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At least 613 records · Page 34

Recent Progress in Characterization of Dust over Land Surfaces with Space-borne Passive Remote Sensing

Among the many components that contribute to air pollution, airborne mineral dust plays an important role due to its biogeochemical impact on the ecosystem and its radiative-forcing effect on the climate system. In East Asia, dust storms frequently accompany the cold and dry air masses that occur as part of springtime cold front systems. Outbreaks of Asian dust storms occur often in the arid and semi-arid areas of northwestern China -about 1.6x10(exp 6) square kilometers including the Gobi and Taklimakan deserts- with continuous expanding of spatial coverage. These airborne dust particles, originating in desert areas far from polluted regions, interact with anthropogenic sulfate and soot aerosols emitted from Chinese mega-cities during their transport over the mainland. Adding the intricate effects of clouds and marine aerosols, dust particles reaching the marine environment can have drastically different properties than those from their sources. Furthermore, these aerosols, once generated over the source regions, can be transported out of the boundary layer into the free troposphere and can travel thousands of kilometers across the Pacific into the United States and beyond. In this paper, we will demonstrate the capability of a new satellite algorithm to retrieve aerosol properties (e.g., optical thickness, single scattering albedo) over bright-reflecting surfaces such as urban areas and deserts. Such retrievals have been difficult to perform using previously available algorithms that use wavelengths from the mid-visible to the near IR because they have trouble separating the aerosol signal from the contribution due to the bright surface reflectance. This new algorithm, called Deep Blue, utilizes blue-wavelength measurements from instruments such as SeaWiFS and MODIS to infer the properties of aerosols, since the surface reflectance over land in the blue part of the spectrum is much lower than for longer wavelength channels. Reasonable agreements have been achieved between Deep Blue retrievals of aerosol optical thickness and those directly from AERONET sunphotometers over desert and semi-desert regions. New Deep Blue products will allow scientists to determine quantitatively the aerosol properties near sources using high spatial resolution measurements from SeaWiFS and MODIS-like instruments. Long-term satellite measurements (1998 - 2007) from SeaWiFS will be utilized to investigate the interannual variability of source, pathway, and dust loading associated with the Asian dust storm outbreaks. In addition, monthly averaged aerosol optical thickness during the springtime from SeaWiFS will also be compared with the MODIS Deep Blue products.

Hsu, N. Christina↗

Atmospheric Research 2018 Technical Highlights

Atmospheric research in the Earth Sciences Division (610) consists of research and technology development programs dedicated to advancing knowledge and understanding of the atmosphere and its interaction with the climate of Earth. The Division’s goals are to improve understanding of the dynamics and physical properties of precipitation, clouds, and aerosols; atmospheric chemistry, including the role of natural and anthropogenic trace species on the ozone balance in the stratosphere and the troposphere; and radiative properties of Earth’s atmosphere and the influence of solar variability on the Earth’s climate. Major research activities are carried out in the Mesoscale Atmospheric Processes Laboratory, the Climate and Radiation Laboratory, the Atmospheric Chemistry and Dynamics Laboratory, and the Wallops Field Support Office. The overall scope of the research covers an end-to-end process, starting with the identification of scientific problems, leading to observation requirements for remote sensing platforms, technology and retrieval algorithm development; followed by flight projects and satellite missions; and eventually, resulting in data processing, analyses of measurements, and dissemination from flight projects and missions.

Highlights↗

Dust Modeling with GEOS-Chem: Evidence for Acidic Uptake on Dust Surfaces during INTEX-B

We use measurements of aerosol ion composition and size made from the DC8 aircraft during the 2006 INTEX-B airborne campaign to identify mineral dust signatures, and look for evidence for interaction of dust with acidic components. Coating of dust with sulfate or nitrate favors the role of dust particles as cloud condensation nucleii, can promote further uptake of SO2 and N2O5, can impact NOx/HNO3 partitioning, and can shift sulfate or nitrate towards larger sizes, affecting atmospheric lifetimes for both aerosol and gas components. Mineral dust had a pervasive presence on flights made during the Northern Pacific deployment of the INTEX-B mission. We use scatter plots of ion mixing ratios with Na+ and Ca(2+) to distinguish sea salt and mineral components of the aerosol distribution, respectively. Positive correlations of non-sea-salt sulfate and nitrate with calcium indicate that the dusty air stream is associated with polluted air masses. Sulfate-ammonium scatter plots indicate sulfate to be primarily in the form of (NH4)2SO4. A positive correlation between Ca(2+) and NO-, but little evidence of NH4NO3, suggests that NO3- may be associated with mineral dust surfaces. 3-d model simulations conducted with the GEOS-Chem chemical transport model indicate that transpacific transport from East Asia was principally responsible for the dust observed from the aircraft over the Pacific. We compare the aerosol component relationships in the model with those observed. Uptake of sulfate and nitrate on the dust is not yet represented in the model.

