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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
NASA NTRS2009

Improved Blackbody Temperature Sensors for a Vacuum Furnace

Some improvements have been made in the design and fabrication of blackbody sensors (BBSs) used to measure the temperature of a heater core in a vacuum furnace. Each BBS consists of a ring of thermally conductive, high-melting-temperature material with two tantalum-sheathed thermocouples attached at diametrically opposite points. The name "blackbody sensor" reflects the basic principle of operation. Heat is transferred between the ring and the furnace heater core primarily by blackbody radiation, heat is conducted through the ring to the thermocouples, and the temperature of the ring (and, hence, the temperature of the heater core) is measured by use of the thermocouples. Two main requirements have guided the development of these BBSs: (1) The rings should have as high an emissivity as possible in order to maximize the heat-transfer rate and thereby maximize temperature-monitoring performance and (2) the thermocouples must be joined to the rings in such a way as to ensure long-term, reliable intimate thermal contact. The problem of fabricating a BBS to satisfy these requirements is complicated by an application-specific prohibition against overheating and thereby damaging nearby instrumentation leads through the use of conventional furnace brazing or any other technique that involves heating the entire BBS and its surroundings. The problem is further complicated by another application-specific prohibition against damaging the thin tantalum thermocouple sheaths through the use of conventional welding to join the thermocouples to the ring. The first BBS rings were made of graphite. The tantalum-sheathed thermocouples were attached to the graphite rings by use of high-temperature graphite cements. The ring/thermocouple bonds thus formed were found to be weak and unreliable, and so graphite rings and graphite cements were abandoned. Now, each BBS ring is made from one of two materials: either tantalum or a molybdenum/titanium/zirconium alloy. The tantalum-sheathed thermocouples are bonded to the ring by laser brazing. The primary advantage of laser brazing over furnace brazing is that in laser brazing, it is possible to form a brazed connection locally, without heating nearby parts to the flow temperature of the brazing material. Hence, it is possible to comply with the prohibition against overheating nearby instrumentation leads. Also, in laser brazing, unlike in furnace brazing, it is possible to exert control over the thermal energy to such a high degree that it becomes possible to braze the thermocouples to the ring without burning through the thin tantalum sheaths on the thermocouples. The brazing material used in the laser brazing process is a titanium-boron paste. This brazing material can withstand use at temperatures up to about 1,400 C. In thermal-cycling tests performed thus far, no debonding between the rings and thermocouples has been observed. Emissivity coatings about 0.001 in. (.0.025 mm) thick applied to the interior surfaces of the rings have been found to improve the performance of the BBS sensors by raising the apparent emissivities of the rings. In thermal-cycling tests, the coatings were found to adhere well to the rings.

Farmer, Jeff↗
DOE OSTI2021

A practical guide to quartz crystal microbalance with dissipation monitoring of thin polymer films

Quartz crystal microbalance with dissipation (QCM-D) monitoring is a powerful tool used to sensitively examine the real-time responses of polymer films to external responses. For example, the technique is commonly used to monitor film growth, material adsorption, thin film swelling, and ion exchange. With its rapidly expanding use, this review is intended to introduce new users to the basic principles of QCM-D, along with practical challenges and remedies specific to polymer thin films. For both new and experienced users, specific case studies are highlighted including layer-by-layer assembly, electrochemical QCM-D, swelling, sensing, and biological application. Finally, the review recommends future directions for research and areas of growth.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Toward efficient single-atom catalysts for renewable fuels and chemicals production from biomass and CO 2

Transformation of biomass and CO 2 into renewable value-added chemicals and fuels has been identified as a promising strategy to fulfill high energy demands, lower greenhouse gas emissions, and exploit under-utilized resources. Cost-effective and performance-efficient catalysts are of great importance to lowering the conversion cost of biomass and CO 2 . Significant progress has been made to advance the catalyst design for these processes, with metal catalysts playing a critical role in many involved catalytic reactions. Traditional nanoparticle-based metal catalysts still require improvement in metal utilization rates, stability, and selectivity tunability. Single-atom catalysts, which have maximum atomic efficiency and a uniform and tunable metal center, as well as an adjustable metal-support interaction, provide potential opportunities to boost catalyst efficiency and thermal stability. Their well-defined and uniform structure also provides advantages to fundamental studies for understanding of the intrinsic reaction mechanism and site requirement in biomass and CO 2 conversion. In this article, we summarize and highlight the recent advances in converting biomass and CO 2 to renewable fuels and chemicals using single-atom catalysts. We discuss the design principles of single-atom catalysts and their potential applications to biomass and CO 2 upgrading as well as the origins of catalytic activity. Moreover, we compare the catalytic efficiency of various catalysts reported thus to provide a fair assessment of these catalysts. Finally, perspectives are given on the interesting fields that may guide future studies.

