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At least 595 records · Page 33

Hydroporphyrin-Doped Near-Infrared-Emitting Polymer Dots for Cellular Fluorescence Imaging

We report Near-infrared (NIR) fluorescent semiconductor polymer dots (Pdots) have shown great potential for fluorescence imaging due to their exceptional chemical and photophysical properties. This paper describes the synthesis of NIR emitting Pdots with great control and tunability of emission peak wavelength. The Pdots were prepared by doping poly [(9,9-dioctylfluorenyl-2,7-diyl)-altco-(1,4-benzo-(2,1’,3)-thiadiazole)] (PFBT), a semiconducting polymer commonly used as a host polymer in luminescent Pdots, with a series of chlorins and bacteriochlorins with varying functional groups. Chlorins and bacteriochlorins are ideal dopants due to their high hydrophobicity, which precludes their use as molecular probes in aqueous biological media but on the other hand prevents their leakage when doped into Pdots. Additionally, chlorins and bacteriochlorins have narrow deep-red to NIR emission bands and the wide array of synthetic modifications available for modifying their molecular structure enables tuning their emission predictably and systematically. Transmission electron microscopy (TEM) and dynamic light scattering (DLS) measurements show the chlorin and bacteriochlorin-doped Pdots to be nearly spherical with an average diameter of 46±12 nm. Efficient energy transfer between PFBT and the doped chlorins or bacteriochlorins decreases the PFBT donor emission to near baseline level and increases the emission of the doped dyes that serve as acceptors. The chlorin and bacteriochlorindoped Pdots show narrow emission bands ranging from 640 nm to 820 nm depending on the doped dye. The paper demonstrates the utility of the systematic chlorin and bacteriochlorin synthesis approach by preparing Pdots of varying emission peak wavelength, utilizing them to visualize multiple targets using wide field fluorescence microscopy, binding them to secondary antibodies, and determining the binding of secondary antibody-conjugated Pdots to primary antibody-labeled receptors in plant cells. Additionally, the chlorin and bacteriochlorin doped Pdots show a blinking behavior that could enable their use in super resolution imaging methods like STORM.

13C-NMR↗

Advanced Microstructured BaTiO 3 -Embedded PVDF–HFP/PEO Film for Enhanced Triboelectric Interface in Self-Sufficient Energy Generation and Sensing

The global reliance on fossil fuels and natural gas has largely dominated the energy production field, but due to finite resource depletion and escalating greenhouse gas emissions, the immediate exploration of sustainable energy alternatives to mitigate climate change and ensure resource security has been a major concern. There has been extensive research into other more renewable methods of energy production, such as wind and hydropower. Of these current energy generation types, there are many areas of untapped potential from the mechanical movements generated ambiently not only in the large scale of power generation but also on a smaller scale. The piezoelectric and triboelectric effects are phenomena where these ambient mechanical movements can generate electrical energy. Developing a hybrid system that leverages both mechanical stress and surface charges presents an ideal opportunity to exploit these untapped energy sources. Producing a hybrid PVDF–HFP/PEO film with perovskite BaTiO 3 (BTO) enables ambient power harvesting from both mechanical movement and surface charge. The optimized cell produced a potential of up to 15 V and a current of 200 nA with a 68 kΩ resistor, a substantial increase from a base system with an average of 2.1 V and 40 nA. These hybrid TENGs offer significant potential for energy harvesting in small-scale applications, such as health monitoring devices and indicators in electric circuits.

Ybarra, Rigobert [University of Texas Rio Grande V↗

New Apparatus for Neutron Capture Measurements on Extra Small Radioactive Samples: The DICER Instrument at LANSCE

We report the neutron capture cross section, the probability per unit area a neutron is absorbed by a nucleus followed by the emission of gamma ray(s), is an important quantity in several fields such as astrophysics, nuclear criticality safety, radiochemical diagnostics, nuclear medicine, nuclear forensics and nuclear security. Accurate knowledge of how neutrons interact with matter is a crucial component to understand physical processes in depth. A great example is the understanding of how our universe was created, a quest that requires accurate modeling in which neutron capture cross sections are a key ingredient

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Enhanced quantum radiation with flying-focus laser pulses

The emission of a photon by an electron in an intense laser field is one of the most fundamental processes in electrodynamics and underlies the many applications that utilize high-energy photon beams. This process is typically studied for electrons colliding head-on with a stationary-focus laser pulse. Here, we show that the energy lost by electrons in the quantum regime and the yield of emitted photons can be substantially increased by replacing a stationary-focus pulse with an equal-energy flying-focus pulse whose focus co-propagates with the electrons. Furthermore, these advantages of the flying focus result from the energy loss and the photon yield scaling more favorably with the interaction time than the laser intensity in the quantum regime, with the latter also holding in the classical regime. Monte Carlo simulations of electrons colliding with equal-energy stationary and flying-focus laser pulses demonstrate these advantages.

