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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 613 records · Page 34
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Critical role of oxide anchoring groups in organic electron transport layers for perovskite solar cell stability

Charge transport layers (CTLs) play a critical role in the performance and long-term stability of perovskite solar cells (PSCs) by facilitating efficient charge extraction and providing interfacial stabilization. For organic CTLs, different functional groups have been designed to modulate the interactions with the substrate. Anchoring groups are used to establish strong adhesion to transparent conductive oxides (TCOs) but are not routinely incorporated in organic CTL design. In this study, we investigate the influence of anchoring groups in organic electron transport layers (ETLs) on PSC performance and stability by synthesizing and evaluating two naphthalene diimide (NDI)-based ETLs: NDI-(PhPA) 2 , functionalized with polar phenyl phosphonic acid (PhPA) groups, and NDI-(PhBr) 2 , modified with nonpolar bromophenyl (PhBr) groups. X-ray photoelectron spectroscopy confirms that PhPA functionalization leads to NDIs anchored onto fluorine-doped tin oxide (FTO) following chemical bath deposition, while NDI-(PhBr) 2 shows no detectable surface presence after deposition. We show that NDI-(PhPA) 2 deposits as a thin film on FTO, exhibiting strong adhesion, high solvent resistance, and enhanced light and thermal stability, achieving a maximum device efficiency of 14.3%. Stability assessments conducted under continuous illumination at 25 °C for 200 hours and at 65 °C for 100 hours demonstrate performance on par with TiO 2 -based ETLs. In contrast, NDI-(PhBr) 2 , which lacks strong anchoring interactions, fails to adhere to the FTO surface, resulting in a rapid decrease in efficiency over a few hours, comparable to devices without an ETL. These findings highlight the importance of anchoring groups in organic CTLs for achieving long-term PSC stability under operational conditions.

Kim, Sanggyun [Georgia Institute of Technology, At↗
DOE OSTI2023

Operando Temperature Measurements of Photovoltaic Laser Power Converter Devices Under Continuous High-Intensity Illumination

Photovoltaic devices that operate under extremely high irradiances, such as laser power converters (LPCs), may also operate at elevated temperatures, even under active cooling, as the result of large temperature gradients. We demonstrate the operation of GaAs LPC devices under orders of magnitude of irradiances up to 150 W/cm 2 in a monochromatic laser simulator with an active cooling stage. The steady-state open-circuit voltage (V OC ) as a function of irradiance is known to droop at high irradiance as the result of junction heating, but the junction temperature can be difficult to measure by conventional methods. Fast, transient V OC measurements under these extreme operating conditions are used here to determine the junction temperature. Empirical V OC temperature coefficients of the devices at each irradiance of interest are determined and used as an integral part of this technique. We show that the thermal design of different LPC devices strongly affects the operating temperature of the junctions. Knowledge of the operating temperature can be a strong tool for understanding the nature of loss mechanisms and improving the design for the operation of photovoltaic LPCs at high irradiances. Furthermore, this technique can be used for laboratory devices during initial design as well as to characterize mass-produced and packaged devices for quality control.

14 SOLAR ENERGY↗
DOE OSTI2020

Method for conducting in situ high-temperature digital image correlation with simultaneous synchrotron measurements under thermomechanical conditions

This work presents a novel method of obtaining in situ strain measurements at high temperature by simultaneous digital image correlation (DIC), which provides the total strain on the specimen surface, and synchrotron x-ray diffraction (XRD), which provides lattice strains of crystalline materials. DIC at high temperature requires specialized techniques to overcome the effects of increased blackbody radiation that would otherwise overexpose the images. The technique presented herein is unique in that it can be used with a sample enclosed in an infrared heater, remotely and simultaneously with synchrotron XRD measurements. The heater included a window for camera access, and the light of the heater lamps is used as illumination. High-temperature paint is used to apply a random speckle pattern to the sample to allow the tracking of displacements and the calculation of the DIC strains. An inexpensive blue theatrical gel filter is used to block interfering visible and infrared light at high temperatures. This technique successfully produces properly exposed images at 870 °C and is expected to perform similarly at higher temperatures. The average strains measured by DIC were validated by an analytical calculation of the theoretical strain. Simultaneous DIC and XRD strain measurements of Inconel 718 (IN718) tensile test specimens were performed under thermal and mechanical loads and evaluated. Finally, this approach uses the fact that with DIC, the total strain is measured, including plastic strain, while with XRD, only elastic strain is captured. The observed differences were discussed with respect to the effective deformation mechanisms.