Fairlie, T. Duncan↗

Simultaneous Retrieval of Aerosol and Surface Optical Properties from Combined Airborne- and Ground-Based Direct and Diffuse Radiometric Measurements

This paper presents a new method for simultaneously retrieving aerosol and surface reflectance properties from combined airborne and ground-based direct and diffuse radiometric measurements. The method is based on the standard Aerosol Robotic Network (AERONET) method for retrieving aerosol size distribution, complex index of refraction, and single scattering albedo, but modified to retrieve aerosol properties in two layers, below and above the aircraft, and parameters on surface optical properties from combined datasets (Cloud Absorption Radiometer (CAR) and AERONET data). A key advantage of this method is the inversion of all available spectral and angular data at the same time, while accounting for the influence of noise in the inversion procedure using statistical optimization. The wide spectral (0.34-2.30 m) and angular range (180 ) of the CAR instrument, combined with observations from an AERONET sunphotometer, provide sufficient measurement constraints for characterizing aerosol and surface properties with minimal assumptions. The robustness of the method was tested on observations made during four different field campaigns: (a) the Southern African Regional Science Initiative 2000 over Mongu, Zambia, (b) the Intercontinental Transport Experiment-Phase B over Mexico City, Mexico (c) Cloud and Land Surface Interaction Campaign over the Atmospheric Radiation Measurement (ARM) Central Facility, Oklahoma, USA, and (d) the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) over Elson Lagoon in Barrow, Alaska, USA. The four areas are dominated by different surface characteristics and aerosol types, and therefore provide good test cases for the new inversion method.

Gatebe, C. K.↗

LASE Measurements of Water Vapor, Aerosol, and Cloud Distributions in Saharan Air Layers and Tropical Disturbances

LASE (Lidar Atmospheric Sensing Experiment) on-board the NASA DC-8 measured high resolution profiles of water vapor and aerosols, and cloud distributions in 14 flights over the eastern North Atlantic during the NAMMA (NASA African Monsoon Multidisciplinary Analyses) field experiment. These measurements were used to study African easterly waves (AEWs), tropical cyclones (TCs), and the Saharan Air Layer(s) (SAL). Interactions between the SAL and tropical air were observed during the early stages of the TC development. These LASE measurements represent the first simultaneous water vapor and aerosol lidar measurements to study the SAL and its impact on AEWs and TCs. Examples of profile measurements of aerosol scattering ratios, aerosol extinction coefficients, aerosol optical thickness, water vapor mixing ratios, RH, and temperature are presented to illustrate their characteristics in SAL, convection, and clear air regions. LASE data suggest that the SAL suppresses low-altitude convection at the convection-SAL interface region. Mid-level convection associated with the AEW and transport are likely responsible for high water vapor content observed in the southern regions of the SAL on August 20, 2008. This interaction is responsible for the transfer of about 7 x 10(exp 15) J latent heat energy within a day to the SAL. Measurements of lidar extinction-to-backscatter ratios in the range 36+/-5 to 45+/-5 are within the range of measurements from other lidar measurements of dust. LASE aerosol extinction and water vapor profiles are validated by comparison with onboard in situ aerosol measurements and GPS dropsonde water vapor soundings, respectively.

Ismail, Syed↗

Comment on 'A note on the possible connection between the El Chichon eruption and ocean production in the northwest Arabian Sea during 1982' by A. E. Strong

Strong argues that the El Chichon aerosol cloud resulted in relaxed southwest monsoon circulation and the dramatically reduced seasonal phytoplankton bloom documented in the northwestern Arabian Sea during summer and fall of 1982. It is argued here that Strong's ideas suggest a clear demonstration of an atmosphere-ocean interaction with implications for the ocean's biological CO2 pump. Strong's paper highlights the fundamentally different effects of volcanic aerosols on satellite infrared and visible band observations of the ocean.

