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Results for “Spectrum analysis”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Modeling of human operator dynamics in simple manual control utilizing time series analysis

Time series analysis is applied to model human operator dynamics in pursuit and compensatory tracking modes. The normalized residual criterion is used as a one-step analytical tool to encompass the processes of identification, estimation, and diagnostic checking. A parameter constraining technique is introduced to develop more reliable models of human operator dynamics. The human operator is adequately modeled by a second order dynamic system both in pursuit and compensatory tracking modes. In comparing the data sampling rates, 100 msec between samples is adequate and is shown to provide better results than 200 msec sampling. The residual power spectrum and eigenvalue analysis show that the human operator is not a generator of periodic characteristics.

Agarwal, G. C.↗
NASA NTRS1987

Surface inspection: Research and development

Surface inspection techniques are used for process learning, quality verification, and postmortem analysis in manufacturing for a spectrum of disciplines. First, trends in surface analysis are summarized for integrated circuits, high density interconnection boards, and magnetic disks, emphasizing on-line applications as opposed to off-line or development techniques. Then, a closer look is taken at microcontamination detection from both a patterned defect and a particulate inspection point of view.

Batchelder, J. S.↗
NASA NTRS1994

Mg II absorption in a sample of 56 steep-spectrum quasars

We present an analysis of the statistical properties of Mg II absorbers found in the spectra of 56 intrinsically faint, steep-spectrum radio quasars. We observe for the first time a significant excess of associated Mg II absorbers over the number expected from cosmologically distributed absorbers. This result is in contrast to previous Mg II surveys in which the QSOs were optically selected. This distinction is similar to the result for associated C IV absorbers, in which intrinsically faint, steep-spectrum quasars show excess associated absorption and intrinsically bright QSOs (both radio-loud and radio-quiet) do not show an excess. From our spectra a statistically complete list of absorption lines is derived, and we find 29 Mg II absorbers, 18 of which have not been previously reported. We also determine several characteristics of the quasar emission lines in our spectra. The Mg II absorber distribution as a function of redshift and equivalent width is calculated both for our sample alone and from our sample combined with spectra from other surveys. For the redshift distribution n(z) = n(1 + z)(exp gamma), we obtain, using the combined sample, the values gamma = 1.11 +/- 0.46 for W(min) = 0.6 A and gamma = 2.47 +/- 0.68 for W(min) = 1.0 A. We find that the distribution fo strong absorbers is inconsistent with no evolution at a confindence level between 2.2 and 2.9 sigma, depending on the deceleration parameter q(sub 0). The deviation from no evolution is similar to what had been previously reported.

Aldcroft, Thomas L.↗
NASA NTRS1975

The radio spectrum of Vela supernova and its implication on the propagation of cosmic rays from sources

A detailed analysis of the radio spectrum of the Vela supernova remnant has been carried out to show that the positive spectral shape below 80 MHz can be understood on the basis of Razin effect. This result requires most of the gas in the remnant to be stratified into high density clumps with intense magnetic fields and large cosmic ray densities. The free-free emission is found to be partly responsible for the observed flat radio spectrum. In order to account for both the gamma ray flux above 100 MeV and the radio spectrum, the equipartition between the cosmic ray density and magnetic field seems to break down. The total cosmic ray energy residing in the supernova is found to be about ten to the forty-ninth ergs, which is much smaller than the value obtained without taking into account the stratification of gas.

Stephens, S. A.↗
DOE OSTI2024

The BOSS bispectrum analysis at one loop from the Effective Field Theory of Large-Scale Structure

Abstract We analyze the BOSS power spectrum monopole and quadrupole, and the bispectrum monopole and quadrupole data, using the predictions from the Effective Field Theory of Large-Scale Structure (EFTofLSS). Specifically, we use the one loop prediction for the power spectrum and the bispectrum monopole, and the tree level for the bispectrum quadrupole. After validating our pipeline against numerical simulations as well as checking for several internal consistencies, we apply it to the observational data. We find that analyzing the bispectrum monopole to higher wavenumbers thanks to the one-loop prediction, as well as the addition of the tree-level quadrupole, significantly reduces the error bars with respect to our original analysis of the power spectrum at one loop and bispectrum monopole at tree level. After fixing the spectral tilt to Planck preferred value and using a Big Bang Nucleosynthesis prior, we measureσ 8 = 0.794 ± 0.037,h = 0.692 ± 0.011, and Ω m = 0.311 ± 0.010 to about 4.7%, 1.6%, and 3.2%, at 68% CL, respectively.This represents an error bar reduction with respect to the power spectrum-only analysis of about 30%, 18%, and 13% respectively. Remarkably, the results are compatible with the ones obtained with a power-spectrum-only analysis, showing the power of the EFTofLSS in simultaneously predicting several observables. We find no tension with Planck.

