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At least 595 records · Page 33

Techniques for extreme attitude suspension of a wind tunnel model in a magnetic suspension and balance system

Although small scale magnetic suspension and balance systems (MSBSs) for wind tunnel use have been in existence for many years, they have not found general application in the production testing of flight vehicles. One reason for this is thought to lie in the relatively limited range of attitudes over which a wind tunnel model may be suspended. Modifications to a small MSBS to permit the suspension and control of axisymmetric models over angles of attack from less than zero to over ninety degrees are reported. Previous work has shown that existing arrangement of ten electromagnets was unable to generate one of the force components needed for control at extreme attitudes. Examination of possible solutions resulted in a simple alteration to rectify this deficiency. To generate the feedback signals to control the suspended model, an optical position sensing system using collimated laser beams and photodiode arrays was installed and tested. An analytical basis was developed for distributing the demands for force and moment needed for model stabilization amonge the electromagnets over the full attitude range. This was implemented by an MSBS control program able to continually adjust the distribution for the instantaneous incidence in accordance with prescheduled data. Results presented demonstrate rotations of models from zero to ninety degrees at rates up to ninety degrees per second, with pitching rates rising to several hundred degrees per second in response to step-change demands. A study of a design for a large MSBS suggests that such a system could be given the capability to control a model in six degrees of freedom over an unlimited angle of attack range.

Parker, David Huw↗

The control and estimation of large space structures

A shape control or estimation problem for a large space structure can be modeled by a partial differential equation which represents changes in shape with respect to space and time, together with spatially discrete forcing functions or observations which represent the placement of actuators or sensors at discrete points along the structure. The use of Green's functions to convert boundary value problems into integral equations provides a convenient treatment of this mixture of continuous and discrete mathematics. Control and estimation algorithms are developed for the one-dimensional static beam to illustrate this technique.

Weeks, C.↗

Toward Improved Charge Separation through Conformational Control in Copper Coordination Complexes

The continued development of solar energy as a renewable resource necessitates the design and study of new approaches to sustaining photodriven charge separation (CS). To this end, we present a bioinspired approach in which triggered conformational changes are used to control electron transfer (ET) events. We report, photo-induced conformational rearrangements of a ligand are translated into changes in the coordination geometry and environment about a bound metal ion. Taking advantage of the differential coordination properties of Cu I and Cu II , these dynamics facilitate intramolecular ET from Cu I to the ligand to create a CS state. The synthesis and photophysical characterization of CuCl(dpaa R ) (dpaa = dipicolylaminoacetophenone, with R = H and OMe) is presented. These ligands incorporate a fluorophore into their framework that gives rise to a twisted intramolecular charge transfer (TICT) excited state. Excited state ligand twisting provides a tetragonal coordination geometry capable of capturing Cu II in the CS state when an internal ortho-OMe binding site is present (as in dpaaOMe). We employ NMR, IR, EPR, and optical spectroscopies, X-ray diffraction, and electrochemical methods to establish the ground state properties of the Cu I and Cu II complexes. We then investigate the photophysical dynamics of these Cu I complexes via time-resolved photoluminescence (TR-PL), and optical transient absorption (OTA) spectroscopies. We show that relative to controls lacking a TICT-active ligand, the lifetime of the CS state is enhanced ~1000-fold. Further, the presence of the ortho-OMe substituent greatly enhances the lifetime of the TICT* state and biases the coordination environment toward Cu II . The presence of Cu I decreases photoinduced degradation from 14 to <2% but does not result in significant quenching via ET. Factors affecting CS in these systems are discussed, laying the groundwork for our strategy toward solar energy conversion.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

AIRES-NODE

This software package performs time series forecasting for engineering systems using neural controlled differential equations. Neural controlled differential equations are continuous time analogues to recurrent neural networks. AIRES-NODE is particularly well suited for dynamic systems which are subject to external forcing terms and time-dependent boundary conditions. AIRES-NODE provides an encoder-decoder architecture which allows for variable-length forecasts to be made and is not limited to a fixed time step size when forecasting. Additionally, by utilizing a novel combination of a variational autoencoder and neural controlled differential equations, the AIRES-NODE package is capable of producing probabilistic future forecasts.

