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At least 595 records · Page 33

Mechanisms for the Intraseasonal Variability of Tropospheric Ozone over the Indian Ocean during the Winter Monsoon

We synthesize daily sonde (vertical) information and daily satellite (horizontal) information to provide an empirical description of ozone origins over the northern Indian Ocean during the INDOEX (Indian Ocean Experiment) field campaign (February-March 1999). This area is shown to be a significant portion of the "high-ozone tropics". East-west O3 features and their flow are identified, and ozone origins are compared to other tropical regions, using water vapor as a second tracer. In the study period, multiple processes contribute to O3 column enhancements, their importance varying strongly by latitude: (1) Low-altitude O3 pollution over the northern Indian Ocean mainly originates from the Indian subcontinent and is traceable to high emission areas. Convective activity south of Sri Lanka helps direct ozone outflow from the northern Indian subcontinent. (2) Middle tropospheric O3 maxima over the northern Indian Ocean originate from various sources, often transitioning within a few hours. Convective venting of Asian pollutants can add 20-30 ppbv to the middle troposphere at 5degN-10degN, alternating with stratospheric influence. (3) A number of cases suggest that strong mixing-in of stratospheric air along the subtropical jet raised tropospheric O3 in early March by approx.40-50 ppbv, especially poleward of approx. 10degN. (4) Influences of lightning and large-scale biomass burning were not strong during this period, in contrast to the situation in Africa and the South Atlantic or locally in Southeast Asia. This work illustrates successes and limitations in approaches to synthesizing disparate information on trace-gas distributions taken from satellite retrieval products and ozonesondes.

Chatfield, R. b.↗

Water Weakening of Calcium Oxide

Chemomechanical processes such as water weakening can control the permeability and deformation of rocks and manmade materials. Here, atomistic modeling and nanomechanical experiments were used to identify molecular origins of chemomechanical effects in calcium oxide (CaO) and its effect on observed elastic, plastic, and brittle deformation. Classical molecular dynamics simulations with the bond order-based reactive force-field ReaxFF were used to assess brittle fracture. In the presence of water, CaO fractured earlier and more often during quasi-static loading, with a calculated reduction in fracture toughness of ~80% associated with changes in the stress distribution around the crack tip. Experimentally, elastic and plastic deformation of CaO surfaces exposed to water was assessed experimentally using in situ liquid nanoindentation. Nanoindentation showed that following exposure to water, the contact hardness decreased by 1–2 orders of magnitude and decreased the modulus by 2–3 orders of magnitude due to surface hydroxylation. Furthermore, the strong chemomechanical effects on the mechanical processes in CaO suggests that minerals with similar structures may exhibit comparable effects, influencing the stability of cements and geomaterials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Room-temperature valley-selective emission in Si-MoSe 2 heterostructures enabled by high-quality-factor chiroptical cavities

Transition metal dichalcogenides possess valley pseudospin, enabling coupling between photon spin and electron spin for classical and quantum information processing. However, rapid valley-dephasing processes have impeded the development of scalable, high-performance valleytronic devices operating at room temperature. Here we demonstrate that a chiral resonant metasurface can enable room-temperature valley-selective emission in MoSe 2 monolayers independent of excitation polarization. This platform provides circular eigen-polarization states with a high quality factor (Q-factor) and strong chiral near-field enhancement. The fabricated Si chiral metasurfaces exhibit chiroptical resonances with Q-factors up to 450 at visible wavelengths. We reveal degrees of circular polarization (DOP) reaching a record high of 0.5 at room temperature. Our measurements show that the high DOP can be attributed to the significantly increased chiroptical local density of states, which enhances valley-specific radiative transition rates by a factor of ~13. Our work could facilitate the development of ultracompact chiral classical and quantum light sources.

