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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34

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NASA NTRS1982

Properties of dust in the Martian atmosphere and its effect on temperature structure

Data from the Viking lander imaging experiment and the IRIS experiment on board the Mariner 9 Orbiter are used to develop a one-dimensional radiative-convective model to describe the Mars temperature profile. Photography was employed to determine the optical depth, mean size, shape, visible absorption coefficient, and vertical distribution of aerosols in the Mars atmosphere. The calculation procedures are outlined, particularly for the particle size distribution function, which indicated a cross-sectional average particle radius of 2.5 microns. Dust-free conditions in the atmosphere near the equator and at lower altitudes permit full surface absorption of sunlight and subsequent adiabatic lapse rates. Difficulties were encountered in accurately modeling temperature profiles to fit Viking lander data, and resultant variations are attributed to effects of both suspended dust particles and large scale circulation.

Pollack, J. B.↗

NASA NTRS1982

Characterization of the outgassing of spacecraft materials

Equations which describe material outgassing in spaceflight conditions are integrated over temperatures up to 125 C and with outgassing kinetic energies up to 40 kcal/mole. The outgassing rate is noted to be formulated as an expression of sublimation and evaporation, and can be a function of the materials of the outgassing process. The predicted mass loss rates for various materials are compared with mass loss rates from materials with known activation energies, e.g., silicone and solar panel samples, held at different temperatures and for varying time lengths. The comparisons are made for first order and more complex outgassing kinetics. The technique is concluded to be useful for a quick characterization of candidate materials for spaceflight considerations when contamination is a significant factor.

Scialdone, J. J.↗

NASA NTRS1993

Check valve with poppet dashpot/frictional damping mechanism

An inline check valve for a flow line where the valve element is guided for inline travel forward and rearward of a valve sealing member and is spring biased to a closed sealing condition is presented. One of the guides for the valve element includes a dashpot housing with a bore and plunger member to control the rate of travel of the valve element in either direction, providing a guiding function. The plunger member is arranged with a dashpot ring to frictionally contact the dashpot bore and has an interior tortuous flow path from one side to the other side of the dashpot ring. The dashpot housing is not anchored to the valve body so that the valve can be functional even if the dashpot ring becomes jammed in the dashpot housing.

Morris, Brian G.↗

NASA NTRS1999

Probabilistic Analysis of Aircraft Gas Turbine Disk Life and Reliability

Two series of low cycle fatigue (LCF) test data for two groups of different aircraft gas turbine engine compressor disk geometries were reanalyzed and compared using Weibull statistics. Both groups of disks were manufactured from titanium (Ti-6Al-4V) alloy. A NASA Glenn Research Center developed probabilistic computer code Probable Cause was used to predict disk life and reliability. A material-life factor A was determined for titanium (Ti-6Al-4V) alloy based upon fatigue disk data and successfully applied to predict the life of the disks as a function of speed. A comparison was made with the currently used life prediction method based upon crack growth rate. Applying an endurance limit to the computer code did not significantly affect the predicted lives under engine operating conditions. Failure location prediction correlates with those experimentally observed in the LCF tests. A reasonable correlation was obtained between the predicted disk lives using the Probable Cause code and a modified crack growth method for life prediction. Both methods slightly overpredict life for one disk group and significantly under predict it for the other.