Compton scattering↗

Mesozoic Deserts and CO2 Storage: The Glen Canyon Group, Utah, USA

For much of the Mesozoic an extensive desert environment extended across the Western Interior of the USA. These desert systems deposited vast dunefields, including one of the largest ergs preserved in the rock record. The Glen Canyon Group in Utah is a Triassic-Jurassic aged aeolian succession, consisting of thick, laterally extensive aeolian dune deposits, interdune lakes and oases, and dryland fluvial systems. These aeolian deposits have been identified as potential CO2 sequestration reservoirs. The Jurassic-aged Navajo Sandstone has been the subject of research into its potential as a CO2 reservoir, as well as naturally occurring CO2 seeps in the Green River area. It has excellent reservoir properties, consisting of thick sandstones with high porosity and permeability, and has industry data including well logs and core. It occurs in both outcrop and subcrop, allowing for comparison and sense checking of interpretations across small and large scales. The Triassic Wingate Sandstone has received much less attention, however it too is composed of thick aeolian dune deposits. Like the Navajo Sandstone, the Wingate Sandstone has industry data, and occurs in both outcrop and subcrop. Using extensive industry data which exists across Utah is an effective way to pivot from a hydrocarbon focus to CO2 injection, and so contribute to green energy and carbon neutral emission goals. Here we use historic industry data in conjunction with field work, to study the Navajo and Wingate Sandstones and their potential as CO2 reservoirs, in addition to increasing our understanding of lithologic and stratigraphic complexity in one of the most significant aeolian systems in the world.

Mahon, Elizabeth↗

Defining Detection Limits for Continuous Monitoring Systems for Methane Emissions at Oil and Gas Facilities

Networks of fixed-point continuous monitoring systems are becoming widely used in the detection and quantification of methane emissions from oil and gas facilities in the United States. Regulatory agencies and operators are developing performance metrics for these systems, such as minimum detection limits. Performance characteristics, such as minimum detection limits, would ideally be expressed in emission rate units; however, performance parameters such as detection limits for a continuous monitoring system (CMS) will depend on meteorological conditions, the characteristics of emissions at the site where the CMS is deployed, the positioning of CMS devices in relation to the emission sources, and the amount of time allowed for the CMS to detect an emission source. This means that certifying the performance of a CMS will require test protocols with well-defined emission rates and durations; initial protocols are now being used in field tests. Field testing results will vary, however, depending on meteorological conditions and the time allowed for detection. This work demonstrates methods for evaluating CMS performance characteristics using dispersion modeling and defines an approach for normalizing test results to standard meteorological conditions using dispersion modeling.

Chen, Qining (ORCID:0000000316908091)↗

Measurement of L-shell emission from mid-Z targets under non-LTE conditions using Transmission Grating Spectrometer and DANTE power diagnostics

In this work, we present the measurement of L-band emission from buried Sc/V targets in experiments performed at the OMEGA laser facility. The goal of these experiments was to study non-local thermodynamic equilibrium plasmas and benchmark atomic physics codes. The L-band emission was measured simultaneously by the time resolved DANTE power diagnostic and the recently fielded time integrated Soreq-Transmission Grating Spectrometer (TGS) diagnostic. The TGS measurement was used to support the spectral reconstruction process needed for the unfolding of the DANTE data. The Soreq-TGS diagnostic allows for broadband spectral measurement in the 120 eV–2000 eV spectral band, covering L- and M-shell emission of mid- and high-Z elements, with spectral resolution λ/Δλ = 8–30 and accuracy better than 25%. The Soreq-TGS diagnostic is compatible with ten-inch-manipulator platforms and can be used for a wide variety of high energy density physics, laboratory astrophysics, and inertial confinement fusion experiments.