42 ENGINEERING↗

Isolated cold plasma regions: Observations and their relation to possible production mechanisms

Regions of enhanced cold plasma, isolated from the main plasmasphere along the Explorer 45 orbit on the equatorial plane, are reported using the sheath induced potentials seen by the electric field experiment. The occurrence of these regions has a strong correlation with negative enhancements of Dst, and their locations are primarily in the noon-dusk quadrant. The data support the concept that changes in large scale convection play a dominant role in the formation of these regions. Plasmatails that are predicted from enhancements of large scale convection electric fields in general define where these regions may be found. More localized processes are necessary to account for the exact configuration and structure seen in these regions and may eventually result in detachment from the main plasmasphere.

Maynard, N. C.↗

Single contact tailored gain phased array of semiconductor lasers

A single contact tailored gain-guided array is demonstrated in which the gain profile across the array is made strongly asymmetric by varying the width of the contact stripes. A proton isolated arary of six (GaAl)As lasers with 5-micron separations and widths varying linearly between 3 and 8 microns had a single lobed far field 2 deg wide, close to the diffraction limit for a single supermode. Fabrication of this device is simple, and suited to large-scale processing techniques. It is also shown that in such an asymmetric gain-guided array the fundamental mode is favored over higher order modes, and that higher order modes can have single lobed far-field patterns differing only slightly from that of the fundamental.

Lindsey, C. P.↗

A model of impulsive acceleration and transport of energetic particles in Mercury's magnetosphere

A qualitative model of substorm processes in the Mercury magnetosphere is presented based on Mariner 10 observations obtained in 1974-1975. The model is predicated on close analogies observed with the terrestrial case. Particular emphasis is given to energetic particle phenomena as observed by Mariner on March 29, 1974. The suggestion is supported that energetic particles up to about 500 keV are produced by strong induced electric fields at 3 to about 6 Mercury radii in the Hermean tail in association with substorm neutral line formation. The bursts of energetic particles produced are, in this model, subsequently confined on closed field lines near Mercury and drift adiabatically on quasi-trapped orbits for many tens of seconds. Such gradient and curvature drift of the particles can explain prominent periodicities of 5-10 s seen in the Mariner for greater than 170-keV electron flux profiles.

Baker, D. N.↗

Atmospheric Electrical Modeling in Support of the NASA F-106 Storm Hazards Project

A recently developed storm electrification model (SEM) is used to investigate the operating environment of the F-106 airplane during the NASA Storm Hazards Project. The model is 2-D, time dependent and uses a bulkwater microphysical parameterization scheme. Electric charges and fields are included, and the model is fully coupled dynamically, microphysically and electrically. One flight showed that a high electric field was developed at the aircraft's operating altitude (28 kft) and that a strong electric field would also be found below 20 kft; however, this low-altitude, high-field region was associated with the presence of small hail, posing a hazard to the aircraft. An operational procedure to increase the frequency of low-altitude lightning strikes was suggested. To further the understanding of lightning within the cloud environment, a parameterization of the lightning process was included in the SEM. It accounted for the initiation, propagation, termination, and charge redistribution associated with an intracloud discharge. Finally, a randomized lightning propagation scheme was developed, and the effects of cloud particles on the initiation of lightning investigated.

Helsdon, John H., Jr.↗

Magnetic reconnection driven by current repulsion

The evolution of an equilibrium consisting of two magnetic islands with oppositely directed currents embedded in a strong magnetic field is investigated, using numerical simulation methods. The rapid development of an ideal magnetohydrodynamic instability is observed, which first rotates and then expels the islands. The growth rate is on the order of the inverse of the Alfven transit time and is much higher than that for magnetic island coalescence. In the nonlinear stage, resistivity becomes important as the reconnection process ensues and dissipates the magnetic energy. The growth rate of the instability is a weak function of the plasma beta and other plasma parameters such as S, the magnetic Reynolds number. An energy principle analysis, based on eigenfunctions obtained from the simulation, confirms the existence of the instability.