Astronomy & Astrophysics↗
DOE OSTI2020

Boron-Made N 2 : Realization of a B$\equiv$B Triple Bond in the B 2 Al 3 – Cluster

Until now, all B≡B triple bonds have been achieved by adopting two ligands in the L→B≡B←L manner. Herein, we report an alternative route of designing the B≡B bonds based on the assumption that by acquiring two extra electrons, an element with the atomic number Z can have properties similar to those of the element with the atomic number Z + 2. Specifically, we show that due to the electron donation from Al to B, the negatively charged B≡B kernel in the B 2 Al 3 – cluster mimics a triple N≡N bond. Comprehensive computational searches reveal that the global minimum structure of B 2 Al 3 – exhibits a direct B–B distance of 1.553 Å, and its calculated electron vertical detachment energies are in excellent agreement with the corresponding values of the experimental photoelectron spectrum. Chemical bonding analysis revealed one σ and two π bonds between the two B atoms, thus confirming a classical textbook B≡B triple bond, similar to that of N 2 .

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Spontaneously broken subsystem symmetries

We investigate the spontaneous breaking of subsystem symmetries directly in the context of continuum field theories by calculating the correlation function of charged operators. Our methods confirm the lack of spontaneous symmetry breaking in some of the existing continuum field theories with subsystem symmetries, as had previously been established based on a careful analysis of the spectrum. We present some novel continuum field theory constructions that do exhibit spontaneous symmetry breaking whenever allowed by general principles. These interesting patterns of symmetry breaking occur despite the fact that all the theories we study are non-interacting.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2025

Raman spectroscopic investigation of UCl 4

Uranium chloride salts are a proposed fuel source for molten salt reactors (MSRs). However, despite their relevance to nuclear energy, they remain understudied, in part because of their air and moisture sensitivity. Here, this work provides the first Raman spectra of UCl 4 from 45 to 3200 cm −1 collected with 532 and 785 nm excitation sources as well as the assignment of 10 identified peaks to their respective vibrational modes. These Raman bands are compared to those for isostructural ThCl 4 , the compositionally related UCl 3 , and the computed Raman bands for UCl 4 from local vibrational mode analysis. The observed spectrum of UCl 4 is in accord with that of ThCl 4 and the computed spectra of UCl 4 . We posit that the observed differences between the spectra of UCl 4 and UCl 3 are useful in differentiating these species for applications such as in situ monitoring of MSR operations.

Anoxic spectroscopy↗
DOE OSTI2026

Ligand Control of Ultrafast Hot-Carrier Cooling in CdSe Quantum Dots by a Coherent Nonadiabatic Mechanism

Using the results from global modeling of the broadband two-dimensional electronic spectrum and an analysis of the concurrent damping of excited-state vibronic coherences, we show herein that a coherent nonadiabatic mechanism converts the electronic excitation energy of the X3 (1P 3/2 –1P e ) exciton state to ligand vibrations on the <50 fs time scale in oleate- and hexadecylamine-capped CdSe quantum dots. A comparison of the rates for the two ligands suggests that this process is promoted by mid-frequency vibrations of the ligands due to modulation of their electron-donating tendency. An intramolecular vibrational redistribution process then follows on the ∼200 fs time scale with both ligands, which accompanies thermalization in the band-edge X1 (1S 3/2 –1S e ) state and dephasing of the spectator ligand vibrations. These findings suggest that charge-separated intermediates associated with photoinduced charge transfer or triplet–triplet excitation energy transfer will be produced with retention of phase coherence in the vibrations that modulate the charge-transfer character of surface-bound organic acceptors.

14 SOLAR ENERGY↗
DOE OSTI2023

Constraints on hadron resonance gas interactions via first-principles Lattice QCD susceptibilities

We investigate extensions of the Hadron Resonance Gas (HRG) Model beyond the ideal case by incorporating both attractive and repulsive interactions into the model. When considering additional states exceeding those measured with high confidence by the Particle Data Group, attractive corrections to the overall pressure in the HRG model are imposed. On the other hand, we also apply excluded-volume corrections, which ensure there is no overlap of baryons by turning on repulsive (anti)baryon-(anti)baryon interactions. We emphasize the complementary nature of these two extensions and identify combinations of conserved charge susceptibilities that allow us to constrain them separately. In particular, we find interesting ratios of susceptibilities that are sensitive to one correction and not the other. This allows us to constrain the excluded volume and particle spectrum effects separately. Analysis of the available lattice results suggests the presence of both the extra states in the baryonstrangeness sector and the repulsive baryonic interaction, with indications that hyperons have a smaller repulsive core than non-strange baryons. We note that these results are interesting for heavy-ion-collision systems at both the LHC and RHIC.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2020

