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At least 595 records · Page 33

Unified micromechanics of damping for unidirectional and off-axis fiber composites

An integrated micromechanics methodology for the prediction of damping capacity in fiber-reinforced polymer matrix unidirectional composites has been developed. Explicit micromechanics equations based on hysteretic damping are presented relating the on-axis damping capacities to the fiber and matrix properties and fiber volume ratio. The damping capacities of unidirectional composites subjected to off-axis loading are synthesized from on-axis damping values. Predicted values correlate satisfactorily with experimental measurements. The hygro-thermal effect on the damping performance of unidirectional composites caused by temperature and moisture variations is also modeled. The damping contributions from interfacial friction between broken fibers and matrix are incorporated. Finally, the temperature rise in continuously vibrating composite plies is estimated. Application examples illustrate the significance of various parameters on the damping performance of unidirectional and off-axis fiber reinforced composites.

Saravanos, Dimitris A.↗

US computer research networks: Domestic and international telecommunications capacity requirements

The future telecommunications capacity and connectivity requirements of the United States (US) research and development (R&D) community raise two concerns. First, would there be adequate privately-owned communications capacity to meet the ever-increasing requirements of the US R&D community for domestic and international connectivity? Second, is the method of piecemeal implementation of communications facilities by individual researchers cost effective when viewed from an integrated perspective? To address the capacity issue, Contel recently completed a study for NASA identifying the current domestic R&D telecommunications capacity and connectivity requirements, and projecting the same to the years 1991, 1996, 2000, and 2010. The work reported here extends the scope of an earlier study by factoring in the impact of international connectivity requirements on capacity and connectivity forecasts. Most researchers in foreign countries, as is the case with US researchers, rely on regional, national or continent-wide networks to collaborate with each other, and their US counterparts. The US researchers' international connectivity requirements, therefore, stem from the need to link the US domestic research networks to foreign research networks. The number of links and, more importantly, the speeds of links are invariably determined by the characteristics of the networks being linked. The major thrust of this study, therefore, was to identify and characterize the foreign research networks, to quantify the current status of their connectivity to the US networks, and to project growth in the connectivity requirements to years 1991, 1996, 2000, and 2010 so that a composite picture of the US research networks in the same years could be forecasted. The current (1990) US integrated research network, and its connectivity to foreign research networks is shown. As an example of projections, the same for the year 2010 is shown.

Kratochvil, D.↗

Cooperative Research and Development Agreement between National Energy Technology Laboratory and University of Kentucky (Abstract)

The National Energy Technology Laboratory (NETL) and University of Kentucky (Participant) will collaborate in the development of “Deep Learning Potential-based Molecular Dynamics Simulation Investigation of Chemical Conversion-Absorption Coupling of CO 2 at Air-Reactive Deep Eutectic Solvent Interface.” This project is supported by DOE-Office of Science Graduate Student Research (SCGSR) program and managed by Oak Ridge Institute for Science and Education (ORISE). Deep eutectic solvents (DESs) are promising alternative sorbents for direct air capture (DAC) CO 2 due to their low vapor pressure, low corrosion, non-toxicity, relatively low cost, and biodegradable nature. Understanding the CO 2 reaction-transport mechanisms at the interface can help develop cost-effective DAC by DESs with high capacity and stability. The collaboration will investigate the absorption and chemical conversion of CO 2 at the air-DES interface to facilitate the development of novel DAC technology using reactive DESs. The anticipated results will make DAC more efficient, allow more sustainable use of our Nation’s fossil energy resources, and advance NETL’s ongoing CO 2 capture efforts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Development of Position-Sensitive Magnetic Calorimeters for X-Ray Astronomy