Brock, John C.↗

Updraft Dynamics and Microphysics: On the Added Value of The Cumulus Thermal Reference Frame in Simulations of Aerosol–Deep Convection Interactions

One fundamental question about atmospheric moist convection processes that remains debated is whether, or under which conditions, a relevant variability in background aerosol concentrations may have a significant dynamical impact on convective clouds and their associated precipitation. Furthermore, current climate models must parameterize both the microphysical and the cumulus convection processes, but this is usually implemented separately, whereas in nature there is a strong coupling between them. As a first step to improve our understanding of these two problems, we investigate how aerosol concentrations modify key properties of updrafts in eight large-eddy-permitting regional simulations of a case study of scattered convection over Houston, Texas, in which convection is explicitly simulated and microphysical processes are parameterized. Dynamical and liquid-phase microphysical responses are investigated using the following two different reference frames: static cloudy updraft grid cells versus tracked cumulus thermals. In both frameworks, we observe the expected microphysical responses to higher aerosol concentrations, such as higher cloud number concentrations and lower rain number concentrations. In terms of the dynamical responses, both frameworks indicate weak impacts of varying aerosol concentrations relative to the noise between simulations over the observationally derived range of aerosol variability for this case study. On the other hand, results suggest that thermals are more selective than cloudy updraft grid cells in terms of sampling the most active convective air masses. For instance, vertical velocity from thermals is significantly higher at upper levels than when sampled from cloudy updraft grid points, and several microphysical variables have higher average values in the cumulus thermal framework than in the cloudy updraft framework. In addition, the thermal analysis is seen to add rich quantitative information about the rates and covariability of microphysical processes spatially and throughout tracked thermal lifecycles, which can serve as a stronger foundation for improving subgrid-scale parameterizations.

aerosols↗

Updraft Dynamics and Microphysics: On the Added Value of the Cumulus Thermal Reference Frame in Simulations of Aerosol–Deep Convection Interactions

One fundamental question about atmospheric moist convection processes that remains debated is whether or under what conditions a relevant variability in background aerosol concentrations may have a significant dynamical impact on convective clouds and their associated precipitation. Furthermore, current climate models must parameterize both the microphysical and the cumulus convection processes, but this is usually implemented separately, whereas in nature there is a strong coupling between them. As a first step to improve our understanding of these two problems, we investigate how aerosol concentrations modify key properties of updrafts in eight large-eddy permitting regional simulations of a case study of scattered convection over Houston, Texas, in which convection is explicitly simulated and microphysical processes are parameterized. Dynamical and liquid-phase microphysical responses are investigated using two different reference frames: static cloudy-updraft grid cells versus tracked cumulus thermals. In both frameworks we observe the expected microphysical responses to higher aerosol concentrations, such as higher cloud number concentrations and lower rain number concentrations. In terms of the dynamical responses, both frameworks indicate weak impacts of varying aerosol concentrations relative to the noise between simulations over the observationally derived range of aerosol variability for this case study. On the other hand, results suggest that thermals are more selective than cloudy-updraft grid cells in terms of sampling the most active convective air masses. For instance, vertical velocity from thermals is significantly higher at upper levels than when sampled from cloudy-updraft grid points, and several microphysical variables have higher average values in the cumulus thermal framework than in the cloudy-updraft framework. In addition, the thermal analysis is seen to add rich quantitative information about the rates and covariability of microphysical processes spatially and throughout tracked thermal lifecycles, which can serve as a stronger foundation for improving subgrid-scale parameterizations.

