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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33

Solar PV Energy: Myths and Realities (Spanish Translation)

Solar energy is growing at record rates, but its rapid expansion brings little-discussed challenges. I will present the global deployment goals and how these translate into future amounts of waste and critical material needs. I will also address common myths about end of life, toxicity, and the real impacts of technological changes, and why research in reliability and field testing is essential to ensure a resilient, sustainable network prepared for the next decades of photovoltaic growth.

14 SOLAR ENERGY↗

Improving Solar PV Degradation Prediction Certainty: PREDICTS2 (Final Technical Report)

The rate and type of in-service PV performance degradation vary for different module designs, vintages, and operating climates. The current IEC 61215 module qualification testing standard can be used to identify design and manufacturing flaws that may lead to early life failures, but it was not intended to accurately predict degradation rates in the first 5 to 10 years of a PV plant’s lifetime, nor long-term performance, under varied operating conditions. Correlations between accelerated aging data and real-world degradation data are needed to better predict wear-out degradation in response to environmental stressors, such as elevated temperature, temperature cycling, moisture, wind load, and solar radiation. The PREDICTS2 project aged 36 pristine-condition ‘spare’ modules from a commercial PV power plant in the U.S. Southwest using the IEC 61215 and Qualification Plus (Qual Plus) testing standards. The study is unique in its ability to compare performance degradation data for fielded modules operating outdoors for 6 years in a commercial plant environmental with degradation data for modules of the same make, model and vintage that have been aged artificially in an indoor laboratory. Changes in individual module current-voltage (I-V) curve data were measured before and after the artificial aging process and compared to I-V curve data for the fielded modules. This project advanced the industry’s understanding of how environmental stressors affect performance degradation and established relationships between degradation mechanisms and changes to module electrical parameters and power loss. Improved certainty in degradation rates is expected to be the greatest source of LCOE reduction resulting from this project. Reducing the spread in the degradation rate probability distribution lowers project risk, which translates to lower project financing costs.

14 SOLAR ENERGY↗

Tensile and Fatigue Testing and Material Hardening Model Development for 508 LAS Base Metal and 316 SS Similar Metal Weld under In-air and PWR Primary Loop Water Conditions

This report provides an update on an assessment of environmentally assisted fatigue for light water reactor components under extended service conditions. This report is a deliverable in September 2015 under the work package for environmentally assisted fatigue under DOE’s Light Water Reactor Sustainability program. In an April 2015 report we presented a baseline mechanistic finite element model of a two-loop pressurized water reactor (PWR) for systemlevel heat transfer analysis and subsequent thermal-mechanical stress analysis and fatigue life estimation under reactor thermal-mechanical cycles. In the present report, we provide tensile and fatigue test data for 508 low-alloy steel (LAS) base metal, 508 LAS heat-affected zone metal in 508 LAS–316 stainless steel (SS) dissimilar metal welds, and 316 SS-316 SS similar metal welds. The test was conducted under different conditions such as in air at room temperature, in air at 300 oC, and under PWR primary loop water conditions. Data are provided on materials properties related to time-independent tensile tests and time-dependent cyclic tests, such as elastic modulus, elastic and offset strain yield limit stress, and linear and nonlinear kinematic hardening model parameters. The overall objective of this report is to provide guidance to estimate tensile/fatigue hardening parameters from test data. Also, the material models and parameters reported here can directly be used in commercially available finite element codes for fatigue and ratcheting evaluation of reactor components under in-air and PWR water conditions.