Melis, Matthew E.↗

NASA NTRS2002

Constitutive Relation in Transitional Granular Flows

To study the constitutive behavior of granular materials, the presence of gravity is detrimental. Although empirical relations have been obtained for engineering designs to control granular flows on Earth, it is not known how well these Earthbound relations can be used in another gravity field. Fundamental understanding must be derived to reliably design for granular flows in space exploration. There are two extremes of granular flows of which significant amount of knowledge is available. One deals with a dense and quasi-static situation where the deformation rate nearly vanishes. The other deals with dilute and rapidly fluctuating grain velocities where particle inertia dominates. This project, funded by the NASA Microgravity Fluid Physics Program, aims to study this transitional regime via physical experiments and computer simulations. A conceptual model has been established as described below. There are two natural time scales in a granular flow. One is the travel time between two consecutive collisions and the other is the duration of a collision contact. At a very low shear-rate, the shear-induced particle velocity is low. Hence the travel time between collisions is longer than the contact time between colliding particles. Binary collisions prevail. As the shear-rate increases, the traveling time between collisions reduces and the probability of multiple collisions goes up. These particle groups disperse shortly after and new groups form. When shear-rate is further increased, clusters grow in size due to an increasing chance for free particles to join before groups have the time to disperse. The maximum cluster size may depend on the global concentration and material properties. As the solid concentration approaches zero, the cluster size goes to one particle diameter. The maximum possible cluster size under any condition is the container size, provided that the shear flow is inside a container. The critical shear-rates that dictate the initiation of the multiple contacts, and the size and lifetime of the collision clusters, are functions of the concentration also. A 'regime' theory has been proposed by Babic et al. This theory suggested that both the solid concentration, C, and the non-dimensional shear-rate, B, are important in determining the regimes of the granular constitutive law. Additional information is included in the original extended abstract.

Shen, Hayley H.↗

DOE OSTI2024

Leveraging Triphenylphosphine-Containing Polymers to Explore Design Principles for Protein-Mimetic Catalysts

Complex interactions between noncoordinating residues are significant yet commonly overlooked components of macromolecular catalyst function. While these interactions have been demonstrated to impact binding affinities and catalytic rates in metalloenzymes, the roles of similar structural elements in synthetic polymeric catalysts remain underexplored. Using a model Suzuki–Miyuara cross-coupling reaction, we performed a series of systematic studies to probe the interconnected effects of metal–ligand cross-links, electrostatic interactions, and local rigidity in polymer catalysts. To achieve this, a novel bifunctional triphenylphosphine acrylamide (BisTPPAm) monomer was synthesized and evaluated alongside an analogous monofunctional triphenylphosphine acrylamide (TPPAm). In model copolymer catalysts, increased initial reaction rates were observed for copolymers untethered by Pd complexation (BisTPPAm-containing) compared to Pd-cross-linked catalysts (TPPAm-containing). Further, incorporating local rigidity through secondary structure-like and electrostatic interactions revealed nonmonotonic relationships between composition and the reaction rate, demonstrating the potential for tunable behavior through secondary-sphere interactions. Lastly, through rigorous cheminformatics featurization strategies and statistical modeling, we quantitated relationships between chemical descriptors of the substrate and reaction conditions on catalytic performance. Collectively, these results provide insights into relationships among the composition, structure, and function of protein-mimetic catalytic copolymers.

Catalysts↗

NASA NTRS1997

Kinetics and Mechanism of the Reaction of Hydoxyl Radicals with Acetonitrile under Atmospheric Conditions

