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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33

Determining Heats of Combustion of Gaseous Hydrocarbons

Enrichment-oxygen flow rate-ratio related to heat of combustion. Technique developed for determining heats of combustion of natural-gas samples. Based on measuring ratio m/n, where m is (volmetric) flow rate of oxygen required to enrich carrier air in which test gas flowing at rate n is burned, such that mole fraction of oxygen in combustion-product gases equals that in carrier air. The m/n ratio directly related to heats of combustion of saturated hydrocarbons present in natural gas.

Singh, Jag J.↗

Particle acceleration by intense auroral VLF turbulence

Broadband turbulence in the lower-hybrid to plasma frequency range is found in a variety of forms in the suprauroral region, most notably as auroral hiss and VLF saucers. When the turbulence is intense, it is observed to be associated with ion conics (ions heated transverse to the geomagnetic field) and 'counter-streaming' electron fluxes (heated in both directions parallel to the field). A review is presented of the dispersion and propagation characteristics of whistler resonance-cone waves, which comprise the turbulence. Plasma simulation and mesoscale (Monte Carlo) simulation techniques are used to illustrate the interaction of the ambient plasma with the turbulence. These calculations demonstrate how this interaction results in transverse heating of the ions and parallel heating of the electrons of the plasma, leading to the formation of the observed heated and accelerated particle fluxes.

Retterer, John M.↗

Cooling apparatus and couplings therefor

The present invention relates generally to the field of thermal transfer and, more specifically, to a direct-interface, fusible heat sink for non-venting, regenerable, and self-contained thermal regulation. A quick connect coupling includes a male and a female portion. The female portion is frozen in a container of solid-phase coolant fluid, i.e., water, so that passages in the housing are blocked by ice initially. The ice is melted by direct interface with liquid coolant fluid delivered from the male portion. The present invention has advantages in that the phase change material remains sealed at all times, including during regeneration. Also, it uses quick-disconnect couplings that allow the phase change material to completely fill the container and is easily handled in microgravity without spills, leakage, or handling of phase change material.

Lomax, Curtis↗

The polarization and directivity of solar-flare hard X-ray bremsstrahlung from a thermal source

The polarization and directivity of hard X-ray bremsstrahlung from a thermal source consisting of a region in which a thermal flux drives a pair of steel collisionless conduction fronts were evaluated. The conduction fronts are symmetrically driven from a central region, heated by the flare energy dissipation process. By comparing results with similar calculations based on a nonthermal thick-target electron beam model of the source, it was aimed to determine the degree to which the observed polarization and directivity of solar flare hard X-rays favor either model. Results which exhibit significant polarization and directivity of the hard X-ray radiation emitted by the source are produced by using Maxwellian electron-phase-space distribution functions modified to take into account a directional heat flux and a steady direct current in the X-ray source, and a fully relativistic treatment of the bremsstrahlung emission process. The results are consistent with solar hard X-ray anisotropy and polarization observations to date, although these observations are too crude to be conclusive.

Emslie, A. G.↗

Effect of Ga and P dopants on the thermoelectric properties of n-type SiGe

The purpose of this study was to hot-press improved n-type Si80Ge20/GaP samples directly (without any heat treatment) and to confirm that a Ga/P ratio less than one increases the solubility of P and, hence, improves the power factor and Z. One of the three samples (Ga/P = 0.43) had an improvement in Z of about 20 percent between 400 and 1000 C over that for standard SiGe. This demonstrates that improved samples can be pressed directly and that a Ga/P ratio less than one is necessary. The other two samples (Ga/P = 0.33 and 0.50) had Z's equal to or less than that of standard SiGe but had a lower hot-pressing temperature than the improved sample.

Draper, S. L.↗

Geothermal Play Fairway Analysis of Low-Temperature Resources for Sedimentary Basin Geothermal Play Types: An Example in the Denver Basin

This project is part of a nationwide effort to highlight the advantages of incorporating low-temperature geothermal resource evaluation into the implementation of combined heat and power (CHP), and geothermal direct use (GDU) technologies (e.g., space heating and/or cooling). The initiative aims to hasten the nation's decarbonization process by exploring the potential for using low-temperature geothermal resources (< 150 Degrees Celsius) in selected sedimentary basins that have several population centers. The Play Fairway Analysis (PFA) techniques were modified from earlier studies of sedimentary basin geothermal play types (SBGPTs) that assessed the viability of low-temperature resources. The decision-making process for leveraging low-temperature geothermal resources for GDU and CHP applications is complex and considers a variety of factors, including geological, economic, and risk criteria. This study covers workflows, relevant datasets, python code, and both common and composite maps used to create low-temperature geothermal resource favorability maps for the Denver Basin, which extends across Colorado, Nebraska, and Wyoming. The replication of these methodologies in other SBGPTs can evaluate potential for low-temperature resources. The proposed geothermal PFA approach for low-temperature geothermal resources includes: (1) identifying available relevant data and grouping data sets into PFA criteria (e.g., geological, economic, and risk criteria); (2) analyzing data gaps enable future focalized exploration; (3) performing uncertainty quantification; (4) weighting relevant data; (5) developing favorability and common risk maps for low-temperature geothermal resources to identify potential locations for more focused data collection. This project will facilitate future deployment of CHP and GDU by providing data, tools, and a workflow applicable to low-temperature geothermal resources in sedimentary basins.