Richard, R. L.↗

Laboratory Measurements on Charging of Individual Micron-Size Apollo-11 Dust Grains by Secondary Electron Emissions

Observations made during Apollo missions, as well as theoretical models indicate that the lunar surface and dust grains are electrostatically charged, levitated and transported. Lunar dust grains are charged by UV photoelectric emissions on the lunar dayside and by the impact of the solar wind electrons on the nightside. The knowledge of charging properties of individual lunar dust grains is important for developing appropriate theoretical models and mitigating strategies. Currently, very limited experimental data are available for charging of individual micron-size size lunar dust grains in particular by low energy electron impact. However, experimental results based on extensive laboratory measurements on the charging of individual 0.2-13 micron size lunar dust grains by the secondary electron emissions (SEE) have been presented in a recent publication. The SEE process of charging of micron-size dust grains, however, is found to be very complex phenomena with strong particle size dependence. In this paper we present some examples of the complex nature of the SEE properties of positively charged individual lunar dust grains levitated in an electrodynamic balance (EDB), and show that they remain unaffected by the variation of the AC field employed in the above mentioned measurements.

Tankosic, D.↗

The SUMup Dataset: Compiled Measurements of Surface Mass Balance Components over Ice Sheets and Sea Ice with Analysis over Greenland

Increasing atmospheric temperatures over ice cover affect surface processes, including melt, snowfall, and snow density. Here, we present the Surface Mass Balance and Snow on Sea Ice Working Group (SUMup) dataset, a standardized dataset of Arctic and Antarctic observations of surface mass balance components. The July 2018 SUMup dataset consists of three subdatasets, snow/firn density (https://doi.org/10.18739/A2JH3D23R), at least near-annually resolved snow accumulation on land ice (https://doi.org/10.18739/A2DR2P790), and snow depth on sea ice (https://doi.org/10.18739/A2WS8HK6X), to monitor change and improve estimates of surface mass balance. The measurements in this dataset were compiled from field notes, papers, technical reports, and digital files. SUMup is a compiled, community-based dataset that can be and has been used to evaluate modeling efforts and remote sensing retrievals. Active submission of new or past measurements is encouraged. Analysis of the dataset shows that Greenland Ice Sheet density measurements in the top 1m do not show a strong relationship with annual temperature. At Summit Station, Greenland, accumulation and surface density measurements vary seasonally with lower values during summer months. The SUMup dataset is a dynamic, living dataset that will be updated and expanded for community use as new measurements are taken and new processes are discovered and quantified.

Montgomery, Lynn↗

Tackling P3HT:Y‐Series Miscibility Through Advanced Processing for Tunable Aggregation

Abstract Polymer and small molecule blend thin films are of strong interest for organic electronics and particularly organic solar cells. The high miscibility in blends of ordinary P3HT and state‐of‐the‐art Y‐series non‐fullerene acceptors (NFAs) suppresses phase separation and aggregation challenging successful charge separation and transport. In a recent work, current‐induced doping (CID) is introduced, a method to precisely control the aggregation of Poly(3‐hexylthiophene) (P3HT) in solution. The highly ordered pre‐aggregation in solution is used here to control the P3HT aggregation in neat films and blends with Y12 (BTP‐4F‐12). This results in a 25‐fold increase in hole mobility in P3HT organic field‐effect transistor (OFET) devices and tunability of the P3HT aggregate quality in the presence of Y12 over large ranges. At the same time, particularly the Y12 long‐range ordering is heavily suppressed by increasing P3HT aggregation. However, solvent vapor annealing (SVA) leads to an extraordinarily high Y12 ordering, changes in the crystal orientation of Y12, and a further improvement of P3HT aggregation. A broad range of different degrees of aggregation of both materials can therefore be obtained in the final thin films solely by changing processing parameters without changing the composition of the material system.

