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At least 595 records · Page 33

Measurement of tropospheric OH by laser long-path absorption spectroscopy

OH-radicals are measured by laser long-path absorption spectroscopy. A tunable Nd:YAG/dye laser system provides broadbanded light at 308 nm. The beam is expanded to 0.3 m and pointed to an array of retroreflectors placed at a distance of 2800 m. The returning beam is separated from the outgoing beam and focused into a spectrometer of 0.3 pm resolution. A 1024 element diode array is used as a detector. The signal is digitized by a 14 bit analog to digital converter. The ultimate aim is a detection limit of 10(exp 5) molecules cm(exp -3) of OH. However the measurements in 1991 allowed only the recognition of OH absorptions corresponding to 3 x 10(exp 6) OH cm(exp -3) with a signal to noise ratio of two. Improvements of the instrument are under way. The advantages of the DOAS method are: the accuracy of detection is guaranteed because loss of OH radicals within the device is avoided, the rate of OH production by the device is negligible, and absorptions of other trace gases could be corrected for; and the calibration procedure for the device is fast and easy. The disadvantages of the system are: time resolution is about minutes because about ten spectra had to be added to keep the noise level down, the OH concentration is averaged along the whole light path, weight (500 kg) and size (4x4 m) of the device; and approximately 10 l/min of coolant and supply of 8 kW electrical power are necessary.

Kraft, Michael↗

Absolute calibration and atmospheric versus mineralogic origin of absorption features in 2.0 to 2.5 micron Mars spectra obtained during 1993

We obtained new high resolution reflectance spectra of Mars during the 1993 opposition from Mauna Kea Observatory using the UKIRT CGS4 spectrometer. Fifty spectra of 1600-2000 km surface regions and a number of standard star spectra were obtained in the 2.04 to 2.44 micron wavelength region on 4 February 1993 UT. Near-simultaneous observations of bright standard stars were used to perform terrestrial atmospheric corrections and an absolute flux calibration. Using the known magnitude of the stars and assuming blackbody continuum behavior, the flux from Mars could be derived. A radiative transfer model and the HITRAN spectral line data base were used to compute atmospheric transmission spectra for Mars and the Earth in order to simulate the contributions of these atmospheres to our observed data. Also, we examined the ATMOS solar spectrum in the near-IR to try to identify absorption features in the spectrum of the Sun that could be misinterpreted as Mars features. Eleven absorption features were detected in our Mars spectra. Our data provide no conclusive identification of the mineralogy responsible for the absorption features we detected. However, examination of terrestrial spectral libraries and previous high spectral resolution mineral studies indicates that the most likely origin of these features is either CO3(sup 2-), HCO3(-), or HSO4(-) anions in framework silicates or possibly (Fe, Mg)-OH bonds in sheet silicates.

Bell, James F., III↗

Possible spinel absorption bands in S-asteroid visible reflectance spectra

Minor absorption bands in the 0.55 to 0.7 micron wavelength range of reflectance spectra of 10 S asteroids have been found and compared with those of spinel-group minerals using the modified Gaussian model. Most of these S asteroids are consistently shown to have two absorption bands around 0.6 and 0.67 micron. Of the spinel-group minerals examined in this study, the 0.6 and 0.67 micron bands are most consistent with those seen in chromite. Recently, the existence of spinels has also been detected from the absorption-band features around 1 and 2 micron of two S-asteroid reflectance spectra, and chromite has been found in a primitive achondrite as its major phase. These new findings suggest a possible common existence of spinel-group minerals in the solar system.

Hiroi, T.↗

Absorption in 3C 212

3C 212 (Q0855+143) is a red quasar with ambiguous evidence for strong low-energy X-ray absorption in its ROSAT spectrum (Elvis et al. 1994). We combine Einstein and ROSAT data with ultraviolet absorption-line strengths to investigate the physical state of the absorber. We find that a highly ionized absorber (U approximately 0.3) provides a consistent fit to both X-ray and UV data as well as providing a significantly improved fit to the X-ray spectrum. The absorber is outflowing with a velocity of approximately 1600 km/sec with respect to the Mg II emission line, situated outside the broad emission-line region (BELR) and has low density. The alternative blackbody fit to the X-ray data is excluded if the source has not varied, and it is also unable to predict the UV absorption lines. This is the second case of an X-ray absorber identified with a UV absorber (the first one being 3C 351; Mathur et al. 1994) and suggests that UV/X-ray absorbers may be common. This is an exciting possibility as the combination of UV and X-ray constraints is very powerful in determining the physical conditions of an absorber.

