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At least 595 records · Page 33

Design of a magnetic circuit for a cryogenic undulator in Taiwan photon source

The plan for beamlines in Phase II at Taiwan Photon Source is to construct two new BioSAXS and nano-ARPES beamlines. A highly brilliant light source can be produced with a cryogenic undulator, and many synchrotron facilities have been developed and operated with these in their storage rings. The development of a cryogenic undulator became a target for a light source in TPS phase II. A cryogenic undulator with period of length 15 mm will be made in a hybrid magnetic structure, and use PrFeB permanent-magnet materials. A maximum magnetic field 1.31 T is estimated at gap 4 mm and temperature about 100 K. The spectral performance of a TPS cryogenic undulator is presented in this paper.

43 PARTICLE ACCELERATORS↗

Site Occupancy Preference and Magnetic Properties in Nd 2 (Fe,Co) 14 B

Partial replacement of Fe by Co is an effective method to increase Curie temperature (T C ) , which improves the thermal stability of magnetic properties in Nd 2 Fe 14 B-based permanent magnets. The correlation between Fe substitution and magnetic properties has been studied in Nd 2 (Fe,Co) 14 B via a first-principles calculation. The calculated Fe substitution energies indicate that the Co atoms avoid the 8 j 2 site, which agrees with the experiments. The Co atoms are ferromagnetically coupled with Fe sublattice and show magnetic moments of about 1.2 to 1.7 μ B at different crystallographic sites, less than that of Fe (2.1–2.7 μ B ), resulting in the decrease in total magnetization at ground state (0 K) with increasing Co content. The effective exchange interaction parameter, derived from the energy difference between varied magnetic structures, increases from 7.8 meV to 17.0 meV with increasing Co content from x = 0 to x = 14 in Nd 2 Fe 14–x Co x B. This change in the effective exchange interaction parameter is responsible for the enhancement of T C in Nd 2 (Fe,Co) 14 B. The total magnetization at 300 K, derived from mean-field theory, shows a peak maximum value at x = 1 in Nd 2 Fe 14–x Co x B. The phenomenon results from the interplay between the reduction of the magnetic moment in the Fe(Co) sublattice and the enhancement of T C with increasing Co content.

36 MATERIALS SCIENCE↗

Bias-field equalizer for bubble memories

Magnetoresistive Perm-alloy sensor monitors bias field required to maintain bubble memory. Sensor provides error signal that, in turn, corrects magnitude of bias field. Error signal from sensor can be used to control magnitude of bias field in either auxiliary set of bias-field coils around permanent magnet field, or current in small coils used to remagnetize permanent magnet by infrequent, short, high-current pulse or short sequence of pulses.

Keefe, G. E.↗

Magnetic and microstructural properties of some lodestones

A lodestone is an iron ore that behaves as a permanent magnet. A protolodestone is an iron ore capable of being charged sufficiently strongly to behave as a permanent magnet. In the present paper, important criteria are established which distinguish lodestones from other iron ores. Magnetic hysteresis-loop data provide evidence that the massive pieces of lodestone behave magnetically as fine intergrowths rather than coarse multidomain material. This means that the iron ores have been magnetically hardened. The nature and scale of the hardening microstructure is illustrated by photo micrographs. The mechanism of charging the protolodestone appears to be either transient magnetic fields with lightning-discharge currents, or presently obscure aspects of magnetization intensity enhancement associated with maghemitization of massive iron ores.

Wasilewski, P. J.↗

Magnetically self-assembled SrFe12O19/Fe-Co core/shell particles

Epitaxial growth to synthesize core/shell-structured materials is limited because large lattice mismatches are common between materials. Magnetically hard/soft, core/shell-structured materials can be potentially used for rare-earth free permanent magnets, but their synthesis presents a challenge. We report a wet chemistry method to synthesize core/shell structured particles consisting of a magnetically hard SrFe12O19 core and a soft Fe-Co shell, with a lattice mismatch of similar to 100%, which cannot be achieved by conventional epitaxial growth or other alternative methods. When decreasing the size of the magnetically soft Fe-Co nanoclusters to below 5 nm, we show that they can be magnetically attracted by the hard SrFe12O19 to form core/shell structured particles. An AC demagnetization experiment demonstrates the formation mechanism of the core/shell particles, and their magnetic hysteresis loop shows potential for use as rare-earth free permanent magnets. Published by Elsevier B.V.