Fraenkel, M. (ORCID:0000000291939544)↗

Understanding the role of flow dynamics in thermoacoustic combustion instability

Thermoacoustic combustion instability is one of the most challenging operational issues in several high-performance, low-emissions combustion technologies, including gas turbines, aircraft engines, rockets, and industrial boilers. Driven by the coupling between combustor acoustics and flame heat release rate fluctuations, thermoacoustic combustion instability can lead to reduced operability, increased emissions, and, in the most extreme cases, catastrophic failure of combustor components. The feedback loop between acoustics and combustion is often facilitated by fluid mechanic oscillations, referred to as “velocity coupling,” whereby acoustic oscillations drive flow fluctuations, which in turn create fluctuations in the flame. The character of these fluid mechanic oscillations is highly dependent on the structure of the flow field and the receptivity of the flow to external excitation. Combustor flow fields use features like fluid recirculation and shear to enhance flame holding and reduce emissions, but these are also the same features that can make the flow receptive to acoustic excitation or even drive self-excited oscillations. Here, in this paper, we discuss the basics of thermoacoustic instability with a focus on the role of hydrodynamic oscillations in typical combustor flows. To facilitate this discussion, we explore the hydrodynamic instability characteristics of several key combustor unit flows (wakes, swirling jets, etc.) and show how the hydrodynamic stability of a flow is an important consideration in determining a combustor’s propensity for thermoacoustic oscillations. Several examples of coupling between hydrodynamics and thermoacoustics are discussed to illustrate this important link. The paper concludes by discussing the potential for designing flow fields that are thermoacoustic instability resistant, either through a reduction in the receptivity of the flow or through nonlinear coupling mechanisms by which self-excited flow instabilities can suppress velocity-coupled combustion oscillations.

42 ENGINEERING↗

Characterization of detachment inferred from the Balmer line ratios in JET-ILW low-confinement mode plasmas

Spectroscopic measurements of the hydrogenic Balmer-α and Balmer-γ line emission in JET-ILW low-confinement mode (L-mode) deuterium plasmas are used to assess the onset of volume recombination in the low-field side (LFS) divertor. The evolution of the EDGE2D-EIRENE predicted Balmer-γ to Balmer-α emission ratio from low-recycling to detached conditions is in qualitative agreement with the measured ratio. In low-recycling conditions the EDGE2D-EIRENE predicted line-emission is within 30% of measured emission, in high-recycling within 20%t, and in detached conditions lower by a factor of 2.5.

Divertor visible spectroscopy↗

Magnetically Arrested Circumbinary Accretion Flows

Abstract Binary systems with comparable masses and a surrounding accretion disk can accrete gas through spiral accretion streams penetrating the central cavity formed by tidal interactions. Using three-dimensional Newtonian magnetohydrodynamics simulations, we investigate the possibility of a magnetically arrested accretion flow through the cavity. Rather than solely continuously feeding the binary through spiral accretion streams, the accretion is regulated by the strong magnetic field inside the cavity. Transport of mass and angular momentum onto the binary then proceeds largely periodically in magnetic flux eruption episodes. The ejected flux tubes carry angular momentum outward and away from the binary, inject hot plasma into the disk, and can launch flares. This likely intermittent scenario could have potential implications for the emission signatures of supermassive black hole binaries and shed light onto the role magnetic fields play in the binary’s orbital evolution.

Astronomy & Astrophysics↗

Plasma screening in mid-charged ions observed by K-shell line emission

Dense plasma environment affects the electronic structure of ions via variations of the microscopic electrical fields, also known as plasma screening. This effect can be either estimated by simplified analytical models, or by computationally expensive and to date unverified numerical calculations. We have experimentally quantified plasma screening from the energy shifts of the bound-bound transitions in matter driven by the x-ray free electron laser (XFEL). This was enabled by identification of detailed electronic configurations of the observed Kα, Kβ and Kγ lines. This work paves the way for improving plasma screening models including connected effects like ionization potential depression and continuum lowering, which will advance the understanding of atomic physics in the Warm Dense Matter regime.

