Search NASA⌕ Search

SEARCH · Search NASA

Results for “Spectroscopic”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 595 records · Page 33

A spectroscopic method for calibration of solar extreme ultraviolet instrumentation

A method of calibrating solar extreme ultraviolet spectrographs in space using coronal emission lines of known relative intensity is presented and demonstrated. This approach is useful for recalibrating orbiting instruments that may be subject to degradation during extended periods of operation. The calibration results are insensitive to the physical distribution of emitting plasma in any likely solar coronal source. It is suggested that this technique may be useful for calibration of spectrographs used in the study of laboratory plasmas.

Neupert, W. M.↗

Spectroscopic measurements of the 8- to 13-micrometer transmission of the upper atmosphere following the El Chichon eruptions

Infrared transmission spectra of the atmosphere above 11-km altitude were obtained at latitudes from 2 deg S to 50 deg N in December 1982. A circular variable-interference filter spectrometer mounted in a Convair 990 (the Galileo II) aircraft was used to obtain spectra of the sun through different air masses. Comparisons of spectra through different air masses provide atmospheric transmission measurements that show not only normal absorption features, such as those from CO2 and O3, but also additional absorption near 8.5 microns consistent with H2SO4 aerosols. The average fractional absorption from latitude 10 deg N to 41 deg N at 8.5 microns was 0.02/air mass, half of which was attributable to aerosols.

Witteborn, F. C.↗

IUE spectrophotometry of the DA4 primary in the short-period white dwarf-red dwarf spectroscopic binary Case 1

Low-resolution ultraviolet International Ultraviolet Explorer spectra of the DA white dwarf Case 1 are presented. The spectra show the presence of the 1400 A feature, already discovered in several other DA stars, and of a shallower trough in the 1550-1700 A range. A model atmosphere analysis of the ultraviolet energy distribution of the Ly-alpha red wing yields T(e) = 13,000 + or - 500 K. Possible interpretations of the 1400 A feature are reviewed. Case 1 is the coolest white dwarf found in a short-period, detached white dwarf-red dwarf binary, and its cooling time is consistent with estimates of the efficiency of angular momentum removal mechanisms in the phases subsequent to common envelope binary evolution.

Sion, E. M.↗

A high resolution spectroscopic study of the oxygen molecule

A high resolution spectrometer which incorporates a narrow line width tunable dye laser was used to make absorption profiles of 57 spectral lines in the Oxygen A-Band at pressures up to one atmosphere in pure O2. The observed line profiles are compared to the Voigt, and a collisionally narrowed, profile using a least squares fitting procedure. The collisionally narrowed profile compares more favorable to the observed profiles. Values of the line strengths and self broadening coeffiencients, determined from the least square fitting process, are presented in tabular form. It is found that the experssion by Watson are in closest agreement with the experimentally determined strengths. The self broadening coefficients are compared with the measurements of several other investigators.

Ritter, K. J.↗

The calibration of photographic and spectroscopic films: A densitometric analysis of IIaO film flown aboard the Space Shuttle 3

Three canisters of IIaO film were prepared along with packets of color film from the National Geographic Society, which were placed on the Space Shuttle. The ultimate aim was to obtain reasonably accurate data concerning the background fogging effects as related to the total environment experience of the film including the groundbased packing and loading of the film from Goddard Space Flight Center to Cape Kennedy. The affects of solar wind, humidity, cosmic rays, the Van Allen Belt radiation exposure, various thermal effects, and reentry and off-loading of the film during takeoff and 8 days, 3 hour 15 minute orbit are of particular interest.