47 OTHER INSTRUMENTATION↗
NASA NTRS1979

Gating effects in Halobacterium halobium membrane transport

The transport of Na(+) via an H(+)/Na(+) antiporter and of aspartate and serine via Na(+)/amino acid symport systems was studied in Halobacterium halobium cell envelope vesicles. Gradients for H(+) were produced by illuminating the bacteriorhodopsin-containing vesicles at different light intensities, and the rate and extent of Na(+) transport were followed as functions of the electrochemical potential difference for protons. The coupling of Na(+) and H(+) gradients suggested a translocation stoichiometry of 2H(+)/Na(+) for the antiporter. The rate of Na(+) transport increases steeply above a critical transmembrane electrochemical proton gradient, and since the electrical and the chemical potentials of H(+) at this threshold point vary with the experimental conditions, while the sum of these potentials is constant, it was concluded that the gating of the Na(+) transport is caused by the total electrochemical gradient.

Lanyi, J. K.↗
NASA NTRS1983

Enhancement of lettuce yield by manipulation of light and nitrogen nutrition

Several levels of photosynthetic photon flux density (PPFD) were tested for effects on growth of 4 cultivars of lettuce (Lactuca sativa L.) under controlled-environment conditions. Growth of 'Salad Bowl', 'Bibb', and 'Ruby' was greater at 932 micromoles s-1 m-2 than at < or = 644 micromoles s-1 m-2 under a 16-hour photoperiod. Thirty mM NO3- or 5 mM NH4+ + 25 mM NO3- increased leaf dry weight while reducing leaf chlorosis in 'Salad Bowl' and 'Grand Rapids' relative to that with 15 mM NO3-, and reduced leaf purpling in 'Bibb' and 'Ruby' with little or no effect on yield. Continuous illumination with 455 or 918 micromoles s-1 m-2 stimulated yield of 'Salad Bowl' and 'Bibb' when 30 mM N as NH4+ + NO3- was used relative to that with 15 mM NO3-.

Nitrogen/metabolism↗
NASA NTRS2006

Detection of Water Hazards for Autonomous Robotic Vehicles

Four methods of detection of bodies of water are under development as means to enable autonomous robotic ground vehicles to avoid water hazards when traversing off-road terrain. The methods involve processing of digitized outputs of optoelectronic sensors aboard the vehicles. It is planned to implement these methods in hardware and software that would operate in conjunction with the hardware and software for navigation and for avoidance of solid terrain obstacles and hazards. The first method, intended for use during the day, is based on the observation that, under most off-road conditions, reflections of sky from water are easily discriminated from the adjacent terrain by their color and brightness, regardless of the weather and of the state of surface waves on the water. Accordingly, this method involves collection of color imagery by a video camera and processing of the image data by an algorithm that classifies each pixel as soil, water, or vegetation according to its color and brightness values (see figure). Among the issues that arise is the fact that in the presence of reflections of objects on the opposite shore, it is difficult to distinguish water by color and brightness alone. Another issue is that once a body of water has been identified by means of color and brightness, its boundary must be mapped for use in navigation. Techniques for addressing these issues are under investigation. The second method, which is not limited by time of day, is based on the observation that ladar returns from bodies of water are usually too weak to be detected. In this method, ladar scans of the terrain are analyzed for returns and the absence thereof. In appropriate regions, the presence of water can be inferred from the absence of returns. Under some conditions in which reflections from the bottom are detectable, ladar returns could, in principle, be used to determine depth. The third method involves the recognition of bodies of water as dark areas in short-wavelength infrared (SWIR) images. This method is based on the fact, well known among experts in remote sensing, that water bodies of any appreciable depth appear very dark in near-infrared, overhead imagery. Even under a thick layer of marine fog, SWIR illumination is present. Hence, this method may work even in the presence of clouds, though it is unlikely to work at night. Snow and ice also exhibit very strong absorption at wavelengths greater than about 1.4 m. Hence, the wavelength range of about 1.5 to 1.6 m might be useable in this method for recognizing water, snow, and ice. One notable drawback of this method is that useful look-ahead distance could be limited by surface reflections. The fourth method, intended for use at night, involves the contrast between water and terrain in thermal-infrared (medium-wavelength infrared) imagery. This method is based on the fact that at night, water is usually warmer than the adjacent terrain. Look-ahead distance could be limited in this method because, for reasons not yet fully understood, water appears to darken in the thermal infrared with increasing distance.