Metallic magnetic calorimeters (MMC) are one of the most promising devices to provide very high energy resolution needed for future astronomical x-ray spectroscopy. MMC detectors can be built to large detector arrays having thousands of pixels. Position-sensitive magnetic (PoSM) microcalorimeters consist of multiple absorbers thermally coupled to one magnetic micro calorimeter. Each absorber element has a different thermal coupling to the MMC, resulting in a distribution of different pulse shapes and enabling position discrimination between the absorber elements. PoSMs therefore achieve the large focal plane area with fewer number of readout channels without compromising spatial sampling. Excellent performance of PoSMs was achieved by optimizing the designs of key parameters such as the thermal conductance among the absorbers, magnetic sensor, and heat sink, as well as the absorber heat capacities. Micro fab ri - cation techniques were developed to construct four-absorber PoSMs, in which each absorber consists of a two-layer composite of bismuth and gold. The energy resolution (FWHM full width at half maximum) was measured to be better than 5 eV at 6 keV x-rays for all four absorbers. Position determination was demonstrated with pulse-shape discrimination, as well as with pulse rise time. X-ray microcalorimeters are usually designed to thermalize as quickly as possible to avoid degradation in energy resolution from position dependence to the pulse shapes. Each pixel consists of an absorber and a temperature sensor, both decoupled from the cold bath through a weak thermal link. Each pixel requires a separate readout channel; for instance, with a SQUID (superconducting quantum interference device). For future astronomy missions where thousands to millions of resolution elements are required, having an individual SQUID readout channel for each pixel becomes difficult. One route to attaining these goals is a position-sensitive detector in which a large continuous or pixilated array of x-ray absorbers shares fewer numbers of temperature sensors. A means of discriminating the signals from different absorber positions, however, needs to be built into the device for each sensor. The design concept for the device is such that the shape of the temperature pulse with time depends on the location of the absorber. This inherent position sensitivity of the signal is then analyzed to determine the location of the event precisely, effectively yielding one device with many sub-pixels. With such devices, the total number of electronic channels required to read out a given number of pixels is significantly reduced. PoSMs were developed that consist of four discrete absorbers connected to a single magnetic sensor. The design concept can be extended to more than four absorbers per sensor. The thermal conductance between the sensor and each absorber is different by design and consequently, the pulse shapes are different depending upon which absorber the xrays are received, allowing position discrimination. A magnetic sensor was used in which a paramagnetic Au:Er temperature-sensitive material is located in a weak magnetic field. Deposition of energy from an x-ray photon causes an increase in temperature, which leads to a change of magnetization of the paramagnetic sensor, which is subsequently read out using a low noise dc-SQUID. The PoSM microcalorimeters are fully microfabricated: the Au:Er sensor is located above the meander, with a thin insulation gap in between. For this position-sensitive device, four electroplated absorbers are thermally linked to the sensor via heat links of different thermal conductance. One pixel is identical to that of a single-pixel design, consisting of an overhanging absorber fabricated directly on top of the sensor. It is therefore very strongly thermally coupled to it. The three other absorbers are supported directly on a silicon-nitride membrane. These absorbers are thermally coupled to the sensor via Ti (5 nm)/Au250 nm) metal links. The strength of the links is parameterized by the number of gold squares making up the link. For detector performance, experimentally different pulse-shapes were demonstrated with 6 keV x-rays, which clearly show different rise times for different absorber positions. For energy resolution measurement, the PoSM was operated at 32 mK with an applied field that was generated using a persistent current of 50 mA. Over the four pixels, energy resolution ranges from 4.4 to 4.7 eV were demonstrated.

Bandler, SImon↗

An Agent-Based Model for Analyzing Control Policies and the Dynamic Service-Time Performance of a Capacity-Constrained Air Traffic Management Facility

Simple agent-based models may be useful for investigating air traffic control strategies as a precursory screening for more costly, higher fidelity simulation. Of concern is the ability of the models to capture the essence of the system and provide insight into system behavior in a timely manner and without breaking the bank. The method is put to the test with the development of a model to address situations where capacity is overburdened and potential for propagation of the resultant delay though later flights is possible via flight dependencies. The resultant model includes primitive representations of principal air traffic system attributes, namely system capacity, demand, airline schedules and strategy, and aircraft capability. It affords a venue to explore their interdependence in a time-dependent, dynamic system simulation. The scope of the research question and the carefully-chosen modeling fidelity did allow for the development of an agent-based model in short order. The model predicted non-linear behavior given certain initial conditions and system control strategies. Additionally, a combination of the model and dimensionless techniques borrowed from fluid systems was demonstrated that can predict the system s dynamic behavior across a wide range of parametric settings.