316 Stainless Steel↗

KATNAL1 is a more active and stable isoform of katanin, and is expressed dominantly in neurons

Highlights: • Neurons predominantly express KATNAL1 compared with KATNA1. • When introduced in cells, KATNAL1 showed higher microtubule-severing activity. • Cycloheximide chase analysis revealed that KATNAL1 is more stable in cells. • Knockdown of KATNAL1 but not KATANA1 resulted in enhancement of process elongation. Microtubule severing is essential for reorganization of microtubules during neuronal migration and process elongation. Katanin is a microtubule-severing enzyme, of which the major catalytic subunits are katanin A1 (KATNA1) and katanin A-like 1 (KATNAL1). The domain organization of the two subunits are almost the same; however, little is known about their functional difference. Here, we compared the expression pattern, microtubule-severing activity, intracellular degradation and knockdown phenotype in cultured cells of the two subunits. While KATNA1 was expressed ubiquitously among tissues of young adult mice, KATNAL1 was highly expressed in the brain and the testis. Neurons expressed almost only KATNAL1. When introduced into Neuro2a cells, KATNAL1 showed higher microtubule-severing activity. Cycloheximide chase analysis revealed that KATNAL1 is more stable in cells. To elucidate which part of the molecules are responsible for these characteristics, we generated chimeric molecules by swapping the amino-terminal and carboxyl-terminal halves between the two subunits. Experiments using these chimeras revealed that the amino-terminal half region is the determinant for their characteristics. Furthermore, KATNAL1 knockdown in Neuro2a cells resulted in enhancement of process elongation, while KATNA1 knockdown showed no effect. These data suggest that more active and more stable katanin subunit, KATNAL1, plays more important role in process elongation.

60 APPLIED LIFE SCIENCES↗

Exploratory analysis and performance prediction of big data transfer in High-performance Networks

Big data transfer in large-scale scientific and business applications is increasingly carried out over connections with guaranteed bandwidth provisioned in High-performance Networks (HPNs) via advance bandwidth reservation. Provisioning agents need to carefully schedule data transfer requests, compute network paths, and allocate appropriate bandwidths. Such reserved bandwidths, if not fully utilized, could be simply wasted due to the exclusive access during the approved time window, and cause extra overhead and complexity for resource management. This calls for accurate performance prediction to reserve bandwidths that match actual needs and avoid over-provisioning. We employ machine learning algorithms to predict big data transfer performance based on extensive performance measurements collected in the past several years from data transfer tests using different protocols and toolkits between various end sites on several real-life physical or emulated testbeds. We first analyze the performance patterns in response to a comprehensive list of parameters in end-host systems, network connections, and data transfer applications, which motivate the use of machine learning and also help us identify the effects of latent factors. We then propose threshold- and clustering-based methods to eliminate negative effects of latent factors in data preprocessing and build a robust performance predictor based on customized domain-oriented loss functions. The performance of the proposed methods is verified by extensive experiments using SVR and RFR as well as theoretical analysis of the general performance bound.

97 MATHEMATICS AND COMPUTING↗

Measurements of Argon-39 from locations near historic underground nuclear explosions

Measurement of radioactive gas seepage from an underground nuclear explosion is one of the primary methods to confirm whether an event was nuclear in nature. Radioactive noble gas indicators that are commonly targeted by such measurements (e.g. 133Xe, 37Ar) have half-lives of 35 days or less. Argon-39, an activation product similar to 37Ar, is produced by the interaction between neutrons and potassium in the surrounding geology and has a half-life of 269 years. Measurements taken at three sites near three historic underground nuclear test locations at the Nevada National Security Site have all shown highly elevated levels of 39Ar in subsurface air decades after the test events. Elevated levels of 39Ar (30-50 times background) were also detected in atmospheric air collected roughly 30 cm above ground level near two of these sites, and outside the entrance of the one tunnel site. These measurements demonstrate that 39Ar has the potential to be a long-term signature of an underground nuclear event which can be reliably detected at the surface or in the shallow subsurface. This radionuclide detection of an underground nuclear event decades after the event takes place is in contrast to the commonly held assumption that detecting underground nuclear events via radionuclides at the surface needs to be done in a matter of months. Depending upon what further studies show about the robustness of this signature in a variety of geological settings, it may in fact be easy to detect underground nuclear events at the surface for a very long time post-detonation.