Chemistry↗

Wide Bandgap Generation (WBGen): Developing the Future Wide Bandgap Power Electronics Engineering Workforce

This Final Technical Report (FTR) summarizes the work conducted at the Center for Power Electronics Systems (CPES) under the Wide-Bandgap Generation (WBGen) fellowship and traineeship program established by the Advanced Manufacturing and Technologies Office (AMMTO) of the U.S. Department of Energy Office of Energy Efficiency and Renewable Energy (EERE) at Virginia Tech, which had as main objective to train the next generation of U.S. citizen power engineers with wide-bandgap (WBG) power semiconductor expertise, with the intent to aid in fulfilling the future workforce needs in this field. The latter was deemed of strategic importance given the fast-paced growth observed—and predicted—in the demand of this technical expertise, whose practitioners have become the enablers and executioners of the electrification transformation process that not just the U.S., but the whole world, is currently undergoing as it seeks for more effective and efficient ways to use energy. As such, the WBGen program set forth to achieve its educational goals, which in addition sought to broaden the range of WBG-based power electronics by conducting research and development on high-efficiency grid apparatus and high-efficiency electrical power systems, and to also enhance the power engineering curriculum by formalizing WBG-oriented design procedures replacing existent yet now obsolete design procedures developed for Silicon (Si) based power electronics. This effort led CPES to spearhead the development of a new major within The Bradley Electrical and Computer Engineering (ECE) Department at Virginia Tech, namely Electronic Power and Energy Systems (EPES), which coalesced power electronics and power systems courses to provide undergraduate students with a strong formation in the power engineering field, while creating a pipeline of graduate students that could pursue the WBG-based curriculum and conduct research at CPES. In all, in what is considered a true success, eight of the twenty WBGen fellows that graduated program were recruited from the ECE department undergraduate cohort. The traineeship emphasized as well, from its beginning, the partnership with industry and national laboratories, which took advantage of the successful industry consortium at CPES that has historically been formed by 80–90 power and energy companies working in close collaboration with the center. This gave WBGen fellows the accessibility and possibility to conduct internships at partner facilities during the summer months, focused solely on the evaluation, testing, and adoption of WBG devices, which were many times tightly related to their respective research work and plans. In addition, WBGen fellows conducted their main research work within the confines of research programs at CPES conducted with these industry partners, providing them with a unique opportunity to develop not just their technical expertise—while advancing their knowledge, but to also learn and practice a slew of skills needed for their professional growth. As such, the fellows tackled a variety of WBG-related research topics, from device reliability and capability aspects as well as packaging and integration, encompassing the use of advanced materials and new structures, current sharing challenges, and insulation systems, to advanced gate-drivers with integrated sensors and protection mechanisms and active current- and voltage-based control, to optimized layouts seeking to maximize the switching and power processing performance of these devices, to power processing solutions adopting Gallium-Nitride (GaN) and Silicon-Carbide (SiC) power semiconductors for a variety of applications; including radiation-hardened converters for space dc distribution systems, direct three-phase ac-to-ac power converters for aerospace systems, dc-ac inverters for automotive traction drives, high-frequency isolated dc-dc battery chargers also for heavy transportation systems, and medium-voltage dc-dc and dc-ac converters for distribution systems and future power grids. The WBGen program ultimately graduated a total of 20 power engineers, all experts on WBG-based power electronics, awarding 18 M.S. and 2 PhD degrees in the process. These fellows, all U.S. citizens, allowed CPES to increase the number of citizens students to 33 % at the peak of the program, as the traineeship made possible the recruitment of talent with more attractive graduate research assistantship (GRA) contracts. Unfortunately, the present U.S. citizen enrollment at CPES has declined back to historic levels—approximately 10 %, as the regular GRA rates are not competitive enough when compared with entry-level industry jobs. In all, WBGen fellows published a total of 7 peer-reviewed journal articles, 44 papers at international technical conferences, made 42 presentations at international technical conferences, and filed 4 invention disclosures and patent applications, which have since then been granted by the U.S. Patent and Trademark Office (USPTO). Their contribution to CPES, Virginia Tech, the United States, and the world, has been significant, and continues to yield results thanks to the exemplary career that the fellows have initiated at many of the partners of the program, which include Wolfspeed, Raytheon Technologies, Infineon, Lockheed Martin, Dominion Energy, Northrop Grumman, Rivian, Aerospace Corporation, Sandia National Laboratory, National Renewable Energy Laboratory, John Hopkins University, and Virginia Tech.