Xu, X↗

Machine learning assisted search for Fe–Co–C ternary compounds with high magnetic anisotropy

We employ a machine learning (ML)-guided framework to explore rare earth free magnetic materials, specifically focusing on Fe–Co–C ternary compounds for potential use in permanent magnets. Utilizing a specifically trained crystal graph convolutional neural network model, we efficiently screen a vast space of nearly a million substitutional structures to select 620 promising structures for further investigation by first-principles calculation. We predict five low-energy metastable Fe–Co–C compounds with formation energy less than 150 meV/atom above the convex hull. These compounds exhibit high magnetization (Js > 1.0 T) and significant magnetic anisotropy (K1 > 1.0 MJ/m3), making them promising candidates for permanent magnet applications. The phonon calculations indicate these compounds are dynamically stable. Our ML-guided framework demonstrates the utility of rapidly identifying novel materials with tailored magnetic properties.

36 MATERIALS SCIENCE↗

Eddy Current Loss Model Unifying the Effects of Reaction Field and Non-Homogeneous 3-D Magnetic Field

In this article, a new analytical method is proposed to estimate eddy currents inside linear conductive materials. The novel closed-form formulation takes into account the effects of both conductor reaction field that dominates at high frequencies as well as the spatially non-homogeneous nature of the magnetic field penetrating the material. Although the model is suitable for most kinds of permanent magnet machines, it is particularly useful for Surface-mounted Permanent Magnet (SPM) machines where both of these phenomena are prominent. The numerical implementation of the proposed model, which consists of a combination of the method of images and 4-D Fourier transform, is presented. The model is then validated against 2-D and 3-D finite element models (FEMs) for a simple magnetic circuit, showing good agreement. Finally, the eddy current magnet loss in an SPM synchronous machine is evaluated and results are discussed.

Sahu, Raj↗

Advances in Processing, Manufacturing, and Applications of Magnetic Materials

Magnetic materials are increasingly important for many green energy technologies. Probably, the best known of these are permanent magnets. They are used to supply a magnetic field and are widely used in actuators, motors, generators, data storage, and sensors. These are “hard magnets,” meaning that they retain a large permanent magnetization (difficult to be demagnetized), which is what makes them so useful in motors where an opposing magnetic field can be used to push against them. A coercivity (resistance to demagnetization) of ~400 Oe (32,000 A/m) or more is typically the threshold value for a hard magnet and is typical of isotropic sintered ferrite (SrFe 12 O 19 ) such as found in many “refrigerator magnets.” Comparably important soft magnets are useful for directing magnetic fields and can be very easily (de)magnetized. As such, they typically have a coercivity < 12.5 Oe (1000 A/m), and specialized very soft magnets can have coercivities < 0.00125 Oe (1 A/m). Some common applications include coil cores, transformer cores, and magnetic shielding. Additionally, they are important for many AC electrical applications such as inductors, filters, and resonators, particularly at high frequencies up to and including microwaves.

36 MATERIALS SCIENCE↗

Frequency Support of PMSG-WTG Based on Improved Inertial Control

With increasing integrations of large-scale systems based on permanent magnet synchronous generator wind turbine generators (PMSG-WTGs), the overall inertial response of a power system will tend to deteriorate as a result of the decoupling of rotor speed and grid frequency through the power converter as well as the scheduled retirement of conventional synchronous generators. Thus, PMSG-WTGs can provide value to an electric grid by contributing to the system's inertial response by utilizing the inherent kinetic energy stored in their rotating masses and fast power control. In this work, an improved inertial control method based on the maximum power point tracking operation curve is introduced to enhance the overall frequency support capability of PMSG-WTGs in the case of large supply-demand imbalances. Moreover, this method is implemented in the CART2-PMSG integrated model in MATLAB/Simulink to investigate its impact on the wind turbine's structural loads during the inertial response process. Simulation results indicate that the proposed method can effectively reduce the frequency nadir, arrest the rate of change of frequency, and mitigate the secondary frequency drop while imposing no negative impact on the major mechanical components of the wind turbine.

17 WIND ENERGY↗

Hybrid Superconducting Magnetic Bearing (HSMB) for high load devices

Lifting capacities greater than 41 N/cm(exp 2) (60 psi) at 77 K have been achieved with a new type of levitation (hybrid) using a combination of permanent magnets and high quality melt-mixtured YBa2Cu3O(7-delta) (YBCO). The key concept of the hybrid superconducting magnetic bearing (HSMB) is the use of strong magnetic repulsion and attraction from permanent magnets for high levitation or suspension forces in conjunction with a superconductor's flux pinning characteristics to counteract the inherent instabilities in a system consisting of magnets only. To illustrate this concept, radial and axial forces between magnet/superconductor, magnet/magnet, and magnet/superconductor/magnet, were measured and compared for the thrust bearing configuration

Mcmichael, C. K.↗

Axial flux motor

Provided is an axial flux motor including a rotor having a wound ribbon core, the wound ribbon core including a metal amorphous nanocomposite material. The axial flux motor further includes a stator assembly spaced apart from the rotor along a rotation axis of the rotor. The stator assembly includes a body including a metal amorphous nanocomposite material and a plurality of permanent magnets substantially free of rare-earth materials. The plurality of permanent magnets is arranged on the body of the stator assembly.