Daniel Hernandez-Deckers↗

Microphysical modeling of cirrus. 1: Comparison with 1986 FIRE IFO measurements

We have used a one-dimensional model of cirrus formation to study the development of cirrus clouds during the 1986 First ISCCP (International Satellite Cloud Climatology Project) Regional Experiment (FIRE) intensive field observations (IFO). The cirrus model includes microphysical, dynamical, and radiative processes. Sulfate aerosols, solution drops, ice crystals, and water vapor are all treated as interactive elements in the model. Ice crystal size distributions are fully resolved based on calculations of homogeneous freezing nucleation, growth by water vapor deposition, evaporation, coagulation, and vertical transport. We have focused on the cirrus observed on November 1, 1986. Vertical wind speed for the one-dimensional simulation is taken from a mesoscale model simulation for the appropriate time period. The mesoscale model simulation suggested that strong upward motions over Wyoming and subsequent horizontal transport of upper level moisture were responsible for the cirrus observed over Wisconsin on this date. We assumed that our one-dimensional model could be used to represent a vertical column moving from Wyoming to Wisconsin over a period of several hours. Ice crystal nucleation occurs in our model in the 8 to 10-km region as a result of the strong updrafts (and cooling) early in the simulation. Growth, coagulation, and sedimentation of these ice crystals result in a broad cloud region (5-10 km thick) with an optical depth of 1-2 after a few hours, in agreement with the FIRE measurements. Comparison with aircraft microphysical measurements made over Wisconsin indicates that the simulation generated reasonable ice water content, but the predicted ice number densities are too low, especially for radii less than about 50 microns. Sensitivity tests suggest that better agreement between simulated and observed microphysical properties is achieved if the nucleation rate is higher or stronger vertical mixing (perhaps associated with multidimensional motions) is present.

Jensen, Eric J.↗

Climatic impact of volcanic eruptions

Studies have attempted to 'isolate' the volcanic signal in noisy temperature data. This assumes that it is possible to isolate a distinct volcanic signal in a record that may have a combination of forcings (ENSO, solar variability, random fluctuations, volcanism) that all interact. The key to discovering the greatest effects of volcanoes on short-term climate may be to concentrate on temperatures in regions where the effects of aerosol clouds may be amplified by perturbed atmospheric circulation patterns. This is especially true in subpolar and midlatitude areas affected by changes in the position of the polar front. Such climatic perturbation can be detected in proxy evidence such as decrease in tree-ring widths and frost rings, changes in the treeline, weather anomalies, severity of sea-ice in polar and subpolar regions, and poor grain yields and crop failures. In low latitudes, sudden temperature drops were correlated with the passage overhead of the volcanic dust cloud (Stothers, 1984). For some eruptions, such as Tambora, 1815, these kinds of proxy and anectdotal information were summarized in great detail in a number of papers and books (e.g., Post, 1978; Stothers, 1984; Stommel and Stommel, 1986; C. R. Harrington, in press). These studies lead to the general conclusion that regional effects on climate, sometimes quite severe, may be the major impact of large historical volcanic aerosol clouds.

Rampino, Michael R.↗

Burning conditions and transportation pathways determine biomass-burning aerosol properties in the Ascension Island marine boundary layer

Abstract. African biomass-burning aerosol (BBA) in the southeast Atlantic Ocean (SEA) marine boundary layer (MBL) is an important contributor to Earth's radiation budget, yet its representation remains poorly constrained in regional and global climate models. Data from the Layered Atlantic Smoke Interactions with Clouds (LASIC) field campaign on Ascension Island (7.95° S, 14.36° W) provide insight into how burning conditions, fuel type, transport pathways, and atmospheric processing affect the chemical, microphysical, and optical properties of BBA between June and September 2017. A total of 10 individual plume events characterize the seasonal evolution of the BBA properties. Early-season inefficient fires, determined by low refractory black carbon to above-background carbon monoxide mixing ratios (rBC : ΔCO), led to enhanced concentrations of organic- and sulfate-rich aerosols. Mid-season efficient fires, determined by higher rBC : ΔCO values, led to rBC-enriched BBA. A mix of efficient and inefficient fires later in the season resulted in conflicting BBA properties. Prolonged transport (∼ 10 d) through the MBL and lower free troposphere (FT) facilitated chemical and aqueous-phase processing, which led to a reduction in organic aerosol mass concentrations. This resulted in lower organic aerosol (OA) to rBC (OA : rBC) mass ratios (2–5) in the MBL compared to higher values (5–15) in the nearby FT. These atmospheric and cloud oxidation processes yield more light-absorbing BBA and explain the notably low single-scattering albedo at 530 nm (SSA530) values (< 0.80) observed in the MBL. This study establishes a robust correlation between SSA530 and OA : rBC across the MBL and FT, underscoring the dependency of optical properties on chemical composition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Burning conditions and transportation pathways determine biomass-burning aerosol properties in the Ascension Island marine boundary layer

