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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33

Decomposition of ethylene on small Pd particles

New results have been obtained which contribute to the understanding of hydrocarbon reactions on the surface of highly dispersed metal systems. Small particle of Pd were grown by electron beam evaporation on cleavage planes of high purity natural mica under ultrahigh vacuum conditions. Samples were subsequently characterized by transmission electron microscopy. Average particle sizes ranged from about 1 to 10 nm diameter. The chemisoption and decomposition of C2H4 on the Pd particles was studied using Auger electron spectroscopy and flash thermal desorption. It is shown that (a) C2H4 decomposes on Pd particles at room temperature, (b) specific surface sites are causing decomposition, and (c) the proportion of such active sites is significantly greater for the smaller metal particles. This enhanced reactivity may be due to an increase in the density of step, corner, and edge sites with a decrease in particle size.

Durrer, W. G.↗

Exact Calculation of Nonideal Fields Demonstrates Their Dominance of Injection in Relativistic Reconnection

Magnetic reconnection is an important source of energetic particles in systems ranging from astrophysics to the laboratory. The large separation of spatiotemporal scales involved makes it critical to determine the minimum physical model containing the necessary physics for modeling particle acceleration. Here, by resolving the energy gain from ideal and nonideal magnetohydrodynamic electric fields self-consistently in kinetic particle-in-cell simulations of reconnection, we conclusively show the dominant role of the nonideal field for the early stage of energization known as injection. The importance of the nonideal field increases with magnetization, guide field, and in three dimensions, indicating its general importance for reconnection in natural astrophysical systems. We obtain the statistical properties of the injection process from the simulations, paving the way for the development of extended MHD models capable of accurately modeling particle acceleration in large-scale systems. The novel analysis method developed in this study can be applied broadly to give new insight into a wide range of processes in plasma physics.

79 ASTRONOMY AND ASTROPHYSICS↗

Examination of flow and nonflow factorization methods in small collision systems

Two-particle correlations have been used extensively to study hydrodynamic flow patterns in heavy-ion collisions. In small collision systems, such as $p + p$ and $p + A$, where particle multiplicities are much smaller than in $A + A$ collisions, nonflow effects from jet correlations, momentum conservation, particle decays, etc. can be significant, even when imposing a large pseudorapidity gap between the particles. A number of techniques to subtract the nonflow contribution in two-particle correlations have been developed by experiments at the CERN Large Hadron Collider (LHC) and then used to measure particle flow in $p + p$ and $p + Pb$ collisions. Recently, experiments at the BNL Relativistic Heavy Ion Collider (RHIC) have explored the possibility of adopting these techniques for small collision systems at lower energies. In this paper, we test these techniques using Monte Carlo generators pythia and hijing, which do not include any collective flow, and ampt, which does. We find that it is crucial to examine the results of such tests both for correlations integrated over particle transverse momentum $p_T$ and differentially as a function of $p_T$. Our results indicate reasonable nonflow subtraction for $p + p$ collisions at the highest LHC energies, while failing if applied to $p + p$ collisions at RHIC. In the case of $p + Au$ collisions at RHIC, both hijing and ampt results indicate a substantial over-estimate of nonflow for $p_T ≳ GeV/c$ and hence an underestimate of elliptic flow and overestimate of triangular flow.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Design Evaluation of a Next-Generation High-Temperature Particle Receiver for Concentrating Solar Thermal Applications

High-temperature particle receivers are being developed to achieve temperatures in excess of 700 °C for advanced power cycles and solar thermochemical processes. This paper describes designs and features of a falling particle receiver system that has been evaluated and tested at the National Solar Thermal Test Facility at Sandia National Laboratories. These advanced designs are intended to reduce heat losses and increase the thermal efficiency. Novel features include aperture covers, active air flow, particle flow obstructions, and optimized receiver shapes that minimize advective heat losses, increase particle curtain opacity and uniformity, and reduce cavity wall temperatures. Control systems are implemented in recent on-sun tests to maintain a desired particle outlet temperature using an automated closed-loop proportional–integral–derivative controller. These tests demonstrate the ability to achieve and maintain particle outlet temperatures approaching 800 °C with efficiencies between 60 and 90%, depending on incident power, mass flow, and environmental conditions. Lessons learned regarding the testing of design features and overall receiver operation are also presented.

