass and cost are of great interest, especially since launch cost is driven in part by the mass of the payload. Concentrators must also be able to survive the wide temperature excursions on the lunar surface. Identifying smart structures which compensate for changes in concentrator geometry brought about by temperature extremes are of interest. Some applications may benefit from the ability to change the concentrator's focal pattern at will. This paper addresses a method of designing a single reflective strip to produce a desired focal pattern through the use of controlled buckling. Small variations in the cross section over the length of the reflective strip influence the distribution of light in the focal region. A finite element method of analysis is utilized here which calculates the curve produced for a given strip cross section and axial load. Varying axial force and strip cross section over the length of the reflective strip provide a means of optimizing ray convergence in the focal region. Careful selection of a tapered cross section yields a reflective strip that approximates a parabola. An array of reflective strips under controlled buckling produces a light weight concentrator and adjustments in the compression of individual strips provide a means of compensating for temperature excursions or changing the focal pattern at will.

buckling↗
DOE OSTI2018

Structure Sensitivity of Acrolein Hydrogenation by Platinum Nanoparticles on Ba x Sr 1- x TiO 3 Nanocuboids

The structure sensitivity of Pt nanoparticles (Pt N ) for gas-phase acrolein (AC) hydrogenation was probed for Pt N on Ba x Sr 1- x TiO 3 nanocuboid supports with (0 0 1) facets in a combined theoretical and experimental study. The in situ selectivity for allyl alcohol increased with the increase of the Sr concentration in the support, which corresponds to modifications in the stable Winterbottom shape and lattice strain of the Pt nanoparticles as a result of the interfacial energy between Pt and the Ba x Sr 1- x TiO 3 supports. “Local model” nanofacets of the Pt surface, edge, and corner morphologies were developed as compact representations of adsorption and reaction sites. DFT was used as the primary modeling tool for the equilibrium adsorption states. We argue that adsorption on edge sites is critically important for the overall allyl alcohol selectivity of Pt N catalysts. A simple model was developed to represent Pt N strain effects caused by its interaction with the substrate. Bader topological atom, spherical volume averaging charge, and modified bond valence sum analyses were used to understand the bonding structure. Density of states analysis was performed for the structures of Pt N , adsorbed AC, and intermediate products to examine adsorbate–particle interactions. The simulated hydrogenation of AC on Pt N nanofacets was compared to the in situ hydrogenation of AC by Pt N on Ba x Sr 1- x TiO 3 to examine the effects of facet, edge, and corner sites on the overall selectivity.

bio-inspired↗
NASA NTRS2004

Lunar and Planetary Science XXXV: Missions and Instruments: Hopes and Hope Fulfilled