Johnson, Christine M.↗

Status of the CUORE and results from the CUORE-0 neutrinoless double beta decay experiments

CUORE is a 741 kg array of TeO 2 bolometers for the search of neutrinoless double beta decay of 130 Te. The detector is being constructed at the Laboratori Nazionali del Gran Sasso, Italy, where it will start taking data in 2015. If the target background of 0.01 counts/(keV·kg·y) will be reached, in five years of data taking CUORE will have a 1σ half life sensitivity of 10 26 y. CUORE-0 is a smaller experiment constructed to test and demonstrate the performances expected for CUORE. The detector is a single tower of 52 CUORE-like bolometers that started taking data in spring 2013. The status and perspectives of CUORE will be discussed, and the first CUORE-0 data will be presented.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Degradation in Ni-Rich LiNi 1– x – y Mn x Co y O 2 /Graphite Batteries: Impact of Charge Voltage and Ni Content

Ni-rich LiNi 1– x–y Mn x CoyO 2 (NMC) materials are attractive as cathodes for Li-ion batteries due to their high energy density and low Co content. However, these materials may display poor electrochemical reversibility relating to structural and interfacial instabilities. The influence of Ni content and level of delithiation during charge on degradation mechanisms and relevance to electrochemical cycling behavior are probed for LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622) and LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) cathode materials in a full cell configuration under two upper voltage limits (4.1 and 4.3 V). The combined use of dQ/dV analysis of electrochemical voltage profiles, operando XRD, and postcycling scanning electron microscopy (SEM) measurements indicates that a major contributor to capacity fade is the large anisotropic volume change from an H2 $\leftrightarrows$ H3 phase transition and associated mechanical degradation particularly for NMC811. Notably, transition metal dissolution and deposition on the negative electrode are found to correlate with the structural changes occurring in the cathode under high voltage charge. X-ray photoelectron spectroscopy (XPS) analyses of the cycled cathodes reveal a more organic-rich cathode–electrolyte interphase (CEI) when cycling to 4.3 V with lower relative amounts of LiF. Surface reconstruction is not a significant factor under these cycling conditions as determined by soft X-ray absorption spectroscopy (sXAS) analysis. The results emphasize the opportunity to match the electrochemical test parameters with the specific NMC active material to mitigate degradation and extend cycle life.

36 MATERIALS SCIENCE↗

Rapid, Sensitive, Label-Free Electrical Detection of SARS-CoV-2 in Nasal Swab Samples

Rapid diagnosis of coronavirus disease 2019 (COVID-19) is key for the long-term control of severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) amid renewed threats of mutated SARS-CoV-2 around the world. Here, we report on an electrical label-free detection of SARS-CoV-2 in nasopharyngeal swab samples directly collected from outpatients or in saliva-relevant conditions by using a remote floating-gate field-effect transistor (RFGFET) with a 2-dimensional reduced graphene oxide (rGO) sensing membrane. RFGFET sensors demonstrate rapid detection (<5 min), a 90.6% accuracy from 8 nasal swab samples measured by 4 different devices for each sample, and a coefficient of variation (CV) < 6%. Also, RFGFET sensors display a limit of detection (LOD) of pseudo-SARS-CoV-2 that is 10 000-fold lower than enzyme-linked immunosorbent assays, with a comparable LOD to that of reverse transcriptionpolymerase chain reaction (RT-PCR) for patient samples. To achieve this, comprehensive systematic studies were performed regarding interactions between SARS-CoV-2 and spike proteins, neutralizing antibodies, and angiotensin-converting enzyme 2, as either a biomarker (detection target) or a sensing probe (receptor) functionalized on the rGO sensing membrane. Finally, taken together, this work may have an immense effect on positioning FET bioelectronics for rapid SARS-CoV-2 diagnostics.