Gurecky, William [Oak Ridge National Laboratory (O↗

Bulk ultrafine grained/nanocrystalline metals via slow cooling

Cooling, nucleation, and phase growth are ubiquitous processes in nature. Effective control of nucleation and phase growth is of significance to yield refined microstructures with enhanced performance for materials. Recent studies reveal that ultrafine grained (UFG)/nanocrystalline metals exhibit extraordinary properties. However, conventional microstructure refinement methods, such as fast cooling and inoculation, have reached certain fundamental limits. It has been considered impossible to fabricate bulk UFG/nanocrystalline metals via slow cooling. Here, we report a new discovery that nanoparticles can refine metal grains to ultrafine/nanoscale by instilling a continuous nucleation and growth control mechanism during slow cooling. The bulk UFG/nanocrystalline metal with nanoparticles also reveals an unprecedented thermal stability. This method overcomes the grain refinement limits and may be extended to any other processes that involve cooling, nucleation, and phase growth for widespread applications.

36 MATERIALS SCIENCE↗

Minimum Control Requirements for Advanced Life Support Systems

Advanced control technologies are not necessary for the safe, reliable and continuous operation of Advanced Life Support (ALS) systems. ALS systems can and are adequately controlled by simple, reliable, low-level methodologies and algorithms. The automation provided by advanced control technologies is claimed to decrease system mass and necessary crew time by reducing buffer size and minimizing crew involvement. In truth, these approaches increase control system complexity without clearly demonstrating an increase in reliability across the ALS system. Unless these systems are as reliable as the hardware they control, there is no savings to be had. A baseline ALS system is presented with the minimal control system required for its continuous safe reliable operation. This baseline control system uses simple algorithms and scheduling methodologies and relies on human intervention only in the event of failure of the redundant backup equipment. This ALS system architecture is designed for reliable operation, with minimal components and minimal control system complexity. The fundamental design precept followed is "If it isn't there, it can't fail".

Boulange, Richard↗

Approximate Scheduling of DERs with Discrete Complex Injections

Rapid penetration of renewable energy based Distributed Energy Resources (DER) has the potential to exacerbate the challenges inherent in grid frequency and voltage regulation. However, their real time controllability can be leveraged to not only mitigate such challenges, but improve the economics and quality of grid operations. A plethora of DER scheduling algorithms have been developed for fast and efficient scheduling of these resources. These algorithms schedule the complex - real and reactive power injected into (or drawn from) the grid by the DERs under various cost objective functions and grid constraints. However, a vast majority of such algorithms assume the feasible range of power injections to be continuous. In reality, the control options available for several DERs form a discrete space. This implies that the feasible range of power injections also forms a discrete space. This makes DER scheduling an NP-hard problem. Integer/Mixed Integer program based algorithms, which guarantee optimality in the objective value, have been developed. But these are prohibitively expensive in terms of computational time requirements. On the other hand, fast heuristic based solutions have also been developed. But as they do not provide any guarantee on the optimality of the objective, or on satisfying the constraints, they are unreliable for grid operations. Recent works have developed approximation algorithms which offer the best of both the approaches above: (near) optimality and low computational complexity, both of which are governed by a user defined accuracy parameter ϵ. In this work, we significantly improve upon such existing works by developing an approximation algorithm which schedules DERs with complex injections (as opposed to only real injection) and whose runtime is polynomial (as opposed to exponential) in 1/ϵ. We provide theoretical analysis and support them with experimental results to validate the guarantees provided by our approximation algorithm.

14 SOLAR ENERGY↗

Control of nonlinear systems represented in quasilinear form

Methods to synthesize controllers for nonlinear systems are developed by exploiting the fact that under mild differentiability conditions, systems of the form: x-dot = f(x) + G(x)u can be represented in quasilinear form, viz: x-dot = A(x)x + B(x)u. Two classes of control methods are investigated. The first is zero-look-ahead control, where the control input depends only on the current values of A(x) and B(x). For this case the control input is computed by continuously solving a matrix Riccati equation as the system progresses along a trajectory. The second is controllers with look-ahead, where the control input depends on the future behavior of A(x) and B(x). These controllers use the similarity between quasilinear systems and linear time varying systems to find approximate solutions to optimal control type problems. The methods that are developed are not guaranteed to be globally stable. However in simulation studies they were found to be useful alternatives for synthesizing control laws for a general class of nonlinear systems.