Physics - Plasma physics↗

Specific features of fluorescence transfer in multiply scattering randomly inhomogeneous layers under intense laser pumping

Based on the analysis of experimental data on the effect of the pulsed laser pump intensity on the spectral properties and the size of the fluorescent response zone in randomly inhomogeneous fluorescent layers, we found that the amplification of spontaneous and stimulated emission significantly affects the statistical properties of the propagation lengths of the fluorescent field partial components in the layers. The experiments are performed with layers of SiO{sub 2} and TiO{sub 2} nanoparticles saturated with rhodamine 6G, pumped by 532-nm laser radiation in the intensity range corresponding to the transient regime from excitation of spontaneous fluorescence to random lasing in the layer. The experimental data are compared with the results of statistical modelling of fluorescence transfer. It is shown that, even at a pump intensity below the random lasing threshold, the spontaneous emission amplification in a layer leads to a significant increase in the contributions to the fluorescence response from partial components with propagation lengths much larger than the layer thickness. This can be interpreted as a manifestation of the quasi-waveguide effect, in which the probability of propagation of diffuse fluorescence components along the layer over distances many times greater than its thickness and the size of the pumped region increases significantly with a decrease in the characteristic radiation amplification length in the layer. (paper)

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Magnetohydrodynamic simulations preliminarily predict the habitability and radio emission of TRAPPIST-1e

TRAPPIST-1e, an Earth-sized exoplanet in the habitable zone of the nearby M dwarf TRAPPIST-1, may experience magnetospheric responses that vary with stellar space weather, which could potentially influence both its habitability and radio emissions. Our objective is to investigate how different Earth-like magnetospheric configurations of TRAPPIST-1e – specifically variations in dipolar magnetic field strength and axial tilt – respond to diverse stellar space weather conditions, including events analogous to coronal mass ejections (CMEs), and to assess their implications for potential habitability and expected radio emissions. We conducted 3D magnetohydrodynamic simulations of the TRAPPIST-1e system using the PLUTO code in spherical coordinates. The planetary magnetic field was modelled as dipolar, with equatorial strengths from Earth-like to several times stronger. The dipole axis spans a representative range of axial tilts. We investigate four stellar wind environments, from sub-Alfvénic flow to CME-like disturbances. Planetary shielding was quantified based on the magnetopause standoff distance, and radio powers were estimated via empirical scaling laws. Our simulations show that both shielding and radio power depend strongly on the magnetic configuration. Stronger fields increase protection, while larger tilts reduce it. Radio power increases with both field strength and tilt across all wind regimes. An Earth-like magnetic field can provide effective shielding even under intense CMEs, whereas high tilts require stronger fields. Predicted radio powers reach ~10 20 erg s −1 during CMEs, making bursts from close-in, magnetised planets more detectable. However, for TRAPPIST-1e, the maximum cyclotron frequency lies below the Earth’s ionospheric cutoff (~10 MHz), making ground-based detection currently infeasible.

Sun: magnetic fields↗

Complex multicomponent spectrum analysis with Deep Neural Network

Here, in this paper, we present the use of deep neural networks to estimate physical parameters from complex optical emission spectra of the D β /H β transition. Specifically, we focus on estimating the radio frequency electric field vector of the lower hybrid wave and isotope ratio within the scrape-off-layer plasma of the WEST tokamak. Fitting the spectral data using a traditional non-linear least squares analysis requires many free parameters and is computationally expensive, rendering the data unusable for real-time control. By implementing relatively small neural networks, the physical parameters can be directly extracted from the spectral data with reasonable accuracy in a few milliseconds. The deep neural network prediction can serve as input for a reduced model using least-squares fitting or for real-time control. We show that deep neural networks can be an effective tool for analyzing complex multicomponent spectra, providing a speedup of more than 10 5 times compared to least residual analysis, with an accuracy of 0.5% for the isotope ratio, and 0.09 kV/cm and 0.38 kV/cm for the RF radial and poloidal electric field respectively.

47 OTHER INSTRUMENTATION↗

Hestia-SWIFL: hourly anthropogenic fossil fuel CO2 and heat on the 2km WRF grid, version 1.1

The Hestia-SWIFL version 1.1 anthropogenic heat (AH) and fossil fuel CO2 (FFCO2) emissions data product represent emissions due to the combustion of fossil fuel and cement production within the state of Arizona from 2019 to 2022. This product was developed as part of the Southwest Urban Corridor Integrated Field Laboratory (SW-IFL) project, which aims to provide new knowledge and tools that address extreme heat, air quality, climate change and related urban environmental issues by integrating high-resolution observations, modeling, and civic engagement. The emissions are generated using a bottom-up/engineering approach and are tied to results generated by the Vulcan Project version 4, an effort to quantify space/time-resolved FFCO2 & AH emissions for the entire United States landscape. A large number of data sources are combined to best estimate the emissions at fine scales such as air quality emissions data, traffic flow data, building information, sociodemographic information, and fuel statistics. The AH product provides emissions for two emissions sources (transportation and point source emissions) in units of Watts per hour per square meter (W/m2) per year (annual files) or per hour (hourly files). The FFCO2 product provides emissions from nine individual emission sectors as well as the total, and in units of tons of carbon (tC) per grid cell per year or per hour. The output made available here places the native spatial resolution of the Hestia FFCO2 & AH emissions data product (points, lines, and polygons) into a regularized 2km x 2km grid at hourly and annual temporal resolutions, and stored in netCDF files. The exact spatial extent is defined by the ASU Weather Research Forecast (WRF) simulation grid. All data are processed using R/Python pm high-performance computing system. 2-27-2026 updates: Bugs in airport hourly profile (both AH and FFCO2) and building spatial patterns (FFCO2 only) were fixed. Hourly emissions are reprocessed for all years to reflect those changes.