Hammond, E. C., Jr.↗

A CCD System for Photometry of Direct and Spectroscopic Images

A charge-coupled device (CCD) for direct imagery at the focus of a ground-based telescope and for high dispersion spectroscopy of stars is evaluated. The CCD is an RCA SID 53612 thinned, buried channel array of 512x320 30-micron square pixels that are back-illuminated and refrigerated to about -60 C in a rugged, RF-shielded vacuum housing. The double-correlated sampling (integrator) readout system, the Z80 microprocessor readout control system, and the data collection system are described. The readout noise is 120 electron-hole pairs (ehp) per pixel per readout, the thermal dark current is 50 ehp/pixel/sec, and the scale of the 12-bit analog-to-digital converter is 25 ehp/AD unit. Unique features of this system are compared to other astronomical implementations of the same model of CCD.

Frecker, J. E.↗

Spectroscopic observations of selected stellar systems

Spectra of very luminous, high temperature stars, the o-type stars with the largest masses among stars, and the Wolf-Rayet (W-R) stars are studied. These stars are characterized by strong stellar winds which produce signiicant mass loss. The nature and evolution of these winds are studied to learn the densities, velocity structue, ionization balance, and composition. The IUE satellite provides the best way to study these phenomena because many of the most important ground state and excited state lines of common highly ionized species are found in the spectral range.

Conti, P. S.↗

A spectroscopic study of LMC X-4

The orbital radial velocity semi-amplitude of the binary star system LMC X-4 primary was determined to be 37.9 + or - 2.4 km/s from measurements of the hydrogen absorption lines. The semi-amplitude of the He I and He II absorption lines are consistent with this, namely 44.9 + or - 5.0 and 37.3 + or - 5.3 km/s. The phase and shape of the radial velocity curves of the three ions are consistent with a circular orbit and an ephemeris based upon X-ray measurements of the neutron star, with the exception that the He II absorption line radial velocity curve has detectable shape distortion. Measurements of the He II LAMBOA 4686 emission line velocity are consistent with a phase shifted sine wave of semi-amplitude 535 km/s, a square wave of semi-amplitude 407 km/s, or high order harmonic fits. The spectral type was found to be 08.5 IV-V during X-ray eclipse. Variations to types as early as 07 occur, but not as a function or orbital phase. Absorption line peculiarities were noted on 6 of 58 spectra.

Petro, L. D.↗

High-resolution spectroscopic observation of Vela X-1 in the hard X-ray energy range

The first high resolution (1.2 keV FWHM hard X-ray equal to or greater than 20 keV) observation of Vela X-1 is reported. Data were accumulated during a 5 hour balloon flight launched on December 5, 1984. A summed epoch analysis yields a light curve and period (283 sec) consistent with previous measurements. Significant pulsations were present to an energy of 60 keV. No statistically significant features were observed in the energy spectrum and the spectrum is well fit (x sup 2 = 17.8 for 16 d.o.f.) by a simple exponential spectrum with an E folding length of 10.8 + or - 1.0 keV.

Tueller, J.↗

Diurnal variations of atmospheric nitric oxide - Ground-based infrared spectroscopic measurements and their interpretation with time-dependent photochemical model calculations

Total vertical column amounts of NO have been derived from infrared solar absorption spectra recorded near sunrise and sunset with the 0.01 per cm resolution Fourier transform interferometer at the national Solar Observatory on Kitt peak (elevation 2095 m, latitude 31.9 degrees N) on February 23, 1981. The results show an increase in NO concentration in the morning, late afternoon values about 40 percent higher than in the morning, and a decrease in NO concentration prior to sunset. The measured diurnal changes in the total vertical column amount are compared with values obtained from time-dependent photochemical calculations.

Rinsland, C. P.↗

Spectroscopic measurements of atmospheric HCN at northern and southern latitudes

A number of lines belonging to the nu(3) fundamental vibration-rotation band of hydrogen cyanide (HCN) have been identified in atmospheric infrared absorption spectra obtained on high-altitude balloon flights at 32 deg N in 1976 and at 30 deg S in 1977. Quantitative analysis of these spectral features has resulted in the first determination of atmospheric HCN concentrations in the Southern Hemisphere, as well as an independent estimate of stratospheric HCN abundance in the Northern Hemisphere. Within the uncertainties of the present and previous measurements, the Northern Hemisphere result is consistent with those of other investigators, and Southern Hemisphere HCN concentrations appear to be similar to those in the Northern Hemisphere.

