SEARCH · Search NASA
Results for “Solar”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Random poly(3‐hexylthiophene‐ co ‐3‐cyanothiophene‐ co ‐3‐(2‐ethylhexyl)thiophene) copolymers with high open‐circuit voltage in polymer solar cells
ABSTRACT For the purpose of developing poly(3‐hexylthiophene) (P3HT) based copolymers with deep‐lying highest occupied molecular orbital (HOMO) levels for polymer solar cells with high open‐circuit voltage ( V oc ), we report a combined approach of random incorporation of 3‐cyanothiophene (CNT) and 3‐(2‐ethylhexyl)thiophene (EHT) units into the P3HT backbone. This strategy is designed to overcome CNT content limitations in recently reported P3HT‐CNT copolymers, where incorporation of more than 15% of CNT into the polymer backbone leads to impaired polymer solubility and raises the HOMO level. This new approach allows incorporation of a larger CNT content, reaching even lower‐lying HOMO levels. Importantly, a very low HOMO level of −5.78 eV was obtained, representing one of the lowest HOMO values for exclusively thiophene‐based polymers. Lower HOMO levels result in higher V oc and higher power conversion efficiencies (PCE) compared to the previously reported P3HT‐CNT copolymers containing only 3‐hexylthiophene and CNT units. As a result, solar cells based on P3HT‐CNT‐EHT(15:15) , which contains 70% of P3HT, 15% of CNT and 15% of EHT, yield a V oc of 0.83 V in blends with PC 61 BM while preserving high fill factor (FF) and high short‐circuit current density ( J sc ), resulting in 3.6% PCE. Additionally, we explored the effect of polymer number‐average molecular weight ( M n ) on the optoelectronic properties and solar cell performance for the example of P3HT‐CNT‐EHT(15:15). The organic photovoltaic (OPV) performance improves with polymer M n increasing from 3.4 to 6.7 to 9.6 kDa and then it declines as M n further increases to 9.9 and to 16.2 kDa. The molecular weight study highlights the importance of not only the solar cell optimization, but also the significance of individual polymer properties optimization, in order to fully explore the potential of any given polymer in OPVs. The broader ramification of this study lies in potential application of these high band gap copolymers with low‐lying HOMO level in the development of ternary blend photovoltaics as well as tandem OPV. © 2015 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54 , 1526–1536
Improving Prediction of Surface Solar Irradiance Variability by Integrating Observed Cloud Characteristics and Machine Learning
A 5-year, 1-minute resolution observational dataset of clouds and solar radiation was produced that includes two metrics of the variability in surface solar irradiance due to cloud type and fractional sky cover. Multiple regression models were trained to fit observations of surface solar irradiance variability from those two cloud property predictors. We found that ensemble tree-based methods, Random Forest and Gradient Boosting Machine, have the least overfitting issues and showed the best performance with an R2 of 0.42. While the observational data trained in this study was only from one site, the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) Southern Great Plains (SGP) site in Oklahoma, initial comparisons of the seasonality of the statistics suggest that these results are relatively weather regime independent; the generality of such a finding across sites will be tested in future work. The observational data and developed machine learning model are being used to create a numerical weather prediction model parameterization to enable day-ahead solar variability prediction in a computationally efficient way. This is a first step towards creating a new paradigm of predicting day-ahead variability with the potential to provide a new tool to improve grid operation, planning, and resilience.
Modelling heterogeneous interfaces for solar water splitting
The generation of hydrogen from water and sunlight offers a promising approach for producing scalable and sustainable carbon-free energy. The key of a successful solar-to-fuel technology is the design of efficient, long-lasting and low-cost photoelectrochemicalcells (PECs), which are responsible for absorbing sunlight and driving water splitting reactions. To this end, a detailed understanding and control of heterogeneous interfaces between photoabsorbers, electrolytes and catalysts present in PECs is essential. This paper reviews recent progress and open challenges in predicting physicochemical properties of heterogeneous interfaces for solar water splitting applications using first-principles-based approaches, and highlights the key role of these calculations in interpreting increasingly complex experiments.
A simulation of convective dynamo in the solar convective envelope: Maintenance of the solar-like differential rotation and emerging flux
We report the results of a magnetohydrodynamic (MHD) simulation of a convective dynamo in a model solar convective envelope driven by the solar radiative diffusive heat flux. The convective dynamo produces a large-scale mean magnetic field that exhibits irregular cyclic behavior with oscillation time scales ranging from about 5 to 15 yr and undergoes irregular polarity reversals. The mean axisymmetric toroidal magnetic field is of opposite signs in the two hemispheres and is concentrated at the bottom of the convection zone. The presence of the magnetic fields is found to play an important role in the self-consistent maintenance of a solar-like differential rotation in the convective dynamo model. Without the magnetic fields, the convective flows drive a differential rotation with a faster rotating polar region. In the midst of magneto-convection, we found the emergence of strong super-equipartition flux bundles at the surface, exhibiting properties that are similar to emerging solar active regions.
