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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 595 records · Page 33
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Globular cluster formation - The fossil record

Properties of globular clusters which have remained unchanged since their formation are used to infer the internal pressures, cooling times, and dynamical times of the protocluster clouds immediately prior to the onset of star formation. For all globular clusters examined, it is found that the cooling times are much less than the dynamical times, implying that the protoclusters must have been maintained in thermal equilibrium by external heat sources, with fluxes consistent with those found in previous work, and giving the observed rho-T relation. Self-gravitating clouds cannot be stably heated, so that the Jeans mass forms an upper limit to the cluster masses. The observed dependence of protocluster pressure upon galactocentric position implies that the protocluster clouds were in hydrostatic equilibrium after their formation. The pressure dependence is well fitted by that expected for a quasi-statically evolving background hot gas, shock heated to its virial temperature. The observations and inferences are combined with previous theoretical work to construct a picture of globular cluster formation.

Murray, Stephen D.↗
NASA NTRS1996

Volatile Hydroxide Species of Common Protective Oxides and their Role in High Temperature Corrosion

Thermodynamic data for volatile hydroxides and oxyhydroxides formed from the reaction of water vapor with Cr2O3, SiO2, A12O3, Y2O3,. and ZrO2 were assembled. The volatile species formed at temperatures between 800 and 2200K in model combustion environments containing 10% water vapor and 10% oxygen at 1 and 10 bar total pressure were calculated using free energy minimization techniques. Assuming an acceptable maximum vapor pressure limit for volatile species of 10 bar, an upper use temperature for these oxides was determined at 1 and 10 bar total pressure. The dependence of these volatile species on both water vapor and oxygen pressure was determined.

Opila, Elizabeth J.↗
DOE OSTI2022

Frhodo: A program for simulating chemical kinetic measurements and optimizing kinetic mechanisms

Chemical kinetic simulations are frequently used to extract kinetic and mechanistic information from experimental data by fitting simulations to the data. For simple systems of consecutive single channel reactions this is a relatively straightforward task. However, as the complexity of the system increases and particularly for systems involving competitive multi-channel reactions manually optimizing a mechanism to obtain the best fits to a range of experimental data quickly becomes a time-intensive and challenging process, especially when rate coefficients have pressure and temperature dependencies. There is considerable potential for exploiting automated optimization methods to rapidly screen reaction mechanisms and optimize the fit by adjusting rate coefficients within well-defined constraints. A new chemical kinetics simulation program, Frhodo, has been developed for this purpose. The program allows either manual simulation of individual experiments or fully automated optimization against a range of experimental data by adjusting user selected reactions within user defined constraints. Frhodo incorporates machine learning-based optimization routines that work by either minimizing standardized residuals or through Bayesian parameter estimation. Frhodo's optimization capabilities are demonstrated by reexamining two previously studied systems of relevance to combustion. Dissociation of diacetyl followed by recombination of methyl radicals is an example of a sequence of single channel, consecutive reactions. Pyrolysis of 2-methyl furan exemplifies multi-channel, unimolecular reactions that are often encountered and have temperature and pressure dependencies in the rate coefficients of the channels and branching ratios between them. For both systems the optimization routines resulted in solutions similar to the original studies. Finally, comments are made on the strengths and limitations of the approach.

0D simulation↗
DOE OSTI2026

Hydrogen release from aqueous based LOHCs: The role of water in the potassium formate/bicarbonate cycle

Here, in this study, we evaluate the chemical and physical properties governing the potential round-trip efficiency of an aqueous formate/bicarbonate cycle for hydrogen storage, with a particular focus on potassium formate as a potential liquid hydrogen carrier. Using thermodynamic parameters, we predict the conversion of formate to bicarbonate across varying temperatures and pressures, revealing that hydrogen release is relatively insensitive to temperature but highly dependent on pressure. Our findings indicate that hydrogen uptake is highly efficient, whereas hydrogen release poses a greater challenge, necessitating detailed optimization to enhance round-trip efficiency. We calculate the solubility limits of bicarbonate salts influenced by the common ion effect to enable the prediction of target conversion ranges that prevent the precipitation of potassium bicarbonate in a reactor. Furthermore, the energy efficiency of hydrogen release was assessed based on the heating requirements of the aqueous solutions. This analysis maximizes the round-trip efficiency by balancing the solubility limits of bicarbonate, the heat capacity of aqueous formate solutions and conversion based on thermodynamic equilibria. Taking these factors into consideration we suggest reaction conditions that could be utilized in a systems analysis to calculate the levelized cost of storage using the bicarbonate/formate cycle at commercial scales.