60 APPLIED LIFE SCIENCES↗

Linking international technical specifications for acoustic characterization of marine energy converter sounds with environmental compliance criteria

As new ocean energy technologies emerge and are deployed for testing and operations, sound emissions are a potential concern for environmental effects to marine life. Consistent acoustic measurement and data analysis methods can help promote comparisons of technologies and transferability between project sites. In 2022, acoustic emissions from a prototype scale wave energy converter (WEC) were characterized for a range of environmental conditions and power generation states in the coastal waters off southern California using a set of international technical specifications. Results from the international technical specification analyses were applied to United States regulatory threshold criteria for acoustic impacts to marine mammals and examined in the context of European underwater noise monitoring guidelines. Weighted 24 hour cumulative sound exposure levels SEL24h calculated from the highest power generation state WEC sound pressure levels were often more than 20 dB below threshold criteria for temporary threshold shifts in five relevant marine mammal hearing groups. Following European Union recommendations for analyses and reporting, WEC sound characterization in third octave bands centered at 63 Hz and 125 Hz show clear spatial decay of WEC-generated noise, with more pronounced attenuation at 63 Hz, and a less marked but still detectable gradient at 125 Hz, collectively suggesting a relatively confined acoustic footprint under the observed conditions. The value of the international technical specification approach is highlighted by the isolation of WEC sounds from the surrounding soundscape. This allows for a robust characterization of acoustic emissions through a range of device power generation and sea states. Furthermore, in threshold-based regulatory contexts like the U.S., this facilitates direct evaluation of source contributions, while in broader monitoring frameworks used in the E.U. it provides a reproducible foundation for assessing the contribution of emerging ocean energy technologies to the underwater acoustic environment.

Haxel, Joseph H. (ORCID:0000000273864761)↗

Contrasting decays of 3-quasiparticle isomers in 173 W: A discerning test of 𝐾 conservation and 𝐾 mixing

Two isomers with K π = 19/2 + at 1876 keV with a half-life of 21(1) ns, and K π = 23/2− at 2159 keV with a half-life of 93(6) ns have been identified in 173 W, the lightest tungsten isotope to exhibit this phenomenon. An unusually high number of 13 branches have been established in the decay of the K π = 23/2 − isomer. This decay is associated with transitions involving significantly higher degrees of K forbiddenness and is in sharp contrast with the usual preferential deexcitation through branches, which are less forbidden, as is evident for the K π = 19/2 + state in 173 W. The inclusion of K-mixing effects, arising from band crossings in the sequences to which decays with larger degrees of K forbiddenness are observed, can qualitatively account for this contrasting behavior. These results provide a striking illustration of the competition between K conservation and K mixing in the decay of such isomers.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Assessing the accuracy of time-fraction and ductility exhaustion approaches for creep-fatigue damage prediction through feature-test validation

Determining creep-fatigue damage formation is critical for elevated temperature components integrity. This study evaluates creep-fatigue assessments with emphasis on differences between creep damage models. Evaluated are the time-fraction model and the classical and stress-modified ductility exhaustion creep damage models. This work extends the domain of stress-modified ductility exhaustion models by introducing and validating such formalism to Ni-based alloys. The fidelity of the assessments was benchmarked against uniaxial creep-fatigue and multiaxial feature tests of Alloy 617. For uniaxial specimens, best estimate predictions rank ductility exhaustion as the most accurate and precise and time-fraction as markedly conservative. For feature tests, ductility exhaustion predictions are within < 4.0 times difference, whereas time-fraction underpredicts life by factors of 7–14. The observations suggest ductility exhaustion models as alternative to time-fraction models in design codes for situations requiring characterization of the design margin. Further work in employing such models to assess other relevant phenomena (e.g., stress relaxation cracking) is discussed.