African biomass-burning aerosol (BBA) in the southeast Atlantic Ocean (SEA) marine boundary layer (MBL) is an important contributor to Earth’s radiation budget yet its representation remains poorly constrained in regional and global climate models. Data from the Layered Atlantic Smoke Interactions with Clouds (LASIC) field campaign on Ascension Island (-7.95° N, -14.36° E) detail how fire source regions (burning conditions and fuel type), transport pathways, and longer-term chemical processing affect the chemical, microphysical, and optical properties of the BBA in the remote MBL between June and September of 2017. Ten individual plume events characterize the seasonal evolution of BBA characteristics. Inefficient burning conditions, determined by the mass ratio of refractory black carbon to above-background carbon monoxide (rBC:ΔCO), enhance organic- and sulfate-rich aerosol concentrations in June–July. In contrast, the heart of the burning season exhibited higher rBC:ΔCO values indicative of efficient burning conditions, correlating with more rBC-enriched BBA. Toward the end of the burning season, a mix of burning conditions results in increased variation of the BBA properties. The BBA transit to Ascension Island was predominantly through slow-moving pathways in the MBL and lower free troposphere (FT), facilitating prolonged chemical transformations through heterogeneous and aqueous phase processes. Heterogeneous oxidation can persist for up to 10 days, resulting in a considerable decrease in organic aerosol (OA) mass. OA to rBC mass ratios (OA:rBC) in the MBL between 2 and 5 contrast to higher values of 5 to 15 observed in the nearby FT. Conversely, early-season aqueous-phase processes primarily contributed to aerosol oxidation and some aerosol production, but not appreciable aerosol removal. These two chemical processes yield more light-absorbing BBA in the MBL than in the FT and explain the notably low scattering albedo at 530 nm (SSA 530 ) values (< 0.80) at Ascension Island. This study establishes a robust correlation between SSA 530 and OA:rBC across both MBL and FT, underscoring the dependency of optical properties on chemical composition. These findings highlight how the interplay between chemical composition and atmospheric processing can be improved in global and regional climate models. Questions remain on the mixing of aerosols with different pathway histories, and on what accounts for the doubling of the mass absorption coefficient in the boundary layer.

54 ENVIRONMENTAL SCIENCES↗

Anthropogenic Air Pollution Observed Near Dust Source Regions in Northwestern China During Springtime 2008

Trace gases and aerosols were measured in Zhangye (39.082degN, 100.276degE, 1460 m a.s. 1.), a rural site near the Gobi deserts in northwestern China during spring 2008. Primary trace gases (CO:265 ppb; SO2:3.4 ppb; NO(*y): 4.2 ppb; hereafter results given as means of hourly data) in the area were lower than in eastern China, but still indicative of marked anthropogenic emissions. Sizable aerosol mass concentration (153 micro-g/cu m) and light scattering (159/Mm at 500 nm) were largely attributable to dust emissions, and aerosol light absorption (10.3/Mm at 500 nm) was dominated by anthropogenic pollution. Distinct diurnal variations in meteorology and pollution were induced by the local valley terrain. Strong daytime northwest valley wind cleaned out pollution and was replaced by southeast mountain wind that allowed pollutants to build up overnight. In the afternoon, aerosols had single scattering albedo (SSA, 500 mn) of 0.95 and were mainly of supermicron particles, presumably dust, while at night smaller particles and SSA of 0.89-0.91 were related to Pollution. The diverse local emission sources were characterized: the CO/SO2, CO/NO(y), NO(y)/SO2 (by moles), and BC/CO (by mass) ratios for small point sources such as factories were 24.6-54.2, 25.8-35.9, 0.79-1.31, and 4.1-6.1 x 10(exp -3), respectively, compared to the corresponding inventory ratios of 43.7-71.9, 23.7-25.7, 1.84-2.79, and 3.4-4.0 x 10(exp -3) for the industrial sector in the area. The mixing between dust and pollution can be ubiquitous in this region. During a dust storm shown as an example, pollutants were observed to mix with dust, causing discernible changes in both SSA and aerosol size distribution. Further interaction between dust and pollutants during transport may modify the properties of dust particles that are critical for their large-scale impact on radiation, clouds, and global biogeochemical cycles.

