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Results for “Rigidity function”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS1974

The viscous lubrication of rolling and sliding rigid cylinders

The viscous lubrication of rolling and sliding cylinders is studied both independently and with the aid of much of the previous work done by other investigators. Building upon the specialized results of others, a problem formulation is obtained which encompasses the general viscous fluid as well as the linear viscous fluid. A uniform solution technique is derived which is adequate for the general problem formulation. Results obtained for three special classes of viscosity functions are presented.

Carlson, S. F.↗
DOE OSTI2023

TRPV4-Rho GTPase complex structures reveal mechanisms of gating and disease

Crosstalk between ion channels and small GTPases is critical during homeostasis and disease, but little is known about the structural underpinnings of these interactions. TRPV4 is a polymodal, calcium-permeable cation channel that has emerged as a potential therapeutic target in multiple conditions. Gain-of-function mutations also cause hereditary neuromuscular disease. Here, we present cryo-EM structures of human TRPV4 in complex with RhoA in the ligand-free, antagonist-bound closed, and agonist-bound open states. These structures reveal the mechanism of ligand-dependent TRPV4 gating. Channel activation is associated with rigid-body rotation of the intracellular ankyrin repeat domain, but state-dependent interaction with membrane-anchored RhoA constrains this movement. Notably, many residues at the TRPV4-RhoA interface are mutated in disease and perturbing this interface by introducing mutations into either TRPV4 or RhoA increases TRPV4 channel activity. Together, these results suggest that RhoA serves as an auxiliary subunit for TRPV4, regulating TRPV4-mediated calcium homeostasis and disruption of TRPV4-RhoA interactions can lead to TRPV4-related neuromuscular disease. These insights will help facilitate TRPV4 therapeutics development.

59 BASIC BIOLOGICAL SCIENCES↗
NASA NTRS1975

Effort of spanwise variation of turbulence on the normal acceleration of airplanes with small span relative to turbulence scale

A rigid airplane with an unswept wing is analyzed. The results show that the power spectrum, relative to that for a one-dimensional turbulence field, is significantly attenuated at the higher frequencies even for airplanes with arbitrarily small ratios of span to scale of turbulence. This attenuation is described by a simple weighting function of frequency that depends only on aspect ratio. The weighting function, together with the attenuation due to the unsteady flow of gust penetration, allows the determination of the average rate of zero crossings for airplanes having very small spans without recourse to an integral truncation which is often required in calculations based on a one-dimensional turbulence field.

Pratt, K. G.↗
NASA NTRS1976

Unsteady flow past wings having sharp-edge separation

A vortex-lattice technique is developed to model unsteady, incompressible flow past thin wings. This technique predicts the shape of the wake as a function of time; thus, it is not restricted by planform, aspect ratio, or angle of attack as long as vortex bursting does not occur and the flow does not separate from the wing surface. Moreover, the technique can be applied to wings of arbitrary curvature undergoing general motion; thus, it can treat rigid-body motion, arbitrary wing deformation, gusts in the freestream, and periodic motions. Numerical results are presented for low-aspect rectangular wings undergoing a constant-rate, rigid-body rotation about the trailing edge. The results for the unsteady motion are compared with those predicted by assuming quasi-steady motion. The present results exhibit hysteretic behavior.

Atta, E. H.↗
NASA NTRS1987

Service-Life Extension of Explosive Escape Devices

Chemical and functional tests yield conservative service-life estimates. Approach to extension of service lives of explosive devices in aircraft escape system developed, supported by testing of representative candidate devices to evaluate quantitatively effects of service, age, and degradation, and to enable responsible, conservative service-life determinations. Five types of explosive components evaluated: rigid and flexible explosive transfer lines; one-way transfers; flexible, linear-shaped charges; and initiation-handles. Extension of service in realistic manner provides both cost savings and increased system reliability.