09 BIOMASS FUELS↗
DOE OSTI2024

The carbon challenge: Design, synthesis, and chemisorption behavior of solid sorbents in direct air capture of carbon dioxide

Direct air capture (DAC) of CO 2 is a promising solution for reducing the carbon footprint through "negative emission" technology. However, the low CO 2 concentration (~400 ppm) and the dynamic nature of DAC processes present challenges in designing effective sorbent systems. Recent advancements in material design and structural engineering have led to the development of high-performance solid sorbents, offering a more stable, safe, and energy-efficient alternative to traditional liquid CO 2 capture methods. This review highlights progress in solid sorbent-based DAC, focusing on amine-modified materials, hydrogen-bonded frameworks, and ionic liquid-engineered scaffolds. The discussion covers design principles, synthesis methodologies, and their impact on CO 2 chemisorption, comparing the advantages and limitations of each approach. Characterization techniques, especially operando methods and computational tools, are reviewed to understand sorbent behavior during CO 2 integration and release. The reaction pathways and interaction mechanisms of these sorbents with CO 2 are analyzed to guide future design. Additionally, the CO 2 chemisorption behaviors, including capacity, sorption kinetics, recyclability, and durability in the presence of gaseous impurities and under humid conditions will be evaluated and compared. Further, the review offers unique insights into the physical properties, chemical structures, and surface engineering effects of these sorbents, based on comprehensive characterization and evaluation techniques.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Defect Thermodynamics and Transport Properties of Perovskite and Fluorite Materials for Solid-Oxide and Proton Conducting Oxide Cells Evaluated Based on Density Functional Theory Modeling

Density functional theory based defect thermodynamic modeling was performed to determine the effect of humidity and H2/O2 gas pressure on various defect chemistry and transport properties of perovskite and fluorite oxides for solid-oxide and proton-conducting-oxide cell applications, with inclusion of the electronic-conducting oxides (as electrodes) and insulating oxides (as electrolytes). Automatic defect generation workflow and first-principles charged defect analysis were implemented on NETL Joule supercomputer for modeling defect equilibria and transport properties of insulating oxides as electrolytes in SOCs and proton-conducting ceramic cells. A GNU Octave defect model subroutines were developed to facilitate defect modeling of electronic conducting oxides in a wide range of operating conditions guided by modeling and experiments. The model includes the hydride defect formation reaction under reducing conditions and allows to incorporate nonstoichiometry effects on the defect thermodynamic parameters. The developed model serves as a platform to facilitate fundamental understanding of the defect thermodynamics in SOC oxide materials and can be used as a novel tool in computational materials screening for SOC and other energy applications.

Lee, Yueh-Lin↗
NASA NTRS1993

The systems engineering overview and process (from the Systems Engineering Management Guide, 1990)

The past several decades have seen the rise of large, highly interactive systems that are on the forward edge of technology. As a result of this growth and the increased usage of digital systems (computers and software), the concept of systems engineering has gained increasing attention. Some of this attention is no doubt due to large program failures which possibly could have been avoided, or at least mitigated, through the use of systems engineering principles. The complexity of modern day weapon systems requires conscious application of systems engineering concepts to ensure producible, operable and supportable systems that satisfy mission requirements. Although many authors have traced the roots of systems engineering to earlier dates, the initial formalization of the systems engineering process for military development began to surface in the mid-1950s on the ballistic missile programs. These early ballistic missile development programs marked the emergence of engineering discipline 'specialists' which has since continued to grow. Each of these specialties not only has a need to take data from the overall development process, but also to supply data, in the form of requirements and analysis results, to the process. A number of technical instructions, military standards and specifications, and manuals were developed as a result of these development programs. In particular, MILSTD-499 was issued in 1969 to assist both government and contractor personnel in defining the systems engineering effort in support of defense acquisition programs. This standard was updated to MIL-STD499A in 1974, and formed the foundation for current application of systems engineering principles to military development programs.

