SEARCH · Search NASA
Results for “Pyrolysis”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Promotion of particle formation by resonance-stabilized radicals during hydrocarbon pyrolysis
Not Available
Production of Aliphatic-Linked Polycyclic Hydrocarbons during Radical-Driven Particle Formation from Propyne and Propene Pyrolysis
Not Available
Sustainable marine fuel production through mild hydrotreating of catalytic fast pyrolysis bio-oil
Not Available
Flame spray pyrolysis optimization via statistics and machine learning
Not Available
Ethanol pyrolysis kinetics using H 2 O time history measurements behind reflected shock waves
The thermal decomposition of ethanol has been studied under pyrolytic conditions behind reflected shock waves in the 1250 to 1677 K temperature range, at an average pressure of 1.31 atm for a mixture highly diluted in Ar. A laser absorption technique was utilized to measure H 2 O time-histories, and the detailed kinetics mechanism (AramcoMech2.0) was selected among various models from the literature based on its a priori agreement with the experimental data. Sensitivity and rate-of-production analyses were performed and showed that the C 2 H 5 OH→C 2 H 4 + H 2 O (R1) decomposition pathway is almost the sole reaction contributing to H 2 O formation at the early times under the present conditions, allowing an a priori direct measurement of its rate coefficient k 1 . The rate coefficient was determined to be defined as the Arrhenius equation k 1 (s -1 ) = 3.37 × 10 11 exp (–27174 K/T), which is in very good agreement with Kiecherer et al. (2015), where k 1 was also directly determined under similar conditions. Secondary chemical reactions taking place in the thermal decomposition have very low influence in the H 2 O formation during the time-frame selected, leading to an uncertainty for k 1 of approximately 20%. The full H 2 O time histories are useful for validating the full ethanol kinetics mechanism for future validation.
A comprehensive experimental and improved kinetic modeling study on the pyrolysis and oxidation of propyne
Not Available
Ultrasonic-assisted catalytic transfer hydrogenation for upgrading pyrolysis-oil
Not Available
Plastics to fuel or plastics: Life cycle assessment-based evaluation of different options for pyrolysis at end-of-life
Not Available
Graphitizable Pitch from Microwave Plasma Pyrolysis of Natural Gas
An innovative approach of microwave plasma was utilized to convert natural gas into tar, from which a highly graphitizable pitch was derived using fractional distillation. The natural gas-derived pitch (NGDP) was thoroughly characterized, and the graphitizability of the carbonized NGDP was assessed using polarized light microscopy. The NGDP and, for comparison, needle coke, petroleum coke, and shot coke were subjected to graphitization heat treatment (GR) at 2500 °C. Results indicate that the graphitizability of the NGDP exceeds those of all industrial standard cokes. The GR-NGDP showed the highest degree of graphitization and crystallite size among all samples.
Ambient Temperature NO Adsorber Derived from Pyrolysis of Co-MOF(ZIF-67)
Not Available
Kinetic Study of Polyvinyl Chloride Pyrolysis with Characterization of Dehydrochlorinated PVC
In this paper, we study the kinetics of polyvinyl chloride (PVC) decomposition using a combination of experimental and computational approaches. Here, we develop a simplified kinetic model that contains only two steps: dehydrochlorination of PVC and further decomposition of the PVC residue. The model is consistent with density functional theory (DFT) calculations and experimental data. Dehydrochlorination is an autocatalytic reaction that starts with a tertiary chloride (Cl) and generates hydrogen chloride (HCl) and benzene as the main products. Benzene and HCl formation rates showed similar trends, indicating that HCl likely catalyzes a homolytic carbon-carbon (C-C) bond cleavage, which gives rise to benzene and an aliphatic fragment. We characterized the structure of dehydrochlorinated PVC (PVC residue) by using thermal gravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FTIR), and nuclear magnetic resonance spectroscopy (NMR). FTIR and NMR results indicate that the PVC residue contains 20% quaternary carbon content, indicating a high concentration of cross-linked molecules. We predict that the most probable structure in the cross-linked centers of the PVC residue is cyclohexadiene, which is supported by DFT calculations, FTIR, and NMR.
Pyrolysis Vacuum-Assisted Plasma Ionization Ion Mobility–Mass Spectrometry for Insoluble Polymer Analysis
Wire-based metal additive manufacturing utilizes the ability of additive manufacturing to fabricate complex geometries with high deposition rates (above 7 kg/h), thus finding applications in the fabrication of large-scale components, such as stamping dies. Traditionally, the workhorse materials for stamping dies have been martensitic steels. However, the complex thermal gyrations induced during additive manufacturing can cause the evolution of an inhomogeneous microstructure, which leads to a significant scatter in the mechanical properties, especially the toughness. Therefore, to understand these phenomena, arc-based additive AISI 410 samples were fabricated using robotic gas metal arc welding (GMAW) and were subjected to a detailed characterization campaign. The results show significant scatter in the tensile properties as well as Charpy V-notch impact toughness data, which was then correlated to the microstructural heterogeneity and delta (δ) ferrite formation. Post-processing (austenitizing and tempering) treatments were developed and an ~70% reduction in the scatter of tensile data and a four-times improvement in the toughness were obtained. The changes in mechanical properties were rationalized based on the microstructure evolution during additive manufacturing. Based on these, an outline to tailor the composition of “printable” steels for tooling with isotropic and uniform mechanical properties is presented and discussed.
Ga/ZSM-5 catalyst improves hydrocarbon yields and increases alkene selectivity during catalytic fast pyrolysis of biomass with co-fed hydrogen
An integrated experimental and computational study to understand the catalytic upgrading of biomass vapors into high yield of alkenes.
Ex situ upgrading of pyrolysis vapors over PtTiO 2 : extraction of apparent kinetics via hierarchical transport modeling
Chemical reaction kinetics enable predictive scaling studies and process sensitivity analyses that can substantially accelerate commercial deployment of new catalytic transformation technologies.