54 ENVIRONMENTAL SCIENCES↗

Limits on Leptonic TeV Emission from the Cygnus Cocoon with Swift-XRT

$\gamma$-ray observations of the Cygnus Cocoon, an extended source surrounding the Cygnus X star-forming region, suggest the presence of a cosmic ray accelerator reaching energies up to a few PeV. The very-high-energy (VHE; 0.1-100~TeV) $\gamma$-ray emission may be explained by the interaction of cosmic-ray hadrons with matter inside the Cocoon, but an origin of inverse Compton radiation by relativistic electrons cannot be ruled out. Inverse Compton $\gamma$-rays at VHE are accompanied by synchrotron radiation peaked in X-rays. Hence, X-ray observations may probe the electron population and magnetic field of the source. We observed eleven fields in or near the Cygnus Cocoon with the Neil Gehrels Swift Observatory's X-Ray Telescope (Swift-XRT) totaling 110 ksec. We fit the fields to a Galactic and extra-galactic background model and performed a log-likelihood ratio test for an additional diffuse component. We found no significant additional emission and established upper limits in each field. By assuming that the X-ray intensity traces the TeV intensity and follows an dN/dE ∝ E -2.5 spectrum, we obtained a 90% upper limit of F X < 8.7 x 10 -11 erg cm -2 s -1 or 5.2 x10 -11 erg cm -2 s -1 on the X-ray flux of the entire Cygnus Cocoon between 2 and 10 keV depending on the choice of hydrogen column density model. This suggests that no more than one quarter of the $\gamma$-ray flux at 1 TeV is produced by inverse Compton scattering, when assuming an equipartition magnetic field of ~20 μG.

79 ASTRONOMY AND ASTROPHYSICS↗

Coherent emission from surface Josephson plasmons in striped cuprates

The interplay between charge order and superconductivity remains one of the central themes of research in quantum materials. In the case of cuprates, the coupling between striped charge fluctuations and local electromagnetic fields is especially important, as it affects transport properties, coherence, and dimensionality of superconducting correlations. Here, we study the emission of coherent terahertz radiation in single-layer cuprates of the La 2-x Ba x CuO 4 family, for which this effect is expected to be forbidden by symmetry. We find that emission vanishes for compounds in which the stripes are quasi-static but is activated when c-axis inversion symmetry is broken by incommensurate or fluctuating charge stripes, such as in La 1.905 Ba 0.095 CuO 4 and in La 1.845 Ba 0.155 CuO 4 . In this case, terahertz radiation is emitted by surface Josephson plasmons, which are generally dark modes, but couple to free space electromagnetic radiation because of the stripe modulation.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Identification and control of the exhaust using gas perturbations in the DIII-D tokamak

This paper presents perturbative experiments that enable the validation and development of control-oriented models for exhaust control. We identify the response of the divertor plasma and scrape-off layer in the DIII-D tokamak to deuterium and nitrogen multi-sine perturbations, in favorable and unfavorable field directions for H-mode access. We obtained good signal-to-noise ratios in the 1–10 Hz frequency range by measuring Balmer-alpha, Lyman-alpha, and N 4+ line emission, radiated power, and neutral pressure. We find a similar phase response across gas species and magnetic field directions, while the gain response is nonlinear. With these experiments, we identify a control-oriented model to design a divertor radiated power controller to track specified reference waveforms in conjunction with resonant magnetic perturbations. Although the physics basis for compatibility between detachment and resonant magnetic perturbation edge-localized mode suppression remains to be demonstrated, the present results provide a robust controller that represents a promising step toward future joint control strategies.

detachment control↗