New Limits on Bosonic Dark Matter, Solar Axions, Pauli Exclusion Principle Violation, and Electron Decay from the Majorana Demonstrator
Here, we present new limits on exotic keV-scale physics based on 478 kg d of Majorana Demonstrator commissioning data. Constraints at the 90% confidence level are derived on bosonic dark matter (DM) and solar axion couplings, Pauli exclusion principle violating (PEPV) decay, and electron decay using monoenergetic peak signal limits above our background. We set our most stringent DM constraints for 11.8 keV mass particles, limiting g A e < 4.5 × 10 -13 for pseudoscalars and ( α ' / α ) < 9.7 × 10 -28 for vectors. We also report a 14.4 keV solar axion coupling limit of g$eff\atop{AN}$ × g A e < 3.8 × 10 -17 , a 1/2 β 2 < 8.5 × 10 - 48 limit on the strength of PEPV electron transitions, and a lower limit on the electron lifetime of τ e > 1.2 × 1 0 24 yr for e - → invisible.
Machine Learning for Solar Accessibility: Implications for Low-Income Solar Expansion and Profitability
The solar industry in the US typically uses a credit score such as the FICO score as an indicator of consumer utility payment performance and credit worthiness to approve customers for new solar installations. Using data on over 800,000 utility payment performance and over 5,000 demographic variables, we compare machine learning and econometric models to predict the probability of default to credit-score cutoffs. Here, we compare these models across a variety of measures, including how they affect consumers of different socio-economic backgrounds and profitability. We find that a traditional regression analysis using a small number of variables specific to utility repayment performance greatly increases accuracy and LMI inclusivity relative to FICO score, and that using machine learning techniques further enhances model performance. Relative to FICO, the machine learning model increases the number of low-to-moderate income consumers approved for community solar by 1.1% to 4.2% depending on the stringency used for evaluating potential customers, while decreasing the default rate by 1.4 to 1.9 percentage points. Using electricity utility repayment as a proxy for solar installation repayment, shifting from a FICO score cutoff to the machine learning model increases profits by 34% to 1882% depending on the stringency used for evaluating potential customers.
ROTATION PERIODS FOR COOL STARS IN THE 4 Gyr OLD OPEN CLUSTER M67, THE SOLAR–STELLAR CONNECTION, AND THE APPLICABILITY OF GYROCHRONOLOGY TO AT LEAST SOLAR AGE
We report rotation periods for 20 cool (FGK) main sequence member stars of the 4 Gyr-old open cluster M67 (=NGC 2682), obtained by analyzing data from Campaign 5 of the K2 mission with the Kepler Space Telescope . The rotation periods delineate a sequence in the color–period diagram (CPD) of increasing period with redder color. This sequence represents a cross-section at the cluster age of the surface P = P ( t , M ), suggested in prior work to extend to at least solar age. The current Sun is located marginally (approximately 1 σ ) above M67 in the CPD, as its relative age leads us to expect, and lies on the P = P ( t , M ) surface to within measurement precision. We therefore conclude that the solar rotation rate is normal as compared with cluster stars, a fact that strengthens the solar–stellar connection. The agreement between the M67 rotation period measurements and prior predictions further implies that rotation periods, especially when coupled with appropriate supporting work such as spectroscopy, can provide reliable ages via gyrochronology for other similar FGK dwarfs from the early main sequence to solar age and likely until the main sequence turnoff. The M67 rotators have a rotational age of 4.2 Gyr with a standard deviation of 0.7 Gyr, implying that similar field stars can be age-dated to precisions of ∼17%. The rotational age of the M67 cluster as a whole is therefore 4.2 Gyr, but with a lower (averaged) uncertainty of 0.2 Gyr.
Solar wind rare gas analysis: Trapped solar wind helium and neon in Surveyor 3 material
The He-4 and Ne-20 contents in sections of the Surveyor 3 support strut samples were determined by optical and scanning electron microscopy and are compared to the results of the Apollo solar wind composition (SWC) experiments. The He-4/Ne-20 ratio in the samples from the sunlit side of the strut was approximately 300; the ratios determined in Apollo 12 lunar fines and SWC foil were below 100. The He-4/He-3 ratios were also determined, and the ratio obtained from Surveyor 3 material is higher than those found with Apollo 11 and 12 SWC experiments. The effects of spallation by cosmic rays or solar protons, stripping by cosmic ray or energetic solar alpha particles, recycling of solar wind He and radiogenic Ne, He from terrestrial atmosphere, mass discrimination near the moon, mass dependence of trapping probability, diffusion, and contamination by lunar dust are considered.
The solar wind near the sun - The solar envelope.
Recent observational data and models for the structure of the solar envelope are discussed, with emphasis on those physical processes in the envelope which are decisive in determining solar wind states at 1 AU. Diffusion of relativistic solar flare protons, collisionless damping of a variable flux of hydromagnetic waves, heat transfer from electrons to protons, acceleration by Alfven waves, and magnetic field effects are examined from the viewpoint of possible contributions to solar wind behavior.