common ion effect↗
DOE OSTI2025

First-Principles Study of Molecular Hydrogen Activation by Defects in Boron Nitride

Here, we used density functional theory simulations in combination with ab initio thermodynamics to determine the H 2 partial pressure (p H2 )-dependent energetics associated with H 2 activation and recovery at various defect sites in hexagonal boron nitride (h-BN). We found that some defects are very reactive with hydrogen, thereby definitely trapping hydrogen in defective h-BN. However, depending on hydrogen partial pressure, less reactive defect sites can be populated. Because of the lower binding capability of these sites, they would allow hydrogen to be recycled and recovered. For small defect sizes, we found that hydrogen preferentially binds to nitrogen sites by forming N–H bonds, and if no N sites are available then boron sites would be the next to bind hydrogen. Hydrogen dissociation via frustrated Lewis pair is found to be more favorable than forming only N–H bonds but only if the defect size is large enough to accommodate steric effects. For specific conditions such as T = 400 K, p H2 = 1 bar, and only considering one molecular H 2 per defect, three defects, namely, the N monovacancy, 3V(1B2N), and hexagonal 6V(3B3N) could play a role in both the activation and recycling of H 2 as they would be reacting enough to allow a favorable splitting of H 2 while not binding too strongly to allow its recovery. More broadly, a range of p H2 and hydrogen loading conditions were investigated for different types of defects and the finding suggests that p H2 could be used to fine-tune the Gibbs free energy of hydrogenation, thereby allowing several types of defects at different hydrogen loading contents to play a role in the activation/recovery process of H 2 in defective h-BN.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1989

On the structure of pressure fluctuations in simulated turbulent channel flow

Pressure fluctuations in a turbulent channel flow are investigated by analyzing a database obtained from a direct numerical simulation. Detailed statistics associated with the pressure fluctuations are presented. Characteristics associated with the rapid (linear) and slow (nonlinear) pressure are discussed. It is found that the slow pressure fluctuations are larger than the rapid pressure fluctuations throughout the channel except very near the wall, where they are about the same magnitude. This is contrary to the common belief that the nonlinear source terms are negligible compared to the linear source terms. Probability density distributions, power spectra, and two-point correlations are examined to reveal the characteristics of the pressure fluctuations. The global dependence of the pressure fluctuations and pressure-strain correlations are also examined by evaluating the integral associated with Green's function representations of them. In the wall region where the pressure-strain terms are large, most contributions to the pressure-strain terms are from the wall region (i.e., local), whereas away from the wall where the pressure-strain terms are small, contributions are global. Structures of instantaneous pressure and pressure gradients at the wall and the corresponding vorticity field are examined.

Kim, John↗
NASA NTRS1989

On the structure of pressure fluctuations in simulated turbulent channel flow

Pressure fluctuations in a turbulent channel flow are investigated by analyzing a database obtained from a direct numerical simulation. Detailed statistics associated with the pressure fluctuations are presented. Characteristics associated with the rapid (linear) and slow (nonlinear) pressure are discussed. It is found that the slow pressure fluctuations are larger than the rapid pressure fluctuations throughout the channel except very near the wall, where they are about the same magnitude. This is contrary to the common belief that the nonlinear source terms are negligible compared to the linear source terms. Probability density distributions, power spectra, and two-point correlations are examined to reveal the characteristics of the pressure fluctuations. The global dependence of the pressure fluctuations and pressure-strain correlations are also examined by evaluating the integral associated with Green's function representations of them. In the wall region where the pressure-strain terms are large, most contributions to the pressure-strain terms are from the wall region (i.e., local), whereas away from the wall where the pressure-strain terms are small, contributions are global. Structures of instantaneous pressure and pressure gradients at the wall and the corresponding vorticity field are examined.

