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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS1999

Studies of Radiation and Microphysics in Cirrus and Marine Stratocumulus Clouds

Two tasks were completed during this period. In the first, we examined the polarization of millimeter-wavelength radar beams scattered by ice crystals. Because of their non-spherical shape and size, ice crystals depolarize the incident polarized radar beam. In principle, this depolarization can be used to identify ice from liquid water, as well as provide some information on size. However, the amount of de-polarization is small, producing only a weak signal at the receiver. Our task was to determine the magnitude of such a signal and decide if our radar would be capable of measuring it under typical cirrus conditions. The theoretical study was carried out by Henrietta Lemke, a visiting graduate student from Germany. She had prior experience using a discrete dipole code to compute scattering depolarization. Dr. Kultegin Aydin of the Penn State Electrical Engineering Department, who is also expert in this area, consulted with us on this project at no cost to the project. Our conclusion was that the depolarization signal is too weak to be usefully measured by our system. Therefore we proceeded no further in this study. The second task involved the study of the effect of stratus microphysics on surface cloud forcing. Manajit Sengupta, a graduate student, and the project PI jointly carried out this task. The study used data culled from over a year of continuous radar and radiometer observations at the Atmospheric Radiation Measurement (ARM) site in Oklahoma. The study compared solar radiation calculations made using constant microphysics with calculations made using a retrieved mean particle size. The results showed that on average the constant microphysics produced the correct forcing when compared with the observed forcing. We conclude, therefore, that there is little impetus on radiation grounds alone to include explicit microphysics in climate models. The question of pollutant particle emission impacts on microphysics remains to be resolved. A manuscript is in preparation and will be submitted this year.

Source record↗
DOE OSTI2023

Demonstration of p-side down green light emitting diodes with high external quantum efficiencies

GaN/(In,Ga)N heterostructure based visible Light Emitting Diodes (LED) have enabled a wide range of solid-state lighting applications through excellent efficiency and power output in the shorter wavelengths (≤ 475nm) of violet/blue emission. However, the efficiency of emitters in the longer wavelength range (≥ 500nm) drops drastically due to the need to include higher Indium-content in the InGaN quantum wells. Large average polarization fields for high Indium-content quantum wells for conventional P-up structure, opposes the depletion field leading to large electrostatic barriers for both electrons and holes injection. LEDs fabricated along the N-polar direction with a p-up orientation or Ga-polar direction with p-down orientation lower such electrostatic barriers to carrier injection due to alignment of the polarization dipole field and depletion region field. This can therefore theoretically improve the electrical injection efficiency and reduce the forward voltage of operation. Such a Ga-polar p-down LED requires a bottom buried tunnel junction to avoid current spreading issues for a buried p-GaN layer. In this report, we demonstrate for the first time Ga-polar p-down green emitting LEDs using bottom tunnel junctions and having external quantum efficiencies comparable to those of equivalent p-up LEDs grown by Metal Organic Chemical Vapor Deposition (MOCVD).

36 MATERIALS SCIENCE↗
DOE OSTI2020

Three-beam rotational coherent anti-Stokes Raman spectroscopy thermometry in scattering environments

Three-beam rotational coherent anti-Stokes Raman scattering (CARS) measurements performed in highly scattering environments are susceptible to contamination by two-beam CARS signals generated by the pump–probe and Stokes–probe interactions at the measurement volume. If this occurs, differences in the Raman excitation bandwidth between the two-beam and three-beam CARS signals can add significant errors to the spectral analysis. This interference to the best of our knowledge has not been acknowledged in previous three-beam rotational CARS experiments, but may introduce measurement errors up to 25% depending on the temperature, amount of scattering, and differences between the two-beam and three-beam Raman excitation bandwidths. Here, the presence of two-beam CARS signal contamination was experimentally verified using a femtosecond–picosecond rotational CARS instrument in two scattering environments: (1) a fireball generated by a laboratory-scale explosion that contained particulate matter, metal fragments, and soot, and (2) a flow of air and small liquid droplets. A polarization scheme is presented to overcome this interference. By rotating the pump and Stokes polarizations +55° and –55° from the probe, respectively, the two-beam and three-beam CARS signals are orthogonally polarized and can be separated using a polarization analyzer. Using this polarization arrangement, the Raman-resonant three-beam CARS signal amplitude is reduced by a factor of 2.3 compared to the case where all polarizations are parallel. This method is successfully demonstrated in both scattering environments. A theoretical model is presented, and the temperature measurement error is studied for different experimental conditions. The criteria for when this interference may be present are discussed.