Simizu, Satoru↗

An Analytical Model for Non-Uniform Magnetic Field Effects on Two-Dimensional Laminar Jet Diffusion Flames

In 1846, Michael Faraday found that permanent magnets could cause candle flames to deform into equatorial disks. He believed that the change in flame shape was caused by the presence of charged particles within the flames interacting with the magnetic fields. Later researchers found that the interaction between the flame ions and the magnetic fields were much too small to cause the flame deflection. Through a force analysis, von Engel and Cozens showed that the change in the flame shape could be attributed to the diamagnetic flame gases in the paramagnetic atmosphere. Paramagnetism occurs in materials composed of atoms with permanent magnetic dipole moments. In the presence of magnetic field gradients, the atoms align with the magnetic field and are drawn into the direction of increasing magnetic field. Diamagnetism occurs when atoms have no net magnetic dipole moment. In the presence of magnetic gradient fields, diamagnetic substances are repelled towards areas of decreasing magnetism. Oxygen is an example of a paramagnetic substance. Nitrogen, carbon monoxide and dioxide, and most hydrocarbon fuels are examples of diamagnetic substances. In order to evaluate the usefulness of these magnets in altering flame behavior, a study has been undertaken to develop an analytical model to describe the change in the flame length of a laminar diffusion jet in the presence of a nonuniform magnetic field.

Calvert, M. E.↗

Motor/Generator and Inverter Characterization for Flywheel System Applications

The Advanced Electrical Systems Development Branch at NASA Glenn Research Center (GRC) has been involved in the research and development of high speed flywheels systems for satellite energy storage and attitude applications. These flywheels will serve as replacement for chemical nickel hydrogen, nickel cadmium batteries and gyroscopic wheels. The advantages of using flywheel systems for energy storage on satellites are high energy density, high power density, long life, deep depth of discharge, and broad operating temperature ranges. A flywheel system for space applications consist of a number of flywheel modules, the motor/generator and magnetic bearing, and an electronics package. The motor/generator electronics package includes a pulse-width modulated inverter that drives the flywheel permanent magnet motor/generator located at one end of the shaft. This summer, I worked under the direct supervision of my mentor, Walter Santiago, and the goal for this summer was to characterize motor generator and inverter attributes in order to increase their viability as a more efficient energy storage source for space applications. To achieve this goal, magnetic field measurements around the motor/generator permanent magnet and the impedance of the motor/generator three phase windings were characterized, and a recreation of the inverter pulse width modulated control system was constructed. The Flywheel modules for space use are designed to maximize energy density and minimize loss, and attaining these values will aid in locating and reducing losses within the flywheel system as a whole, making flywheel technology more attractive for use as energy storage in future space applications.

Tamarcus, Jeffries L.↗

Magnetism of directly ordered Sm-Co clusters

Sm-Co bulk alloys have shown superior permanent-magnet properties, but research on Sm-Co nanoparticles is challenging because of the need to control particle size, size-distribution, crystalline ordering, and phase purity. In the present study, a cluster-deposition method was used to produce Sm-Co nanoparticles having desired crystal structures without the requirement of subsequent high-temperature thermal annealing. Poorly crystallized SmCo5 nanoparticles exhibit a low room-temperature coercivity of only 100 Oe, whereas crystalline SmCo5 and Sm2Co17 nanoparticles show room-temperature coercivities of 2000 and 750 Oe, respectively. The direct synthesis of Sm-Co nanoparticles having sizes of less than 10 nm and a high degree of atomic ordering is an important step toward creating nanoparticle building blocks for permanent-magnets and other significant applications. (C) 2012 American Institute of Physics. [doi:10.1063/1.3677668]

Balamurugan, B↗

Towards synthetic L 1 0 -FeNi: Detecting the absence of cubic symmetry in Laser-Ablated Fe-Ni nanoparticles

The L 1 0 crystal structure underlines an important class of chemically ordered alloys that exhibits uniaxial magnetocrystalline anisotropy. The near-equiatomic L 1 0 -FeNi extracted from meteorites has demonstrated intriguing magnetic properties for permanent magnet applications. However, the synthesis of this chemically ordered non-cubic structure has been a longstanding challenge. Here, in this work, we demonstrate the absence of cubic symmetry in near-equiatomic Fe-Ni nanoparticles synthesized by picosecond-pulsed laser ablation in liquids. The non-cubic phase detected in these particles can only be L 1 0 -FeNi or hexagonal close-packed (HCP) FeNi, and the absence of cubic symmetry was unequivocal. The orientation relationship between the non-cubic phase and the adjacent cubic phase was characterized by a series of transmission electron microscopy (TEM) techniques, which consistently suggests that the formation of the non-cubic phase involves a martensitic transformation process.