Mathur, Smita↗

Lick optical spectra of quasar HS 1946+7658 at 10 kilometers per second resolution Lyman-alpha forest and metal absorption systems

We present optical spectra of the most luminous known quasi stellar object (QSO) HS 1946+7658 (z(sub em) = 3.051). Our spectra have both full wavelength coverage, 3240-10570 A, and in selected regions, either high signal-to-noise ratio, SNR approximately equals 40-100, or unusually high approximately 10 km/sec resolution, and in parts of the Ly alpha forest and to the red of Ly alpha emission they are among the best published. We find 113 Ly alpha systems and six metal-line systems, three of which are new. The metal systems at z(sub abs) = 2.844 and 3.050 have complex velocity structure with four and three prominent components, respectively. We find that the system at z(sub abs) = 2.844 is a damped Ly alpha absorption (DLA) system, with a neutral hydrogen column density of log N(H I) = 20.2 +/- 0.4, and it is the cause of the Lyman limit break at lambda approximately equals 3520 A. We believe that most of the H I column density in this system is in z(sub abs) = 2.8443 component which shows the strongest low-ionization absorption lines. The metal abundance in the gas phase of the system is (M/H) approximately equals -2.6 +/- 0.3, with a best estimate of (M/H) = -2.8, with ionizaion parameter log gamma = -2.75, from a photoionization model. The ratios of the logarithmic abundances of C, O, Al, and Si are all within a factor of 2 of solar, which is important for two reasons. First, we believe that the gas abundances which we measure are close to the total abundances, because the ratio of aluminum to other elements is near cosmic, and Al is a refractory element which depletes very readily like chromium, in the interstellar medium. Second, we do not see the enhancement of O with respect to C of (O/C) approximately equals 0.5-0.9 reported in three partial Lyman limit systems by Reimers et al. (1992) and Vogel & Reimers (1993); we measure (O/C) = -0.06 for observed ions and (O/C) approximately equals 0.2 after ionization corrections, which is consistent with solar abundances. We see C II*(lambda 1335) offset by 15 km/sec with respect to C II(lambda 1334), presumably because the gas density varies from 2 to 8 cm(exp -3) with changing velocity in the DLA system. These densities imply that the damped component is 6-25 pc thick, which is reasonable for a single cloud in a cold spiral disk. They also imply that the cloud is relatively highly ionized with more C III than C II, more O III than O I, and log N(H I) = 20.72, which is 3 times the H I column. The system at z(abs) = 1.7382 is also believed to be damped with N(H I) approximately equals 10(exp 21) cm(exp -2), because we see Cr II, but its Ly alpha line will never be seen because it is below the Lyman limit of the other DLA system. We see a 2.6 sigma lack of Ly alpha forest lines well away from the QSO redshift, which may be a chance fluctuation. We also see a correlation between column density N(H I) and Doppler parameter b for 96 unsaturated Ly Alpha forest absorption lines, and although this correlation persists in the 36 Ly alpha lines which lie in regions where the SNR approximately equals 8-16, we agree with Rauch et al. (1993) that it is probably a bogus effect of low supernova remnant (SNR). The same applies to lines with very low b values: in regions where SNR less than or equal to 8 we see many Ly alpha lines which appear to have 10 less than or equal to b less than or equal to 20, but when 8 less than or equal to SNR less than or equal to 16 we see only one line with b less than or equal to 15 km/sec, and two others which we believe have b less than or equal to 20, with values of 20 and 16 km/sec. Traditional Ly alpha line samples which include all lines which have W/sigma(W) greater than or equal to 4 are not adequate to explore the distribution of the properties of individual clouds, because we need much higher (W/sigma(W)) and SNR to avoid the strong biases.