Bement, L. J.↗
NASA NTRS1987

Effect of helicopter blade dynamics on blade aerodynamic and structural loads

The effect of rotor blade dynamics on aerodynamic and structural loads is examined for a conventional, main-rotor helicopter using a comprehensive rotorcraft analysis (CAMRAD) and flight-test data. The impact of blade dynamics on blade section lift-coefficient time histories is studied by comparing predictions from a rigid-blade analysis and an elastic-blade analysis with helicopter flight test data. The elastic blade analysis better predicts high-frequency behavior of section lift. In addition, components of the blade angle of attack such as elastic blade twist, blade flap rate, blade slope velocity, and inflow are examined as a function of blade mode. Elastic blade motion changed blade angle of attack by a few tenths of a degree, and up to the sixth rotor harmonic. A similar study of the influence of blade dynamics on bending and torsion moments was also conducted. A correlation study comparing predictions from several elastic-blade analyses with flight-test data revealed that an elastic-blade model consisting of only three elastic bending modes (first and second flap and first lag), and two elastic torsion modes was sufficient for good correlation.

Heffernan, Ruth M.↗
NASA NTRS1922

The dead weight of the airship and the number of passengers that can be carried

In order to determine an approximate formula giving the weight of a dead load as a function of the volume (V) of the envelope and of the maximum velocity (v), we will take the relative weight of the various parts of the airship (P(sub v), M, V, A, T(sup 34)), adopting a mean value of the coefficients determined. This formula may be adopted both for semi-rigid airships with suspended nacelle and non-rigid envelope, with or without internal suspensions. It may also be adapted to airships with rigid longitudinal beam, with power units on external supports or in nacelles, and with non-rigid envelopes, with or without internal bracing cables.

CROCCO↗
NASA NTRS2003

Ultra-High Temperature Ceramic Composites for Leading Edges

Ultra-high temperature ceramics (UHTC) have performed unreliably due to material flaws and attachment design. These deficiencies are brought to the fore by the low fracture toughness and thermal shock resistance of UHTC. If these deficiencies are overcome, we are still faced with poor oxidation resistance as a limitation on UHTC applicability to reusable launch vehicles. We have been addressing the deficiencies of UHTC for the past two years via a small task at GRC that is in the Airframe part of the Next Generation Launch Technology Program. Our focus is on composite constructions and functional grading to address the mechanical issues and on composition modification to address the oxidation issue. The progress on approaches to improving oxidation resistance by alloying and functional grading will be reported. In particular, initial tests of tantalum additions have shown potential for major improvement. Results for additional tests at higher temperatures will be presented. These oxidation improvements are being incorporated in the composites approaches. Two fabrication approaches are being persued to produce carbon fiber reinforced UHTC composites: prepregging and rigid perform infiltration. Fabrication procedures, microstructures, and initial mechanical property and oxidation results for composites will be reported.

Levine, Stanley R.↗
NASA NTRS1975

A study of attitude control concepts for precision-pointing non-rigid spacecraft

Attitude control concepts for use onboard structurally nonrigid spacecraft that must be pointed with great precision are examined. The task of determining the eigenproperties of a system of linear time-invariant equations (in terms of hybrid coordinates) representing the attitude motion of a flexible spacecraft is discussed. Literal characteristics are developed for the associated eigenvalues and eigenvectors of the system. A method is presented for determining the poles and zeros of the transfer function describing the attitude dynamics of a flexible spacecraft characterized by hybrid coordinate equations. Alterations are made to linear regulator and observer theory to accommodate modeling errors. The results show that a model error vector, which evolves from an error system, can be added to a reduced system model, estimated by an observer, and used by the control law to render the system less sensitive to uncertain magnitudes and phase relations of truncated modes and external disturbance effects. A hybrid coordinate formulation using the provided assumed mode shapes, rather than incorporating the usual finite element approach is provided.