Source record↗
DOE OSTI2017

Qualified display system architecture - 246

There is a need in the nuclear industry for a Qualified Display System (QDS) architecture as described in this paper. The function of the QDS is to process and display Regulatory Guide 1.97 post accident monitoring parameters. The QDS is implemented on the Lockheed Martin Field-Programmable Gate Array (FPGA) based Nuclear Protection and Control (NuPAC) digital platform, coupled with a Qualified Display Controller (QDC) and a Safety Display Unit (SDU). The QDS is designed to meet the requirements of IEEE 603-1991 (endorsed by Regulatory Guide 1.153, Rev. 1), IEEE 497-2002 (endorsed by Regulatory Guide 1.97, Rev. 4), and IEEE 7-4.3.2- 2003 (endorsed by Regulatory Guide 1.152, Rev. 3). The QDS is designed with flexibility such that it can be implemented in an advanced reactor design, Small Modular Reactor (SMR) with any cooling medium, or digital upgrade project for an operating nuclear plant. The QDS has four independent and redundant divisions. Each division has five layers in the architecture: Process variable input signals; Process Protection Logic (PPL); Algorithm Logic (AL), Interface Panel (IP); and Safety Display Unit (SDU). The QDS meets the following design criteria: redundancy, independence, predictability and repeatability, and diversity capability. The QDS architecture also meets the simplicity design principle. The QDS architecture design provides flexibility in the implementation in a plant. The QDS can be implemented in the design of a new advanced plant or as a digital upgrade in an operating plant. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
NASA NTRSDate not supplied

AM Processes Part 2: Principles of Directed Energy Deposition

Directed Energy Deposition (DED) is one of the metal additive manufacturing processes which finds wider industrial applications, particularly for repair and reclamation, and for large structures. This course helps the attendees to understand the fundamental concepts of DED process and covers the topics such as, how the technology works, different DED processes, materials used, and typical applications where this technology is used. The discussion will have a focus on ASTM F3187 – Standard guide for Directed Energy Deposition of Metals. After completing this webinar the attendees will achieve the following: · Identify and understand the different types of DED processes · Understand how to select a DED process and trade criteria · Understand the various materials used for DED processes · Understand the core parameters for the DED processes · Determine potential parts and end application of DED technology

Additive Manufacturing↗
DOE OSTI2019

Computation-Guided Design of LiTaSiO 5 , a New Lithium Ionic Conductor with Sphene Structure

The development of all-solid-state Li-ion batteries requires solid electrolyte materials with many desired properties, such as ionic conductivity, chemical and electrochemical stability, and mechanical durability. Computation-guided materials design techniques are advantageous in designing and identifying new solid electrolytes that can simultaneously meet these requirements. In this joint computational and experimental study, a new family of fast lithium ion conductors, namely, LiTaSiO 5 with sphene structure, are successfully identified, synthesized, and demonstrated using a novel computational design strategy. First-principles computation predicts that Zr-doped LiTaSiO 5 sphene materials have fast Li diffusion, good phase stability, and poor electronic conductivity, which are ideal for solid electrolytes. Experiments confirm that Zr-doped LiTaSiO 5 sphene structure indeed exhibits encouraging ionic conductivity. The lithium diffusion mechanisms in this material are also investigated, indicating the sphene materials are 3D conductors with facile 1D diffusion along the [101] direction and additional cross-channel migration. This study demonstrates a novel design strategy of activating fast Li ionic diffusion in lithium sphenes, a new materials family of superionic conductors.

25 ENERGY STORAGE↗
DOE OSTI2026

Coarse-grained resource allocation modeling for decoding and rewiring microbial metabolism

Microbial metabolism is a complex, emergent system driven by the coordinated interplay of intricate and dynamic molecular processes. To elucidate cellular behavior and enable biotechnological applications, quantitative models that address the inherent complexity of metabolism have been developed from a resource allocation perspective. Here, we synthesize recent advances in coarse-grained resource allocation frameworks and their applications in understanding microbial physiology and guiding gene circuit design. Here, these frameworks reveal global regulatory constraints and predict cellular adaptation to nutrient and environmental changes. In addition, they enable the quantification of metabolic costs, the dissection of circuit–host interactions, and the development of strategies for burden mitigation. Collectively, these modeling frameworks provide a powerful platform for uncovering quantitative principles of microbial growth and engineering robust synthetic biological systems.

coarse-grained modeling↗
DOE OSTI2022

How the Bioinspired Fe 2 Mo 6 S 8 Chevrel Breaks Electrocatalytic Nitrogen Reduction Scaling Relations