15 GEOTHERMAL ENERGY↗

Atypical Particle Heating at a Supercritical Interplanetary Shock

We present the first observations at an interplanetary shock of large amplitude (> 100 mV/m pk-pk) solitary waves and large amplitude (approx.30 mV/m pk-pk) waves exhibiting characteristics consistent with electron Bernstein waves. The Bernstein-like waves show enhanced power at integer and half-integer harmonics of the cyclotron frequency with a broadened power spectrum at higher frequencies, consistent with the electron cyclotron drift instability. The Bernstein-like waves are obliquely polarized with respect to the magnetic field but parallel to the shock normal direction. Strong particle heating is observed in both the electrons and ions. The observed heating and waveforms are likely due to instabilities driven by the free energy provided by reflected ions at this supercritical interplanetary shock. These results offer new insights into collisionless shock dissipation and wave-particle interactions in the solar wind.

Wilson, Lynn B., III↗

Microwave Regenerable Air Purification Device

The feasibility of using microwave power to thermally regenerate sorbents loaded with water vapor, CO2, and organic contaminants has been rigorously demonstrated. Sorbents challenged with air containing 0.5% CO2, 300 ppm acetone, 50 ppm trichloroethylene, and saturated with water vapor have been regenerated, singly and in combination. Microwave transmission, reflection, and phase shift has also been determined for a variety of sorbents over the frequency range between 1.3-2.7 GHz. This innovative technology offers the potential for significant energy savings in comparison to current resistive heating methods because energy is absorbed directly by the material to be heated. Conductive, convective and radiative losses are minimized. Extremely rapid heating is also possible, i.e., 1400 C in less than 60 seconds. Microwave powered thermal desorption is directly applicable to the needs of Advance Life Support in general, and of EVA in particular. Additionally, the applicability of two specific commercial applications arising from this technology have been demonstrated: the recovery for re-use of acetone (and similar solvents) from industrial waste streams using a carbon based molecular sieve; and the separation and destruction of trichloroethylene using ZSM-5 synthetic zeolite catalyst, a predominant halocarbon environmental contaminant. Based upon these results, Phase II development is strongly recommended.

Atwater, James E.↗

Self-Heating Conductive Ceramic Composites for High Temperature Thermal Energy Storage

The absence of affordable and deployable large-scale energy storage poses a major barrier to providing zero-emission energy on demand for societal decarbonization. High temperature thermal energy storage is one promising option with low cost and high scalability, but it is hindered by the inherent complexity of simultaneously satisfying all of the material requirements. Here we design a class of ceramic–carbon composites based on co-optimizing mechanical, electrical, and thermal properties. Further, these composites demonstrate stability in soak-and-hold tests and direct self-heating up to 1,936 °C and 750 thermal cycles from 500 to 1,630 °C without degradation. This thermal performance derives from their composition and microstructural design as verified by in situ high-temperature transmission electron microscopy and X-ray diffraction. They offer both higher energy density and lower cost than conventional storage technologies with a projected system Levelized Cost of Storage below the U.S. Department of Energy’s 2030 target 5 ¢/kWh (electric).

25 ENERGY STORAGE↗

Joule heating and runaway electron acceleration in a solar flare

The hard and soft x ray and microwave emissions from a solar flare (May 14, 1980) were analyzed and interpreted in terms of Joule heating and runaway electron acceleration in one or more current sheets. It is found that all three emissions can be generated with sub-Dreicer electric fields. The soft x ray emitting plasma can only be heated by a single current sheet if the resistivity in the sheet is well above the classical, collisional resistivity of 10(exp 7) K, 10(exp 11)/cu cm plasma. If the hard x ray emission is from thermal electrons, anomalous resistivity or densities exceeding 3 x 10(exp 12)/cu cm are required. If the hard x ray emission is from nonthermal electrons, the emissions can be produced with classical resistivity in the current sheets if the heating rate is approximately 4 times greater than that deduced from the soft x ray data (with a density of 10(exp 10)/cu cm in the soft x ray emitting region), if there are at least 10(exp 4) current sheets, and if the plasma properties in the sheets are characteristic of the superhot plasma observed in some flares by Lin et al., and with Hinotori. Most of the released energy goes directly into bulk heating, rather than accelerated particles.