14 SOLAR ENERGY↗

Water resource recovery modelling 2021 (WRRmod2021 conference)

Our society is transitioning fast into the digital age, spurred by development of cheap and new sensing technology, breakthroughs in computing, and development of efficient algorithms for optimization. This transition is also visible in the field of wastewater treatment and is driving new model developments, especially by exploiting the large data sets available with many utilities. Not surprisingly, WRRmod2021 had featured a strong session on ‘data-driven models and digitalization’ focused on this hot topic. At the same time, engineering practice calls for more robust models for performance evaluation and optimization of both conventional facilities and innovative processes. As a result, the WRRmod2021 program also exhibited sessions on modelling of new process units (e.g., aerobic granular sludge), modelling of the nitrogen cycle, and integrated/plant-wide modelling.

54 ENVIRONMENTAL SCIENCES↗

The protons and electrons trapped in the Jovian dipole magnetic field region and their interaction with Io

Detailed analysis of electrons equal to or greater than 3 MeV and of protons 0.5 to 1.8 MeV and equal to or greater than 35 MeV for both the inbound and the outbound passes of the Pioneer 10 spacecraft. Conclusive evidence is obtained that the trapped radiation in Jupiter's inner magnetosphere is maintained and supplied by inward diffusion from the outer regions of the trapped radiation zone. It is shown that the time required for isotropization of an anisotropic flux by pitch angle scattering inside L approximately equal to 6 is long in comparison with the time required for particles to diffuse inward from L approximately equal to 6 to L approximately equal to 3, that the high-energy protons were not injected at high energies by the Crand (cosmic ray albedo neutron decay) process but were accelerated in the magnetosphere of Jupiter, and that the main conclusions of this analysis are unaffected by use of either the D sub 1 or the D sub 2 magnetic field models. Theoretical studies of the capture of trapped electrons and protons by Io have been carried out, and it is found that the probability of capture by Io depends strongly upon the particle species and kinetic energy.

Simpson, J. A.↗

Results from the Crop Identification Technology Assessment for Remote Sensing (CITARS) project

The author has identified the following significant results. It was found that several factors had a significant effect on crop identification performance: (1) crop maturity and site characteristics, (2) which of several different single date automatic data processing procedures was used for local recognition, (3) nonlocal recognition, both with and without preprocessing for the extension of recognition signatures, and (4) use of multidate data. It also was found that classification accuracy for field center pixels was not a reliable indicator of proportion estimation performance for whole areas, that bias was present in proportion estimates, and that training data and procedures strongly influenced crop identification performance.

Bauer, M. E.↗

High-energy gamma-ray absorption in relativistic magnetospheres

Calculations are made of the propagation of gamma-rays around neutron stars with a dipole magnetic field, including the effects of general relativity and the absorption by the one-photon magnetic pair production process, as a model for the high-energy transport in gamma-ray burst sources and pulsars. The paper discusses the escaping photon beam characteristics as seen by distant observers at different angles with respect to the magnetic axis, for radiation arising from the polar caps of neutron stars of varying degrees of compactness and surface field strengths. The observed beaming depends strongly on the surface field only up to B of about 0.05 times the critical field value, being essentially constant above the value 0.1. The gravitational light bending contributes significantly to broaden the beam profiles especially at low energies above threshold, being sensitive to the stellar radius to mass ratio.

Riffert, H.↗

Nonlinear Landau damping and Alfven wave dissipation

Nonlinear Landau damping has been often suggested to be the cause of the dissipation of Alfven waves in the solar wind as well as the mechanism for ion heating and selective preacceleration in solar flares. We discuss the viability of these processes in light of our theoretical and numerical results. We present one-dimensional hybrid plasma simulations of the nonlinear Landau damping of parallel Alfven waves. In this scenario, two Alfven waves nonresonantly combine to create second-order magnetic field pressure gradients, which then drive density fluctuations, which in turn drive a second-order longitudinal electric field. Under certain conditions, this electric field strongly interacts with the ambient ions via the Landau resonance which leads to a rapid dissipation of the Alfven wave energy. While there is a net flux of energy from the waves to the ions, one of the Alfven waves will grow if both have the same polarization. We compare damping and growth rates from plasma simulations with those predicted by Lee and Volk (1973), and also discuss the evolution of the ambient ion distribution. We then consider this nonlinear interaction in the presence of a spectrum of Alfven waves, and discuss the spectrum's influence on the growth or damping of a single wave. We also discuss the implications for wave dissipation and ion heating in the solar wind.