Matthes, Larry↗
DOE OSTI2022

Evaluation of bifacial module technologies with combined–accelerated stress testing

In view of the increasing interest and market share of bifacial cells and modules, suitable substrates such as glass and transparent backsheets along with ethylene vinyl acetate (EVA) and polyolefin elastomer (POE) encapsulants were examined in combined-accelerated stress testing (C-AST) to evaluate and compare degradation modes. Testing with both monofacial and bifacial cells, we found glass-glass modules with monofacial cells led to greater grid finger breakage than those with polymeric backsheets. Furthermore, this is attributed to previous X-ray topography and modeling work showing higher stress in cells and interconnections in glass-glass modules than glass-backsheet modules. Consistent with the objectives of C-AST, which stresses modules at levels corresponding to the limits seen in the natural environment, we observed the UV-fluorescence signatures of modules tested in C-AST (considering the degradation associated with developing chromophores, moisture penetration and photobleaching effects) to be like those in fielded modules, more so than other chamber stress testing implemented for comparison. We found light-induced degradation (LID) in module types with regenerated (inactive) cells with C-AST, suggesting the possibility of LID destabilization in some field conditions. We could also distinguish potential-induced degradation (PID) on the back of the bifacial passivated emitter and rear cells (PERC) in C-AST. Confirming with ex-situ tests, we found polarization-type PID most prevalent in glass-glass modules with EVA as would be anticipated considering the greater leakage current through such module encapsulation. Unlike PID tests performed in the dark, which can lead to false positive PID test results, field-representative illumination is experienced by the modules on the front and back side while –1200 V system voltage is applied in C-AST, supporting the conclusion that this module type with glass-glass construction would be susceptible to PID in the field.

14 SOLAR ENERGY↗
DOE OSTI2023

Towards linking lab and field lifetimes of perovskite solar cells

Metal halide perovskite solar cells (PSCs) represent a promising low-cost, thin-film photovoltaic (PV) technology, with unprecedented power conversion efficiencies (PCEs) obtained for both single-junction and tandem applications. To push PSCs toward commercialization, it is critical, albeit challenging, to understand device reliability under real-world outdoor conditions where multiple stress factors (e.g., light, heat, humidity) coexist, generating complicated degradation behaviors. It is necessary to identify accelerated indoor testing protocols - which can correlate specific stressors with observed degradation modes in fielded devices - to quickly guide PSC development. Here, we use a state-of-the-art p-i-n PSC stack (with PCE up to ~25.5%) to show that indoor accelerated stability tests can predict our 6-month outdoor aging tests. Device degradation rates under illumination and at elevated temperatures are most instructive for understanding outdoor device reliability. Further, we also find that the indium tin oxide (ITO)/self-assembled monolayer (SAM)-based hole transport layer (HTL)/perovskite interface most strongly affects our device operation stability. Improving the ion-blocking properties of the SAM HTL increases averaged device operational stability at 50 degree C-85 °C by a factor of ~2.8, reaching over 1000 h at 85 °C and to near 8200 h at 50 °C with a projected 20% degradation, which is among the best to date for high-efficiency p-i-n PSCs.