Kim, John↗
NASA NTRS2006

Pressure Effects on Oxygen Concentration Flammability Thresholds of Materials for Aerospace Applications

Spacecraft materials selection is based on an upward flammability test conducted in a quiescent environment in the highest-expected oxygen-concentration environment. However, NASA s advanced space exploration program is anticipating using various habitable environments. Because limited data is available to support current program requirements, a different test logic is suggested to address these expanded atmospheric environments through the determination of materials self-extinguishment limits. This paper provides additional pressure effects data on oxygen concentration and partial pressure self-extinguishment limits under quiescent conditions. For the range of total pressures tested, the oxygen concentration and oxygen partial pressure flammability thresholds show a near linear function of total pressure. The oxygen concentration/oxygen partial pressure flammability thresholds depend on the total pressure and appear to increase with increasing oxygen concentration (and oxygen partial pressure). For the Constellation Program, the flammability threshold information will allow NASA to identify materials with increased flammability risk because of oxygen concentration and total pressure changes, minimize potential impacts, and allow for development of sound requirements for new spacecraft and extraterrestrial landers and habitats.

Hirsch, David↗
NASA NTRS1980

Ultrasonic attenuation and velocity in AS/3501-6 graphite fiber composite

The ultrasonic group velocity and attenuation were measured as a function of frequency for longitudinal and shear waves in the Hercules epoxy matrix (3501-6) and in the principal directions of the unidirectional Hercules graphite fiber epoxy composite (AS/3501-6). Tests were conducted in the frequency ranges 0.25-14 MHz and 0.5-3 MHz for longitudinal and shear wave modes, respectively. While the attenuation increased with frequency for all wave modes, the group velocity was independent of frequency for all wave modes. In studying the effects of transducer-specimen interface couplant and pressure, it was found that for each transducer, there exists a frequency-dependent 'saturation pressure' corresponding to the maximum output amplitude of the signal.

Williams, J. H., Jr.↗
NASA NTRS2011

Embedded Acoustic Sensor Array for Engine Fan Noise Source Diagnostic Test: Feasibility of Noise Telemetry via Wireless Smart Sensors

Aircraft engines have evolved into a highly complex system to meet ever-increasing demands. The evolution of engine technologies has primarily been driven by fuel efficiency, reliability, as well as engine noise concerns. One of the sources of engine noise is pressure fluctuations that are induced on the stator vanes. These local pressure fluctuations, once produced, propagate and coalesce with the pressure waves originating elsewhere on the stator to form a spinning pressure pattern. Depending on the duct geometry, air flow, and frequency of fluctuations, these spinning pressure patterns are self-sustaining and result in noise which eventually radiate to the far-field from engine. To investigate the nature of vane pressure fluctuations and the resulting engine noise, unsteady pressure signatures from an array of embedded acoustic sensors are recorded as a part of vane noise source diagnostics. Output time signatures from these sensors are routed to a control and data processing station adding complexity to the system and cable loss to the measured signal. "Smart" wireless sensors have data processing capability at the sensor locations which further increases the potential of wireless sensors. Smart sensors can process measured data locally and transmit only the important information through wireless communication. The aim of this wireless noise telemetry task was to demonstrate a single acoustic sensor wireless link for unsteady pressure measurement, and thus, establish the feasibility of distributed smart sensors scheme for aircraft engine vane surface unsteady pressure data transmission and characterization.

Zaman, Afroz↗
NASA NTRS1975

Shock-induced deformation features in terrestrial peridot and lunar dunite

Single crystals of terrestrial olivine were experimentally shock-loaded along the 010 line to peak pressures 280, 330, and 440 kbar, and the resulting deformation features were compared to those in olivine from lunar dunite 72415. Recovered fragments were examined to determine the orientation of the planar fractures. With increasing pressure the percentage of pinacoids and prisms decreases, whereas the percentage of bipyramids increases. The complexity of the distribution of bipyramids also increases with increasing pressure. Other shock-induced deformation features, including varying degrees of recrystallization, are found to depend on pressure, as observed by others. Lunar dunite 72415 was examined and found to contain olivine with well-developed shock-deformation features. The relative proportion of pinacoid, prism, and bipyramid planar fractures measured for olivine from 72415 indicates that this rock appears to have undergone shock pressure in the range 330-440 kbar. If this dunite was brought to the surface of the moon as a result of excavation of an Imbrium event-sized impact crater, the shock-pressure range experienced by the sample and the results of cratering calculations suggest that it could have originated no deeper than 50-150 km.

