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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Numerical simulation study of impurity B transport during real-time B powder injection in EAST

To understand the beneficial effects of impurity boron (B) on the plasma, the transport of B species in both atomic and ionic states in the edge plasma and the ensuing evolution of the background plasma are simulated during real-time B powder injection by using two-dimensional fluid code SOLPS-ITER. The initial background plasma profiles for the simulation are reconstructed based on an EAST upper-single null discharge (shot No. 70601). With the injection rate of B atoms, 4.0 × 10 21 atoms/s, the simulation shows that effective charge number is less than 1.1 at the inner boundary R - R sep = -5.2 cm (background plasma density, 5.1 × 10 19 m -3 ) at the outer mid-plane indicating that the B impurity does not have much influence on the energy confinement. The present work finds that the impurity B exhibits very specific features in the edge plasma, mostly present in the narrow region just outside the separatrix. The particular distribution pattern can reduce the heat flux greatly, leading to the divertor detachment. The divertor detachment can be achieved easily under an injection rate of B powder in a reasonable range. This study suggests that the impurity B has a promising potential application in future tokamaks.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Initial instability of round liquid jet at subcritical and supercritical environments

In the present experimental work, the behavior of laminar liquid jet in its own vapor as well as supercritical fluid environment is conducted. Also the study of liquid jet injection into nitrogen (N{sub 2}) environment is carried out at supercritical conditions. It is expected that the injected liquid jet would undergo thermodynamic transition to the chamber condition and this would alter the behavior of the injected jet. Moreover at such conditions there is a strong dependence between thermodynamic and fluid dynamic processes. Thus the thermodynamic transition has its effect on the initial instability as well as the breakup nature of the injected liquid jet. In the present study, the interfacial disturbance wavelength, breakup characteristics, and mixing behavior are analysed for the fluoroketone liquid jet that is injected into N{sub 2} environment as well as into its own vapor at subcritical to supercritical conditions. It is observed that at subcritical chamber conditions, the injected liquid jet exhibits classical liquid jet characteristics with Rayleigh breakup at lower Weber number and Taylor breakup at higher Weber number for both N{sub 2} and its own environment. At supercritical chamber conditions with its own environment, the injected liquid jet undergoes sudden thermodynamic transition to chamber conditions and single phase mixing characteristics is observed. However, the supercritical chamber conditions with N{sub 2} as ambient fluid does not have significant effect on the thermodynamic transition of the injected liquid jet.

42 ENGINEERING↗
DOE OSTI2022

Dynamic development of geochemical reaction fronts during hydraulic stimulation of shale

Injection of acidic hydraulic fracture fluid (HFF) into shale formations for unconventional oil/gas production results in chemical reactions in the shale matrix that can alter fluid transport. Here, we report the results of set of experiments designed to evaluate the impact of calcite dissolution as a function of carbonate mineral content on matrix chemical reactivity and pore-space modification concomitant with imbibition. In this study, we tracked acidic HFF transport in four samples of Wolfcamp shale with calcite contents varying from 4% to 59% by monitoring the rate and spatial extent of bromide tracer transport using synchrotron-based X-ray fluorescence microprobe (XFM) imaging. Concurrently, we also carried out XFM imaging of the spatial distribution of Ca in the Wolfcamp shale cores (as a proxy of calcite distribution). Our approach thus yields a direct record of time-resolved selective ion transport resulting from the penetration of acidic HFF and the associated mineral transformations in the shale cores. We show that the variability in calcite content of Wolfcamp shale samples can directly affect the rate and spatial extent of imbibition. Although reaction of the acidic HFF with carbonates in shales enhances calcite dissolution and increases porosity, the spatial extent of calcite dissolution in the shale matrix is limited due to a rapid neutralization of pH. The relative abundance and spatial distribution of calcite control the chemical saturation state of the HFF progressing into the matrix. As a result, calcite has a major impact on the spatial extent and rate of matrix alteration and thus on HFF transport during subsurface reservoir stimulation. Consequently, increased calcite content in the shale matrix inhibits the spatial extent of the pore-volume increase and, by extension, the spatial extent and rate of imbibition. Our results thus show that the overall rates of calcite dissolution approach the rates of acidic HFF transport (i.e., Damköhler number ~1), which could contribute to the efficiency of subsurface reservoir stimulation. A better understanding of HFF-calcite reaction rates is crucial for improving the prediction and optimization of fluid transport across HFF-shale interfaces during hydraulic fracturing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

