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R(sub nu)-dependent optical and near-ultraviolet extinction

We have derived extinctions A(lambda)/A(V) at the wavelengths of the uvby filters for 22 stars, with a range of values of R(sub nu), from the sample of Cardelli, Clayton, & Mathis (1989, hereafter CCM). We have fit these extinctions, and also UBVRIJHKL, IUE and ANS extinction measurements, with linear relations A(lambda)/A/(V) = a+b/R(sub nu) and fit a and b as a function of x(=1/lambda) with polynomials to obtain an R(sub nu)-dependent mean extinction law (A(x)/A(V) = a(x) + b(x)/R(sub nu))in the optical and near-ultraviolet (1.1/micrometer less than or equal to 3.3/micrometer). This law is virtually identical to the CCM extinction law for large values of R(sub nu)(R(sub nu) approximately 5) but is slightly lower in the near-ultraviolet for smaller R(sub nu) (R(sub nu) approximately 3). The extinction law presented here agrees much better with a high-resolution extinction curve for the diffuse interstellar medium (R(sub nu) approximately 3.1), presented by Bastiaansen (1992), than CCM. The deviations of individual extinction curves from the mean are dominated by observational errors. The wavelength resolution of this work is not high enough to show evidence for or against the existence of very broad structure in optical extinction curves.

O'Donnell, James E.↗

Infrared spectroscopy of lunar mare regolith

Spectra of reflection, emission, and transmission of regolith returned by the Luna 16 automatic station were investigated in the 1.8-13 micrometers region. A reflection maximum was shown to be present in the region 3 to 5 micrometer, along with a corresponding minimum in the emission coefficient. The spectra were interpreted based on a comparison of the optical properties with the chemical and structural properties of the regolith. The regolith in the entire array of properties in the infrared region differs appreciably from terrestrial objects. Spectra of diffuse reflection and the spectra at angles of incidence 0 deg and angles of reflection 15 and 30 deg with samples of the regolith returned by the Apollo 11 and Apollo 12 missions revealed a similarity of the infrared reflection characteristics of the regolith from different lunar mare regions.

M. V. Akhmanova↗

Two-stream theory of reflectance of snow

Spectral reflectance of snow under diffuse illumination is studied using the two-stream approximation of the radiative transfer equation. The scattering and absorption parameters of the radiative transfer equation - the single scattering albedo, the optical depth, and the integrated phase function are obtained from the grain size and density of snow. Analytical expressions for the intensity within the snowpack, the reflectance, and the asymptotic flux extinction coefficient, are given. Good agreement is shown between the theory and available experimental data on visible and near-infrared reflectance, and the asymptotic flux extinction coefficient. The theory may also be used to explain the observed effect of aging on the snow reflectance.

Choudhury, B. J.↗

Radiometric calibration of SPOT 2 HRV - A comparison of three methods

Three methods for determining an absolute radiometric calibration of a spacecraft optical sensor are compared. They are the well-known reflectance-based and radiance-based methods and a new method based on measurements of the ratio of diffuse-to-global irradiance at the ground. The latter will be described in detail and the comparison of the three approaches will be made with reference to the SPOT-2 HRV cameras for a field campaign 1990-06-19 through 1990-06-24 at the White Sands Missile Range in New Mexico.

Biggar, Stuart F.↗

The Ocean Colour Climate Change Initiative: III. A Round-Robin Comparison on In-Water Bio-Optical Algorithms

Satellite-derived remote-sensing reflectance (Rrs) can be used for mapping biogeochemically relevant variables, such as the chlorophyll concentration and the Inherent Optical Properties (IOPs) of the water, at global scale for use in climate-change studies. Prior to generating such products, suitable algorithms have to be selected that are appropriate for the purpose. Algorithm selection needs to account for both qualitative and quantitative requirements. In this paper we develop an objective methodology designed to rank the quantitative performance of a suite of bio-optical models. The objective classification is applied using the NASA bio-Optical Marine Algorithm Dataset (NOMAD). Using in situ Rrs as input to the models, the performance of eleven semianalytical models, as well as five empirical chlorophyll algorithms and an empirical diffuse attenuation coefficient algorithm, is ranked for spectrally-resolved IOPs, chlorophyll concentration and the diffuse attenuation coefficient at 489 nm. The sensitivity of the objective classification and the uncertainty in the ranking are tested using a Monte-Carlo approach (bootstrapping). Results indicate that the performance of the semi-analytical models varies depending on the product and wavelength of interest. For chlorophyll retrieval, empirical algorithms perform better than semi-analytical models, in general. The performance of these empirical models reflects either their immunity to scale errors or instrument noise in Rrs data, or simply that the data used for model parameterisation were not independent of NOMAD. Nonetheless, uncertainty in the classification suggests that the performance of some semi-analytical algorithms at retrieving chlorophyll is comparable with the empirical algorithms. For phytoplankton absorption at 443 nm, some semi-analytical models also perform with similar accuracy to an empirical model. We discuss the potential biases, limitations and uncertainty in the approach, as well as additional qualitative considerations for algorithm selection for climate-change studies. Our classification has the potential to be routinely implemented, such that the performance of emerging algorithms can be compared with existing algorithms as they become available. In the long-term, such an approach will further aid algorithm development for ocean-colour studies.