Fan, Xiao-Ming↗

Hawaii 167: A compact absorption-line object at z = 2.35

During the course of the Hawaii K-band (2.1 micrometer) survey we have detected a compact object, Hawaii 167, lying at a redshift of 2.33, in which are seen both low- and high-ionization absorption lines. In the near-infrared we see broad H alpha emission at a redshift of 2.35 but do not detect the other Balmer lines, (O II) lambda 3727, or (O III) lambda 5007. The absence of strong Mg II or C IV emission in the rest ultraviolet suggests that, at these wavelengths, we may be seeing a poststarburst galaxy rather than a quasar. Indeed, this class of object may be common enough to represent a major episode of galaxy formation, possibly the formation of the spheroids. However, Q0059-2735, the most extreme member of the class of Mg II absorbing broad absorption line quasars, is very similar to the present object, and there may be an evolutionary sequence or some other close connection between Hawaii 167 and the broad absorption line quasars.

Cowie, L. L.↗

The Hubble Space Telescope Quasar Absorption Line Key Project. 10: Galactic H I 21 centimeter emission toward 143 quasars and active Galactic nuclei

Sensitive H I 21 cm emission line spectra have been measured for the directions to 143 quasars and active galactic nuclei (AGNs) chosen from the observing lists for the Hubble Space Telescope (HST) Quasar Absorption Line Key Project. Narrow-band and wide-band data were obtained with the National Radio Astronomy Observatory (NRAO) 43 m radio telescope for each object. The narrow-band data have a velocity resolution of 1 km/s, extend from -220 to +170 km/s, and are corrected for stray 21 cm radiation. The wide-band data have a resolution of 4 km/s and extend from -1000 to +1000 km/s. The data are important for the interpretation of ultraviolet absorption lines near zero redshift in Key Project spectra. Twenty-two percent of the quasars lie behind Galactic high-velocity H I clouds with absolute value of V(sub LSR) greater than 100 km/s whose presence can increase the equivalent width of interstellar absorption lines significantly. This paper contains the emission spectra and measures of the H I velocities and column densities along the sight line to each quasar. We discuss how the measurements can be used to estimate the visual and ultraviolet extinction toward each quasar and to predict the approximate strength of the strong ultraviolet resonance lines of neutral gas species in the HST Key Project spectra.

Lockman, Felix J.↗

Near-infrared absorption spectroscopy of interstellar hydrocarbon grains

We present new 3600 - 2700/cm (2.8 - 3.7 micrometer) spectra of objects whose extinction is dominated by dust in the diffuse interstellar medium. The observations presented here augment an ongoing study of the organic component of the diffuse interstellar medium. These spectra contain a broad feature centered near 3300/cm (3.0 micrometers) and/or a feature with a more complex profile near 2950/cm (3.4 micrometers), the latter of which is attributed to saturated aliphatic hydrocarbons in interstellar grains and is the primary interest of this paper. As in our earlier work, the similarity of the absorption bands near 2950/cm (3.4 micrometers) along different lines of sight and the correlation of these features with interstellar extinction reveal that the carrier of this band lies in the dust in the diffuse interstellar medium (DISM). At least 2.5% of the cosmic carbon in the local interstellar medium and 4% toward the Galactic center is tied up in the carrier of the 2950/cm (3.4 micrometer) band. The spectral structure of the diffuse dust hydrocarbon C-H stretch absorption features is reasonably similar to UV photolyzed laboratory ice residues and is quite similar to the carbonaceous component of the Murchison meteorite. The similarity between the DISM and the meteoritic spectrum suggests that some of the interstellar material originally incorporated into the solar nebula may have survived relatively untouched in primitive solar system bodies. Comparisons of the DISM spectrum to hydrogenated amorphous carbon and quenched carbonaceous composite are also presented. The A(sub V)/tau ratio for the 2950/cm (3.4 micrometer) feature is lower toward the Galactic center than toward sources in the local solar neighborhood (approximately 150 for the Galactic center sources vs. approximately 250 for the local ISM sources). A similar trend has been observed previously for silicates in the diffuse medium by Roche & Aitken, suggesting that (1) the silicate and carbonaceous materials in the DISM may be physically correlated and (2) there is either dust compositional variation in the galaxy or galactic variation in the grain population density distribution. We also note a possible absorption feature near 3050/cm (3.28 micrometers), a wavelength position that is characteristic of polycyclic aromatic hydrocarbons (PAHs).