In Situ Study of CO2 and H2O Partitioning Between Na-Montmorillonite and Variably Wet Supercritical Carbon Dioxide

Shale formations play fundamental roles in large-scale geologic carbon sequestration (GCS) aimed primarily to mitigate climate change, and in smaller-scale GCS targeted mainly for CO2-enhanced gas recovery operations. In both technologies, CO2 is injected underground as a supercritical fluid (scCO2), where interactions with shale minerals could influence successful GCS implementation. Reactive components of shales include expandable clays, such as montmorillonites and mixed-layer illite/smectite clays. In this work, we used in situ X-ray diffraction (XRD) and in situ infrared (IR) spectroscopy to investigate the swelling/shrinkage and water/CO2 sorption of a pure montmorillonite, Na-SWy-2, when the clay is exposed to variably hydrated scCO2 at 50 °C and 90 bar. Measured interlayer spacings and sorbed water concentrations at varying levels of scCO2 hydration are similar to previously reported values measured in air at ambient pressure over a range of relative humidities. IR spectra show evidence of both water and CO2 intercalation, and variations in peak shapes and positions suggest multiple sorbed types with distinct chemical environments. Based on the intensity of the asymmetric CO stretching band of the CO2 associated with the Na-SWy-2, we observed a significant increase in sorbed CO2 as the clay expands from a 0W to a 1W state, suggesting that water props open the interlayer so that CO2 can enter. However, as the clay transitions from a 1W to a 2W state, CO2 desorbs sharply. These observations were placed in the context of two conceptual models concerning hydration mechanisms for expandable clays and were also discussed in light of recent theoretical studies on CO2-H2O-clay interactions. The swelling/shrinkage of expandable clays could affect solid volume, porosity, and permeability of shales. Consequently, the results from this work could aid predictions of shale caprock integrity in large-scale GCS, as well as methane transmissivity in enhanced gas recovery operations.

Environmental Molecular Sciences Laboratory↗
DOE OSTI2022

Avalanches in strong imbibition

Slow injection of non-wetting fluids (drainage) and strongly wetting fluids (strong imbibition) into porous media are two contrasting processes in many respects: the former must be forced into the pore space, while the latter imbibe spontaneously; the former occupy pore bodies, while the latter coat crevices and corners. These two processes also produce distinctly different displacement patterns. However, both processes evolve via a series of avalanche-like invasion events punctuated by quiescent periods. Here, we show that, despite their mechanistic differences, avalanches in strong imbibition exhibit all the features of self-organized criticality previously documented for drainage, including the correlation scaling describing the space-time statistics of invasion at the pore scale.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Intermediate Scale Laboratory Testing to Understand Mechanisms of Capillary and Dissolution Trapping during Injection and Post-Injection of CO 2 in Heterogeneous Geological Formations

Carbon Capture and Storage (CCS) represents a technology aimed to reduce atmospheric loading of CO 2 from power plants and heavy industries by injecting it into deep geological formations, such as saline aquifers. A number of trapping mechanisms contribute to effective and secure storage of the injected CO 2 in supercritical fluid phase (scCO 2 ) in the formation over the long term. The primary trapping mechanisms are structural, residual, dissolution and mineralization. Knowledge gaps exist on how the heterogeneity of the formation manifested at all scales from the pore to the site scales affects trapping and parameterization of contributing mechanisms in models. An experimental and modeling study was conducted to fill these knowledge gaps. Experimental investigation of fundamental processes and mechanisms in field settings is not possible as it is not feasible to fully characterize the geologic heterogeneity at all relevant scales and gathering data on migration, trapping and dissolution of scCO 2 . Laboratory experiments using scCO 2 under ambient conditions are also not feasible as it is technically challenging and cost prohibitive to develop large, two- or three-dimensional test systems with controlled high pressures to keep the scCO 2 as a liquid. Hence, an innovative approach that used surrogate fluids in place of scCO 2 and formation brine in multi-scale, synthetic aquifers test systems ranging in scales from centimeter to meter scale developed used. New modeling algorithms were developed to capture the processes controlled by the formation heterogeneity, and they were tested using the data from the laboratory test systems. The results and findings are expected to contribute toward better conceptual models, future improvements to DOE numerical codes, more accurate assessment of storage capacities, and optimized placement strategies. This report presents the experimental and modeling methods and research results.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