Solar array study for solar electric propulsion spacecraft for the Encke rendezvous mission
The work is described which was performed on the design, analysis and performance of a 20 kW rollup solar array capable of meeting the design requirements of a solar electric spacecraft for the 1980 Encke rendezvous mission. To meet the high power requirements of the proposed electric propulsion mission, solar arrays on the order of 186.6 sq m were defined. Because of the large weights involved with arrays of this size, consideration of array configurations is limited to lightweight, large area concepts with maximum power-to-weight ratios. Items covered include solar array requirements and constraints, array concept selection and rationale, structural and electrical design considerations, and reliability considerations.
Comparative evaluation of solar, fission, fusion, and fossil energy resources. Part 1: Solar energy
The utilization of solar energy to meet the energy needs of the U.S. is discussed. Topics discussed include: availability of solar energy, solar energy collectors, heating for houses and buildings, solar water heater, electric power generation, and ocean thermal power.
Solar flare particles - Energy-dependent composition and relationship to solar composition
Plastic and glass track detectors on rockets and Apollo spacecraft have been used to determine the composition of particles from He to Ni at energies from 0.1 to 50 MeV per nucleon in several solar flares of widely varying intensities. At low energies the composition of solar particles is enriched in heavy elements by an amount, relative to the asymptotic high-energy composition, that increases with atomic number from Z = 2 up to at least Z = 50, that decreases with energy, and that varies from flare to flare. At high energies (usually beyond an energy of 5 to 20 MeV per nucleon) the composition becomes independent of energy and, though somewhat variable from flare to flare, approximates the composition of the solar atmosphere. A table of abundances of the even-Z elements from He to Ni (plus N) in solar particles is constructed by averaging the asymptotic high-energy abundances in several flares.
Flat-plate solar-collector performance evaluation with a solar simulator as a basis for collector selection and performance prediction
This paper reports the measured thermal efficiency and evaluation of 23 collectors which differ according to absorber material (copper, aluminum, steel), absorber coating (nonselective black paint, selective copper oxide, selective black nickel, selective black chrome), type of glazing material (glass, Tedlar, Lexan, anti-reflection glass), the use of honeycomb material and the use of vacuum to prevent thermal convection losses. The collectors are given performance rankings based on noon-hour solar conditions and all-day solar conditions. The determination with the simulator of an all-day collector performance is made possible by tests at different incident angles. The solar performance rankings are made based on whether the collector is to be used for pool heating, hot water, absorption air conditioning, heating, or for a solar Rankine machine.
A possible correlation between maxima of the far ultraviolet solar irradiance and central meridian passages of solar magnetic sector boundaries
Satellite observations of the sun over almost 5 yrs show that principally two UV active longitudes have persisted over a significant portion of this observational period. A comparison between the position of solar magnetic sector boundaries and UV enhancements of the sun seems to show, at least during the year 1969, that the UV maxima tend to occur near the times when a solar sector boundary is near central meridian. An estimate of the magnitude of the variable UV solar energy input into the atmosphere resulting from the rotation of active solar longitudes is that for wavelengths less than 175 nm and down to H Lyman-alpha it exceeds the annual variation, whereas at longer wavelengths it is less.
Solar seismology. I - The stability of the solar p-modes
The stability of the radial p-modes of the sun is investigated by computing nonadiabatic eigenvalues and eigenfunctions for a solar envelope model which extends from an inner radius of about 0.3 solar radius out to an optical depth of about 0.0003. The calculations take into account in a crude fashion the response of the convective flux to the oscillation. The dynamical effect of turbulence in the convection zone is parametrized in terms of a turbulent shear viscosity. The results show that if damping by turbulent viscosity is neglected, all modes with periods longer than 6 minutes are unstable. The familiar kappa-mechanism, which operates in the H ionization-H(-) opacity region, is the dominant source of driving of the oscillations. Modes with periods shorter than 6 minutes are stabilized by radiative damping in the solar atmosphere. When turbulent dissipation of pulsational energy is included, all modes are predicted to be stable. However, the margin of stability is very small. In view of the large uncertainty that must be assigned to the estimate of turbulent damping, it is concluded that theoretical calculations cannot unequivocally resolve the question of the stability of the solar p-modes.
Verification test of the MSFC solar simulator using a Honeywell double-covered liquid solar collector
Additional verification data to support the utilization of the MSFC Solar Simulator for testing solar collectors was obtained. The Honeywell double-covered liquid solar collector number 2 for which thermal performance data under natural outdoor conditions had been previously obtained was installed on the Solar Simulator and subjected to a series of eight tests under various conditions of wind flow rate. Although these test conditions were not absolutely identical to those of the outdoor tests, they are considered to be sufficiently representative to provide a basis for an accurate comparative analysis of the data recorded for both test programs.
Preliminary design package for solar collector and solar pump
A solar-operated pump using an existing solar collector, for use on solar heating and cooling and hot water systems is described. Preliminary design criteria of the collector and solar-powered pump is given including: design drawings, verification plans, and hazard analysis.