Pendleton, Y. J.↗

Multiphase gas in quasar absorption-line systems

In the standard model for H I Lyman-limit (LL) quasar absorption-line systems, the absorbing matter is galactic disk and halo gas, heated and photoionized by the metagalactic radiation field produced by active galaxies. In recent Hubble Space Telescope (HST) observations (Reimers et al. 1992; Vogel & Reimers 1993; Reimers & Vogel 1993) of LL systems along the line of sight to the quasar HS 1700+6416, surprisingly high He I/H I ratios and a wide distribution of column densities of C, N, and O ions are deduced from extreme ultraviolet absorption lines. We show that these observations are incompatible with photoionization equilibrium by a single metagalactic ionizing background. We argue that these quasar absorption systems possess a multiphase interstellar medium similar to that of our Galaxy, in which extended hot, collisionally ionized gas is responsible for some or all of the high ionization stages of heavy elements. From the He/H ratios we obtain -4.0 less than or = log U less than or = -3.0, while the CNO ions are consistent with hot gas in collisional ionization equilibrium at log T = 5.3 and (O/H) = -1.6. The supernova rate necessary to produce these heavy elements and maintain the hot-gas energy budget of approximately 10(exp 41.5) ergs/s is approximately 10(exp -2)/yr, similar to that which maintains the 'three-phase' interstellar medium in our own Galaxy. As a consequence of the change in interpretation from photoionized gas to a multiphase medium, the derived heavy-element abundances (e.g., O/C) of these systems are open to question owing to substantial ionization corrections for unseen C V in the hot phase. The metal-line ratios may also lead to erroneous diagnostics of the shape of the metagalactic ionizaing spectrum and the ionizing parameter of the absorbers.

Giroux, Mark L.↗

Vacuum Ultraviolet Absorption Measurements of Atomic Oxygen in a Shock Tube

The absorption of vacuum ultraviolet light by atomic oxygen has been measured in the Electric Arc-driven Shock Tube (EAST) Facility at NASA-Ames Research Center. This investigation demonstrates the instrumentation required to determine atomic oxygen concentrations from absorption measurements in impulse facilities. A shock wave dissociates molecular oxygen, producing a high temperature sample of atomic oxygen in the shock tube. A probe beam is generated with a Raman-shifted ArF excimer laser. By suitable tuning of the laser, absorption is measured over a range of wavelengths in the region of the atomic line at 130.49 nm. The line shape function is determined from measurements at atomic oxygen densities of 3x10(exp 17) and 9x10(exp 17) cm(exp -3). The broadening coefficient for resonance interactions is deduced from this data, and this value is in accord with available theoretical models.

Meyer, Scott Andrew↗

Vacuum Ultraviolet Absorption Measurements of Atomic Oxygen in a Shock Tube

The absorption of vacuum ultraviolet light by atomic oxygen has been measured in the Electric Arc-driven Shock Tube (EAST) Facility at NASA-Ames Research Center. This investigation demonstrates the instrumentation required to determine atomic oxygen concentrations from absorption measurements in impulse facilities. A shock wave dissociates molecular oxygen, producing a high temperature sample of atomic oxygen in the shock tube. A probe beam is generated with a Raman-shifted ArF excimer laser. By suitable tuning of the laser, absorption is measured over a range of wavelengths in the region of the atomic line at 130.49 nm. The line shape function is determined from measurements at atomic oxygen densities of 3 x 10(exp 17) and 9 x 10(exp 17) cm(exp -3). The broadening coefficient for resonance interactions is deduced from this data, and this value is in accord with available theoretical models.