Coetsee, Josef A.↗

A Non-Linear Approach to Spacecraft Formation Control in the Vicinity of a Collinear Libration Point

An expanding interest in mission design strategies that exploit libration point regions, demands the continued development of enhanced, efficient, control algorithms for station-keeping and formation maintenance. Linear control strategies have been developed for station-keeping. However, their region of stability is bounded by the assumptions required for linearizing the governing equations of motion. For example, reference [I] discusses the development of a linear control design for maintaining a halo orbit about the Earth-Moon L2 libration point. Trial runs indicated the trajectory was unstable for starting points exceeding 45,000 km from the L2 point. Also, there was significant growth in the control effort required to maintain the orbit as the nominal radius increased. This result is a consequence of the increased influence of the system non-linearities, as the trajectory deviated from the linearization point, L2. As an alternative, this paper presents the development of a non-linear control strategy, based on a Hamiltonian formulation of the equations of motion. The control strategy is applied to the problem of formation maintenance, rather than simple station

Luquette, Richard J.↗

A Non-Linear Approach to Spacecraft Formation Control in the Vicinity of a Collinear Libration Point

An expanding interest in mission design strategies that exploit libration point regions demands the continued development of enhanced, efficient, control algorithms for station-keeping and formation maintenance. This paper discusses the development of a non-linear, formation maintenance, control algorithm for trajectories in the vicinity of a libration point. However, the formulation holds for any trajectory governed by the equations of motion for the restricted three body problem. The control law guarantees exponential convergence, based on a Lyaponov analysis. FreeFlyer and MATLAB provide the simulation environment for controller performance evaluation. The simulation, modeled after the MAXIM Pathfinder mission, maintains the relative position of a "follower" spacecraft with respect to a "leader" spacecraft, stationed near the L2 libration point in the Sun-Earth system. Evaluation metrics are fuel usage and tracking accuracy.

Luquette, Richard J.↗

Experiment K-317: Bone resorption in rats during spaceflight

Direct measurement of bone resorption in flight and synchronous control rats is described. Continuous tracer administration techniques were used, with replacement of dietary calcium with isotopically enriched Ca40 and measurement by neutron activation analysis of the Ca48 released by the skeleton. There is no large change in bone resorption in rats. Based on the time course of changes, the measured 20-25% decrease in resorption is probably secondary to a decrease in total body calcium turnover. The excretion of sodium, potassium and zinc all increase during flight, sodium and potassium to a level 4-5 times control values.

Cann, C. E.↗

Entanglement engineering of optomechanical systems by reinforcement learning

Entanglement is fundamental to quantum information science and technology, yet controlling and manipulating entanglement—so-called entanglement engineering—for arbitrary quantum systems remains a formidable challenge. There are two difficulties: the fragility of quantum entanglement and its experimental characterization. We develop a model-free deep reinforcement-learning (RL) approach to entanglement engineering, in which feedback control together with weak continuous measurement and partial state observation is exploited to generate and maintain desired entanglement. We employ quantum optomechanical systems with linear or nonlinear photon–phonon interactions to demonstrate the workings of our machine-learning-based entanglement engineering protocol. In particular, the RL agent sequentially interacts with one or multiple parallel quantum optomechanical environments, collects trajectories, and updates the policy to maximize the accumulated reward to create and stabilize quantum entanglement over an arbitrary amount of time. The machine-learning-based model-free control principle is applicable to the entanglement engineering of experimental quantum systems in general.