The titles in this section include: 1) Mars Global Surveyor Mars Orbiter Camera in the Extended Mission: The MOC Toolkit; 2) Mars Odyssey THEMIS-VIS Calibration; 3) Early Science Operations and Results from the ESA Mars Express Mission: Focus on Imaging and Spectral Mapping; 4) The Mars Express/NASA Project at JPL; 5) Beagle 2: Mission to Mars - Current Status; 6) The Beagle 2 Microscope; 7) Mars Environmental Chamber for Dynamic Dust Deposition and Statics Analysis; 8) Locating Targets for CRISM Based on Surface Morphology and Interpretation of THEMIS Data; 9) The Phoenix Mission to Mars; 10) First Studies of Possible Landing Sites for the Phoenix Mars Scout Mission Using the BMST; 11) The 2009 Mars Telecommunications Orbiter; 12) The Aurora Exploration Program - The ExoMars Mission; 13) Electron-induced Luminescence and X-Ray Spectrometer (ELXS) System Development; 14) Remote-Raman and Micro-Raman Studies of Solid CO2, CH4, Gas Hydrates and Ice; 15) The Compact Microimaging Spectrometer (CMIS): A New Tool for In-Situ Planetary Science; 16) Preliminary Results of a New Type of Surface Property Measurement Ideal for a Future Mars Rover Mission; 17) Electrodynamic Dust Shield for Solar Panels on Mars; 18) Sensor Web for Spatio-Temporal Monitoring of a Hydrological Environment; 19) Field Testing of an In-Situ Neutron Spectrometer for Planetary Exploration: First Results; 20) A Miniature Solid-State Spectrometer for Space Applications - Field Tests; 21) Application of Laser Induced Breakdown Spectroscopy (LIBS) to Mars Polar Exploration: LIBS Analysis of Water Ice and Water Ice/Soil Mixtures; 22) LIBS Analysis of Geological Samples at Low Pressures: Application to Mars, the Moon, and Asteroids; 23) In-Situ 1-D and 2-D Mapping of Soil Core and Rock Samples Using the LIBS Long Spark; 24) Rocks Analysis at Stand Off Distance by LIBS in Martian Conditions; 25) Evaluation of a Compact Spectrograph/Detection System for a LIBS Instrument for In-Situ and Stand-Off Detection; 26) Analysis of Organic Compounds in Mars Analog Samples; 27) Report of the Organic Contamination Science Steering Group; 28) The Water-Wheel IR (WIR) - A Contact Survey Experiment for Water and Carbonates on Mars; 29) Mid-IR Fiber Optic Probe for In Situ Water Detection and Characterization; 30) Effects of Subsurface Sampling & Processing on Martian Simulant Containing Varying Quantities of Water; 31) The Subsurface Ice Probe (SIPR): A Low-Power Thermal Probe for the Martian Polar Layered Deposits; 32) Deploying Ground Penetrating Radar in Planetary Analog Sites to Evaluate Potential Instrument Capabilities on Future Mars Missions; 33) Evaluation of Rock Powdering Methods to Obtain Fine-grained Samples for CHEMIN, a Combined XRD/XRF Instrument; 34) Novel Sample-handling Approach for XRD Analysis with Minimal Sample Preparation; 35) A New Celestial Navigation Method for Mars Landers; 36) Mars Mineral Spectroscopy Web Site: A Resource for Remote Planetary Spectroscopy.

Source record↗
NASA NTRS2019

Comparison of high-resolution airborne soil moisture retrievals to SMAP soil moisture during the SMAP validation experiment 2016 (SMAPVEX16)

The NASA's Soil Moisture Active Passive (SMAP) mission conducted a field experiment with its partners over two 40-km agricultural domains in Iowa and Manitoba in the summer of 2016 to address concerns observed in SMAP soil moisture (SM) retrievals over agricultural areas. The experiment featured airborne Passive Active L-band System (PALS) flights over each domain with intensive ground measurements and dense networks of SM monitoring stations. With two intensive observation periods separated in time (May 28–June 20 and July 14–August 16), the flights captured both early-season/low vegetation and later-season/high-vegetation conditions. The comparison of the PALS brightness temperature (TB) measurements to the SMAP TB observed over the sites resulted in root mean square difference (RMSD) of 2.8 K and 4.0 K for vertical and horizontal polarizations, respectively. The subsequent SM analysis rescaled the PALS TB with the SMAP TB to allow equitable comparisons between the SM retrievals from the two instruments. The PALS SM retrieval algorithm used the SM sampled by the ground teams during the overpass days for tuning, and was parameterized by a high-resolution vegetation water content product calibrated using vegetation samples collected during the experiment. The tuning process was not able to find a satisfactory result with a temporally constant set of parameters in the single channel algorithm for the two intensive observation periods of the experiment. This result indicated that the rapid change in the vegetation structure during the growth stages and likely variation in the surface roughness conditions were not compatible with rigid parameterization over the entire period. However, using seasonally variable parameters we found that it was possible to retrieve soil moisture with satisfactory accuracy. Comparative analysis with the SMAP SM product included aggregation of the PALS SM to the SMAP pixel-scale. The RMSD between the PALS SM and the aggregated manual field samples was <0.04 m3/m3 with Pearson correlation >0.85 for both sites. The comparison between different in situ sources indicated that the soil moisture network measurements were not the source of the large biases observed for SMAP over the sites reported in earlier studies. Therefore, the results suggested the rapidly growing vegetation and the early-season surface condition changes not captured by the SMAP algorithm caused the SMAP retrieval errors. In addition, the significant deviations of the vegetation water content used by the SMAP product from the calibrated vegetation water content obtained during the experiment compounds the problem.