Mills, Brantley H.↗

Diffusiophoresis in narrow channel flows

We report that flows containing suspended colloidal particles and dissolved solutes are found in a multitude of natural and man-made systems including hydraulic fractures, water filtration systems and microfluidic devices, e.g. those designed for biological or medical applications. In these types of systems, unexpected particle dynamics such as rapid particle transport and focusing has been observed in the presence of local solute gradients due to the cooperating or competing effects of fluid advection and particle diffusiophoresis, the latter driven by local chemical gradients. We develop analytical expressions for the fluid, solute and particle dynamics in long, narrow channels due to the combined influence of pressure-driven channel flow with diffusiophoretic and diffusioosmotic effects. The results confirm a rapid particle focusing effect that can be controlled by manipulating the particle, solute and flow properties, as well as the channel’s geometry and surface chemistry. Thus, we propose a new approach for performing microfluidic zeta potentiometry, as well as techniques for sorting, concentrating and/or capturing particles based on their sizes or zeta potentials. Lastly, we demonstrate that diffusioosmotic effects can be used to pump fluid against a pressure gradient.

42 ENGINEERING↗

Thermal transport in a noncommutative hydrodynamics

We find the hydrodynamic equations of a system of particles constrained to be in the lowest Landau level. We interpret the hydrodynamic theory as a Hamiltonian system with the Poisson brackets between the hydrodynamic variables determined from the noncommutativity of space. We argue that the most general hydrodynamic theory can be obtained from this Hamiltonian system by allowing the Righi-Leduc coefficient to be an arbitrary function of thermodynamic variables. We compute the Righi-Leduc coefficient at high temperatures and show that it satisfies the requirements of particle-hole symmetry, which we outline.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Application of extremum seeking for time-varying systems to resonance control of RF cavities

A recently developed form of extremum seeking for time-varying systems is implemented in hardware for the resonance control of radio-frequency cavities without phase measurements. Normal conducting RF cavity resonance control is performed via a slug tuner, while superconducting TESLA-type cavity resonance control is performed via piezo actuators. The controller maintains resonance by minimizing reflected power by utilizing model-independent adaptive feedback. Unlike standard phase-measurement-based resonance control, the presented approach is not sensitive to arbitrary phase shifts of the RF signals due to temperature-dependent cable length or phasemeasurement hardware changes. The phase independence of this method removes common slowly varying drifts and required periodic recalibration of phase-based methods. A general overview of the adaptive controller is presented along with the proof of principle experimental results at room temperature. Lastly, this method allows us to both maintain a cavity at a desired resonance frequency and also to dynamically modify its resonance frequency to track the unknown time-varying frequency of an RF source, thereby maintaining maximal cavity field strength, based only on power-level measurements.

47 OTHER INSTRUMENTATION↗

Dataset for manuscript "Rotational Memory Function of SPC/E water"

Memory effect are essential for dynamics of condensed materials and are responsible for non-exponential relaxation of correlation functions of dynamic variables through the memory function entering the memory equation. Memory functions of dipole rotations for polar liquids have never been calculated. We present here calculations of memory functions and single-dipole rotations and of the overall system dipole moment for SPC/E water measured by dielectric spectroscopy. The memory functions for single-particle and collective dynamics turn out to be nearly identical. This result validates theories of dielectric spectroscopy in terms of single-particle time correlation function and the connection between the collective and single-particle relaxation times in terms of the Kirkwood factor. The dataset includes single particle and system dipole moments, including their time-dependence.

74 ATOMIC AND MOLECULAR PHYSICS↗

Fast-neutron spectrometer developments

Li6 sandwich-type neutron spectrometer is equipped with proportional counter for particle identification. System uses current-sensitive preamplifiers to minimize pile-up of gamma-ray and particle pulses.