ChemoMechanical Controls on Induced Seismicity

In recent years, seismicity rates in the US have dramatically risen due to increased activity in onshore oil and gas production. This project attempts to tie observations about induced seismicity to dehydration reactions in laumontite, a common mineral found in fault gouge in crystalline basement formations. It is the hypothesis of this study that in addition to pressurerelated changes in the in situ stress state, the injection of wastewater pushes new fluids into crystalline fault fracture networks that are not in chemical equilibrium with the mineral assemblages, particularly laumontite in fault gouge. Experiments were conducted under hydrothermal conditions where samples of laumontite were exposed to NaC1 brines at different pH values. After exposure to different fluid chemistries for 8 weeks at 90° C, we did not observe substantial alteration of laumontite. In hydrostatic compaction experiments, all samples deformed similarly in the presence of different fluids. Pore pressure decreases were observed at the start of a 1 week hold at 85° C in a 1M NaC1 pH 3 solution, suggesting that acidic fluids might stabilize pore pressures in basement fault networks. Friction experiments on laumontite and kaolinite powders showed both materials have similar coefficients of friction. Mixtures with partial kaolinite content showed a slight decrease in the coefficient of friction, which could be sufficient to trigger slip on critically stressed basement faults.

58 GEOSCIENCES↗
DOE OSTI2020

Distributed Acoustic Sensing (DAS) Seismic Monitoring of CO 2 Injected for Enhanced Oil Recovery in Northern Michigan (Volume II.C)

The Midwest Regional Carbon Sequestration Partnership (MRCSP) was founded in 2003 as part of the U.S. Department of Energy’s (DOE’s) Regional Carbon Sequestration Partnership initiative. Since its founding, MRCSP has made significant strides toward making CCUS a viable option for states in the region. The public/private consortium, funded through the DOE Regional Carbon Sequestration Initiative, brings together nearly 40 industry partners and 10 states. Battelle, as the project lead, oversees research, development and operations and coordinates activities among the partners. The incremental, phased approach has built a valuable knowledge base for the industry and paved the way for commercial-scale adoption of CCUS technologies. From 2008 to 2020, MRCSP Phase III focused on the development of large-scale injection projects. This report is part of a series of reports prepared under the Midwestern Regional Carbon Sequestration Partnership (MRCSP) Phase III (Development Phase). These reports summarize and detail the findings of the work conducted under the Phase III project. This report describes the monitoring study conducted to assess the effectiveness of DAS (Distributed Acoustic Sensing) -based VSP (Vertical Seismic Profiling) technology for delineating CO 2 injected into the Silurian-age pinnacle reefs in northern Michigan, the host rocks for the MRCSP Phase III demonstration project. The DAS VSP study was conducted in the Chester 16 reef, one of several reefs in Otsego County Michigan that is operated by Core Energy, LLC of Traverse City, Michigan. Time-lapse DAS VSP was implemented at the Chester 16 reef to attempt to detect approximately 85,000 tonnes of CO 2 injected into the A-1 Carbonate and Brown Niagaran Formations. A baseline survey was conducted in February 2017 prior to injecting CO 2 and a repeat survey was conducted in August 2018. During the interim period between the baseline and repeat surveys, CO 2 was injected into the Chester 16 reef via the 6-16 injection well without production (withdrawal) of fluids from the reef. A grid of 181 source positions consisting of 44 vibrator positions, plus 137 dynamite shot locations, was used to give approximately continuous spatial coverage of the injection zone (A-1 Carbonate and upper Brown Niagaran) in the area between the two wells.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2022

Big Hill Geomechanical Analysis Using M-D Viscoplastic Material Model

The integrity of wellbores at the interbed between the caprock and salt is a serious concern in the Big Hill site. For the remediation and life extension of wellbores, more accurate predictions from the global model are needed. The Big Hill global model is improved using the M-D viscoplastic contact surface model and the mesh containing the interbed layer with contact surfaces between the salt and caprock layers, and fault blocks in overburden and caprock layers. The model calibration has been performed based on the cavern volumetric closures obtained from the Caveman calculations. The results agree well from 1991 to the early 2000s. The difference starts to widen after that, it might be because of frequent fluid movement and raw water injection. Therefore, the predictions from this improved model could be used to examine the structural integrity of caverns in Big Hill salt dome.