42 ENGINEERING↗
DOE OSTI2022

Designing Damage-Resistant Multilayer Dielectric Gratings for Petawatt-Class Lasers

We have successfully developed high efficiency dielectric gratings for chirped pulse amplification (CPA) pulse compression with a focus on improving damage thresholds for high peak power. Specifically, we focused on developing first-of-kind designs that operate at TM polarization. Unpublished modeling within our group shows that the electric field enhancement in the solid material for gratings operating at TM can be significantly less than for TE. Subsequently, the laser damage threshold of TM gratings should be higher by potentially a factor of 2X.

42 ENGINEERING↗
DOE OSTI2025

Impacts of the Conductive Networks on Solid‐State Battery Operation

The micromorphology of composite cathodes is known to play a vital role in determining all-solid-state battery (ASSB) performance. However, much of our current understanding is derived from empirical observations, lacking a deeper mechanistic foundation. The “rocking chair” concept of battery chemistry requires maintaining charge neutrality, emphasizing the necessity of examining electrode micromorphology from the perspective of conductive networks. This study systematically investigates the microscopic electrochemical impacts of conductive network micromorphology by varying the Li + -to-e − channel ratio in cathodes comprising LiNbO 3 -coated LiNi 0.8 Co 0.1 Mn 0.1 O 2 , Li 6 PS 5 Cl, and carbon fibers. Utilizing multiscale synchrotron-based spectro-microscopy, we unravel that unbalanced Li + and e − conducting channels intensify charge polarization within active cathode particles and accelerate their degradation. A further model system with X-ray nano-tomography resolved e − and Li + channels indicates that spatially uniform and well-paired Li + and e − conducting channels are highly desirable as they could promote more uniform lithiation/delithiation, mitigating microscopic electrochemical polarization. Electrode-scale X-ray holotomography analysis reveals that the impact of conductive networks is particle-size-dependent, with smaller cathode particles being more significantly affected. These findings provide mechanistic insights into the interplay between conductive networks and all-solid-state battery operation, laying the groundwork for rational design and optimization of cathode architectures in future solid-state battery technologies.

36 MATERIALS SCIENCE↗
NASA NTRS2019

Recent Advances in High Altitude Pseudosatellites (HAPS) and Potential Roles in Future Earth Observing Systems

In August 2001 the NASA Environmental Research Aircraft and Sensor Technology (ERAST) Program flew the Helios aircraft to an altitude of nearly 100,000ft, demonstrating a new type of remote sensing platform. Nearly 20 years later the earth science community has unmet observational requirements to loiter over regions of interest for days or weeks as well as to follow airmasses to study chemistry and dynamics in concert with spaceborne observations. Recent advances in materials science and engineering have enabled improved battery power density, solar panel efficiency, and light yet strong structural materials required to effectively operate high-altitude (50-70k ft altitude) Pseudo-Satellites (HAPS) for 30+ days. The rapid commercialization of small unmanned aircraft has also contributed to the maturation of HAPS by making avionics, GPS, and other sub-systems smaller and less expensive. HAPS payloads provide high-resolution data that complement geostationary and polar orbiting satellites, while also enabling in-situ sampling of atmospheric chemistry and dynamics. Recent commercial interest in HAPS for 4G/5G and WIFI has funded development of a new generation of aircraft available to the science community. Here I report on a project under the NASA Airborne Science Program to test and demonstrate earth observations from a prototype aircraft being developed under a NASA Small Business Innovative Research Phase II. This aircraft will demonstrate the ability for a solar electric aircraft to deliver a 2u cubesat-based passive optical imaging satellite to 70,000ft for 30 or more days. Discussion will include the anticipated maturation timeline for HAPS, development and operational challenges, and examples of mission concepts that might contribute to future earth observing systems.