Li, Can↗

Scientific Objectives, measurement needs, and challenges motivating the PARAGON Aerosol Initiative

A systematic, comprehensive aerosol research framework needs to replace the current, fragmented approach. The Progressive Aerosol Retrieval and Assimilation Global Observing Network (PARAGON) concept (Diner et al. 2004) envisions a coordinated and systematic approach for dramatically improving our understanding of aerosol climate impacts and environmental interactions. Among its scientific motivations is the need to establish, with great confidence, the magnitude of direct anthropogenic aerosol influences on climate and the magnitude and sign of indirect aerosol–cloud effects. Modeling of the industrial era temperature record indicates that net aerosol forcing is slightly less, but opposite in sign, than forcing from anthropogenic greenhouse gases (GHGs). However, the uncertainties in aerosol direct and indirect anthropogenic forcing are of the same magnitude as the effects themselves (Penner et al. 2001; Ramaswamy et al. 2001), and are the dominant sources of uncertainty in current estimates of total anthropogenic climate forcing. A major cause of uncertainty is the tremendous tropospheric aerosol variability in space and time. On regional scales, aerosols can have a much greater effect than GHGs, especially at the earth’s surface.

Wielicki, Bruce A.↗

Aerosol Vertical Turbulent Mass Flux Retrievals Through Novel Remote Sensing Algorithm

Abstract Integrated measurements of aerosol, radiation, cloud, and turbulent transport in the planetary boundary layer (PBL) are essential for understanding and modeling climate and air quality. Here, we developed a new technique for the identification of convective turbulent regions and deriving the vertical distribution of aerosol turbulent mass fluxes within PBL. The algorithm uses retrievals from coherent Doppler lidars and a high spectral resolution lidar. The technique was applied to study particle mass fluxes over 2 months (November–December 2020) during the campaign conducted at the DOE Atmospheric Radiation Measurement Southern Great Plains (SGP) site in Lamont, Oklahoma. The algorithm developed here is capable of continuously deriving vertically resolved (curtains) aerosol mass fluxes. Our data analysis shows that at the site, the 30‐min averaged fluxes at 135 m above the surface were mainly positive (upward) at ∼1 μg m −2 s −1 , suggesting that the surface is the primary source of the particle mass supplied to the boundary layer at the SGP site. Analyses of the individual case studies have revealed that not all the derived fluxes can be linked to surface emissions. Both positive and negative values in a range of ±5 μg m −2 s −1 can be caused by convective thermals interacting between the residual layer and the mixed layer and by rotation of the horizontal wind with the height. Large erroneous negative fluxes can also be caused by drizzling/precipitating clouds. We anticipate that the application of the current technique will lead to a more realistic representation of aerosol mass budgets and bidirectional mixing rates.

54 ENVIRONMENTAL SCIENCES↗

Dust, Pollution, and Biomass Burning Aerosols in Asian Pacific: A Column Surface/Satellite Perspective

Many recent field experiments are designed to study the compelling variability in spatial and temporal scale of both pollution-derived and naturally occurring aerosols, which often exist in high concentrations over eastern/southeastern Asia and along the rim of the western Pacific. For example, the phase-I of ACE-Asia was conducted from March-May 2001 in the vicinity of the Gobi desert, East Coast of China, Yellow Sea, Korea, and Japan, along the pathway of Kosa (severe events that blanket East Asia with yellow desert dust, peaked in the Spring season). Asian dust typically originates in desert areas far from polluted urban regions. During transport, dust layers can interact with anthropogenic sulfate and soot aerosols from heavily polluted urban areas. Springtime is also the peak season for biomass burning in southeastern Asia. Added to the complex effects of clouds and natural marine aerosols, dust particles reaching the marine environment can have drastically different properties than those from the source. Thus, understanding the unique temporal and spatial variations of Asian aerosols is of special importance in regional-to-global climate issues such as radiative forcing, the hydrological cycle, and primary biological productivity in the mid-Pacific Ocean. During ACE-Asia we have measured continuously aerosol physical/optical/radiative properties, column precipitable water amount, and surface reflectivity over homogeneous areas from surface. The inclusion of flux measurements permits the determination of aerosol radiative flux in addition to measurements of loading and optical depth. At the time of the Terra/MODIS (Moderate Resolution Imaging Spectroradiometer), SeaWiFS (Sea-viewing Wide Field-of-view Sensor), TOMS (Total Ozone Mapping Spectrometer) and other satellite overpasses, these ground-based observations can provide valuable data to compare with satellite retrievals over land. A column satellite-surface perspective of Asian aerosols will be presented and will discuss their implications in regional-to-global effects on climate, fresh water redistribution, and health issues. (to be presented in Hawaii, April 28 - May 3, and Beijing, China, May 6 - 10, 2002)