Meyer, Scott Andrew↗

Time-Resolved IR-Absorption Spectroscopy of Hot-Electron Dynamics in Satellite and Upper Conduction Bands in GaP

The relaxation dynamics of hot electrons in the X6 and X7 satellite and upper conduction bands in GaP was directly measured by femtosecond UV-pump-IR-probe absorption spectroscopy. From a fit to the induced IR-absorption spectra the dominant scattering mechanism giving rise to the absorption at early delay times was determined to be intervalley scattering of electrons out of the X7 upper conduction-band valley. For long delay times the dominant scattering mechanism is electron-hole scattering. Electron transport dynamics of the upper conduction band of GaP has been time resolved.

Cavicchia, M. A.↗

Intergalactic Helium Absorption toward High-Redshift Quasars

The recent Hubble Space Telescope (HST) observations of the z(q) = 3.286 quasar Q0302-003 (Jakobsen et at. 1994) and the z(q) = 3.185 quasar Q1935-67 by Tytler (1995) show absorption edges at the redshifted wavelength of He II 304 A. A key goal is to distinguish between contributions from discrete Ly-alpha forest clouds and a smoothly distributed intergalactic medium (IGM). We model the contributions from each of these sources of He II absorption, including the distribution of line Doppler widths and column densities, the 'He II proximity effect' from the quasar, and a self-consistent derivation of the He II opacity of the universe as a function of the spectrum of ionizing sources, with the assumption that both the clouds and the IGM are photoionized. The He II edge can be fully accounted for by He II line blanketing for reasonable distributions of line widths and column densities in the Ly-alpha forest, provided that the ionizing sources have spectral index alpha(s) greater than 1.5, and any He II proximity effect is neglected. Even with some contribution from a diffuse IGM, it is difficult to account for the edge observed by Jakobsen et al. (1994) with a 'hard' source spectrum (alpha(s) less than 1.3). The proximity effect modifies the relative contributions of the clouds and IGM to tau(He II) near the quasar (z approx. less than z(q)) and markedly increases the amount of He II absorption required. This implies, for example, that to account for the He II edge with line blanketing alone, the minimum spectral index alpha(s) must be increased from 1.5 to 1.9. We demonstrate the need for higher resolution observations that characterize the change in transmission as z approaches z(q) and resolve line-free gaps in the continuum. We set limits on the density of the diffuse IGM and suggest that the IGM and Ly-alpha clouds are likely to be a significant repository for dark baryons.

Giroux, Mark L.↗

Radiation Pressure-Driven Magnetic Disk Winds in Broad Absorption Line Quasi-Stellar Objects

We explore a model in which QSO broad absorption lines (BALS) are formed in a radiation pressure-driven wind emerging from a magnetized accretion disk. The magnetic field threading the disk material is dragged by the flow and is compressed by the radiation pressure until it is dynamically important and strong enough to contribute to the confinement of the BAL clouds. We construct a simple self-similar model for such radiatively driven magnetized disk winds, in order to explore their properties. It is found that solutions exist for which the entire magnetized flow is confined to a thin wedge over the surface of the disk. For reasonable values of the mass-loss rate, a typical magnetic field strength such that the magnetic pressure is comparable to the inferred gas pressure in BAL clouds, and a moderate amount of internal soft X-ray absorption, we find that the opening angle of the flow is approximately 0.1 rad, in good agreement with the observed covering factor of the broad absorption line region.

DeKool, Martin↗

X-ray absorption and high redshift quasars

The low energy cut-offs toward radio-loud quasars with z greater than 2, red quasars, and broad absorption line quasars are discussed. The X-ray absorption seems to be common among different types of red shift quasar. The Rosat position sensitive proportional counter (PSPC) spectra of z = 3 quasars and of a red quasar are presented. Broad absorption lines show outflow velocities of up to 0.1 c to 0.2 c. The advantages and the disadvantages of high red shift observations are underlined.