Helios aircraft↗
DOE OSTI2022

Analytical and numerical modeling of optical second harmonic generation in anisotropic crystals using #SHAARP package

Electric-dipole optical second harmonic generation (SHG) is a second-order nonlinear process that is widely used as a sensitive probe to detect broken inversion symmetry and local polar order. Analytical modeling of the SHG polarimetry of a nonlinear optical material is essential to extract its point group symmetry and the absolute nonlinear susceptibilities. Current literature on SHG analysis involves numerous approximations and a wide range of (in)accuracies. We have developed an open-source package called the Second Harmonic Analysis of Anisotropic Rotational Polarimetry (#SHAARP.si) which derives analytical and numerical solutions of reflection SHG polarimetry from a single interface (.si) for bulk homogeneous crystals with arbitrary symmetry group, arbitrary crystal orientation, complex and anisotropic linear dielectric tensor with frequency dispersion, a general SHG tensor and arbitrary light polarization. #SHAARP.si enables accurate modeling of polarimetry measurements in reflection geometry from highly absorbing crystals or wedge-shaped transparent crystals. The package is extendable to multiple interfaces.

36 MATERIALS SCIENCE↗
NASA NTRS1991

Electrostatic fields in a dusty Martian environment

While there have been several studies suggesting the possibility of electrical activity on Mars, to date there have been no measurements to search for evidence of such activity. In the absence of widespread water clouds and convective storm systems similar to those on the Earth and Jupiter, the most likely candidate for the creation of electrostatic charges and fields is triboelectric charging of dust, i.e., the friction between blown dust and the ground, and of dust particles with each other. Terrestrial experience demonstrates that electric fields 5 to 15 kV-m(exp -1) are not uncommon in dust storms and dust devils in desert regions, where the polarity varies according to the chemical composition and grain size. Simple laboratory experiments have demonstrated that modest electrostatic fields of roughly 5,000 V-m(exp -1) may be produced, along with electrical spark discharges and glow discharges, in a simulation of a dusty, turbulent Martian surface environment. While the Viking landers operated for several years with no apparent deleterious effects from electrostatic charging, this may have been at least partly due to good engineering design utilizing pre-1976 electronic circuitry to minimize the possibility of differential charging among the various system components. However, free roaming rovers, astronauts, and airborne probes may conceivably encounter an environment where electrostatic charging is a frequent occurrence, either by way of induction from a static electric field or friction with the dusty surface and atmosphere. This raises the possibility of spark discharges or current surges when subsequent contact is made with other pieces of electrical equipment, and the possibility of damage to modern microelectronic circuitry. Measurements of electrostatic fields on the surface of Mars could therefore be valuable for assessing this danger. Electric field measurements could also be useful for detecting natural discharges that originate in dust storms. This detection could be performed at distances ranging from 10s of km in the case of J-charge-like discharge signatures, to planetary distances if there exists a global electrical circuit or Schumann resonance spectrum.

Sentman, D. D.↗
DOE OSTI2026

Extreme Nanoconfinement Dramatically Enhances Small Molecule Solubility in Nonpolar Polymers

Elucidating gas solubility in confined polymer systems addresses a fundamental gap in polymer physics and has important implications for gas barrier and separation technologies and polymer upcycling reactions. In this study, we examine the solubility of methanol and n-hexane in polystyrene and low-density polyethylene confined within the interstitial pores of disordered silica nanoparticle packings. Using capillary rise infiltration, these polymers are infiltrated into the nanoparticle packings. Gas solubility in these confined polymers is measured using a quartz crystal microbalance. Remarkably, confinement leads to a 10- to ∼100-fold increase in gas solubility. Systematic experiments reveal that pore size plays a dominant role in increasing solubility. In contrast, the molecular weight of the polymer and the surface wetting characteristics of the nanoparticles, achieved by hydrophobically modifying the nanoparticles, have minimal effects. By systematically varying penetrant polarity, polymer crystallinity, pore size, and nanopore surface chemistry, this study isolates geometric nanoconfinement as the dominant factor governing solubility enhancement in confined polymers. Atomistic simulations revealed that confinement and surface−polymer interactions both contribute to enhanced solubility, with polymer packing playing a significant role in modulating gas uptake. Here, these results suggest that the changes in the molecular arrangements of polymer segments underlie the observed trends. This study highlights the potential of confined polymers in engineering the separation performance of membranes and heterogeneously catalyzed polymer upcycling reactions.