42 ENGINEERING↗
NASA NTRS1966

Study of vortex valve for medium temperature solid propellants

Fluid state vortex valve secondary injection control system shows considerable promise for future application to solid propellant rocket engine thrust vector control. The single axis injection system tested would be capable of providing secondary injection thrust vector control using 2000 deg F gas.

Holt, W. D.↗
DOE OSTI2020

Application of an Embedded Fracture and Borehole Modeling Approach to the Understanding of EGS Collab Experiment 1

EGS Collab is a series of meso-scale experiments and associated numerical simulation activities being funded by the United States Department of Energy, Geothermal Technologies Office (GTO) to investigate enhanced geothermal system processes under in-situ stress and slightly elevated temperature conditions. This project is designed to provide scientists and engineers with immediate access to impermeable rock at scales larger than possible in the laboratory, but generally smaller than those for commercial production. Immediate access to rock is provided via the existing drifts of the former Homestake Gold Mine, now operated as the Sanford Underground Research Facility in Lead, South Dakota. The objectives of the EGS Collab project are to develop well controlled fracture networks between injector and producer boreholes using normal and shear stimulation for permeability enhancement. The first experimental site was located off the West Access drift on the 4850 Level (4850 feet below ground surface) in phyllite of the Precambrian Poorman formation, and involved the creation of a fracture network comprising a combination of hydraulic and natural fractures. A second experimental site is now being considered near the battery alcove on the 4100 Level in amphibolite and rhyolite of the Yates Unit. Data generated during these experiments will be compared against predictions of a suite of computer codes specifically designed to solve problems involving coupled thermal, hydrological, geomechanical, and geochemical processes. Comparisons between experimental and numerical simulation results will provide code developers with direction for improvements and verification of process models, build confidence in the suite of available numerical tools, and ultimately identify critical future development needs for the geothermal modeling community. Moreover, conducting thorough comparisons of models, modelling approaches, measurement approaches and measured data, via the EGS Collab project, will serve to identify techniques that are most likely to succeed at the Frontier Observatory for Research in Geothermal Energy (FORGE), the GTO’s flagship EGS research effort. Experiment 1 has comprised a series of successful tests, including a long-term chilled-water circulation test, but the testbed has two atypical EGS elements. Active ventilation in the adjacent drift over a 50-year period cooled the testbed rock mass and hydraulic fracturing intersected monitoring boreholes making them conduits for fluid flow. Numerical simulations executed in support of the design of the EGS Collab Experiment 1, computed a radial temperature distribution and stress gradient orthogonal to the drift axis, resulting in the forecast of an oblong hydraulic fracture geometry, extended in the direction of the drift from the stimulation borehole. This paper describes the numerical simulation of long-term chilled-water circulation test with an embedded fracture and borehole modeling approach. The principal objective of the simulation work is show agreement between experimental observations in terms of production fluid temperatures, monitoring borehole temperatures, injection and production pressures, and tracer recoveries using a single conceptual model for the fracture network, using characterization and monitoring data generally available for EGS. A secondary objective is to improve the numerical simulation result comparisons with additional data available from the broader monitoring equipment within the testbed versus deeper, hotter, and more remote EGS. One complicating factor for comparisons between the numerical simulation results and experimental observations, is the Joule-Thomson heating associated with large pressure drops across the fracture network.

numerical simulation, embedded fractures and boreh↗
DOE OSTI2017

Feasibility Evaluation of Potential Stimulation Methods for Collab Experiment 3. Recommendation Report