Conway, Sheila R.↗

Performance of High-Resolution Mo/Cu Transition Edge Sensors Fabricated Using a Lift-Off Process

The soft X-ray band below ≈0.5 keV is expected to provide rich information on metallicity, temperature, and distribution of hot gas in our galaxy and the intergalactic medium. Resolving these densely spaced emission lines requires energy resolution on the order of 1--2 eV. The low count rates from diffuse astrophysical sources also necessitate large collection areas, particularly for a sounding rocket instrument with short exposure times and limited resources. This translates to large pixel sizes (about 1 mm 2 ) for a reasonable number of read-out channels. To achieve the required energy resolution with 200 nm thin Au absorbers (heat capacity C about 1 pJ/K), we are developing TES microcalorimeters with very high temperature sensitivity (αI), low enough current sensitivity (βI), and minimal excess noise (M). Out of the various fabrication approaches for the TES bilayer we have explored, the lift-off approach (as pioneered for Mo/Au TES by Joel Weber at NIST) so far is the simplest to execute. The simple square TES geometries we have tested to date show promising results for αI and βI. Measured complex impedance and noise for bare devices without absorbers are well described by two-body thermal models and their excess noise is found to be consistent with predictions for mixed-down Johnson noise by Wessels et al. More sensitive measurements with larger heat capacity are planned to accurately determine excess noise. In this paper, we give an overview of the process and summarize results of our detailed characterization measurements for thermal conductance G, αI, βI, and noise for several devices across a range of bias points.

Felix T Jaeckel↗

Solid State Li Ion Batteries Using Si Composite Anodes

Solid Power has teamed with Argonne National Laboratory (ANL) to develop an all solid-state lithium-ion battery (ASSB), enabled by a high-capacity Si anode and a solid state electrolyte (SSE). Replacing liquid electrolytes with solid electrolytes addresses the calendar life challenges that currently limit the widespread adoption of Si anodes. In this project, Si-SSE composite materials have been developed with a specific capacity >1500 mAh/g (at electrode level). A Si anode was coated by using a roll-to-roll process. All-solid-state NMC-Si pouch cells have been assembled and tested. Cycle life of 1100 at 100% DOD has been demonstrated in the solid state Si pouch cell. Excellent calendar life is achieved in the cell via a high temperature storage test.

25 ENERGY STORAGE↗

Technical, economic, and load-following capabilities assessment of grid-connected geothermal and geothermal-solar hybrid systems

The technical and economic performance as well as the load-following capabilities of grid-connected geothermal hybrid systems were assessed in this work. The analyzed geothermal hybrid configuration is composed of a binary geothermal plant integrated with a concentrating solar-thermal system and underground thermal energy storage (UTES) through a primary heat exchanger. Physics-based models for the hybrid system for plant generation capacities of 1, 25, and 50 MW were developed from validated models for each subsystem. Also, an economic model was developed that accounts for different hybrid system capabilities, solar field sizes, and thermal storage duration. The advantage of the geothermal hybrid system was assessed by comparing the performance with the baseline benchmark geothermal plant with a similar configuration and generation capacity. It was found that hybridizing geothermal plants with concentrating solar and thermal energy storage not only improves the thermal efficiency by up to 8 percentage points when additional heat from the solar-UTES loop rises the evaporator temperatures from 70 to 125 °C, but also enhances the load-following capability for the geothermal plant, which can meet a typical residential load profile with a power rate of change 0.25 kW/s with an absolute error under 13 kW for a 1 MW plant. Other benefits of hybridization include resource preservation and a potential LCOE reduction of up to 56% for a 50 MW geothermal hybrid plant having a 50% solar share, a 1.4 solar multiple, and 24-h storage capacity. The results presented in this work demonstrate that hybridizing geothermal systems transforms them into a flexible and cost-effective solution for addressing the dynamic requirements of modern electric grids.