The pulsed laser photolysis-pulsed laser induced fluorescence technique has been employed to determine absolute rate coefficients for the reaction OH + CH3CN (1) and its isotopic variants, OH + CD3CN (2), OD + CH3CN (3), and OD + CD3CN (4). Reactions 1 and 2 were studied as a function of pressure and temperature in N2, N2/O2, and He buffer gases. In the absence of O2 all four reactions displayed well-behaved kinetics with exponential OH decays and pseudo-first rate constants which were proportional to substrate concentration. Data obtained in N2 over the range 50-700 Torr at 298 K are consistent with k(sub 1), showing a small pressure dependence. The Arrhenius expression obtained by averaging data at all pressures in k(sub 1)(T) = (1.1(sup +0.5)/(sub -0.3)) x 10(exp -12) exp[(-1130 +/- 90)/T] cu cm /(molecule s). The kinetics of reaction 2 are found to be pressure dependent with k(sub 2) (298 K) increasing from (1.21 +/- 0.12) x 10(exp -14) to (2.16 +/- 0.11) x 10(exp -14) cm(exp 3)/ (molecule s) over the pressure range 50-700 Torr of N2 at 298 K. Data at pressures greater than 600 Torr give k(sub 2)(T) = (9.4((sup +13.4)(sub -5.0))) x 10(exp -13) exp[(-1180 +/- 250)/T] cu cm/(molecule s). The rates of reactions 3 and 4 are found to be independent of pressure over the range 50-700 Torr of N2 with 298 K rate coefficient given by k(sub 3) =(3.18 +/- 0.40) x 10(exp -14) cu cm/(molecule s) and k(sub 4) = (2.25 +/-0.28) x 10(exp -14) cu cm/(molecule s). In the presence of O2 each reaction shows complex (non-pseudo-first-order) kinetic behavior and/or an apparent decrease in the observed rate constant with increasing [O2], indicating the presence of significant OH or OD regeneration. Observation of regeneration of OH in (2) and OD in (3) is indicative of a reaction channel which proceeds via addition followed by reaction of the adduct, or one of its decomposition products, with O2. The observed OH and OD decay profiles have been modeled by using a simple mechanistic scheme to extract kinetic information about the adduct reations with O2 and branching ratios for OH regeneration. A plausible mechanism for OH regeneration in (2) involves OH addition to the nitrogen atom followed by O2 addition to the cyano carbon atom, isomeriazation and decomposition to D2CO + DOCN + OH. Our results suggest that the OH + CH3CN reaction occurs via a complex mechanism involving both bimolecular and termolecular pathways, analogous to the mechanisms for the the important atmospheric reactions of OH with CO and HNO3.

Hynes, A. J.↗

NASA NTRSDate not supplied

Static and Forced Oscillation Wind Tunnel Tests of A Tandem Propeller Configuration

A series of static and forced oscillation tests were conducted using a tandem propeller configuration in the NASA Langley 12-Foot Low-Speed Tunnel. The primary objectives were to quantify the effect of aerodynamic interactions on propeller thrust and identify conditions where the effect is most significant. A secondary objective was to obtain a preliminary data set from dynamic testing to assess the impact of angular rate on thrust performance. This paper presents analysis of the experimental data, which includes propeller performance measurements and qualitative flow visualization. The static results show that the rear propeller in the tandem configuration can experience thrust degradations greater than 30%. The extent of the wake interaction is a function of the hub separation distance and the advance ratio of the front propeller. Forced oscillation results showed that the front propeller exhibited primarily linear behavior across the conditions tested, whereas the rear propeller exhibited dynamic nonlinearity in the region of significant thrust degradation. These results are intended to support high-fidelity modeling research, particularly for flight dynamics simulation development to aid trajectory prediction, control design, and identification of hazardous conditions for multirotor vehicles.

Aerodynamic Interactions↗

DOE OSTI2019

Electro-Oxidation of Methane on Platinum under Ambient Conditions

Herein, we investigate the electrochemical conversion of methane to CO 2 on platinum electrodes under ambient conditions. Through a combination of experimentation, density functional theory (DFT) calculations, and ab initio kinetic modeling, we have developed an improved understanding of the reaction mechanism and the factors that determine catalyst activity. We hypothesized that the rate-determining methane activation step is thermochemical (i.e., CH 4 (g) → CH 3 * + H * ) as opposed to electrochemical based on a fitted barrier of approximately 0.96 eV that possesses minimal potential dependence. We developed a simple kinetic model based on the assumption of thermochemical methane activation as the rate-determining step, and the results match well with experimental data. Namely, the magnitude of the maximum current density and the electrode potential at which it is realized agree with our ab initio kinetic model. Finally, we expanded our kinetic model to include other transition metals via a descriptor-based analysis and found platinum to be the most active catalyst for the oxidation of methane, which is in line with previously published experimental observations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2019

Cosmogenic Isotopes Unravel the Hydrochronology and Water Storage Dynamics of the Southern Sierra Critical Zone