Snee, L. W.↗
NASA NTRS1960

Effects of Sweep Angle on the Boundary-Layer Stability Characteristics of an Untapered Wing at Low Speeds

An investigation was conducted in the Ames 12-Foot Low-Turbulence Pressure Tunnel to determine the effects of sweep on the boundary-layer stability characteristics of an untapered variable-sweep wing having an NACA 64(2)A015 section normal to the leading edge. Pressure distribution and transition were measured on the wing at low speeds at sweep angles of 0, 10, 20, 30, 40, and 50 deg. and at angles of attack from -3 to 3 deg. The investigation also included flow-visualization studies on the surface at sweep angles from 0 to 50 deg. and total pressure surveys in the boundary layer at a sweep angle of 30 deg. for angles of attack from -12 to 0 deg. It was found that sweep caused premature transition on the wing under certain conditions. This effect resulted from the formation of vortices in the boundary layer when a critical combination of sweep angle, pressure gradient, and stream Reynolds number was attained. A useful parameter in indicating the combined effect of these flow variables on vortex formation and on beginning transition is the crossflow Reynolds number. The critical values of crossflow Reynolds number for vortex formation found in this investigation range from about 135 to 190 and are in good agreement with those reported in previous investigations. The values of crossflow Reynolds number for beginning transitions were found to be between 190 and 260. For each condition (i.e., development of vortices and initiation of transition at a given location) the lower values in the specified ranges were obtained with a light coating of flow-visualization material on the surface. A method is presented for the rapid computation of crossflow Reynolds number on any swept surface for which the pressure distribution is known. From calculations based on this method, it was found that the maximum values of crossflow Reynolds number are attained under conditions of a strong pressure gradient and at a sweep angle of about 50 deg. Due to the primary dependence on pressure gradient, effects of sweep in causing premature transition are generally first encountered on the lower surfaces of wings operating at positive angles of attack.

Boltz, Frederick W.↗
DOE OSTI2021

Interface pinning causes the hysteresis of the hydride transformation in binary metal hydrides

Hydriding and dehydriding transitions in bulk and nanocrystalline binary metal hydrides were studied using the Pd-H model system by measuring pressure-composition isotherms with in situ x-ray diffractometry. Nanocrystalline Pd showed a smaller pressure hysteresis, solvus hysteresis, and hysteresis in lattice parameter, compared to bulk Pd. The time-dependence of pressure equilibration was measured after dosing with aliquots of hydrogen, giving equilibration times that were much faster in the single-phase regions than in the two-phase plateaus. In the broad two-phase plateaus, the pressure relaxations were exponential functions of time. An explanation of hysteresis is developed that is based on a dissipative potential barrier that impedes the motion of the interface due to interactions between lattice defects and the two-phase interface. The exponential pressure relaxations and hysteresis are consistent for this mechanism. For a simple model of the pinning potential, the potential barrier maximum is an order of magnitude less than typical grain boundary energies. These pinning effects are substantially different in the nanocrystalline Pd, suggesting differences in the hydriding mechanism.