Vinas, Adolfo F.↗

Radar Differential Phase Signatures of Ice Orientation for the Prediction of Lightning Initiation and Cessation

The majority of lightning-related casualties typically occur during thunderstorm initiation (e.g., first flash) or dissipation (e.g., last flash). The physics of electrification and lightning production during thunderstorm initiation is fairly well understood. As such, the literature includes a number of studies presenting various radar techniques (using reflectivity and, if available, other dual-polarimetric parameters) for the anticipation of initial electrification and first lightning flash. These radar techniques have shown considerable skill at forecasting first flash. On the other hand, electrical processes and lightning production during thunderstorm dissipation are not nearly as well understood and few, if any, successful techniques have been developed to anticipate the last flash and subsequent cessation of lightning. One promising approach involves the use of dual-polarimetric radar variables to infer the presence of oriented ice crystals in lightning producing storms. In the absence of strong vertical electric fields, ice crystals fall with their largest (semi-major) axis in the horizontal associated with gravitational and aerodynamic forces. In thunderstorms, strong vertical electric fields (100-200 kV m(sup -1)) have been shown to orient small (less than 2 mm) ice crystals such that their semi-major axis is vertical (or nearly vertical). After a lightning flash, the electric field is typically relaxed and prior radar research suggests that ice crystals rapidly resume their preferred horizontal orientation. In active thunderstorms, the vertical electric field quickly recovers and the ice crystals repeat this cycle of orientation for each nearby flash. This change in ice crystal orientation from primarily horizontal to vertical during the development of strong vertical electric fields prior to a lightning flash forms the physical basis for anticipating lightning initiation and, potentially, cessation. Research has shown that radar reflectivity (Z) and other co-polar back-scattering radar measurements like differential reflectivity (Z(sub dr)) typically measured by operational dual-polarimetric radars are not sensitive to these changes in ice crystal orientation. However, prior research has demonstrated that oriented ice crystals cause significant propagation effects that can be routinely measured by most dual-polarimetric radars from X-band (3 cm) to S-band (10 cm) wavelengths using the differential propagation phase shift (often just called differential phase, phi(sub dp)) or its range derivative, the specific differential phase (K(sub dp)). Advantages of the differential phase include independence from absolute or relative power calibration, attenuation, differential attenuation and relative insensitivity to ground clutter and partial beam occultation effects (as long as the signal remains above noise). In research mode, these sorts of techniques have been used to anticipate initial cloud electrification, lightning initiation, and cessation. In this study, we develop a simplified model of ice crystal size, shape, orientation, dielectric, and associated radar scattering and propagation effects in order to simulate various idealized scenarios of ice crystals responding to a hypothetical electric field and their dual-polarimetric radar signatures leading up to lightning initiation and particularly cessation. The sensitivity of the K(sub dp) ice orientation signature to various ice properties and radar wavelength will be explored. Since K(sub dp) is proportional to frequency in the Rayleigh- Gans scattering regime, the ice orientation signatures should be more obvious at higher (lower) frequencies (wavelengths). As a result, simulations at radar wavelengths from 10 cm down to 1 cm (Ka-band) will be conducted. Resonance effects will be considered using the T-matrix method. Since most K(sub dp) Vbased observations have been shown at S-band, we will present ice orientation signatures from C-band (UAH/NASA ARMOR) and X-bd (UAH MAX) dual-polarimetric radars located in Northern Alabama. Issues related to optimal radar scanning for the detection of oriented ice will be discussed. Preliminary suggestions on how these differential phase signatures of oriented ice could contribute to lightning initiation and cessation algorithms will be presented.

Carey, L.D.↗