97 MATHEMATICS AND COMPUTING↗

Production of deuterated biomass by cultivation of Lemna minor (duckweed) in D 2 O

The small aquatic plant duckweed, particularly the genus Lemna , widely used for toxicity testing, has been proposed as a potential source of biomass for conversion into biofuels as well as a platform for production of pharmaceuticals and specialty chemicals. Ability to produce deuterium-substituted duckweed can potentially extend the range of useful products as well as assist process improvement. Cultivation of these plants under deuterating conditions was previously been reported to require addition of kinetin to induce growth and was hampered by anomalies in cellular morphology and protein metabolism. Here, we report the production of biomass with 50–60% deuterium incorporation by long-term photoheterotrophic growth of common duckweed Lemna minor in 50% D 2 O with 0.5% glucose. L. minor grown in 50% D 2 O without addition of kinetin exhibited a lag phase twice that of H 2 O-grown controls, before start of log phase growth at 40% of control rates. Compared to continuous white fluorescent light, growth rates increased fivefold for H 2 O and twofold for 50% D 2 O when plants were illuminated at higher intensity with a metal halide lamp and a diurnal cycle of 12-h light/12-h dark. Deuterium incorporation was determined by a combination of 1 H and 2 H nuclear magnetic resonance (NMR) to be 40–60%. The cellulose from the deuterated plants had an average-number degree of polymerization (DP n ) and polydispersity index (PDI) close to that of H 2 O-grown controls, while Klason lignin content was reduced. Furthermore, the only major gross morphological change noted was root inhibition.

59 BASIC BIOLOGICAL SCIENCES↗

Spaceflight Effects on Mammalian Development Summary of Research

Pregnant rats were flown as small payloads on the Space Shuttle and studied during the flight and for approximately a week after returning to Earth, when they were due to deliver their offspring. Studies of vestibular function in the rat pups were examined as part of the research program. Daily videorecordings were made of the rats' behavior in the Animal Enclosure Modules (AEMS) and in identical compartments maintained in the Orbiter Environment Simulator at the Kennedy Space Center (referred to below as Synchronous Control groups). There was continuous postflight surveillance of the rat dams, including timelapse recordings of labor and delivery. The videorecords provided by crewmembers constitute the best systematic views of spaceflown rats to date, despite the dramatic deterioration of visibility sustained after about the 4th day of flight. We were able to make both qualitative and quantitative observations. Rats were observed to engage in a varied repertoire of species-typical activities within the confines of the AEM. We devised a kinematic coding scheme by which we classified and quantified the movements made by dams in space and in the 1-g control condition. We found that movements involving pitch and yaw were about equivalent in Flight and Synchronous animals. In contrast, Flight dams displayed about seven times more rolling movements than did Control. NASA enabled early access to the AEMs after the Shuttle landed. Rats were intact and healthy. Body weight gain during the 9-11 day flights was equivalent to Controls. Post-flight observations, derived from 24hr/day videorecordings, showed that Flight rats ambulated less, reared fewer times and spent less time bipedal than did controls. Overall, their anti-gravitational responses appeared compromised.

Alberts, Jeffrey↗

Control of Excitonic Energy Transfer in RGB Quantum Dot:Polymer Composites for Tunable White Emission

Tint-controlled white light is crucial for both illumination systems and display applications. Here, in this study, we demonstrate solution-processed quantum-dot light-emitting diodes (QD-LEDs) featuring a red–green–blue (RGB) QD–poly(methyl methacrylate) (PMMA) composite emissive layer (EML) for tunable white electroluminescence (EL). In this composite EML, PMMA functions as a dispersion matrix that modulates the interdot spacing (d), thereby controlling Förster resonance energy transfer (FRET) between QDs. By adjustment of the PMMA content, the balance of R, G, and B emissions is controlled, enabling systematic and continuous tuning of the EL color from greenish to reddish white at a fixed RGB ratio and constant driving bias. Time-resolved photoluminescence measurements confirm that the variation in the exciton lifetime with the PMMA fraction is the primary factor for tuning the EL color. Notably, nearly pure white EL with CIE coordinates close to (0.33, 0.33) is achieved using a diluted PMMA matrix without significant degradation of the electrical properties. Our results demonstrate d as an independent design parameter for decoupling color tuning from RGB composition and electrical operation, providing a versatile design framework for high-quality white- or tint-controlled QD-LEDs toward advanced solid-state lighting and display technologies.