One of the principal questions in hydrology is how and when water leaves the critical zone storage as either stream flow or evapotranspiration. We report on subsurface water storage and storage selection of the Southern Sierra Critical Zone Observatory (California, USA) within the age-ranked storage selection framework, constrained by a novel combination of cosmogenic radioactive and stable isotopes: tritium, sodium-22, sulfur-35, and oxygen-18. We found a significant positive correlation between tritium and stream flow rate and between sulfur-35 and stream flow rate, indicating that the age distribution of stream flow varies with stream flow rate. Storage selection functions that vary with stream flow rate are better able to reproduce tritium concentrations in stream flow than functions that are constant in time. For the Southern Sierra Critical Zone, there is a strong preference to discharge the oldest water in storage during dry conditions but only a weak preference for younger water during wet conditions. The preference of evapotranspiration for younger water, constrained by oxygen-18 in stream water, is essential to parameterize subsurface storage but needs to be confirmed by isotopic or other investigations of evapotranspiration. This is the first study to highlight how a combination of cosmogenic radioactive isotopes reveals the hydrochronology and water storage dynamics of catchments, constrains the subsurface architecture of the critical zone, and provides insight into landscape evolution.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2026

Statistical Uncertainty of Inhalation Dose Coefficients: Impact of Particle Deposition in ICRP 66 Human Respiratory Tract Model

Inhaled radioactive materials can pose a long-term health concern, as the material can be incorporated into the body’s metabolic pathways and remain in organs and tissues for extended durations. During the retention period, the radioactive material may localize in a source organ and irradiate adjacent target organs and tissues. Distribution of these materials changes over time, requiring biokinetic modeling to evaluate their movement through various tissues and organs. The evolving distribution depends on multiple inputs characterizing the inhaled material, such as particle size and size distribution, particle density, aspect ratio, specific radionuclide, the chemical form, and solubility. In addition, biological parameters such as breathing rate, breathing type (nasal or nasal/oral), respiratory system morphometry, tidal volume, functional residual capacity, and anatomical dead space all influence material transport. These aerosol properties and physiological characteristics of the respiratory tract jointly define a range of initial conditions that influence the time-dependent distribution of radioactive material. To evaluate both uncertainty in the initial conditions of inhalation exposure and the final output (committed effective dose) from biokinetic models, a Python-based software tool, Radiological Exposure Dose Calculator (REDCAL), was developed to propagate uncertainty within the human respiratory tract model. Focusing on deposition fraction uncertainty, the primary objective was to characterize the initial activity distribution across respiratory regions as a function of anticipated particle sizes and distributions. The impact of the deposition fraction uncertainty was propagated to committed effective dose coefficients for selected radionuclides in a companion publication. For each particle size, a lognormal distribution, characterized by its geometric mean as defined within ICRP Publication 66, serves as the basis for introducing uncertainty into the physical processes governing deposition in various lung regions. Finally, this study addresses the deposition process and examines how uncertainty in deposition mechanisms affects activity distribution in the airways, ultimately presenting the expected range and standard deviation of deposited activity as a function of particle size.

International Commission on Radiological Protectio↗

DOE OSTI2015

One-dimensional cold cap model for melters with bubblers

The rate of glass production during vitrification in an all-electrical melter greatly impacts the cost and schedule of nuclear waste treatment and immobilization. The feed is charged to the melter on the top of the molten glass, where it forms a layer of reacting and melting material, called the cold cap. During the final stages of the batch-to-glass conversion process, gases evolved from reactions produce primary foam, the growth and collapse of which controls the glass production rate. The mathematical model of the cold cap was revised to include functional representation of primary foam behavior and to account for the dry cold cap surface. The melting rate is computed as a response to the dependence of the primary foam collapse temperature on the heating rate and melter operating conditions, including the effect of bubbling on the cold cap bottom and top surface temperatures. The simulation results are in good agreement with experimental data from laboratory-scale and pilot-scale melter studies. Lastly, the cold cap model will become part of the full three-dimensional mathematical model of the waste glass melter.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2021