Moler, R. B.↗

Molecular dynamics analysis of particle number fluctuations in the mixed phase of a first-order phase transition

Molecular dynamics simulations are performed for a finite nonrelativistic system of particles with Lennard-Jones potential. We study the effect of liquid-gas mixed phase on particle number fluctuations in coordinate subspace. A metastable region of the mixed phase, the so-called nucleation region, is analyzed in terms of a noninteracting cluster model. Large fluctuations due to spinodal decomposition are observed. They arise due to the interplay between the size of the acceptance region and that of the liquid phase. These effects are studied with a simple geometric model. The model results for the scaled variance of particle number distribution are compared with those obtained from the direct molecular dynamic simulations.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Techno-Economic Optimization of CSP Plants with Free-Falling Particle Receivers

Particle receivers are one of the candidates for the next generation of CSP plants, whose goal is to reduce the levelized cost of electricity (LCOE) to 0.05 $/kWh. This paper presents a techno-economic analysis to study if a CSP system with free-falling particle receiver can achieve this goal. The plant analyzed integrates two ground-based bins to store the excess energy and a supercritical CO2 cycle to generate electricity. The model used for the analysis presents several upgrades to previous particle systems models in order to increase its fidelity, accuracy, and representativeness of an actual system. The main upgrades are the addition of off-design conditions during the annual simulations in all the components and an improved receiver model validated against CFD simulations. The size of the main components is optimized to obtain the system configuration with minimum LCOE. The results show that particle CSP systems can reduce the LCOE to 0.056 $/kWh if the configuration is composed of 1.61 × 106 m2 of heliostats, a 250 m high tower with a 537 m2 falling particle curtain, and 16 h thermal energy storage.

54 ENVIRONMENTAL SCIENCES↗

Autonomous quantum to classical transitions and the generalized imaging theorem

The mechanism of the transition of a dynamical system from quantum to classical mechanics is of continuing interest. Practically it is of importance for the interpretation of multi-particle coincidence measurements performed at macroscopic distances from a microscopic reaction zone. We prove the generalized imaging theorem which shows that the spatial wave function of any multi-particle quantum system, propagating over distances and times large on an atomic scale but still microscopic, and subject to deterministic external fields and particle interactions, becomes proportional to the initial momentum wave function where the position and momentum coordinates define a classical trajectory. Now, the quantum to classical transition is considered to occur via decoherence caused by stochastic interaction with an environment. The imaging theorem arises from unitary Schrödinger propagation and so is valid without any environmental interaction. It implies that a simultaneous measurement of both position and momentum will define a unique classical trajectory, whereas a less complete measurement of say position alone can lead to quantum interference effects.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Gas-grain simulation experiment module conceptual design and gas-grain simulation facility breadboard development

This report delineates the Option portion of the Phase A Gas-Grain Simulation Facility study. The conceptual design of a Gas-Grain Simulation Experiment Module (GGSEM) for Space Shuttle Middeck is discussed. In addition, a laboratory breadboard was developed during this study to develop a key function for the GGSEM and the GGSF, specifically, a solid particle cloud generating device. The breadboard design and test results are discussed and recommendations for further studies are included. The GGSEM is intended to fly on board a low earth orbit (LEO), manned platform. It will be used to perform a subset of the experiments planned for the GGSF for Space Station Freedom, as it can partially accommodate a number of the science experiments. The outcome of the experiments performed will provide an increased understanding of the operational requirements for the GGSF. The GGSEM will also act as a platform to accomplish technology development and proof-of-principle experiments for GGSF hardware, and to verify concepts and designs of hardware for GGSF. The GGSEM will allow assembled subsystems to be tested to verify facility level operation. The technology development that can be accommodated by the GGSEM includes: GGSF sample generation techniques, GGSF on-line diagnostics techniques, sample collection techniques, performance of various types of sensors for environmental monitoring, and some off-line diagnostics. Advantages and disadvantages of several LEO platforms available for GGSEM applications are identified and discussed. Several of the anticipated GGSF experiments require the deagglomeration and dispensing of dry solid particles into an experiment chamber. During the GGSF Phase A study, various techniques and devices available for the solid particle aerosol generator were reviewed. As a result of this review, solid particle deagglomeration and dispensing were identified as key undeveloped technologies in the GGSF design. A laboratory breadboard version of a solid particle generation system was developed and characterization tests performed. The breadboard hardware emulates the functions of the GGSF solid particle cloud generator in a ground laboratory environment, but with some modifications, can be used on other platforms.