Andreas Colliander↗
DOE OSTI2020

Understanding and improving model representation of aerosol optical properties for a Chinese haze event measured during KORUS-AQ

KORUS-AQ was an international cooperative air quality field study in South Korea that measured local and remote sources of air pollution affecting the Korean Peninsula during May–June 2016. Some of the largest aerosol mass concentrations were measured during a Chinese haze transport event (24 May). Air quality forecasts using the WRF-Chem model with aerosol optical depth (AOD) data assimilation captured AOD during this pollution episode but overpredicted surface particulate matter concentrations in South Korea, especially PM 2.5 , often by a factor of 2 or larger. Analysis revealed multiple sources of model deficiency related to the calculation of optical properties from aerosol mass that explain these discrepancies. Using in situ observations of aerosol size and composition as inputs to the optical properties calculations showed that using a low-resolution size bin representation (four bins) underestimates the efficiency with which aerosols scatter and absorb light (mass extinction efficiency). Besides using finer-resolution size bins (8–16 bins), it was also necessary to increase the refractive indices and hygroscopicity of select aerosol species within the range of values reported in the literature to achieve better consistency with measured values of the mass extinction efficiency (6.7 m 2 g –1 observed average) and light-scattering enhancement factor (ƒ(RH)) due to aerosol hygroscopic growth (2.2 observed average). Furthermore, an evaluation of the optical properties obtained using modeled aerosol properties revealed the inability of sectional and modal aerosol representations in WRF-Chem to properly reproduce the observed size distribution, with the models displaying a much wider accumulation mode. Other model deficiencies included an underestimate of organic aerosol density (1.0 g cm –3 in the model vs. observed average of 1.5 g cm –3 ) and an overprediction of the fractional contribution of submicron inorganic aerosols other than sulfate, ammonium, nitrate, chloride, and sodium corresponding to mostly dust (17 %–28 % modeled vs. 12 % estimated from observations). These results illustrate the complexity of achieving an accurate model representation of optical properties and provide potential solutions that are relevant to multiple disciplines and applications such as air quality forecasts, health impact assessments, climate projections, solar power forecasts, and aerosol data assimilation.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1985

A cool anomaly off northern California - An investigation using IR imagery and in situ data

The OPTOMA (Ocean Prediction Through Observation, Modeling and Analysis) program is developing an ocean descriptive-predictive system for four-dimensional data assimilation. It is presently concerned with the mesoscale variability in the California Current System (CCS). The present paper has the objective to assess the relationship of surface temperature structure to subsurface temperature structure and flow fields. Surface temperature anomalies are related to the mesoscale horizontal advective and subsurface mass fields. The cool anomaly off northern California in summer 1982 is discussed, taking into account the temperature structure along transects, T-S variations and inferred water masses, variation of horizontal temperature patterns with depth, and synoptic information from IR data.