alcohols↗
DOE OSTI2025

Epitaxial strain tuning of Er 3+ in ferroelectric thin films

Er 3+ color centers are promising candidates for quantum science and technology due to their long electron and nuclear spin coherence times, as well as their desirable emission wavelength. By selecting host materials with suitable, controllable properties, we introduce new parameters that can be used to tailor the Er 3+ emission spectrum. PbTiO 3 is a well-studied ferroelectric material with known methods of engineering different domain configurations through epitaxial strain. By distorting the structure of Er 3+ -doped PbTiO 3 thin films, we can manipulate the crystal fields around the Er 3+ dopant. This is resolved through changes in the Er 3+ resonant fluorescence spectra, tying the optical properties of the defect directly to the domain configurations of the ferroelectic matrix. Additionally, we are able to resolve a second set of peaks for films with in-plane ferroelectric polarization. We hypothesize these results to be due to either the Er 3+ substituting different sites of the PbTiO 3 crystal, differences in charges between the Er 3+ dopant and the original substituent ion, or selection rules. Systematically studying the relationship between the Er 3+ emission and the epitaxial strain of the ferroelectric matrix lays the pathway for future optical studies of spin manipulation by altering ferroelectric order parameters.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Observation of microwave shielding of ultracold molecules

Harnessing the potential wide-ranging quantum science applications of molecules will require control of their interactions. Here, we used microwave radiation to directly engineer and tune the interaction potentials between ultracold calcium monofluoride (CaF) molecules. By merging two optical tweezers, each containing a single molecule, we probed collisions in three dimensions. The correct combination of microwave frequency and power created an effective repulsive shield, which suppressed the inelastic loss rate by a factor of six, in agreement with theoretical calculations. The demonstrated microwave shielding shows a general route to the creation of long-lived, dense samples of ultracold polar molecules and evaporative cooling.

Anderegg, Loïc↗
NASA NTRS1993

Thrust augmentation options for the Beta 2 two-stage-to-orbit vehicle

NASA LeRC is continuing to study propulsion concepts for a horizontal takeoff and landing, fully reusable, two-stage-to-orbit vehicle. This will be capable of launching and returning a 10,000 pound payload to a 100 nautical mile polar orbit using low-risk technology. The vehicle, Beta 2, is a derivative of the USAF/Boeing Beta vehicle which was designed to deliver a 50,000 pound payload to a similar orbit. Beta 2 stages at Mach 6.5 and about 100,000 ft altitude. The propulsion system for the booster is an over/under turbine bypass engine/ramjet configuration. In this paper, several options for thrust augmentation were studied in order to improve the performance of this engine where there was a critical need. Options studies were turbine engine overspeed in the transonic region, water injection at a various turbine engine locations also during the transonic region, and water injection at the turbine engine face during high speed operation. The methodology, constraints, propulsion performance, and mission study results are presented.

Snyder, Christopher A.↗
NASA NTRS2003

COR1 Engineering Test Unit Measurements at the Mauna Loa Solar Observatory, September 2003

The COR1 Engineering Test Unit (ETU), which had been previously tested at the NCAR/HAO and NRL test facilities, was modified into an instrument capable of observing the Sun. It was then taken to the Mauna Loa Solar Observatory to observe the corona. The changes made to observe the Sun were as follows: 1. The plate scale was changed to accommodate the smaller Apogee camera. This change had already been made for the NRL tests. 2. The previous Oriel polarizer was replaced with a commercial Polarcor polarizer from Newport to be more flight-like. However, because of cost and availability considerations, this polarizer was smaller than those which will be used for flight. 3. A structure was placed around the back section of the instrument, to protect it from stray light. 4. A pointing spar borrowed from HAO was used to track the Sun. A few days into the test, it became evident that some artifacts were appearing in the data, and these artifacts were changing as the polarizer was rotated. It was decided to test two other polarizers, the Oriel polarizer which had been used in the previous tests at HAO and NRL, and a Nikon polarizer which was borrowed from a camera belonging to one of the observatory staff members. These three polarizers had much different qualities are shown.

Thompson, William↗
DOE OSTI2022

On the mechanism of performance improvement of electroactive polyvinyl chloride (PVC) gel actuators via conductive fillers

Abstract The electromechanical actuation of transparent plasticized polyvinyl chloride (PVC) gels with conductive fillers were studied. The effects of functionalized carbon nanotubes (CNTs) and 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF 4 ) ionic liquid (IL) on both the electrical conduction and dielectric processes within PVC gels were investigated, and the differences between the two were clarified. Both CNTs and IL were shown to increase the conductivity of the gels and produce larger electromechanical transduction of a contraction actuator, but only CNTs were shown to increase the electrostatic adhesion force of the PVC gels. The addition of charge carriers to the gel via the inclusion of ILs was shown to significantly reduce the conductivity relaxation time, and the transient current upon voltage polarity reversal indicated multiple peaks corresponding to the introduction of carriers with different polarities and mobilities into the gel. This is believed to cause a screening effect, reducing the charge accumulation at the anode that is the foundational basis for PVC gels’ actuation mechanism. A recommendation for preferable conductive fillers for various applications is made.