creep-fatigue↗

Literature Data on Foam Fracturing Fluid

At the beginning of this project, the Temple team spent significant effort to collect data relevant to foam fracturing. More than 40 articles/reports were found in the open literature that reported the properties of aqueous foams under various testing conditions. The foam properties included viscosity and stability in terms of half-life, while were influenced by the foam quality, shear rate, temperature, pressure, as well as surfactants and additives used in making the foam base solutions. As a result, more than 1100 data points were collected, which are included in a master worksheet named "Literature data on Foam Fracturing Fluid". These data points are organized based on following parameters: 1. Literature source, including authors and publication year 2. Gaseous phase (e.g. CO2, N2) 3. Liquid phase (e.g. tap water, DI water, salt water) 4. Surfactants and their concentrations 6. Additives 7. Foam quality 8. Pressure 9. Temperature 10. Viscosity 11. Foam stability, which was characterized by its half-life: Half-life Foam study data base with data analysis was completed and a webpage is designed hosted on public server at https://surfactant-dashboard.herokuapp.com

15 GEOTHERMAL ENERGY↗

Reliability Prediction using FMEA, FTA, and Related Techniques [Slides]

Summary: We presented a reliability analysis framework. We made point estimates of reliability using reliability block diagrams, fault trees, success trees and estimates with uncertainty using expert elicitation, Monte Carlo simulation, Bayesian analysis. Expert elicitation of failure modes and probabilities is labor-intensive, but critical. Bayesian analysis updates information from expert elicitation with data from reliability and aging tests (aging/compatibility data are needed to estimate lower-bound reliabilities at end of life). Estimation by more than one method helps insure consistency and accuracy.

97 MATHEMATICS AND COMPUTING↗

Electrochemical Acid Sequestration to Ease Ocean Acidification (EASE-OA) - CRADA 600 (Abstract)

The PNNL team will coordinate logistics involved with setting up the field trial on the PNNL Sequim campus in collaboration with Ebb Carbon. Facilities on the PNNL Sequim campus are capable of pumping raw or filtered seawater from Sequim Bay at a rate ~45,000 L hr -1 , which can accommodate the 4000 L hr -1 requirement of the 200 ton CO2 yr-1 Ebb Carbon marine carbon dioxide removal (mCDR) system. The primary tasks for the PNNL team are 1) laying out appropriate indoor and outdoor spaces for installing the Ebb Carbon’s mCDR system, 2) facilitating Ebb Carbon’s access to the PNNL’s seawater intake on the PNNL Sequim campus, 3) conducting mesocosm experiments within the PNNL Sequim campus laboratories to test how the brine and base discharged from the Ebb Carbon system affect marine life, and 4) facilitating Ebb Carbon access to the PNNL Sequim installation site and aiding in maintenance as needed. In addition to these tasks, the PNNL team will provide surface water quality data (e.g., salinity, temperature, pH, dissolved O2) from a monitoring station located on the pier to contextualize starting conditions of the seawater used in the mCDR process. Finally, the PNNL team will also consult with Ebb Carbon on strategies for improving overall system performance and next steps for further scaling and/or monitoring the effectiveness of the mCDR system.

54 ENVIRONMENTAL SCIENCES↗

Assessment and Planning of HFIR Test Articles

Burnable absorbers (BAs) are introduced into nuclear fuels to aid in controlling the activity of the irradiated fuel at the beginning of life in a light water reactor (LWR). This improves the efficiency of the reactor since it allows for higher enrichments (> 5 % 235 U) to be used in a LWR, which increases the burnup limit and therefore the cycle length. The purpose of the BA is to absorb neutrons to prevent power peaking, and the concentration of BA is consumed under irradiation. In order to understand the effect of the BAs on the microstructure and thermophysical properties of the fresh and irradiated fuel, neutron irradiation tests will be carried out at the High Flux Isotope Reactor (HFIR). These tests will include Gd 2 O 3 doped UO 2 fuels with concentrations that vary from 4 to 10 weight % Gd 2 O 3 .

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