Rienecker, M. M.↗
NASA NTRS2006

Development of In Situ Instruments for Planetary Exploration - Unique Challenges in Design, Development, and Execution

A viewgraph presentation describing in situ instruments for NASA missions is shown. The topics include: 1) In Situ Instrumentation; 2) Planetary Extremes; 3) Mars Surface Environment; 4) Lunar Precursor Mission Environment; 5) Europa Surface Analogue; 6) Other Parameters; 7) Space In Situ Instrumentation still in its Infancy; 8) Needed Capabilities For In Situ Science; 9) Framework For Putting The Pieces Together; 10) The Wild World of Astrobiology; 11) Timeline; 12) Example: MOD; 13) In Situ Sample Analysis Laboratories are more complex; 14) technologies In Situ Sample Analysis Requires Integration of Many Emerging Advanced Concepts; 15) Supporting technologies for In Situ Laboratories; 16) Micro-laboratory example; 17) In Situ Instrument Classes; and 18) Key for Analytical Instrument:Sample Preparation.

In Situ Instrumentation↗
DOE OSTI2016

The Midlatitude Continental Convective Clouds Experiment (MC3E)

The Midlatitude Continental Convective Clouds Experiment (MC3E), a field program jointly led by the U.S. Department of Energy’s Atmospheric Radiation Measurement program and the NASA Global Precipitation Measurement (GPM) Mission, was conducted in south-central Oklahoma during April – May 2011. MC3E science objectives were motivated by the need to improve understanding of midlatitude continental convective cloud system lifecycles, microphysics, and GPM precipitation retrieval algorithms. To achieve these objectives a multi-scale surface- and aircraft-based in situ and remote sensing observing strategy was employed. A variety of cloud and precipitation events were sampled during the MC3E, of which results from three deep convective events are highlighted. Vertical structure, air motions, precipitation drop-size distributions and ice properties were retrieved from multi-wavelength radar, profiler, and aircraft observations for an MCS on 11 May. Aircraft observations for another MCS observed on 20 May were used to test agreement between observed radar reflectivities and those calculated with forward-modeled reflectivity and microwave brightness temperatures using in situ particle size distributions and ice water content. Multi-platform observations of a supercell that occurred on 23 May allowed for an integrated analysis of kinematic and microphysical interactions. A core updraft of 25 ms-1 supported growth of hail and large rain drops. Data collected during the MC3E campaign is being used in a number of current and ongoing research projects and is available through the DOE ARM and NASA data archives.

Jensen, Mark P.↗
DOE OSTI2022

Bioavailable iron titrations reveal oceanic Synechococcus ecotypes optimized for different iron availabilities

Abstract The trace metal iron (Fe) controls the diversity and activity of phytoplankton across the surface oceans, a paradigm established through decades of in situ and mesocosm experimental studies. Despite widespread Fe-limitation within high-nutrient, low chlorophyll (HNLC) waters, significant contributions of the cyanobacterium Synechococcus to the phytoplankton stock can be found. Correlations among differing strains of Synechococcus across different Fe-regimes have suggested the existence of Fe-adapted ecotypes. However, experimental evidence of high- versus low-Fe adapted strains of Synechococcus is lacking, and so we investigated the transcriptional responses of microbial communities inhabiting the HNLC, sub-Antarctic region of the Southern Ocean during the Spring of 2018. Analysis of metatranscriptomes generated from on-deck incubation experiments reflecting a gradient of Fe-availabilities reveal transcriptomic signatures indicative of co-occurring Synechococcus ecotypes adapted to differing Fe-regimes. Functional analyses comparing low-Fe and high-Fe conditions point to various Fe-acquisition mechanisms that may allow persistence of low-Fe adapted Synechococcus under Fe-limitation. Comparison of in situ surface conditions to the Fe-titrations indicate ecological relevance of these mechanisms as well as persistence of both putative ecotypes within this region. This Fe-titration approach, combined with transcriptomics, highlights the short-term responses of the in situ phytoplankton community to Fe-availability that are often overlooked by examining genomic content or bulk physiological responses alone. These findings expand our knowledge about how phytoplankton in HNLC Southern Ocean waters adapt and respond to changing Fe supply.