Likins, P. W.↗
DOE OSTI2021

Low-frequency Raman signature of Ag-intercalated few-layer MoS 2

Density functional theory based calculations and experimental analysis on a limited number of real samples are performed to study how the presence of silver intercalated in the van der Waals gap of few-layer MoS 2 affects the low-frequency Raman active modes of this material. Silver is found to predominantly affect the breathing-like and shear-like vibrational modes of MoS 2 . These modes correspond to quasi-rigid movements of each individual layer with a restoring force (and, in turn, frequency) that is determined by modulations in the weak interlayer interactions. Noticeable red-shifts with increasing Ag concentration are found for all low-frequency modes. This finding indicates the potential for low-frequency vibrations as useful gauges for practical determination of silver concentration using low-frequency Raman spectroscopy. Finally, this work also describes a semi-classical linear chain model that allows to extrapolate results to a large number of layers. Further, first-principles calculations show how Raman spectroscopy can be used to characterize the quality of the two-dimensional interface between MoS 2 and a silver substrate.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Cooperative Self‐Assembly of Pyridine‐2,6‐Diimine‐Linked Macrocycles into Mechanically Robust Nanotubes

Abstract Nanotubes assembled from macrocyclic precursors offer a unique combination of low dimensionality, structural rigidity, and distinct interior and exterior microenvironments. Usually the weak stacking energies of macrocycles limit the length and mechanical strength of the resultant nanotubes. Imine‐linked macrocycles were recently found to assemble into high‐aspect ratio (>10 3 ), lyotropic nanotubes in the presence of excess acid. Yet these harsh conditions are incompatible with many functional groups and processing methods, and lower acid loadings instead catalyze macrocycle degradation. Here we report pyridine‐2,6‐diimine‐linked macrocycles that assemble into high‐aspect ratio nanotubes in the presence of less than 1 equiv of CF 3 CO 2 H per macrocycle. Analysis by gel permeation chromatography and fluorescence spectroscopy revealed a cooperative self‐assembly mechanism. The low acid concentrations needed to induce assembly enabled nanofibers to be obtained by touch‐spinning, which exhibit higher Young's moduli (1.33 GPa) than many synthetic polymers and biological filaments. These findings represent a breakthrough in the design of inverse chromonic liquid crystals, as assembly under such mild conditions will enable the design of structurally diverse and mechanically robust nanotubes from synthetically accessible macrocycles.

Strauss, Michael J.↗
DOE OSTI2019

Investigation of Solar Proton Access Into the Inner Magnetosphere on 11 September 2017

Here, access of solar energetic protons to the inner magnetosphere on 11 September 2017 is investigated by computing the reverse particle trajectories with the Dartmouth geomagnetic cutoff code (Kress et al., 2010). The maximum and minimum cutoff rigidity at each point along the orbit of Van Allen Probe A is numerically computed by extending the code to calculate cutoff rigidity for particles coming from arbitrary direction. Pulse height analyzed (PHA) data have the advantage of providing individual particle energies and effectively excluding background high-energy proton contamination. This technique is adopted to study the cutoff locations for solar protons with different energy. The results demonstrate that cutoff latitude is lower for solar protons with higher energy, consistent with low-altitude vertical cutoffs. Both the observations and numerical results show that proton access into the inner magnetosphere depends strongly on angle between particle arrival direction and magnetic west. Finally, the numerical result is approximately consistent with the observation that the energy of almost all solar protons stays above the minimum cutoff rigidity.

58 GEOSCIENCES↗
DOE OSTI2025

Correlated solvent coordinates accelerate multi-donor proton-coupled electron transfer

The rate of charge transfer within a discrete donor–acceptor (D/A) pair is well-described by semi-classical electron transfer theory, but the effects of multiple equivalent redox sites remain less understood. We report a series of ground-state intramolecular proton-coupled electron transfer (PCET) complexes designed to isolate the effects of donor number, N, while holding geometry, coupling, and driving forces constant. The [Ru(L) 3−N (OH) N ] 2+ complexes incorporate one, two, or three identical phenolic electron donors linked to Ru through rigid phenanthroline bridges (OH = 2,4-di-tert-butyl-6-(1-methyl-1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)phenol). Upon flash photolysis and oxidative quenching with methyl viologen (MV 2+ ), the transient Ru(III) oxidizes an appended phenol by PCET with the hydrogen-bonded imidazole nitrogen atom functioning as the base. The rate increased by 3.4-fold and 5.7-fold (1.7-fold and 1.9-fold after statistical correction) for two- and three-donor complexes compared to the single-donor system. The supra-statistical acceleration is attributed to a reduced effective outer sphere reorganization energy (λ m ) modeled by a partially shared solvent reaction coordinate, in which a subset of solvent dipoles is already oriented to stabilize charge from any donor. The final phenoxyl radical state is localized due to the transfer of a proton, and the recombination reaction with the viologen radical is not accelerated. These results demonstrate the effects of solvent dynamics on intramolecular PCET rates, offering a new strategy for the design of synthetic charge transfer systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