In support of the Collab Project Milestone 1.4, INL is to submit a recommendation report describing feasible methods to investigate during Experiment 3 to DOE. This report fulfils this FY18Q1 SMART milestone. Twenty one potential methods were consideration for testing as part of Collab Experiment 3. The potential methods have been categorized as; Fracture Initiation, Stimulation Fluids, Stimulation Methods and Flow Control. The categories have been further divided into three general groups (e.g. high, medium, low) based on applicability to the scale of measurement at Collab (~10 meter) and it’s applicably to FORGE. The highest relevant methods (not necessary in order) are: 1) fracture initiation within the borehole, 2) use of slickwater fracturing fluids, 3) use of viscous fracturing fluids, 4) simultaneous stimulation of multiple wells, 5) use of energetic fluids to initiate larger fractures or connect a borehole to existing fractures, 6) injection of diverters to control short circuits and working fluid loss, 7) testing of borehole isolation techniques to control water flow pathways in the reservoir, and 8) use of multiple injection and production wells to characterize a fracture. Fractures created in Experiments 1 and 2 offer the opportunity to test engineering solutions to issues encountered in the stimulation process or during the fracture flow testing. An advantage of using these sites is that there would be a wealth of baseline characterization data for the site, and the borehole monitoring system and experimental infrastructure is already established and could possibly be reused. This suggested potential method list should be considered preliminary due to the timing of this report and the status of Collab Experiments 1 and 2 as well as the need for preliminary modeling to assess each of the proposed methods effectiveness.

15 GEOTHERMAL ENERGY↗
NASA NTRS1985

Flow visualization study of the effect of injection hole geometry on an inclined jet in crossflow

A flow visualization was studied by using neutrally buoyant, helium-filled soap bubbles, to determine the effect of injection hole geometry on the trajectory of an air jet in a crossflow and to investigate the mechanisms involved in jet deflection. Experimental variables were the blowing rate, and the injection hole geometry cusp facing upstream (CUS), cusp facing downstream (CDS), round, swirl passage, and oblong. It is indicated that jet deflection is governed by both the pressure drag forces and the entrainment of free-stream fluid into the jet flow. For injection hole geometries with similar cross-sectional areas and similar mass flow rates, the jet configuration with the larger aspect ratio experienced a greater deflection. Entrainment arises from lateral shearing forces on the sides of the jet, which set up a dual vortex motion within the jet and thereby cause some of the main-stream fluid momentum to be swept into the jet flow. This additional momentum forces the jet nearer the surface. Of the jet configurations, the oblong, CDS, and CUS configutations exhibited the largest deflections. The results correlate well with film cooling effectiveness data, which suggests a need to determine the jet exit configuration of optimum aspect ratio to provide maximum film cooling effectiveness.

Simon, F. F.↗
NASA NTRS1987

Flow visualization study of the effect of injection hole geometry on an inclined jet in crossflow

A flow visualization was studied by using neutrally buoyant, helium-filled soap bubbles, to determine the effect of injection hole geometry on the trajectory of an air jet in a crossflow and to investigate the mechanisms involved in jet deflection. Experimental variables were the blowing rate, and the injection hole geometry cusp facing upstream (CUS), cusp facing downstream (CDS), round, swirl passage, and oblong. It is indicated that jet deflection is governed by both the pressure drag forces and the entrainment of free-stream fluid into the jet flow. For injection hole geometries with similar cross-sectional areas and similar mass flow rates, the jet configuration with the larger aspect ratio experienced a greater deflection. Entrainment arises from lateral shearing forces on the sides of the jet, which set up a dual vortex motion within the jet and thereby cause some of the main-stream fluid momentum to be swept into the jet flow. This additional momentum forces the jet nearer the surface. Of the jet configurations, the oblong, CDS, and CUS configurations exhibited the largest deflections. The results correlate well with film cooling effectiveness data, which suggests a need to determine the jet exit configuration of optimum aspect ratio to provide maximum film cooling effectiveness.

Simon, Frederick F.↗
DOE OSTI2016

Inverse modeling of ground surface uplift and pressure with iTOUGH-PEST and TOUGH-FLAC: The case of CO2 injection at In Salah, Algeria