Gilbert, Naomi E. (ORCID:0000000256915547)↗
NASA NTRS2003

The Pascal Mars Scout Mission

Pascal is a Mars Climate Network Mission that is being developed for NASA's Mars Scout Program. The mission would establish a network of 18 science weather stations distributed across the entire surface of Mars that operates for 3-10 Mars years (5.6- 18.8 Earth years). Pascal's instrument suite combines entry data from accelerometers and descent cameras, with landed data from pressure, opacity, temperature, wind speed, and water vapor to create a detailed global picture of Martian climate and weather. A panoramic landed camera system acquires images every 30 Sols to monitor changes in the landing environment due to winds. Analysis of data from the science stations, taken as often as once every 15 minutes, will provide a depth of understanding that will vastly increase our knowledge of Mars, and significantly impact site selection for future NASA missions. Pascal is the first mission ever to sample - in situ - the full global diversity of Mars and provide a continuous long-term presence on its surface.

Haberle, R. M.↗
NASA NTRS2011

Validation of the MODIS "Clear-Sky" Surface Temperature of the Greenland Ice Sheet

Surface temperatures on the Greenland Ice Sheet have been studied on the ground, using automatic weather station (AWS) data from the Greenland-Climate Network (GC-Net), and from analysis of satellite sensor data. Using Advanced Very High Frequency Radiometer (AVHRR) weekly surface temperature maps, warming of the surface of the Greenland Ice Sheet has been documented from 1981 to present. We extend and refine this record using higher-resolution Moderate-Resolution Imaging Spectroradiometer (MODIS) data from March 2000 to the present. To permit changes to be observed over time, we are developing a well-characterized monthly climate-data record (CDR) of the "clear-sky" surface temperature of the Greenland Ice Sheet using data from both the Terra and Aqua satellites. We use the MODIS ice-surface temperature (IST) algorithm. Validation of the CDR consists of several facets: 1) comparisons between the Terra and Aqua IST maps; 2) comparisons between ISTs and in-situ measurements; 3) comparisons between ISTs and AWS data; and 4) comparisons of ISTs with surface temperatures derived from other satellite instruments such as the Thermal Emission and Reflection Radiometer. In this work, we focus on 1) and 2) above. Surface temperatures on the Greenland Ice Sheet have been studied on the ground, using automatic weather station (AWS) data from the Greenland-Climate Network (GC-Net), and from analysis of satellite sensor data. Using Advanced Very High Frequency Radiometer (AVHRR) weekly surface temperature maps, warming of the surface of the Greenland Ice Sheet has been documented from 1981 to present. We extend and refine this record using higher-resolution Moderate-Resolution Imaging Spectroradiometer (MODIS) data from March 2000 to the present. To permit changes to be observed over time, we are developing a well-characterized monthly climate-data record (CDR) of the "clear-sky" surface temperature of the Greenland Ice Sheet using data from both the Terra and Aqua satellites. We use the MODIS ice-surface temperature (IST) algorithm. Validation of the CDR consists of several facets: 1) comparisons between the Terra and Aqua IST maps; 2) comparisons between ISTs and in-situ measurements; 3) comparisons between ISTs and AWS data; and 4) comparisons of ISTs with surface temperatures derived from other satellite instruments such as the Thermal Emission and Reflection Radiometer. In this work, we focus on 1) and 2) above. First we provide comparisons between Terra and Aqua swath-based ISTs at approximately 14:00 Local Solar Time, reprojected to 12.5 km polar stereographic cells. Results show good correspondence when Terra and Aqua data were acquired within 2 hrs of each other. For example, for a cell centered over Summit Camp (72.58 N, 38.5 W), the average agreement between Terra and Aqua ISTs is 0.74 K (February 2003), 0.47 K (April 2003), 0.7 K (August 2003) and 0.96 K (October 2003) with the Terra ISTs being generally lower than the Aqua ISTs. More precise comparisons will be calculated using pixel data at the swath level, and correspondence between Terra and Aqua IST is expected to be closer. (Because of cloud cover and other considerations, only a few common cloud-free swaths are typically available for each month for comparison.) Additionally, previous work comparing land-surface temperatures (LSTs) from the standard MODIS LST product and in-situ surface-temperature data at Summit Camp on the Greenland Ice Sheet show that Terra MODIS LSTs are about 3 K lower than in-situ temperatures at Summit Camp, during the winter of 2008-09. This work will be repeated using both Terra and Aqua IST pixel data (in place of LST data). In conclusion, we demonstrate that the uncertainties in the CDR will be well characterized as we work through the various facets of its validation.