Communication: Programmable self-assembly of thin-shell mesostructures

For this article, we study numerically the possibility of programmable self-assembly of various thin-shell architectures. They include clusters isomorphic to fullerenes C 20 and C 60 , finite and infinite sheets, tube-shaped and toroidal mesostructures. Our approach is based on the recently introduced directionally functionalized nanoparticle platform, for which we employ a hybrid technique of Brownian dynamics with stochastic bond formation. By combining a number of strategies, we were able to achieve a near-perfect yield of the desired structures with a reduced “alphabet” of building blocks. Among those strategies are the following: the use of bending rigidity of the interparticle bond as a control parameter, programming the morphology with a seed architecture, use of chirality-preserving symmetries for reduction of the particle alphabet, and the hierarchic approach.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2025

Annihilation-limited long-range exciton transport in high-mobility conjugated copolymer films

A combination of ultrafast, long-range, and low-loss excitation energy transfer from the photoreceptor location to a functionally active site is essential for cost-effective polymeric semiconductors. Delocalized electronic wavefunctions along π-conjugated polymer (CP) backbone can enable efficient intrachain transport, while interchain transport is generally thought slow and lossy due to weak chain–chain interactions. In contrast to the conventional strategy of mitigating structural disorder, amorphous layers of rigid CPs, exemplified by highly planar poly(indacenodithiophene-co-benzothiadiazole) (IDT-BT) donor-accepter copolymer, exhibit trap-free transistor performance and charge-carrier mobilities similar to amorphous silicon. Here, we report long-range exciton transport in HJ -aggregated IDTBT thin-film, in which the competing exciton transport and exciton–exciton annihilation (EEA) dynamics are spectroscopically separated using a phase-cycling-based scheme and shown to depart from the classical diffusion-limited and strong-coupling regime. In the thin film, we find an annihilation-limited mechanism with ≪100% per-encounter annihilation probability, facilitating the minimization of EEA-induced excitation losses. In contrast, excitons on isolated IDTBT chains diffuse over 350 nm with 0.56 cm 2 s −1 diffusivity, before eventually annihilating with unit probability on first contact. We complement the pump–probe studies with temperature-dependent photocurrent and EEA measurements from 295 K to 77 K and find a remarkable correspondence of annihilation rate and photocurrent activation energies in the 140 K to 295 K temperature range.

Shi, Yuping (ORCID:0000000318289415)↗
NASA NTRS1992

Modified Synthetic-Discriminant-Function Optical Filter

Experiments demonstrated feasibility of synthetic-discriminant-function filter encoded in binary spatial light modulator. Filter is part of optoelectronic apparatus indicating degree of correlation between input image and any number of training images of same object at various positions and orientations. Used in optical correlator to recognize rotated images, or in tracking system to recognize moving vehicle or other substantially rigid object from any direction.

Reid, Max B.↗
NASA NTRS1998

Crash-Energy Absorbing Composite Structure and Method of Fabrication

A stand-alone, crash-energy absorbing structure and fabrication method are provided. A plurality of adjoining rigid cells are each constructed of resin-cured fiber reinforcement and are arranged in a geometric configuration. The geometric configuration of cells is integrated by means of continuous fibers wrapped thereabout in order to maintain the cells in the geometric configuration. The cured part results in a net shape, stable structure that can function on its own with no additional reinforcement and can withstand combined loading while crushing in a desired direction.

Kellas, Sotiris↗