36 MATERIALS SCIENCE↗

Low Pressure Vapor-assisted Solution Process for Tunable Band Gap Pinhole-free Methylammonium Lead Halide Perovskite Films

Organo-lead halide perovskites have recently attracted great interest for potential applications in thin-film photovoltaics and optoelectronics. Herein, we present a protocol for the fabrication of this material via the low-pressure vapor assisted solution process (LP-VASP) method, which yields ~19% power conversion efficiency in planar heterojunction perovskite solar cells. First, we report the synthesis of methylammonium iodide (CH 3 NH 3 I) and methylammonium bromide (CH 3 NH 3 Br) from methylamine and the corresponding halide acid (HI or HBr). Then, we describe the fabrication of pinhole-free, continuous methylammonium-lead halide perovskite (CH 3 NH 3 PbX 3 with X = I, Br, Cl and their mixture) films with the LP-VASP. This process is based on two steps: i) spin-coating of a homogenous layer of lead halide precursor onto a substrate, and ii) conversion of this layer to CH 3 NH 3 PbI 3-x Br x by exposing the substrate to vapors of a mixture of CH 3 NH 3 I and CH 3 NH 3 Br at reduced pressure and 120 °C. Through slow diffusion of the methylammonium halide vapor into the lead halide precursor, we achieve slow and controlled growth of a continuous, pinhole-free perovskite film. The LP-VASP allows synthetic access to the full halide composition space in CH 3 NH 3 PbI 3-x Br x with 0 ≤ x ≤ 3. Depending on the composition of the vapor phase, the bandgap can be tuned between 1.6 eV ≤ E g ≤ 2.3 eV. In addition, by varying the composition of the halide precursor and of the vapor phase, we can also obtain CH 3 NH 3 PbI 3-x Cl x . Films obtained from the LP-VASP are reproducible, phase pure as confirmed by X-ray diffraction measurements, and show high photoluminescence quantum yield. The process does not require the use of a glovebox.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Development of a continuous synthesis process for carbamazepine using validated in-line Raman spectroscopy and kinetic modelling for disturbance simulation

Mitigation of failure modes in the continuous synthesis (CS) of a drug substance (DS) has the potential to widen the adoption of continuous manufacturing (CM) technologies by the pharmaceutical industry. Here, this work demonstrates the development of a robust continuous process for the synthesis of carbamazepine (CBZ), an essential medicine as per the World Health Organization (WHO), facilitated by kinetic modelling and monitored by in-line Raman spectroscopy. Accurate kinetic modelling and the use of validated process analytical technology (PAT) models for quantitative measurement were found to play an important role in developing CS of drug substances. Kinetic data for the formation of CBZ from iminostilbene (ISB) were collected by batch reaction sampling and high-performance liquid chromatography (HPLC) analysis. A non-linear solver and iterative method was applied to determine two sets of Arrhenius parameters simultaneously for the reaction system by minimizing the standard error of the model fit. The start-up and dynamic equilibrium stages for the CS of CBZ using a continuous stirred tank reactor (CSTR) were modelled based on the batch kinetic data and employed to optimize conversion and simulate process disturbances. An in-line Raman spectroscopy method was successfully developed, validated, and integrated to determine the concentrations of CBZ and ISB within the operating range for the CS. The CS kinetic model was evaluated experimentally from startup to dynamic equilibrium over 10 residence times with monitoring by HPLC and in-line Raman spectroscopy. The developed kinetic model in tandem with in-line Raman spectroscopy successfully predicted disturbances due to changes in process variables and can serve as a useful tool in the future design of advanced process control strategies for the continuous synthesis of CBZ.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Potato growth in response to relative humidity

Potato plants (Solanum tuberosum L. cvs. Russet Burbank, Norland, and Denali) were grown for 56 days in controlled-environment rooms under continuous light at 20C and 50% or 85% RH. No significant differences in total plant dry weight were measured between the humidity treatments, but plants grown under 85% RH produced higher tuber yields. Leaf areas were greater under 50% RH and leaves tended to be larger and darker green than at 85% RH.

Non-NASA Center↗