Hall, Dorothy K.↗
NASA NTRSDate not supplied

AERACEPT (AErosol Rapid Analysis Combined Entry Probe/sonde Technology) for the Nephele Venus Cloud Mission Concept

Nephele is a small atmospheric probe mission concept to determine whether the Venus clouds contain organic matter. Nephele complements larger missions that seek to conduct Venus atmospheric analyses, such as DAVINCI, Venera-D, and the Morning Star missions, by directly sampling and analyzing cloud and haze particles. AERACEPT is an aerosol sampling technology designed to minimize the mass, volume, and complexity required for in situ planetary atmosphere characterization. A single aeroshell functions as a combined entry vehicle, descent probe, and instrumented sonde, combining recent advances in thermal protection materials with heritage technology from planetary and airborne science. The velocity of descent drives aerosol through inlets embedded in the aeroshell’s thermal protection material; inertial separation isolates the particles from the gas stream; and the particle capture surface doubles as the analysis substrate. This method can work without heat shield separation, descent control, or active sample handling; these advantages trade against a smaller sample volume, higher risk of sample heating, and shorter time for analysis and data return. AERACEPT further benefits from modeling of the internal and external flow to understand the particle capture efficiency and bias for size and concentration distributions. AERACEPT is well suited for a Venus mission such as Nephele, where a passive descent trajectory is both subsonic over the altitudes of interest and provides sufficient velocity and pressure differential for the particle sizes of interest. A thermal and flow toolchain developed in-house (Traj→ DPLR→ PATO→ openFOAM) was used to model an 80-cm aeroshell with science operations 63–39 km. These models indicate that AERACEPT will provide ~24 µL accumulated sample of particles ≥ 0.2 µm, substantially above the 2 µL threshold requirement. The worst-case particle heating will be ~14 K above ambient, for the smallest particles at the lowest altitude; most particles will experience ≤ 1 K rise, at which almost all analytes of interest will be unaffected. Plasma jet testing of a small-scale aeroshell-material inlet was recently conducted to validate the thermal model parameters; wind tunnel testing to validate the flow model parameters is underway.

AERACEPT↗
DOE OSTI2014

Polyacrylamide grafting of modified graphene oxides by in situ free radical polymerization

Highlights: • Graphene oxide (GO) was modified by chemical reactions to functionalized GO (FGO). • The FGOs and the GO were then subjected to in situ free radical polymerization. • Hydroxyl groups of GO were the most reactive grafting sites. - Abstract: Graphene oxide (GO) was modified using chemical reactions to obtain three types of functionalized GO sheets (FGO). The FGO sheets and the GO were then subjected to in situ free radical polymerization in order to study the grafting polymerization. The FGO and grafted-.FGO were analyzed with Fourier transform infrared spectroscopy, scanning electronic microscopy, thermo-gravimetric analysis (TGA) and X-ray photoelectron spectroscopy (XPS). The grafting percentages in the materials were calculated using the TGA and XPS results. The FGO sheets with different functional groups exhibited different grafting abilities, and hydroxyl groups were proven to be the most reactive grafting sites for the in situ free radical grafting polymerization of polyacrylamide.