Fiber optic system for direct detection of CO 2 leakage in carbon storage wells (Abbreviated Final Report)

The feasibility study focused on the development of new fiber for distributed chemical sensing that will allow direct detection of CO2 leakages in the environment. This is particularly important for monitoring well integrity for carbon capture and storage (CSS), which can provide early warning for an incoming well failure and potential CO2 leaking through it. We proposed Raman or IR interrogation within gas-filled Holey Fibers (HoFs) interleaved with Fiber Bragg Grating (FBG) sections, so that the location and concentration of the gases would be provided simultaneously. The methodology would overcome current roadblocks to using fiber optics for CO2 (and other gases) detection in wells with direct in-situ measurements of concentration along with other important parameters such as temperature and pressure. We were able to assess commercially available IR/Raman hollow core fiber and demonstrated detection of CO2 through them in our controlled environment setups at various pressure conditions. We have also established the ability of drilling precisely with fs-lases side holes to enable penetration of CO2 into the hollow core fiber and reduce diffusion rates. Open joint collars were also explored with double functionality: to obtain splice to solid core fiber critical for field deployment and create gas ingress locations. Both diffusion-only and pressurized fiber system have been constructed following COMSOL based semi-hybrid optical /fluidodynamics models. FBGs have been identified and procured and characterized. Along the work we leveraged internal modeling/design, photonics/laser characterization, optical fiber fabrication, and AM lab capabilities to design, develop and test in-house components or assemblies. Our results indicate the potential of HoF for CO2 downhole direct detection.

25 ENERGY STORAGE↗

NASA NTRS1982

Dynamic fatigue of a machinable glass-ceramic

To assess the stress corrosion susceptibility of a machinable glass-ceramic, its dynamic fatigue behavior was investigated by measuring its strength as a function of stress rate. Fracture mechanics techniques were used to analyse the results for the purpose of making lifetime predictions for components of this material. This material was concluded to have only moderate resistance to stress in ambient conditions. The effects of specimen size on strength were assessed for the material used in this study: it was concluded that the Weibull edge-flaw scaling law adequately describes the observed strength-size relationship.

Smyth, K. K.↗

NASA NTRS1995

The correlated k-distribution technique as applied to the AVHRR channels

Correlated k-distributions have been created to account for the molecular absorption found in the spectral ranges of the five Advanced Very High Resolution Radiometer (AVHRR) satellite channels. The production of the k-distributions was based upon an exponential-sum fitting of transmissions (ESFT) technique which was applied to reference line-by-line absorptance calculations. To account for the overlap of spectral features from different molecular species, the present routines made use of the multiplication transmissivity property which allows for considerable flexibility, especially when altering relative mixing ratios of the various molecular species. To determine the accuracy of the correlated k-distribution technique as compared to the line-by-line procedure, atmospheric flux and heating rate calculations were run for a wide variety of atmospheric conditions. For the atmospheric conditions taken into consideration, the correlated k-distribution technique has yielded results within about 0.5% for both the cases where the satellite spectral response functions were applied and where they were not. The correlated k-distribution's principal advantages is that it can be incorporated directly into multiple scattering routines that consider scattering as well as absorption by clouds and aerosol particles.