36 MATERIALS SCIENCE↗
NASA NTRS1975

Reentry aerodynamics forces and moments on the engine nozzle of the 146-inch solid rocket booster model 473 tested in MSFC 14 by 14 inch trisonic wind tunnel (SA30F)

A test of a model of the Space Shuttle Solid Rocket Boosters (SRB's) was performed in a 14 x 14 inch Trisonic Wind Tunnel to determine the aerodynamic forces and moments imposed on the nozzle of the SRB during reentry. The model, with scale dimensions equal to 0.5479 of the actual SRB dimensions, was instrumented with a six-component force balance attached to the model nozzle so that only forces and moments acting on the nozzle were measured. A total of 137 runs (20 deg pitch polars) were performed during this test. The angle of attack ranged from 60 to 185 deg, the Reynolds number from 5.2 million to 7.6 million. The Mach numbers investigated were 1.96, 2.74, and 3.48. Five external protuberances were simulated. The effective roll angle simulated was 180 deg. The effects of three different heat shield configurations were investigated.

Johnson, J. D.↗
NASA NTRS1979

An ultraviolet polarimeter for the Solar Maximum Mission

The Solar Maximum Mission experiment contingency will include one instrument originally designed and built for OSO-8. The engineering model of the OSO-8 High Resolution Spectrometer has been rebuilt to make it lightworthy and to encompass several new functions, including solar ultraviolet polarimetry. The rebuilt package is designated as the High Resolution Ultraviolet Spectrometer/Polarimeter. The device that enables polarimetry is a dual channel rotating waveplate system. The waveplates are magnesium fluoride and will allow measurements to be made ranging from the Lyman alpha line to near visible ultraviolet. One wavelength channel will use the polarization characteristics of the spectrometer diffraction grating as the analyzer. The second channel has a built-in four-mirror polarizer. This paper describes the polarimeter design, operation, and calibration.

Calvert, J.↗
NASA NTRS2011

Design, Development and Testing of the GMI Reflector Deployment Assembly

The GMI Reflector Deployment Assembly (RDA) is an articulating structure that accurately positions and supports the main reflector of the Global Microwave Imager (GMI) throughout the 3 year mission life. The GMI instrument will fly on the core Global Precipitation Measurement (GPM) spacecraft and will be used to make calibrated radiometric measurements at multiple microwave frequencies and polarizations. The GPM mission is an international effort managed by the National Aeronautics and Space Administration (NASA) to improve climate, weather, and hydrometeorological predictions through more accurate and frequent precipitation measurements1. Ball Aerospace and Technologies Corporation (BATC) was selected by NASA Goddard to design, build, and test the GMI instrument. The RDA was designed and manufactured by ATK Aerospace Systems Group to meet a number of challenging packaging and performance requirements. ATK developed a flight-like engineering development unit (EDU) and two flight mechanisms that have been delivered to BATC. This paper will focus on driving GMI instrument system requirements, the RDA design, development, and test activities performed to demonstrate that requirements have been met.

Guy, Larry↗
DOE OSTI2020

Exchange bias switching in an antiferromagnet/ferromagnet bilayer driven by spin-orbit torque

Here the electrical manipulation of magnetization and exchange bias in antiferromagnet/ferromagnet thin films could be of use in the development of the next generation of spintronic devices. Current-controlled magnetization switching can be driven by spin-orbit torques generated in an adjacent heavy metal layer, but these structures are difficult to integrate with exchange bias switching and tunnelling magnetoresistance measurements. Here, we report the current-induced switching of the exchange bias field in a perpendicularly magnetized IrMn/CoFeB bilayer structure using a spin-orbit torque generated in the antiferromagnetic IrMn layer. By manipulating the current direction and amplitude, independent and repeatable switching of the magnetization and exchange bias field below the blocking temperature can be achieved. The critical current density for the exchange bias switching is found to be larger than that for CoFeB magnetization reversal. X-ray magnetic circular dichroism, polarized neutron reflectometry measurements and micromagnetic simulations show that a small net magnetization within the IrMn interface plays a crucial role in these phenomena.

42 ENGINEERING↗