The nitrogen reduction reaction (NRR) is a renewable alternative to the energy- and CO 2 -intensive Haber–Bosch NH 3 synthesis process but is severely limited by the low activity and selectivity of studied electrocatalysts. The Chevrel phase Fe 2 Mo 6 S 8 has a surface Fe–S–Mo coordination environment that mimics the nitrogenase FeMo-cofactor and was recently shown to provide state-of-the-art activity and selectivity for NRR. Here, we elucidate the previously unknown NRR mechanism on Fe 2 Mo 6 S 8 via grand-canonical density functional theory (GC-DFT) that realistically models solvated and biased surfaces. Fe sites of Fe 2 Mo 6 S 8 selectively stabilize the key *NNH intermediate via a narrow band of free-atom-like surface d-states that selectively hybridize with p-states of *NNH, which results in Fe sites breaking NRR scaling relationships. These sharp d-states arise from an Fe–S bond dissociation during N 2 adsorption that mimics the mechanism of the nitrogenase FeMo-cofactor. Furthermore, we developed a new GC-DFT-based approach for calculating transition states as a function of bias (GC-NEB) and applied it to produce a microkinetic model for NRR at Fe 2 Mo 6 S 8 that predicts high activity and selectivity, in close agreement with experiments. Furthermore, our results suggest new design principles that may identify effective NRR electrocatalysts that minimize the barriers for *N 2 protonation and *NH 3 desorption and that may be broadly applied to the rational discovery of stable, multinary electrocatalysts for other reactions where narrow bands of surface d-states can be tuned to selectively stabilize key reaction intermediates and guide selectivity toward a target product. Furthermore, our results highlight the importance of using GC-DFT and GC-NEB to accurately model electrocatalytic reactions.

10 SYNTHETIC FUELS↗
DOE OSTI2026

Finite-element-based simulations of electrodes for CO 2 cascade reduction reactions

The multielectron reduction of CO 2 to liquid fuels could be a path to scalable energy storage, but reaching this goal requires major advances in catalysis and systems engineering. Cascade catalysis, which couples sequential reactions without isolating intermediates, has emerged as a promising route to enhance selectivity and efficiency in CO 2 reduction (CO 2 R). In this review, we examine how finite-element-based simulations of continuum model [finite element method (FEM)] approaches are being used to analyze and guide CO 2 R cascade systems. We first outline the fundamentals of cascade catalysis and recent advances in catalytic materials (metallic, molecular, and hybrid architectures). We then focus on FEM developments at the electrode and device scales, emphasizing how these models capture transport phenomena, local microenvironments, and geometry-dependent effects. To clarify design principles, we present case studies of cascade electrodes organized in systems without and with integrated semiconductors. We further emphasize the integration of FEM with multiscale frameworks (density functional theory, molecular dynamics, kinetic Monte Carlo) and its role in bridging atomic-level insights with device-level performance. Finally, we identify current limitations and future prospects, including improved boundary conditions, coupling with operando experiments, and machine learning-accelerated model development. Together, these insights provide design principles for next-generation CO 2 R cascade systems for efficient solar fuel production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Cyber100 Compass User Guide

This document provides an overview of the Cyber100 Compass tool and serves as a guide to users interested in understanding the cybersecurity risks facing their clean energy transition. The National Renewable Energy Laboratory (NREL) developed the Cyber100 Compass tool for cyber risk assessment at the system-of-systems level for system planners trying to reach high levels of renewables. Two offices of the U.S. Department of Energy (DOE) - the Office of Electricity and the Office of Cybersecurity, Energy Security, and Emergency Response-funded NREL to develop this framework that will enable grid system planners to understand and mitigate cybersecurity risk for grids transitioning to high levels of renewable generation, including 100%. Cyber100 Compass can help systems planners apply the principle of security-by-design at scale. Investing in an upfront understanding of system-of-systems (where the constituent systems are operating entities of the different renewable resources) risks from high-renewable grids will result in a more resilient grid at a lower long-term cost.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2026

A Central Plant Retrofit Assessment Guide for Owners

This document offers support to owners considering optimization upgrades, retrofits, or complete replacement of a central plant, with a particular focus on improving energy efficiency and reliability of the central plant, ultimately leading to reduced energy costs. It outlines recommended steps to prepare for and facilitate a thorough central plant assessment, empowering owners to move forward with the appropriate next steps. While the primary focus is on central plants serving commercial and institutional buildings, the principles and recommendations presented can also be adapted for use in other building types, such as industrial or manufacturing facilities.