Phytoplankton↗

Ion beam microtexturing and enhanced surface diffusion

Ion beam interactions with solid surfaces are discussed with particular emphasis on microtexturing induced by the deliberate deposition of controllable amounts of an impurity material onto a solid surface while simultaneously sputtering the surface with an ion beam. Experimental study of the optical properties of microtextured surfaces is described. Measurements of both absorptance as a function of wavelength and emissivity are presented. A computer code is described that models the sputtering and ion reflection processes involved in microtexture formation.

Robinson, R. S.↗

Moorable spectroradiometers in the BIOWATT experiment

A new oceanographic instrument, the MER-2020, has been developed for the long term measurement of bio-optical properties. This instrument is a self-contained reflectance spectroradiometer with 40 megabytes of internal data storage and battery power permitting deployments for as long as 6 months. It can serve as the control and recording center for a variety of other sensors including fluorometers, transmissometers, temperature and conductivity probes. Instruments of this type were deployed at depths to 70 meters on a 5000 meter mooring during the BIOWATT experiment between February and November 1987. Measurements of the spectral diffuse attenuation coefficient and of the remote sensed reflectance from the ten month period in 1987 in the Northern Sargasso Sea are presented. In addition, the temperature, pressure, package orientation and sunlight stimulated natural fluorescence of phytoplankton are discussed. This instrument will be a key part of in situ optical calibration for future remote color sensors, and presently permits direct measurement of long term optical variability, important in visibility and communication problems.

Booth, C. R.↗

Comparison of measurements by different instruments of the far-infrared reflectance of rough, optically black coatings

Two comparisons of available specular infrared measurements using identical or very similar coatings reveal that specular BRDF (bidirectional reflectance distribution function) measurements of rough coatings are comparable but that simple measured reflectances are not. This is seen as indicating that the diffuse component of the measured specular reflectance is significantly larger than that of the specular component. It is noted that the diffuse component of the measurement is a convolution of the intrinsic directional reflectivity of the surface with the instrument function and that because the value of that function increases at the wavelengths under consideration, the diffuse component is larger than would otherwise be expected. The BRDF normalization is found to cause a primitive deconvolution of the instrument function and to produce a quantity that is approximately equal to the mean intrinsic directional reflectivity very near the specular direction. The analysis and comparison of data reveal that nonspecular BRDF measurements at angles well outside the instrument function can be calibrated as well by an image of the source upon the detector as by reference to a known surface.

Smith, S. M.↗

Degradation of optical components in space

This report concerns two types of optical components: multilayer filters and mirrors, and self-scanned imaging arrays using charge coupled device (CCD) readouts. For the filters and mirrors, contamination produces a strong reduction in transmittance in the ultraviolet spectral region, but has little or no effect in the visible and infrared spectral regions. Soft substrates containing halides are unsatisfactory as windows or substrates. Materials choice for dielectric layers should also reflect such considerations. Best performance is also found for the harder materials. Compaction of the layers and interlayer diffusion causes a blue shift in center wavelength and loss of throughput. For sensors using CCD's, shifts in gate voltage and reductions in transfer efficiency occur. Such effects in CCD's are in accord with expectations of the effects of the radiation dose on the device. Except for optical fiber, degradation of CCD's represents the only ionizing-radiation induced effect on the Long Duration Exposure Facility (LDEF) optical systems components that has been observed.