15 GEOTHERMAL ENERGY↗

A Review of Remote Welding and Nondestructive Examination Technologies for the DOE Standard Canister

The U.S. Department of Energy (DOE) manages a wide variety of spent nuclear fuel (SNF) that poses a unique management challenge. To help address this challenge, the DOE Standard Canister (DOESC), designed to remain sealed during handling, storage, transportation, and disposal, was conceptualized as a standardized containment vessel to accommodate DOE-managed SNF. Since 1999, several welding and examination processes have been independently developed for the DOESC’s closure welds. However, neither the DOESC nor these processes have been realized in an operational capacity. This review paper seeks to present and compare previously developed DOESC closure weld, nondestructive examination, and repair processes and technologies. Specific processes developed for the Idaho Spent Fuel Facility, in preparation for the Yucca Mountain geological repository, and the recent Road-Ready Demonstration Project are discussed. Further, specific focus is given to how different operating constraints and the American Society of Mechanical Engineers Boiler and Pressure Vessel Code (BPVC) have driven certain welding and nondestructive examination requirements. Historical DOESC welding and examination strategies are assessed against current regulatory and BPVC requirements. The comparison of welding processes, technologies, and DOESC designs presented in this review paper will inform further construction efforts for other commercial and DOE-managed SNF containments, including the DOESC.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Pilot Development Progress to Demonstrate Electric Thermal Energy Storage (ETES) Using Low-Cost Particles

The rapid growth of variable renewable power generation increases the need to economically store electrical energy over durations up to several days in long-duration energy storage (LDES) applications. LDES can bridge the intermittency of increasing variable renewable energy (VRE) and facilitate emission-free dispatchable electricity to improve the resilience of the grid and provide reliable and potentially cost-effective energy. Several energy storage approaches including mechanical, chemical and electrochemical methods are currently deployed or under development. However, LDES requirements pose unique challenges for scalability, energy capacity, and cost. Electro-thermal energy storage (ETES) can store a large capacity of energy with site flexibility and has attracted significant interest for LDES purposes. This paper shows the progress of developing a demonstration test facility for particle ETES technology including pilot-scale component design and fabrication.

25 ENERGY STORAGE↗

A spacecraft mass memory design using self-structured magnetic bubbles

A self-structured multilayered bubble device developed for spacecraft sensor systems is described. The data link buffer mass memory is analyzed, and system characteristics are estimated based on a nominal 1.6 micron bubble diameter. It is shown that a memory of at least 10 billion bits capacity and 30 megabits per second could be developed with conventional spacecraft constraints.

Stermer, R. L., Jr.↗

The Role of Radial Clearance on the Performance of Foil Air Bearings

Load capacity tests were conducted to determine how radial clearance variations affect the load capacity coefficient of foil air bearings. Two Generation III foil air bearings with the same design but possessing different initial radial clearances were tested at room temperature against an as-ground PS304 coated journal operating at 30,000 rpm. Increases in radial clearance were accomplished by reducing the journal's outside diameter via an in-place grinding system. From each load capacity test the bearing load capacity coefficient was calculated from the rule-of-thumb (ROT) model developed for foil air bearings. The test results indicate that, in terms of the load capacity coefficient, radial clearance has a direct impact on the performance of the foil air bearing. Each test bearing exhibited an optimum radial clearance that resulted in a maximum load capacity coefficient. Relative to this optimum value are two separate operating regimes that are governed by different modes of failure. Bearings operating with radial clearances less than the optimum exhibit load capacity coefficients that are a strong function of radial clearance and are prone to a thermal runaway failure mechanism and bearing seizure. Conversely, a bearing operating with a radial clearance twice the optimum suffered only a 20 percent decline in its maximum load capacity coefficient and did not experience any thermal management problems. However, it is unknown to what degree these changes in radial clearance had on other performance parameters, such as the stiffness and damping properties of the bearings.