42 ENGINEERING↗
NASA NTRS2024

A Collaborative Vision for Deep Space Human Exploration

Artemis will be the first cooperative campaign among nations for crewed planetary exploration. This paradigm shift reflects a collaborative vision for deep space human exploration that embraces the concept that, “If you want to go fast, go alone; If you want to go far, go together.” This paper elaborates on the way the National Aeronautics and Space Administration(NASA)is striving to make its Moon to Mars effort a collaborative endeavor for long-term human exploration of deep space and for the international space community. The agency is making great strides in unifying its workforce, mission directorates, technical authorities, and centers behind shared goals and processes. Enhanced communication and a reinvigoration of systems engineering ideals have been a hallmark of that effort, guided by the Moon to Mars Architecture, which defines what NASA aims to accomplish and how it will execute those goals. This interdisciplinary approach ensures the Artemis campaign supports NASA’s engineering, science, and technology development goals. As of September 2024, over 43 nations have signed the Artemis Accords, which establish a common set of principles for peaceful cooperation in civil space exploration. Building off these efforts, NASA has been engaging in separate and distinct discussions about partner contributions to Artemis. International partnerships for the Artemis campaign include long-standing partners as well as agencies with which NASA has only more recently begun collaborating. The Gateway Program is an early example of both –benefitting from partnerships with Canada, Japan, and Europe forged though decades of cooperation on the International Space Station, as well as a new partnership with the United Arab Emirates. The agency’s Moon to Mars Objectives and Architecture unify the NASA workforce with common goals and shared systems-engineering processes. The architecture offers pathways for broader participation from industry, academia, and international partners. The agency evolves this collaborative approach through its annual Architecture Concept Review cycle, seeking input from the NASA workforce, and through workshops, from industry, academia, and the international space community to refine NASA’s roadmap for exploration. Exploring together, NASA and its partners are setting humanity on the path to long-term presence at the Moon and our eventual journey to Mars

Objective↗
DOE OSTI2024

Modeling and Optimization of Zeolites for Contaminant Removal from Coal Combustion Impoundment Leachates

Coal Combustion Residual (CCR) landfills in the U.S. can lead to elevated contaminant concentrations in groundwater and runoff, particularly of arsenic, boron, and selenium. Zeolites can be readily synthesized from materials contained within the coal combustion ash impoundments and can be cation-exchanged to enhance adsorption capacity, selectivity, and reactivity. However, the optimization of zeolites becomes a daunting task when accounting for the variety of Si:Al ratios, the species of extra-framework cations present, and the zeolite pore structure. Molecular simulations provide methods to study and guide the design of zeolites for the sorption of contaminants from aqueous solution. In this work, models that predict the sorption of arsenic, boron, and selenium from water using cation-exchanged zeolites. Because of the lack of experimental adsorption data for these species of contaminants, models were parametrized to reproduce the results of first-principles calculations and then used to predict sorption for zeolites for a dataset containing 6000 combinations of zeolites and sorption conditions. Machine learning was used to train a model to predict sorption for materials in this database based on the results of the molecular simulations. Next, a genetic algorithm was used to optimize zeolites for the removal of each contaminant from aqueous solution for individual impoundment sites based on contaminant concentrations reported by the Electric Power Research Institute.

Findley, John↗
DOE OSTI2026

Mapping the Gap: Analysis of Nuclear Cybersecurity Education in U.S. Universities

The U.S. nuclear sector is undergoing rapid transformation, driven by the expansion of advanced reactors, digital modernization of legacy systems, and increasing interest in nuclear energy to meet AI-fueled energy demands. However, the cybersecurity talent pipeline is not keeping pace with this growth. This paper investigates the significant gap in nuclear cybersecurity education and proposes scalable strategies for colleges to address this critical need by promoting it as a viable and essential career path. Through a multi-institutional landscape analysis of 16 cybersecurity and 12 nuclear engineering programs, we found that nuclear cybersecurity is largely absent from university curricula. Most students are unaware of the field’s existence, and few institutions offer hands-on training or interdisciplinary exposure. This lack of awareness leads to a shortage of specialized talent, forcing nuclear facilities to retrain generalist hires or rely on costly external consultants. We present a framework for early pipeline cultivation grounded in Social Cognitive Career Theory and workforce development principles. Proposed solutions include student-led clubs, guest lectures, modular classroom kits, and summer boot camps. By increasing visibility and access to nuclear cyber content, we aim to break the self-reinforcing cycle of low awareness and limited specialization. This work underscores the critical role of education and advocacy in cultivating early interest and guiding students toward this emerging field. We call on academic institutions, national laboratories, and industry stakeholders to collaborate in establishing nuclear cybersecurity as a distinct and accessible career path within the broader cybersecurity and nuclear engineering ecosystems.

99 - GENERAL AND MISCELLANEOUS↗
NASA NTRS1989

Acoustic temperature profile measurement technique for large combustion chambers

Measurement of times of flight of sound waves can be used to determine temperatures in a gas. This paper describes a system, based on this principle, that is capable of giving the temperature profile in a nonisothermal gas volume, for example, prevalent in a large furnace. The apparatus is simple, rugged, accurate, and capable of being automated for process control applications. It is basically an acoustic waveguide where the outside temperature profile is transferred to a chosen gas contained inside the guide.

Venkateshan, S. P.↗