Smith, M. A. H.↗

A preliminary spectroscopic assessment of the Spacelab 1/Shuttle optical environment

Attention is given to the Space Lab/Space Shuttle-borne Imaging Spectrometric Observatory's 1150-8000 A spectral data, which was gathered while this instrument package was looking tangentially away from the earth and into the velocity vector. The spectrum is noted to contain the expected atmospheric features, together with bright molecular bands between 6400 and 8000 A. These bands appear to be part of the N2 First Positive system. If most of the emission is due to this system, two excitation mechanisms are implied: direct collisional excitation of the local Shuttle atmosphere by the terrestrial atmosphere, or alternatively a surface interaction which generates metastable N2(A); this subsequently radiates via inverse first positive N2 transitions, followed by first positive transitions.

Torr, M. R.↗

Ultraviolet spectroscopic observations of HD 77581(Vela X-1 = 4U 0900-40)

Ultraviolet spectra of HD 77581 obtained with the IUE satellite in December 1982 and January 1983 are analyzed. The effective temperature is found to be 25,000 + or - 1000 K by comparing its photospheric absorption lines with those in four well-studied B0-B1 supergiants. The distance of 1.9 + or - 0.2 kpc is derived from its luminosity log L/solar-L = +5.53, which is obtained from the effective temperature and from its radius. Circumstellar matter is detected not only in the C IV and Si IV lines but also in Al III, Fe III, C II, and Mg II lines. Profiles of the C IV and Si IV lines show a similar dependence on the orbital phase as in 1978. Two distinct sharp components are found in the shortward-shifted absorptions of the Al III and Fe III lines. Once component is present only in the second half of the orbital period, and its origin may be a 'trailing wake' behind the neutron star. The other component is seen all over the period, and it can be interpreted as originating in a cool expanding region of gas in the orbital plane.

Sadakane, K.↗

Design and technology considerations for the far ultraviolet spectroscopic explorer (FUSE) telescope

An initial assessment of telescope designs satisfying the basic requirements derived for the FUSE mission is presented. A review of recent optical coating technology indicates that normal incidence telescope designs are viable only for wavelengths greater than about 600 A. It is noted that glancing incidence telescope designs, such as the Wolter Type II or thg Wolter-Schwarzschild, are the only designs with acceptable throughputs for the entire FUSE spectral range. Initial design trade studies have established the fundamental framework for the selection of an optimum Type II design satisfying the FUSE science and engineering requirements. It is also found that current optical fabrication technology, e.g., computer controlled polishing, can accommodate meter class glancing incidence components with figure errors commensurate with 1-2 arcsec imaging.

Davila, P. S. M.↗

Spectroscopic observation of Mars

A review is given of what is known about the surface of Mars from reflectance spectroscopy, including some new results and providing an overview of the principles involved. While some form of bound water and/or OH has been known on Mars for many years, a new result presented is the identification of structural OH in a dilute or poorly crystalline magnesian clay. The detection of water ice in the residual north polar cap is noted. Also considered is the role that reflectance spectroscopy will play in the future, from earth and as an important part of the NASA Mars Geosciences/Climatology Orbiter mission.

Singer, R. B.↗

Enhanced Raman spectroscopic study of the coordination chemistry of malononitrile on copper surfaces - Removal of nu(C=N) degeneracy through pi-coordination

Surface-enhanced Raman spectroscopy has been used to study the molecular interactions of malononitrile with copper electrode surfaces. The doubly degenerate CN stretching frequency at 2263/cm is removed when malononitrile adsorbs on copper. Two nu(CN) bands are observed at 2096 and 2204/cm at -0.6 V(SCE). The result shows that only one CN group is pi-coordinated with Cu, which contributes to the observed large shift (-167/cm) in nu(CN). The other CN group is not coordinated to the metal surface.

Loo, B. H.↗