Ground deformation, commonly seen in storage projects, carries useful information about processes occurring in the injection formation. The Krechba gas field at In Salah (Algeria) is one of the best-known sites for studying ground surface deformation during geological carbon storage. At this first industrial-scale on-shore CO 2 demonstration project, satellite-based ground-deformation monitoring data of high quality are available and used to study the large-scale hydrological and geomechanical response of the system to injection. In this work, we carry out coupled fluid flow and geomechanical simulations to understand the uplift at three different CO 2 injection wells (KB-501, KB-502, KB-503). Previous numerical studies focused on the KB-502 injection well, where a double-lobe uplift pattern has been observed in the ground-deformation data. The observed uplift patterns at KB-501 and KB-503 have single-lobe patterns, but they can also indicate a deep fracture zone mechanical response to the injection.The current study improves the previous modeling approach by introducing an injection reservoir and a fracture zone, both responding to a Mohr-Coulomb failure criterion. In addition, we model a stress-dependent permeability and bulk modulus, according to a dual continuum model. Mechanical and hydraulic properties are determined through inverse modeling by matching the simulated spatial and temporal evolution of uplift to InSAR observations as well as by matching simulated and measured pressures. The numerical simulations are in agreement with both spatial and temporal observations. The estimated values for the parameterized mechanical and hydraulic properties are in good agreement with previous numerical results. In addition, the formal joint inversion of hydrogeological and geomechanical data provides measures of the estimation uncertainty.

58 GEOSCIENCES↗
DOE OSTI2014

Impact of induced seismic events on seal integrity, Texas Gulf Coast

Recent publications have suggested that large-scale CO 2 injection could trigger earthquakes and that even small- to moderate-sized earthquakes may threaten the seal integrity of the injection zone, and potentially damage buildings and other surface structures. In this study, we compared seal thickness to estimated fault displacement due to a single hypothetical seismic event in a selected area of the Texas Gulf Coast comprising an offshore strip of state waters along two Texas counties. To evaluate the slip generated by a single seismic event, we compiled well log information on shale/sand sequences and seismic information on fault geometric characteristics of a section of Lower Miocene age. The section is thousands of feet thick and is overlain and underlain by marine shales (Amph. B and Anahuac, respectively) that are relatively easy to correlate between wells. The Amph. B. shale is the secondary and ultimate seal for all injection intervals in the Lower Miocene. Given its thickness, no realistic seismic event or small series of seismic events will offset it significantly. However, this may not be true of smaller local primary seals. An analysis of geophysical logs of a total of 71 wells yielded a total of 2,871 sand / shale binary intervals. An analysis of the dedicated 3D seismic survey counted 723 fault traces at five roughly horizontal horizons within the Lower Miocene Fault displacement estimated using the product of the fault length times an uncertain multiplier coefficient assumed to follow a triangular distribution with a 10 -3 to 10 -5 range and a mode of 8 × 10 -5 . We then compared estimated single-event fault displacements to seal thicknesses by means of a Monte-Carlo analysis. Only 1.8% of thickness/displacement pairs display a displacement greater than 20% of the seal thickness. Only 0.26% of the pairs result in a displacement of half the seal thickness and only 0.05% of thickness/displacement pairs result in a clear seal rupture. The next step was to compare the magnitude of the event generated by such a displacement to documented magnitudes of “large” earthquakes generated by waterflooding and fluid disposal. Based on this analysis, we conclude that seismicity that may arise from CO 2 injection appears not to be a serious complication for CO 2 storage integrity, at least in the Gulf Coast area.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

A Review of Coupled Geochemical–Geomechanical Impacts in Subsurface CO 2 , H 2 , and Air Storage Systems

Increased demand for decarbonization and renewable energy has led to increasing interest in engineered subsurface storage systems for large-scale carbon reduction and energy storage. In these applications, a working fluid (CO 2 , H 2 , air, etc.) is injected into a deep formation for permanent sequestration or seasonal energy storage. The heterogeneous nature of the porous formation and the fluid–rock interactions introduce complexity and uncertainty in the fate of the injected component and host formations in these applications. Interactions between the working gas, native brine, and formation mineralogy must be adequately assessed to evaluate the efficiency, risk, and viability of a particular storage site and operational regime. This study reviews the current state of knowledge about coupled geochemical–geomechanical impacts in geologic carbon sequestration (GCS), underground hydrogen storage (UHS), and compressed air energy storage (CAES) systems involving the injection of CO 2 , H 2 , and air. Specific review topics include (1) existing injection induced geochemical reactions in these systems; (2) the impact of these reactions on the porosity and permeability of host formation; (3) the impact of these reactions on the mechanical properties of host formation; and (4) the investigation of geochemical-geomechanical process in pilot scale GCS. This study helps to facilitate an understanding of the potential geochemical–geomechanical risks involved in different subsurface energy storage systems and highlights future research needs.

08 HYDROGEN↗