Blue, M. D.↗

Synthesis of Fullerenes in Low Pressure Benzene/Oxygen Diffusion Flames

The interest in fullerenes is strongly increasing since their discovery by Kroto et al. in 1985 as products of the evaporation of carbon into inert gas at low pressure. Due to their all carbon closed-shell structure, fullerenes have many exceptional physical and chemical properties and a large potential for applications such as superconductors, sensors, catalysts, optical and electronic devices, polymers, high energy fuels, and biological and medical materials. This list is still growing, because the research on fullerenes is still at an early stage. Fullerenes can be formed not only in a system containing only carbon and an inert gas, but also in premixed hydrocarbon flames under reduced pressure and fuel rich conditions. The highest yields of fullerenes in flames are obtained under conditions of substantial soot formation. There is a need for more information on the yields of fullerenes under different conditions in order to understand the mechanisms of their formation and to enable the design of practical combustion systems for large-scale fullerene production. Little work has been reported on the formation of fullerenes in diffusion flames. In order to explore the yields of fullerenes and the effect of low pressure in diffusion flames, therefore we constructed and used a low pressure diffusion flame burner in this study.

Hebgen, Peter↗

Accretion dynamics and polarized X-ray emission of magnetized neutron stars

The basic ideas of accretion onto magnetized neutron stars are outlined. These are applied to a simple model of the structure of the plasma mound sitting at the magnetic poles of such a star, in which upward diffusion of photons is balanced by their downward advection. This steady flow model of the plasma's dynamical state is used to compute the emission of polarized X-raysfrom the optically thick, birefringent medium. The linear polarization of the continuum radiation emerging from the quasi-static mound is found to be as much as 40 percent at some rotation phases, but is insensitive to the geometry of the accretion flow. The role of the accretion shock, whose detailed polarimetric and spectral characteristics have yet to be calculated, is emphasized as the final determinant of the properties of the emerging X-rays. Some results describing the fully time dependent dynamics of the flow are also presented. In particular, steady flow onto a neutron star is shown to exhibit formation of 'photon bubbles', regions of greatly reduced plasma density filled with radiation which form and rise on millisecond time scale. The possible role of these complex structures in the flow for the formation of the emergent spectrum is briefly outlined.

Arons, Jonathan↗

Cloud Thickness from Offbeam Returns - Thor Lidar

Physical thickness of a cloud layer, and sometimes multiple cloud layers, can be estimated from the time delay of off-beam returns from a pulsed laser source illuminating one side of the cloud layer. In particular, the time delay of light returning from the outer diffuse halo of light surrounding the beam entry point, relative to the time delay at beam center, determines the cloud physical thickness. The delay combined with the pulse stretch gives the optical thickness. The halo method works best for thick cloud layers, typically optical thickness exceeding 2, and thus compliments conventional lidar which cannot penetrate thick clouds. Cloud layer top and base have been measured independently over the ARM/SGP site using conventional laser ranging (lidar) and the top minus base thickness are compared with a cloud top halo estimate obtained from the NASA/Goddard THOR System (THOR = THickness from Offbeam Returns). THOR flies on the NASA P3, and measures the halo timings from several km above cloud top, at the same time providing conventional lidar cloud top height. The ARM/SGP micropulse lidar provides cloud base height for validation.

Cahalan, R.↗

The Primordial Inflation Explorer (PIXIE) Mission

The Primordial Inflation Explorer (PIXIE) is an Explorer-class mission to map the absolute intensity and linear polarization of the cosmic microwave background and diffuse astrophysical foregrounds over the full sky from frequencies 30 GHz to 6 THz (I cm to 50 I-tm wavelength). PIXIE uses a polarizing Michelson interferometer with 2.7 K optics to measure the difference spectrum between two orthogonal linear polarizations from two co-aligned beams. Either input can view either the sky or a temperature-controlled absolute reference blackbody calibrator. The multimoded optics and high etendu provide sensitivity comparable to kilo-pixel focal plane arrays, but with greatly expanded frequency coverage while using only 4 detectors total. PIXIE builds on the highly successful COBEIFIRAS design by adding large-area polarization-sensitive detectors whose fully symmetric optics are maintained in thermal equilibrium with the CMB. The highly symmetric nulled design provides redundant rejection of major sources of systematic uncertainty. The principal science goal is the detection and characterization of linear polarization from an inflationary epoch in the early universe, with tensor-to-scalar ratio r much less than 10(exp -3). PIXIE will also return a rich data set constraining physical processes ranging from Big Bang cosmology, reionization, and large-scale structure to the local interstellar medium. Keywords: cosmic microwave background, polarization, FTS, bolometer

Kogut, Alan J.↗

Intergalactic Photon Spectra from the Far-IR to the UV Lyman Limit for 0 < z < 6 and the Optical Depth of the Universe to High-Energy Gamma Rays