Kratz, David P.↗

NASA NTRS2001

Instability Analysis of a Low-Density Gas Jet Injected into a High-Density Gas

The objective of this study was to determine the effects of buoyancy on the absolute instability of low-density gas jets injected into high-density gas mediums. Most of the existing analyses of low-density gas jets injected into a high-density ambient have been carried out neglecting effects of gravity. In order to investigate the influence of gravity on the near-injector development of the flow, a linear temporal stability analysis and a spatio-temporal stability analysis of a low-density round jet injected into a high-density ambient gas were performed. The flow was assumed to be isothermal and locally parallel; viscous and diffusive effects were ignored. The variables were represented as the sum of the mean value and a normal-mode small disturbance. An ordinary differential equation governing the amplitude of the pressure disturbance was derived. The velocity and density profiles in the shear layer, and the Froude number (signifying the effects of gravity) were the three important parameters in this equation. Together with the boundary conditions, an eigenvalue problem was formulated. Assuming that the velocity and density profiles in the shear layer to be represented by hyperbolic tangent functions, the eigenvalue problem was solved for various values of Froude number. The temporal growth rates and the phase velocity of the disturbances were obtained. It was found that the presence of variable density within the shear layer resulted in an increase in the temporal amplification rate of the disturbances and an increase in the range of unstable frequencies, accompanied by a reduction in the phase velocities of the disturbances. Also, the temporal growth rates of the disturbances were increased as the Froude number was reduced (i.e. gravitational effects increased), indicating the destabilizing role played by gravity. The spatio-temporal stability analysis was performed to determine the nature of the absolute instability of the jet. The roles of the density ratio, Froude number, Schmidt number, and the lateral shift between the density and velocity profiles on the jet s absolute instability were determined. Comparisons of the results with previous experimental studies show good agreement when the effects of these variables are combined together. Thus, the combination of these variables determines how absolutely unstable the jet will be. Experiments were carried out to observe the qualitative differences between a round low-density gas jet injected into a high-density gas (helium jet injected into air) and a round constant density jet (air jet injected into air). Flow visualizations and velocity measurements in the near-injector region of the helium jet show more mixing and spreading of the helium jet than the air jet. The vortex structures develop and contribute to the jet spreading causing the helium jet to oscillate.

Lawson, Anthony Layiwola↗

NASA NTRS2002

Linear Temporal Stability Analysis of a Low-Density Round Gas Jet Injected into a High-Density Gas

It has been observed in previous experimental studies that round helium jets injected into air display a repetitive structure for a long distance, somewhat similar to the buoyancy-induced flickering observed in diffusion flames. In order to investigate the influence of gravity on the near-injector development of the flow, a linear temporal stability analysis of a round helium jet injected into air was performed. The flow was assumed to be isothermal and locally parallel; viscous and diffusive effects were ignored. The variables were represented as the sum of the mean value and a normal-mode small disturbance. An ordinary differential equation governing the amplitude of the pressure disturbance was derived. The velocity and density profiles in the shear layer, and the Froude number (signifying the effects of gravity) were the three important parameters in this equation. Together with the boundary conditions, an eigenvalue problem was formulated. Assuming that the velocity and density profiles in the shear layer to be represented by hyperbolic tangent functions, the eigenvalue problem was solved for various values of Froude number. The temporal growth rates and the phase velocity of the disturbances were obtained. The temporal growth rates of the disturbances increased as the Froude number was reduced (i.e. gravitational effects increased), indicating the destabilizing role played by gravity.

Lawson, Anthony L.↗

NASA NTRS2003

Oxidation of Carbon Fibers in Water Vapor Studied

T-300 carbon fibers (BP Amoco Chemicals, Greenville, SC) are a common reinforcement for silicon carbide composite materials, and carbon-fiber-reinforced silicon carbide composites (C/SiC) are proposed for use in space propulsion applications. It has been shown that the time to failure for C/SiC in stressed oxidation tests is directly correlated with the fiber oxidation rate (ref. 1). To date, most of the testing of these fibers and composites has been conducted in oxygen or air environments; however, many components for space propulsion, such as turbopumps, combustors, and thrusters, are expected to operate in hydrogen and water vapor (H2/H2O) environments with very low oxygen contents. The oxidation rate of carbon fibers in conditions representative of space propulsion environments is, therefore, critical for predicting component lifetimes for real applications. This report describes experimental results that demonstrate that, under some conditions, lower oxidation rates of carbon fibers are observed in water vapor and H2/H2O environments than are found in oxygen or air. At the NASA Glenn Research Center, the weight loss of the fibers was studied as a function of water pressure, temperature, and gas velocity. The rate of carbon fiber oxidation was determined, and the reaction mechanism was identified.

Opila, Elizabeth J.↗