Holman, Gordon D.↗

Is chemical heating a major cause of the mesosphere inversion layer?

A region of thermal enhancement of the mesosphere has been detected on numerous occasions by in situ measurements, remote sensing from space, and lidar techniques. The source of these 'temperature inversion layers' has been attributed in the literature to the dissipation relating to dynamical forcing by gravity wave or tidal activity. However, evidence that gravity wave breaking can produce the inversion layer with amplitude as large as that observed in lidar measurements has been limited to results of numerical modeling. An alternative source for the production of the thermal inversion layer in the mesosphere is the direct deposition of heat by exothermic chemical reactions. Two-dimensional modeling combining a comprehensive model of the mesosphere photochemistry with the dynamical transport of long-lived species shows that the region from 80 to 95 km may be heated as much as 3 to 10 K/d during the night and half this rate during the day. Given the uncertainties in our understanding of the dynamics and chemistry for the mesopause region, separating the two sources by passive observations of the mesosphere thermal structure looks to be difficult. Therefore we have considered an active means for producing a mesopause thermal layer, namely the release of ozone into the upper mesosphere from a rocket payload. The induced effects would include artificial enhancements of the OH and Na airglow intensities as well as the mesopause thermal structure. The advantages of the rocket release of ozone is that detection of these effects by ground-based imaging, radar, and lidar systems and comparison of these effects with model predictions would help quantify the partition of the artificial inversion layer production into sources of dynamical and chemical forcing.

Meriwether, John W.↗

Comparison of visualized turbine endwall secondary flows and measured heat transfer patterns

Various flow visualization techniques were used to define the secondary flows near the endwall in a large heat transfer data. A comparison of the visualized flow patterns and the measured Stanton number distribution was made for cases where the inlet Reynolds number and exit Mach number were matched. Flows were visualized by using neutrally buoyant helium-filled soap bubbles, by using smoke from oil soaked cigars, and by a few techniques using permanent marker pen ink dots and synthetic wintergreen oil. Details of the horseshoe vortex and secondary flows can be directly compared with heat transfer distribution. Near the cascade entrance there is an obvious correlation between the two sets of data, but well into the passage the effect of secondary flow is not as obvious.

Gaugler, R. E.↗

Comparison of visualized turbine endwall secondary flows and measured heat transfer patterns

Various flow visualization techniques were used to define the seondary flows near the endwall in a large heat transfer data. A comparison of the visualized flow patterns and the measured Stanton number distribution was made for cases where the inlet Reynolds number and exit Mach number were matched. Flows were visualized by using neutrally buoyant helium-filled soap bubbles, by using smoke from oil soaked cigars, and by a few techniques using permanent marker pen ink dots and synthetic wintergreen oil. Details of the horseshoe vortex and secondary flows can be directly compared with heat transfer distribution. Near the cascade entrance there is an obvious correlation between the two sets of data, but well into the passage the effect of secondary flow is not as obvious. Previously announced in STAR as N83-14435

Gaugler, R. E.↗

Quantifying the Wave Driving of the Stratosphere

The zonal mean eddy heat flux is directly proportional to the wave activity that propagates from the troposphere into the stratosphere. This quantity is a simple eddy diagnostic which is easily calculated from conventional meteorological analyses. Because this "wave driving" of the stratosphere has a strong impact on the stratospheric temperature, it is necessary to compare the impact of the flux with respect to stratospheric radiative changes caused by greenhouse gas changes. Hence, we must understand the precision and accuracy of the heat flux derived from our global meteorological analyses. Herein, we quantify the stratospheric heat flux using five different meteorological analyses, and show that there are 30% differences between these analyses during the disturbed conditions of the northern hemisphere winter. Such large differences result from the planetary differences in the stationary temperature and meridional wind fields. In contrast, planetary transient waves show excellent agreement amongst these five analyses, and this transient heat flux appears to have a long term downward trend.