36 MATERIALS SCIENCE↗
NASA NTRS2019

Performance of Landsat-8 and Sentinel-2 Surface Reflectance Products for River Remote Sensing Retrievals of Chlorophyll-A and Turbidity

Rivers and other freshwater systems play a crucial role in ecosystems, industry, transportation and agriculture. Despite the more than 40 years of inland water observations made possible by optical remote sensing, a standardized reflectance product for inland waters is yet forthcoming. The aim of this work is to compare the standard USGS land surface reflectance product to two Landsat-8 and Sentinel-2 aquatic remote sensing reflectance products over the Amazon, Columbia and Mississippi rivers. Landsat-8 reflectance products from all three routines are then evaluated for their comparative performance in retrieving chlorophyll-a and turbidity in reference to shipborne, underway in situ validation measurements. The land surface product shows the best agreement (4 percent Mean Absolute Percent Difference) with field measurements of radiometry collected on the Amazon River and generates 36 percent higher reflectance values in the visible bands compared to aquatic methods (ACOLITE (Atmospheric Correction for OLI (Operational Land Imager) 'lite') and SeaDAS (Sea-viewing Wide Field-of-View Sensor (SeaWiFS) Data Analysis System)) with larger differences between land and aquatic products observed in Sentinel-2 (0.01 per steraradian) compared to Landsat-8 (0.001 per steraradian). Choice of atmospheric correction routine can bias Landsat-8 retrievals of chlorophyll-a and turbidity by as much as 59 percent and 35 percent respectively. Using a more restrictive time window for matching in situ and satellite imagery can reduce differences by 5–31 percent depending on correction technique. This work highlights the challenges of satellite retrievals over rivers and underscores the need for future optical and biogeochemical research aimed at improving our understanding of the absorbing and scattering properties of river water and their relationships to remote sensing reflectance.

Landsat-8↗
DOE OSTI2025

Cooperative Effects Associated with High Electrolyte Concentrations in Driving the Conversion of CO2 to C2H4 on Copper

Compared to a conventional electrolyte concentration of 1 M HCOOK, the use of a highly concentrated 7.1 M HCOOK electrolyte increases the Faradaic efficiency (FE) ratio of C2H4/CO from 2.2 +- 0.3 to 18.3 +- 4.8 at -1.08 V vs. reversible hydrogen electrode (RHE) on a Cu gas-diffusion electrode. Based on electrochemical analysis and ab initio molecular dynamics (AIMD) simulation, the identity and concentration of the cation and anion play more important roles in controlling the CO2R reaction pathway than the bulk CO2 solubility and the bulk pH of electrolytes. In situ attenuated reflectance surface enhanced infrared absorption spectroscopy (ATR-SEIRAS) suggests that, unlike 1 M HCOOK, the *CO-bridge-binding mode on Cu is dominant in 7.1 M HCOOK electrolyte, which potentially results in less CO release and higher yield of C2H4. This study demonstrates that although we can tailor the electrolyte composition to shift product selectivity, the factors that control the product selectivity are numerous and cannot be distilled down into one correlated property-reactivity relationship.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1990

Radiative transfer based retrieval of reflectance from calibrated radiance imagery measured by an imaging spectrometer for lithological mapping of the Clark Mountains, California

Spectral radiance imagery measured by the Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) are reduced to reflectance through compensation for atmospheric scattering, water vapor absorption, absorption of the well mixed gases, solar irradiance and the solar zenith angle. The LOWTRAN 7 (Kneizys et al., 1989) radiative transfer code form the basis for this retrieal. LOWTRAN 7 is constrained with water vapor determinations from the AVIRIS radiance data through an algorithm operating on the 940 nm atmospheric water band for every spatial element. In situ measurements of atmospheric optical depths are used to constrain the LOWTRAN 7 aerosol models. Accuracy of the retrieved reflectance spectra is evaluated with respect to surface spectra measured at the time of the overflight. The mineral bastnaesite is identified in the analysis of the retrieved reflectance imagery. These reflectance data provide a means to map the subtle mineral gradients in the PreCambrian block of the Clark Mountain range in southeastern California for geological analysis.

Green, Robert O.↗