36 MATERIALS SCIENCE↗

Electronic, magnetic, and magnetocrystalline anisotropy properties of light lanthanides

Theoretical understanding of interactions between localized and mobile electrons and the crystal environment in light lanthanides is important because of their key role in much needed magnetic anisotropy in permanent magnet materials that have a great impact in automobile and wind turbine applications. We report electronic, magnetic, and magnetocrystalline properties of these basic light lanthanide elements studied from advanced density functional theory (DFT) calculations. We find that the inclusion of onsite 4f electron correlation and spin orbit coupling within the full-potential band structure is needed to understand the unique magnetocrystalline properties of these light lanthanides. The onsite electron correlation, spin orbit coupling, and full potential for the asphericity of charge densities must be taken into account for the proper treatment of 4f states. We find the variation of total energy as a function of lattice constants that indicate multiple structural phases in Ce contrasting to a single stable structure obtained in other light lanthanides. The 4f orbital magnetic moments are partially quenched as a result of crystalline electric field splitting that leads to magnetocrystalline anisotropy. The charge density plots have similar asphericity and environment in Pr and Nd indicating similar magnetic anisotropy. However, Ce and Sm show completely different asphericity and environment as both orbital moments are significantly quenched. In addition, the Fermi surface structures exemplified in Nd indicate structural stability and unravel a cause of anisotropy. The calculated magnetocrystalline anisotropy energy (MAE) reveals competing c-axis and in-plane anisotropies, and also predicts possibilities of unusual structural deformations in light lanthanides. The uniaxial magnetic anisotropy is obtained in the double hexagonal closed pack structures of the most of the light lanthanides, however, the anisotropy is reduced or turned to planar in the low symmetry structures. As a result, through crystal field calculations we also illustrate the crystal field ground state 4f multiplets of light lanthanides.

36 MATERIALS SCIENCE↗

Ferromagnetism of Fe 3 Sn and alloys

Hexagonal Fe 3 Sn has many of the desirable properties for a new permanent magnet phase with a Curie temperature of 725 K, a saturation moment of 1.18 MA/m. and anisotropy energy, K 1 of 1.8 MJ/m 3 . However, contrary to earlier experimental reports, we found both experimentally and theoretically that the easy magnetic axis lies in the hexagonal plane, which is undesirable for a permanent magnet material. One possibility for changing the easy axis direction is through alloying. We used first principles calculations to investigate the effect of elemental substitutions. The calculations showed that substitution on the Sn site has the potential to switch the easy axis direction. Transition metal substitutions with Co or Mn do not have this effect. We attempted synthesis of a number of these alloys and found results in accord with the theoretical predictions for those that were formed. However, the alloys that could be readily made all showed an in-plane easy axis. The electronic structure of Fe 3 Sn is reported, as are some are magnetic and structural properties for the Fe 3 Sn 2 , and Fe 5 Sn 3 compounds, which could be prepared as mm-sized single crystals.

36 MATERIALS SCIENCE↗

Optimization and Comparison of Modern Offshore Wind Turbine Generators Using GeneratorSE 2.0

As the offshore wind industry keeps growing at a rapid pace, developers are bracing themselves for a huge demand in critical rare earth metals which will threaten an already vulnerable supply chain. The wind energy industry is addressing this problem by investing in modern generator technologies that employ magnets with reduced rare earth content and high-field magnets enabled by rare-earth-free superconductors. In this paper we introduce the National Renewable Energy Laboratory's newly advanced GeneratorSE 2.0, which is a design and optimization tool that was developed to investigate the feasibility of such modern generators. Two direct-drive generator topologies with different magnet materials and mounting arrangements are investigated: an outer-rotor, V-shaped interior permanent magnet generator, and an inner-rotor normally conducting armature, paired with a low-temperature superconducting field with race-track coils. These technologies were evaluated for a range of power ratings between 15 and 25 MW, which represent the next generation of offshore wind turbines for both fixed-bottom and floating applications. The analyses indicate a new trend favoring the low-temperature superconducting technology for the direct-drive system.

direct-drive generators↗