Tsay, Si-Chee↗

Characterization of carbonaceous aerosols during TRACER-CAT

Absorbing aerosols (AA) have an important impact on the global radiation budget and cloud properties. The composition and properties of AA can vary substantially throughout the atmosphere, depending on the particle source and the influence of chemical aging. Uncertainties associated with the radiative effects of AA remain substantial. A key contributor to this uncertainty is understanding the extent to which coatings in general, and water uptake especially, alters absorption by AA particles and how this depends on particle composition. We deployed new and existing experimental tools during the Tracking Aerosol Convection Interactions Experiment (TRACER) campaign in Houston, TX as part of the Carbonaceous Aerosols Thrust (CAT) to provide detailed characterization of aerosol optical, chemical, and physical properties. Our TRACER-CAT measurements complemented and expanded on the planned TRACER instrumentation, allowing for more detailed characterization of aerosol properties of relevance to cloud development (a core focus of TRACER), such as the composition of particles that can act as cloud condensation nuclei, than would otherwise be available. Our measurements have allowed for assessment of the relationship(s) between AA optical properties (with a focus on absorption) and the chemical and physical characteristics (including the mixing state of black carbon (BC) containing particles). These field observations occurred in collaboration with Los Alamos National Laboratory in summer 2022 during the TRACER intensive operating period. The instrumentation we co-deployed provided for measurement of (i) multi-wavelength dry aerosol absorption, scattering, and extinction, (ii) the size-dependent composition and abundance of sub-micron aerosol, differentiating between those particles that do and do not contain BC, (iii) BC-specific concentrations and size distributions, (iv) particle size, and (v) the first field measurements at an ARM site of the influence of RH on multi-wavelength absorption by ambient AA. We have leveraged the natural variability of the atmosphere and of aerosol sources in the Houston region to (i) specifically disentangle contributions to light absorption from BC, absorbing organic carbon (brown carbon), and coatings on BC, (ii) characterize the mixing state of BC and assess the factors that give rise to compositional differences between BC-containing and BC-free aerosol, and (iii) establish how water uptake influences absorption and how any such effect depends on particle composition and BC mixing state. Overall, our study contributed to the mission of the Atmospheric System Research program in multiple ways. Through the deployment of complementary, advanced instrumentation for characterization of a wide range of aerosol properties our work helped to maximize the scientific impact of the TRACER campaign. Our work also allowed for development of new insights into the relationship(s) between aerosol composition, hygroscopicity, and the mixing state of BC with aerosol optical properties. Through this, our work has provided knowledge that can improve understanding and model representation of aerosol processes as they affect the Earth’s radiation budget.

54 ENVIRONMENTAL SCIENCES↗

Evaluation of Ice Nucleating Particles and Their Sources in the Central Arctic during MOSAiC

The Arctic is warming faster than any other region on Earth, causing glaciers to melt, frozen ground to thaw, and the Arctic Ocean's ice to shrink. These consequential changes induce feedback loops that exacerbate warming and affect weather and climate worldwide. Microscopic airborne particles called "aerosols" and clouds in the sky are crucial for regulating heat and light reaching the Arctic surface. However, the magnitude of their effects is not adequately quantified, especially in the central Arctic, where they impact temperatures directly over the sea ice. Unique aerosols called "ice nucleating particles" (INPs), which play a significant role in cloud ice production, remain understudied. Understanding how ice forms in clouds is critical in the Arctic, as it affects cloud lifespan, interactions with heat and light, and precipitation. In this project, we conducted the first-ever observations of INPs in the middle of the Arctic over a whole year, covering the entire period when sea ice grows and melts. Furthermore, these are the first observations of INPs in different size ranges throughout the year, anywhere in the world. We use DNA sequencing to evaluate the presence of various types of microorganisms, while INP measurements on seawater, sea ice, snow, and meltwater samples help assess potential local Arctic sources of INPs. The results from this work are currently being used to improve the accuracy of Arctic cloud formation in various models.

54 ENVIRONMENTAL SCIENCES↗