Elvis, Martin↗

Laboratory Evaluation and Application of Microwave Absorption Properties Under Simulated Conditions for Planetary Atmospheres

Radio absorptivity data for planetary atmospheres obtained from spacecraft radio occultation experiments, entry probe radio signal absorption measurements, and earth-based radio astronomical observations can be used to infer abundances of microwave absorbing constituents in those atmospheres, as long as reliable information regarding the microwave absorbing properties of potential constituents is available. The use of theoretically-derived microwave absorption properties for such atmospheric constituents, or using laboratory measurements of such properties taken under environmental conditions which are significantly different than those of the planetary atmosphere being studied, often leads to significant misinterpretation of available opacity data. For example, laboratory measurements completed recently by Kolodner and Steffes (ICARUS 132, pp. 151-169, March 1998, attached as Appendix A) under this grant (NAGS-4190), have shown that the opacity from gaseous H2SO4 under simulated Venus conditions is best described by a different formalism than was previously used. The recognition of the need to make such laboratory measurements of simulated planetary atmospheres over a range of temperatures and pressures which correspond to the altitudes probed by both spacecraft entry probe and orbiter radio occultation experiments and by radio astronomical observations, and over a range of frequencies which correspond to those used in such experiments, has led to the development of a facility at Georgia Tech which is capable of making such measurements. It has been the goal of this investigation to conduct such measurements and to apply the results to a wide range of planetary observations, both spacecraft and earth-based, in order to determine the identity and abundance profiles of constituents in those planetary atmospheres.

Steffes, Paul G.↗

Vacuum Ultraviolet Absorption Measurements of Atomic Oxygen in a Shock Tube

The absorption of vacuum ultraviolet light by atomic oxygen has been measured in the Electric Arc-driven Shock Tube (EAST) Facility at NASA-Ames Research Center. This investigation demonstrates the instrumentation required to determine atomic oxygen concentrations from absorption measurements in impulse facilities. A shock wave dissociates molecular oxygen, producing a high temperature sample of atomic oxygen in the shock tube. A probe beam is generated with a Raman-shifted ArF excimer laser. By suitable tuning of the laser, absorption is measured over a range of wavelengths in the region of the atomic line at 130.49 nm. The line shape function is determined from measurements at atomic oxygen densities of 3 x 10(exp 17) and 9 x 10(exp 17)/cu cm. The broadening coefficient for resonance interactions is deduced from this data, and this value is in accord with available theoretical models.

Meyer, Scott Andrew↗

Compensation for Spherical Geometric and Absorption Effects on Lower Thermospheric Emission Intensities Derived from High Earth Orbit Images

Remote sensing of the atmosphere from high earth orbit is very attractive due to the large field of view obtained and a true global perspective. This viewpoint is complicated by earth curvature effects so that slant path enhancement and absorption effects, small from low earth orbit, become dominant even at small nadir view angles. The effect is further complicated by the large range of local times and solar zenith angles in a single image leading to a modulation of the image intensity by a significant portion of the diurnal height variation of the absorbing layer. The latter effect is significant in particular for mesospheric, stratospheric and auroral emissions due to their depth in the atmosphere. As a particular case, the emissions from atomic oxygen (130.4 and 135.6 nm) and molecular nitrogen (two LBH bands, LBHS from 140 to 160 nm and LBHL from 160 to 180 nm) as viewed from the Ultraviolet Imager (UVI) are examined. The LBH emissions are of particular interest since LBHS has significant 02 absorption while LBHL does not, In the case of auroral emissions this differential absorption, well examined in the nadir, gives information about the height of the emission and therefore the energy of the precipitating particles. Using simulations of the viewing geometry and images from the UVI we examine these effects and obtain correction factors to adjust to the nadir case with a significant improvement of the derived characteristic energy. There is a surprisingly large effect on the images from the 02 diurnal layer height changes. An empirical compensation to the nadir case is explored based on the local nadir and local zenith angles for each portion of the image. These compensations are demonstrated as applied to the above emissions in both auroral and dayglow images and compared to models. The extension of these findings to other instruments, emissions and spectral regions is examined.

Swift, W.↗