Newman, Paul A.↗

Environmentally Safer, Less Toxic Fire-Extinguishing Agents

Fire-extinguishing agents comprising microscopic drops of water microencapsulated in flame-retardant polymers have been proposed as effective, less toxic, non-ozone-depleting, non-globalwarming alternatives to prior fire-extinguishing agents. Among the prior fire-extinguishing agents are halons (various halocarbon fluids), which are toxic and contribute both to depletion of upperatmospheric ozone and to global warming. Other prior fire-extinguishing agents are less toxic and less environmentally harmful but, in comparison with halons, are significantly less effective in extinguishing fires. The proposal to formulate new waterbased agents is based on recent success in the use of water mist as a fire-suppression agent. Water suppresses a flame by reducing the flame temperature and the concentration of oxygen available for the combustion process. The temperature is reduced because the water droplets in the mist absorb latent heat of vaporization as they evaporate. The concentration of oxygen is reduced because the newly generated water vapor displaces air. Unfortunately, water mists are difficult to produce in confined spaces and can evaporate before they reach the bases of flames. The proposal addresses both of these issues: The proposed fire-extinguishing agents would be manufactured in microencapsulated form in advance, eliminating the problem of generating mists in confined spaces. Because of the microencapsulation, the droplets would not evaporate until exposed directly to the heat of flames. In addition, the proposal calls for the introduction of free radicals that would inhibit the propagation of the chemical reactions of the combustion reactions. Manufacturing of a fire-extinguishing agent according to the proposal would begin with the formulation of a suitable polymer (e.g., a polybromostyrene) that would contribute free radicals to the combustion process. The polymer would be dissolved in a suitable hydrocarbon liquid (e.g., toluene). Water would be dispersed in the polymer/toluene solution, then another hydrocarbon liquid (e.g., hexane) that is not a solvent for the polymer would be added to the mixture to make the dissolved polymer precipitate onto the water droplets. The resulting polymer-coated droplets would be removed from the coating mixture by filtration, dried, and stored for use.

Parrish, Clyde F.↗

Analysis and Optimization of a Multi-Layer Integrated Organic Substrate for High Current GaN HEMT-Based Power Module

In this paper, analysis and optimization of a multi-layer organic substrate for high current GaN HEMT based power module are discussed. The organic multi-layer substrates can provide high electrical performance in terms of low parasitic inductance in the power loop by providing vertical layout, and shielding for reduction of common-mode noise, a common problem in fast switching power converters. Furthermore, high performance cooling solutions, such as micro-channel heat sinks, can be directly bonded to the substrate for optimum thermal management. The structure of the proposed architecture, thermal analysis and optimization of layer thickness, thermo-mechanical stress analysis of the GaN HEMT and development of a high-performance heat sink are discussed.

47 OTHER INSTRUMENTATION↗

Thermodynamics of the dipole-octupole pyrochlore magnet Ce 2 Hf 2 O 7 in applied magnetic fields

The recently discovered dipole-octupole pyrochlore magnet Ce 2 Hf 2 O 7 is a promising three-dimensional quantum spin liquid candidate which shows no signs of ordering at low temperature. Here we investigate the thermodynamic response to magnetic fields applied along the global [110] direction using specific heat measurements and fits using numerical methods, and solve the corresponding magnetic structure using neutron diffraction. Specific heat data in moderate fields are reproduced well, however, at high fields the agreement is not satisfactory. We especially observe a two-step release of entropy, a finding that demands a review of both theory and experiment. We address it within the framework of three possible scenarios, including an analysis of the crystal field Hamiltonian not restricted to the two-dimensional single-ion doublet subspace. We conclusively rule out two of these scenarios and find qualitative agreement with a simple model of field misalignment with respect to the crystalline direction. As a result, we discuss the implications of our findings for [111] applied fields and for future experiments on Ce 2 Hf 2 O 7 and its sister compounds.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Below Ambient and Cryogenic Thermal Testing

Methods and apparatus for the testing of below-ambient temperature thermal insulation systems have been developed based on boiloff calorimetry. Boiloff calorimetry provides a direct measure of heat flow for below-ambient temperature conditions. The effective thermal conductivity (ke) and heat flux (q) of a test specimen are calculated for a fixed environmental condition (warm boundary temperature; cold boundary temperature; ambient or vacuum pressure). Through its heat of vaporization, liquid nitrogen (LN2) serves as the energy meter. Different apparatus have been built for flat-plate, cylindrical, and pipeline test specimens. Boundary temperatures can range from 353 K down to 77 K (80 C to -196 C). By interposing different insulation layers on the cold boundary, the cryogenic boiloff method is suitable for a wide range of below-ambient temperature applications. A cylindrical apparatus, Cryostat-100, as well as the pipeline test apparatus, Cryostat-P100, are thermally guarded and directly measure absolute thermal performance in watts. Pipe insulation systems can be mechanical, double-walled, or vacuum-jacketed including materials such as foams, cellular glass, aerogel blankets, clam-shell panels, and multilayer insulation. Two test pipelines, 12-meter-long, are mounted between two cold box assemblies. The test pipeline diameter is from 25-mm to 76-mm while the maximum outside diameter including insulation is up to 204-mm. The cold pipe tester design and test methods are discussed, as well as results for select thermal insulation materials. Progress toward a comparative type, bench-top cold pipe tester (Cryostat-P200) is also discussed.

Fesmire, James E.↗