An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage

Water under nanoconfinement at ambient conditions has exhibited low-dimensional ice formation and liquid–solid phase transitions, but with structural and dynamical signatures that map onto known regions of water’s phase diagram. Using terahertz (THz) absorption spectroscopy and ab initio molecular dynamics, we have investigated the ambient water confined in a supramolecular tetrahedral assembly, and determined that a dynamically distinct network of 9 ± 1 water molecules is present within the nanocavity of the host. The low-frequency absorption spectrum and theoretical analysis of the water in the Ga 4 L 6 12– host demonstrate that the structure and dynamics of the encapsulated droplet is distinct from any known phase of water. A further inference is that the release of the highly unusual encapsulated water droplet creates a strong thermodynamic driver for the high-affinity binding of guests in aqueous solution for the Ga 4 L 6 12– supramolecular construct.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Rutin is a potent senomorphic agent to target senescent cells and can improve chemotherapeutic efficacy

Aging is a major risk factor for most chronic disorders, for which cellular senescence is one of the central hallmarks. Senescent cells develop the pro-inflammatory senescence-associated secretory phenotype (SASP), which significantly contributes to organismal aging and age-related disorders. Development of senotherapeutics, an emerging class of therapeutic agents to target senescent cells, allows to effectively delay aging and alleviate chronic pathologies. Here we report preliminary outputs from screening of a natural medicinal agent (NMA) library for senotherapeutic candidates and validated several agents with prominent potential as senomorphics. Rutin, a phytochemical constituent found in a number of plants, showed remarkable capacity in targeting senescent cells by dampening expression of the full spectrum SASP. Further analysis indicated that rutin restrains the acute stress-associated phenotype (ASAP) by specifically interfering with the interactions of ATM with HIF1α, a master regulator of cellular and systemic homeostasis activated during senescence, and of ATM with TRAF6, part of a key signaling axis supporting the ASAP development toward the SASP. Conditioned media produced by senescent stromal cells enhanced the malignant phenotypes of prostate cancer cells, including in vitro proliferation, migration, invasion, and more importantly, chemoresistance, while rutin remarkably downregulated these gain-of-functions. Although classic chemotherapy reduced tumor progression, the treatment outcome was substantially improved upon combination of a chemotherapeutic agent with rutin. Our study provides a proof of concept for rutin as an emerging natural senomorphic agent, and presents an effective therapeutic avenue for alleviating age-related pathologies including cancer.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2020

Biomineralization of Cu 2 S Nanoparticles by Geobacter sulfurreducens

Biomineralization of Cu has been shown to control contaminant dynamics and transport in soils. However, very little is known about the role that subsurface microorganisms may play in the biogeochemical cycling of Cu. In this study, we investigate the bioreduction of Cu(II) by the subsurface metal-reducing bacterium Geobacter sulfurreducens. Rapid removal of Cu from solution was observed in cell suspensions of G. sulfurreducens when Cu(II) was supplied, while transmission electron microscopy (TEM) analyses showed the formation of electron-dense nanoparticles associated with the cell surface. Energy-dispersive X-ray spectroscopy (EDX) point analysis and EDX spectrum image maps revealed that the nanoparticles are rich in both Cu and S. This finding was confirmed by X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) analyses, which identified the nanoparticles as Cu 2 S. Biomineralization of Cu x S nanoparticles in soils has been reported to enhance the colloidal transport of a number of contaminants, including Pb, Cd, and Hg. However, formation of these Cu x S nanoparticles has only been observed under sulfate-reducing conditions and could not be repeated using isolates of implicated organisms. As G. sulfurreducens is unable to respire sulfate, and no reducible sulfur was supplied to the cells, these data suggest a novel mechanism for the biomineralization of Cu 2 S under anoxic conditions. The implications of these findings for the biogeochemical cycling of Cu and other metals as well as the green production of Cu catalysts are discussed.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Search for Joint Multimessenger Signals from Potential Galactic Cosmic-Ray Accelerators with HAWC and IceCube

The origin of high-energy galactic cosmic rays is yet to be understood, but some galactic cosmic-ray accelerators can accelerate cosmic rays up to PeV energies. The high-energy cosmic rays are expected to interact with the surrounding material or radiation, resulting in the production of gamma-rays and neutrinos. To optimize for the detection of such associated production of gamma-rays and neutrinos for a given source morphology and spectrum, a multimessenger analysis that combines gamma-rays and neutrinos is required. In this study, we use the Multi-Mission Maximum Likelihood framework with IceCube Maximum Likelihood Analysis software and HAWC Accelerated Likelihood to search for a correlation between 22 known gamma-ray sources from the third HAWC gamma-ray catalog and 14 yr of IceCube track-like data. No significant neutrino emission from the direction of the HAWC sources was found. We report the best-fit gamma-ray model and 90% CL neutrino flux limit from the 22 sources. From the neutrino flux limit, we conclude that, for five of the sources, the gamma-ray emission observed by HAWC cannot be produced purely from hadronic interactions. We report the limit for the fraction of gamma-rays produced by hadronic interactions for these five sources.

79 ASTRONOMY AND ASTROPHYSICS↗