Radil, Kevin↗

Burst Pressure Solutions of Thin and Thick-Walled Cylindrical Vessels

Pressure vessels (PVs) are widely used in the energy industry. Accurate burst pressure is critical to structural design and safe operation for both thin and thick-walled PVs. The traditional strength theories utilized a single-parameter material property, such as the yield stress or the ultimate tensile stress (UTS) to develop failure models for determining the yield or ultimate pressure carrying capacity in the PV design. The UTS-based Barlow formula is a typical burst pressure model developed from the Tresca strength theory that provides the basis for developing regulation rules and failure models for different industry design codes, such as ASME BPVC, ASME B31.3, and ASME B31G, among others. In order to reduce the conservatism of the Tresca strength model, ASME BPVC recently adapted failure models developed from the von Mises strength theory for the PV design and analysis. It has been commonly accepted that the burst pressure of pipelines depends on the UTS and strain hardening exponent, n, of the pipeline steel. An average shear stress yield theory was thus developed, and the Zhu-Leis solution of burst pressure was obtained as a function of UTS and n for thin-walled line pipes. Experiments showed that the Zhu-Leis solution provides an accurate, reliable prediction of burst pressure for defect-free thin-walled pipes. In order to extend the Zhu–Leis solution to thick-walled cylindrical PVs, this paper defined three new flow stresses, modified the traditional strength theories, and obtained three new burst pressure solutions that are valid for both thin and thick-walled cylindrical vessels. The proposed flow stresses are able to describe the tensile strength and the plastic flow response of PVs for a strain hardening steel. The associated strength theories were then developed in terms of the Tresca, von Mises, and Zhu-Leis yield criteria. From these new strength theories, three burst pressure solutions were obtained for thick-walled cylinders, where the von Mises solution is an upper bound prediction, the Tresca solution is a lower bound prediction, and the Zhu-Leis solution is an intermediate prediction of burst pressure for thick-walled cylinders. Lastly, the proposed burst pressure solutions were evaluated and validated by two large datasets of full-scale burst tests for thick-walled tubes and for thin-walled pipes.

42 ENGINEERING↗

Reversible (De)Intercalation of Hydrated Zn 2+ in Mg 2+ -Stabilized V 2 O 5 Nanobelts with High Areal Capacity

The rechargeable aqueous zinc ion battery (ZIB) is regarded as one of the most promising candidates for large-scale energy storage applications due to its low-cost and eco-friendly properties. However, the development of a suitable cathode operating with high areal capacity and uncovering the relevant reaction mechanisms remain challenging. Herein, the application of Mg 0.26 V 2 O 5 ∙0.73H 2 O (MVO) nanobelts as a ZIB cathode is demonstrated. In situ FT-IR reveals the shift of OH stretching from 3350 cm -1 to 3200 cm -1 , corresponding to the hydration shell of Zn 2+ , while in situ Raman suggests the interlayer charges creening effect, which would boost the intercalation of hydrated Zn 2+ . Density function theory reveals that the hydrated Zn 2+ can lower the Coulombic repulsion at the electrode-electrolyte interface and circumvents the desolvation penalty of hydrated Zn 2+ during the (de)intercalation process. Additionally, excellent structure stability and large interlayer spacing guarantee the highly reversible (de)intercalation of hydrated Zn 2+ . Therefore, the MVO nanobelts exhibit a high areal capacity of 2.12 mAh cm -2 at 0.05 A g -1 , outstanding cycling stability of 2500 cycles at 10 A g -1 with a mass loading of 5 mg cm -2 . Finally, it is believed that the use of hydrated intercalation charge carriers will boost further studies in other multivalent rechargeable batteries.

25 ENERGY STORAGE↗

Long life, rechargeable nickel-zinc battery

A production version of the inorganic separator was evaluated for improving the life of the nickel-zinc system. Nickel-zinc cells (7-10 Ah capacities) of different electrode separator configurations were constructed and tested. The nickel-zinc cells using the inorganic separator encasing the zinc electrode, the nickel electrode, or both electrodes had shorter lives than cells using Visking and cellophane separation. Cells with the inorganic separation all fell below 70% of their theoretical capacity within 30 cycles, but the cells constructed with organic separation required 80 cycles. Failure of the cells using the ceramic separator was irreversible capacity degradation due to zinc loss through cracks developed in the inorganic separator. Zinc loss through the separator was minimized with the use of combinations of the inorganic separator with Visking and cellophane. Cells using the combined separation operated 130 duty cycles before degrading to 70% of their theoretical capacity.