36 MATERIALS SCIENCE↗
NASA NTRS1987

Three-step cylindrical seal for high-performance turbomachines

A three-step cylindrical seal configuration representing the seal for a high performance turbopump (e.g., the space shuttle main engine fuel pump) was tested under static (nonrotating) conditions. The test data included critical mass flux and pressure profiles over a wide range of inlet temperatures and pressures for fluid nitrogen and fluid hydrogen with the seal in concentric and fully eccentric positions. The critical mass flux (leakage rate) was 70% that of an equivalent straight cylindrical seal with a correspondingly higher pressure drop based on the same flow areas of 0.3569 sq cm but 85% that of the straight seal based on the third-step flow area of 0.3044 sq cm. The mass flow rates for the three step cylindrical seal in the fully eccentric and concentric positions were essentially the same, and the trends in flow coefficient followed those of a simple axisymmetric inlet configuration. However, for inlet stagnation temperatures less than the thermodynamic critical temperature the pressure profiles exhibited a flat region throughout the third step of the seal, with the pressure magnitude dependent on the inlet stagnation temperature. Such profiles represent an extreme positive direct stiffness. These conditions engendered a crossover in the pressure profile upstream of the postulated choke that resulted in a local negative stiffness. Flat and crossover profiles resulting from choking within the seal are practically unknown to the seal designer. However, they are of critical importance to turbomachine stability and must be integrated into any dynamic analysis of a seal of this configuration. In addition, choking is highly dependent on geometry, inlet-to-backpressure ratio, and inlet temperature and can occur within the seal even though the backpressure is above the critical pressure.

Hendricks, Robert C.↗
NASA NTRS1978

A theoretical study of a laminar diffusion flame

Theoretical models of an axisymmetric laminar diffusion flame are discussed, with an emphasis on the behavior of such flames at increasing pressures. The flame-sheet or Burke-Schumann model (in terms of Bessel functions) and various boundary layer numerical solutions are presented and their results compared with experimental data. The most promising theoretical model combines the numerical flow field solution of the Patankar-Spalding computer code with the Pratt-Wormeck chemical reaction subroutine. The flame shapes for pressures of 1, 5, 10, 20, and 50 atmospheres were computed and agree remarkably well with experimental data. There is a noticeable shape change with pressure, believed to be a result of buoyancy effects. The chemical concentration profiles do not exhibit much dependence on pressure, a reflection of the fact that only one chemical mechanism was utilized at all pressures.

Frair, K. L.↗
NASA NTRS1993

Influence of heat transfer rates on pressurization of liquid/slush hydrogen propellant tanks

A multi-dimensional computational model of the pressurization process in liquid/slush hydrogen tank is developed and used to study the influence of heat flux rates at the ullage boundaries on the process. The new model computes these rates and performs an energy balance for the tank wall whereas previous multi-dimensional models required a priori specification of the boundary heat flux rates. Analyses of both liquid hydrogen and slush hydrogen pressurization were performed to expose differences between the two processes. Graphical displays are presented to establish the dependence of pressurization time, pressurant mass required, and other parameters of interest on ullage boundary heat flux rates and pressurant mass flow rate. Detailed velocity fields and temperature distributions are presented for selected cases to further illuminate the details of the pressurization process. It is demonstrated that ullage boundary heat flux rates do significantly effect the pressurization process and that minimizing heat loss from the ullage and maximizing pressurant flow rate minimizes the mass of pressurant gas required to pressurize the tank. It is further demonstrated that proper dimensionless scaling of pressure and time permit all the pressure histories examined during this study to be displayed as a single curve.

Sasmal, G. P.↗
NASA NTRS2007

Measurement of the Temperature Dependence of Line Mixing and Pressure Broadening Parameters between 296 and 90 K in the v3 band of 12CH4 and their Influence on Atmospheric Methane Retrievals

We measured the temperature dependence of the nitrogen broadening, narrowing and line-mixing coefficients of four lines of the P9 manifold in the v3 band of 12CH4 for atmospheric purposes. The data were collected using our tunable diode laser (TDL) spectrometer with active wavenumber control coupled to a newly developed cold Herriott cell with a path length of 5.37 m and a temperature uniformity of better than 0.01 K along the cell. We recorded and analyzed spectra recorded at sample temperature between 90 K and room temperature. We have investigate the influence of our new results in the inversion model used to retrieve methane profiles from atmospheric spectra; our new results make it possible to retrieve significantly more precise methane profiles. The atmospheric spectra we utilized were obtained by several of us with a balloon-born Fourier Transform infrared experiment in a limb configuration. Differences up to 7% on the retrieved volume mixing ratio were found compared to an inversion model using only HITRAN04 spectroscopic parameters.

Mondelain, Didier↗