We calculate the intergalactic photon density as a function of both energy and redshift for 0<z<6 for photon energies from.003 eV to the Lyman limit cutoff at 13.6 eV in a (Omega)CDM universe with (Omega)(Lambda)=0.7 and (Omega)m=0.3. The basic features of our backward-evolution model for galaxies were developed in earlier papers by Malkan & Stecker. With a few improvements, we find that this evolutionary model gives predictions of new deep number counts from Spitzer, as well as a calculation of the spectral energy distribution of the diffuse infrared background, which are in good agreement with the data. We then use our calculated intergalactic photon densities to extend previous work on the absorption of high-energy Gamma-rays in intergalactic space owing to interactions with low-energy photons and the 2.7 K cosmic microwave background radiation. We calculate the optical depth of the universe, Tau , for Gamma-rays having energies from 4 GeV to 100 TeV emitted by sources at redshifts from 0 to 5. We also give an analytic fit with numerical coefficients for approximating (E(Gamma), z). As an example of the application of our results, we calculate the absorbed spectrum of the blazar PKS 2155-304 at z=0.117 and compare it with the spectrum observed by the HESS air Cerenkov Gamma-ray telescope array.

Stecker, F. W.↗

The PACE-MAPP Algorithm: Coupled Ocean/Aerosol Products

The PACE-MAPP algorithm, under development for combined SPEXone, HARP2 and OCI observations from NASA’s future Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) satellite mission, directly inverts the coupled atmosphere-ocean system to retrieve aerosol optical and microphysical properties and ocean optical properties simultaneously. PACE-MAPP thus retrieves the spectrally-resolved inherent optical properties of the Earth’s waters: the spectral particulate scattering coefficient, b_p (λ), the spectral absorption coefficient for particulates and color-dissolved matter, a_tot (λ), and the spectral particulate backscatter efficiency, b ̃_"bp". From these three spectrally-resolved components, we can derive the spectral particulate hemispherical backscattering coefficient b_bp (λ) and the spectral diffuse attenuation coefficient K_"d" (λ). Direct comparisons of b_"bp" (532) and K_"d" (532) are made to collocated High-Spectral Resolution Lidar (HSRL) in-water measurements. The PACE-MAPP algorithm was tested using PACE-analog datasets collected by Research Scanning Polarimeter (RSP) observations during the NASA NAAMES (The North Atlantic Aerosols and Marine Ecosystems Study) and SABOR (Ship-Aircraft Bio-Optical Research) airborne campaigns, both of which also include ship-based in situ measurements.

Snorre Alfred Moen Stamnes↗

Molecular and atomic clouds associated with infrared cirrus in Ursa Major

Observations of CO and H I revealed that in Ursa Major the high-latitude far-infrared 'cirrus' emission discovered by the Infrared Astronomical Satellite comes from molecular and atomic clouds. These clouds differ sufficiently from the large clouds in the Galactic plane so that the ratio of H2 column density to velocity-integrated CO radiation temperature, N(H2)/W(CO), derived from Galactic plane surveys, may not apply to them. On the assumption of a constant gas-to-dust ratio, it is argued that the cirrus emission in Ursa Major is a good mass tracer, since both the atomic and the molecular gas are probably optically thin at visual wavelengths, and the grains are heated not by local sources but by the background field of Galactic starlight. The N(H2)/W(CO) ratio thus derived for those diffuse clouds, is significantly lower than the ratio applicable to Galactic plane surveys.

De Vries, Hendrik Willem↗

Measurements of diffusion limited solidification at varying gravity

The environment of the NASA KC-135 low gravity aircraft was employed to examine the effects of g-jitter on the growth of a solidification diffusion layer for 28 wt pct NH4Cl-H2O, a metal alloy model material. The hypothesis that jitter (vibrational) effects account for previously observed low gravity growth anomalies was investigated by comparing optical data (central dark ground method) for 10-squared g(e) (earth's gravity) KC-135 growth conditions and 1 g(e) laboratory conditions. Accelerometer data obtained during the flight program showed the KC-135 low gravity environment to have extreme levels of jitters.

Mccay, T. D.↗

Evidence for a multiphase, inhomogeneous interstellar medium in damped Ly alpha systems

The large optical depth in absorption of the Ly-alpha line in damped Ly-alpha systems implies that the emission line produced by H2 regions is very broad, since the number of diffusions is very large. The emission lines observed in DLy-alpha systems are narrow, a fact that can only be explained if the emission comes from the outer layers alone, or if the interstellar medium (ISM) is clumpy and multiphase. It is shown how discrete, cold H1 clouds embedded in a hot, fully ionized phase, produce narrow lines. This might provide evidence for a supernova remnant SNR-dominated ISM at high redshift, in agreement with the observed metallicity and chemical evolution models. Other high redshift galaxies also offer evidence for such a multiphase, in homogeneous ISM.

Valls-Gabaud, David↗