Zamel, James M.↗

Maximal temperature in a simple thermodynamical system

Temperature in a simple thermodynamical system is not limited from above. It is also widely believed that it does not make sense talking about temperatures higher than the Planck temperature in the absence of the full theory of quantum gravity. Here, we demonstrate that there exist a maximal achievable temperature in a system where particles obey the laws of quantum mechanics and classical gravity before we reach the realm of quantum gravity. Namely, if two particles with a given center of mass energy come at the distance shorter than the Schwarzschild diameter apart, according to classical gravity they will form a black hole. It is possible to calculate that a simple thermodynamical system will be dominated by black holes at a critical temperature which is about three times lower than the Planck temperature. That represents the maximal achievable temperature in a simple thermodynamical system.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Heat Transfer Phenomena in Concentrating Solar Power Systems.

Concentrating solar power (CSP) utilizes solar thermal energy to drive a thermal power cycle for the generation of electricity. CSP systems are facilitated as large, centralized power plants , such as power towers and trough systems, to take advantage of ec onomies of scale through dispatchable thermal energy storage, which is a principle advantage over other energy generation systems . Additionally, the combination of large solar concentration ratios with high solar conversion efficiencies provides a strong o pportunity of employment of specific power cycles such as the Brayton gas cycle that utilizes super critical fluids such as supercritical carbon dioxide (s CO 2 ) , compared to other sola r - fossil hybrid power plants. A comprehensive thermal - fluids examination is provided by this work of various heat transfer phenomena evident in CSP technologies. These include sub - systems and heat transfer fundamental phenomena evident within CSP systems , which include s receivers, heat transfer fluids (HTFs), thermal storage me dia and system designs , thermodynamic power block systems/components, as well as high - temperature materials. This work provides literature reviews, trade studies, and phenomenological comparisons of heat transfer media (HTM) and components and systems, all for promotion of high performance and efficient CSP systems. In addition, f urther investigations are also conducted that provide advanced heat transfer modeling approaches for gas - particle receiver systems , as well as performance/efficiency enhancement re commendations, particularly for solarized supercritical power systems .

14 SOLAR ENERGY↗

Method for fluidizing and coating ultrafine particles, device for fluidizing and coating ultrafine particles

The invention provides a method for dispersing particles within a reaction field, the method comprising confining the particles to the reaction field using a standing wave. The invention also provides a system for coating particles, the system comprising a reaction zone; a means for producing fluidized particles within the reaction zone; a fluid to produce a standing wave within the reaction zone; and a means for introducing coating moieties to the reaction zone. The invention also provides a method for coating particles, the method comprising fluidizing the particles, subjecting the particles to a standing wave; and contacting the subjected particles with a coating moiety.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Three-dimensional analysis using polygons in particle and heavy ion transport code system (PHITS) - 25504

Recently a function to treat tetrahedral-mesh geometry was introduced in Particle and Heavy Ion Transport code System (PHITS). Owing to this function, three-dimensional analysis using polygons became possible. The work flow of the three-dimensional analysis using a particular polygon object was demonstrated, converting the data into tetrahedral mesh with the tetrahedral-mesh generator TetGen, computing the radiation transport with PHITS, and finally analyzing with three-dimensional data analysis application ParaView. (author)

61 RADIATION PROTECTION AND DOSIMETRY↗

Gamma-ray imaging of Np-237 metal using an organic glass imager

Neutron and gamma-ray imaging systems are deployed within the field of nuclear safeguards for the detection and localization of special nuclear materials and other materials of interest. 237 Np is one of these materials of interest due its presence in spent nuclear fuel and potential for use in nuclear weapons when purified. Here, for the first time, a 6 kg neptunium sphere (98.8 wt% 237 Np) was measured using a dual-particle imager, from the University of Michigan, consisting of organic glass and inorganic scintillators. The novel composition of organic glass scintillator was recently developed at Sandia National Labs and has been used in particle imaging systems due to its time resolution and particle discrimination capabilities. Gamma-ray energy spectra from single and coincident events were extracted and the sequencing of Compton scatter and photoelectric absorption gamma-ray events was used to generate images using simple backprojection. The emissions of interest in this work are the 312 keV and 416 keV gamma rays from 233 Pa, a daughter isotope from the neptunium decay series. The results of this work show that there is close agreement between the true source location in angular space and the converged location from the gamma ray images created using the system. The gamma spectroscopy from single and coincident events also identified the characteristic emission from the daughter isotope and could be used to assist with the identification of 237 Np. Furthermore, successful localization of the source with 5 s of data demonstrates the practical application of the imaging system for imaging and detection of material in weapons-useable quantities.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