Luksha, E.↗

Offshore Wind Market Report: 2023 Edition

The Offshore Wind Market Report: 2023 Edition provides detailed information on the U.S. and global offshore wind energy industries to inform policymakers, researchers, and analysts about technology, economic, and market trends. The scope of the report covers the status of over 293 global operating offshore wind energy projects as well as the broader global pipeline of projects in various stages of development through December 31, 2022. To provide up-to-date information and discussion on this emerging industry in the United States, this report tracks the significant U.S. domestic industry progress and events from January 1, 2022, through May 31, 2023. The U.S. offshore wind energy project development pipeline has reached a potential generating capacity of over 52 gigawatts, and the industry has seen strong support from state and federal governments (such as from the Inflation Reduction Act of 2022 and the announced Floating Offshore Wind Shot to reduce the cost of floating wind by 70%). There are contracts for over 17 gigawatts of the electricity from these offshore wind projects and state policies are in place to procure over 42 gigawatts by 2040. Although some projects are facing economic headwinds due to rising costs and higher interest rates (corresponding to project cost increases of 11% - 30% in 2022), there has still been significant investment in a domestic supply chain (including manufacturing facilities, new vessels, and upgraded or planned ports). Technologies continue to evolve as offshore wind turbines in the 15-megawatt class advance towards commercial production. Key offshore wind energy market indicators, such as commercial leasing, state energy planning targets, procurement policies, offtake agreements, and federal support for U.S. jobs and supply chain development, point toward sustained market growth when viewed together, but the macroeconomic hurdles facing the first generation of commercial projects could significantly stunt that growth.

17 WIND ENERGY↗

The impact of H2S emissions on future geothermal power generation - The Geysers region, California

The future potential for geothermal power generation in the Geysers region of California is as much as 10 times the current 502 MW(e) capacity. However, environmental factors such as H2S emissions and institutional considerations may play the primary role in determining the rate and ultimate level of development. In this paper a scenario of future geothermal generation capacity and H2S emissions in the Geysers region is presented. Problem areas associated with H2S emissions, H2S abatement processes, plant operations, and government agency resources are described. The impact of H2S emissions on future development and the views of effected organizations are discussed. Potential actions needed to remove these constraints are summarized.

Leibowitz, L. P.↗

Essential effect of the electrolyte on the mechanical and chemical degradation of LiNi 0.8 Co 0.15 Al 0.05 O 2 cathodes upon long-term cycling

Capacity fading during long-term cycling (>1500×) is still a critical challenge for Li-ion batteries that use Ni-rich layered oxides, e.g. LiNi 0.8 Co 0.15 Al 0.05 O 2 (NCA), as the cathode. Microcracks have been previously recognized as one of the primary reasons for the observed capacity fade. Although there exists a generally developed mechanical understanding of microcracks, the role of the electrolyte has not been clearly understood, especially after extended cycling and at the atomic scale. Here, we unveil the microstructural evolution of spherical NCA secondary particles after long-term cycling using scanning transmission electron microscopy accompanied with electron energy loss spectroscopy. In this work, we found that the microcracks initiated and grew through grain boundaries, which then serve as the pathway for electrolyte penetration into secondary NCA particles. Additionally, the rock-salt phase reconstruction is prone to occur at the (003) surfaces of the primary particles or the crack surfaces, largely due to electrolyte (LiPF 6 EC/EMC) corrosion. Crack propagation within the NCA grains is primarily a joint consequence from electrolyte corrosion and mechanical strain during lithiation/delithiation. During extended cycling, due to the distinctive surface facets, the primary grains located in the center of the secondary particles experience more intensive electrolyte corrosion, leading to a reduced contact with nearby particles, impairing the overall capacity. These results establish the initiation and growth mechanism of microcracks and voids in NCA-based cathodes during cycling and point out the role of the electrolyte in affecting the degradation of NCA-based cathodes.

25 ENERGY STORAGE↗