14 SOLAR ENERGY↗
DOE OSTI2025

Carbon-carbon interactions in warm dense titanium carbide

Encouraged by experimental reports of diamond precipitation in carbon-containing materials under warm dense matter conditions and in shock compression experiments, we examine the behavior of carbon in TiC using density functional theory-molecular dynamics simulations. Two polymorphs of TiC are considered, the ambient-pressure B1 ($Fm$$\overline{3}$$m$) structure in which C-C interactions are prevented by geometric constraints, and a high-pressure Cmcm structure in which C atoms condense into zigzag chains. Chemistry-inspired bonding analyses confirm the covalently bound nature of these chains and further illuminate important interatomic interactions in both structures. Upon melting of B1 TiC, new short-range C-C interactions develop in the liquid, while the pre-existing C-C interactions in Cmcm TiC persist in the liquid. Here, the resulting carbon networks in the melt provide a promising environment for eventual diamond nucleation.

Ab initio molecular dynamics↗
NASA NTRS1984

Accretion by magnetic neutron stars. II - Plasma entry into the magnetosphere via diffusion, polar cusps, and magnetic field reconnection

A variety of entry modes were investigated to determine whether most of the accreting plasma enters the magnetosphere as a result of hydromagnetic instability or via other means. It is shown that diffusion is never important under the conditions of interest, nor is the loss-cone entry through the polar cusps when the plasma is collisionless. Although the loss-cone entry rate can be significantly increased if the plasma in the cusps cools and becomes collisional, this cannot stabilize the magnetosphere. The descent of the cusps cannot be the dominant entry process if the star has a persistent luminosity greater than about 10 to the 36th erg/s and a substantial fraction of the magnetosphere is illuminated. This, however, can be a significant entry process for much lower luminosities or strongly anisotropic illumination. The possibility that plasma entry via reconnection can stabilize the magnetosphere is also unlikely.

Elsner, R. F.↗
NASA NTRS2006

Fluorescent Approaches to High Throughput Crystallography

We have shown that by covalently modifying a subpopulation, less than or equal to 1%, of a macromolecule with a fluorescent probe, the labeled material will add to a growing crystal as a microheterogeneous growth unit. Labeling procedures can be readily incorporated into the final stages of purification, and the presence of the probe at low concentrations does not affect the X-ray data quality or the crystallization behavior. The presence of the trace fluorescent label gives a number of advantages when used with high throughput crystallizations. The covalently attached probe will concentrate in the crystal relative to the solution, and under fluorescent illumination crystals show up as bright objects against a dark background. Non-protein structures, such as salt crystals, will not incorporate the probe and will not show up under fluorescent illumination. Brightly fluorescent crystals are readily found against less bright precipitated phases, which under white light illumination may obscure the crystals. Automated image analysis to find crystals should be greatly facilitated, without having to first define crystallization drop boundaries as the protein or protein structures is all that shows up. Fluorescence intensity is a faster search parameter, whether visually or by automated methods, than looking for crystalline features. We are now testing the use of high fluorescence intensity regions, in the absence of clear crystalline features or "hits", as a means for determining potential lead conditions. A working hypothesis is that kinetics leading to non-structured phases may overwhelm and trap more slowly formed ordered assemblies, which subsequently show up as regions of brighter fluorescence intensity. Preliminary experiments with test proteins have resulted in the extraction of a number of crystallization conditions from screening outcomes based solely on the presence of bright fluorescent regions. Subsequent experiments will test this approach using a wider range of proteins. The trace fluorescently labeled crystals will also emit with sufficient intensity to aid in the automation of crystal alignment using relatively low cost optics, further increasing throughput at synchrotrons.

Pusey, Marc L.↗
NASA NTRS1998

Measurements of Heat Transfer, Flow, and Pressures in a Simulated Turbine Blade Internal Cooling Passage

An experimental study was made to obtain quantitative information on heat transfer, flow, and pressure distribution in a branched duct test section that had several significant features of an internal cooling passage of a turbine blade. The objective of this study was to generate a set of experimental data that could be used for validation of computer codes that would be used to model internal cooling. Surface heat transfer coefficients and entrance flow conditions were measured at nominal entrance Reynolds numbers of 45,000, 335,000, and 726,000. Heat transfer data were obtained by using a steady-state technique in which an Inconel heater sheet is attached to the surface and coated with liquid crystals. Visual and quantitative flow-field data from particle image velocimetry measurements for a plane at midchannel height for a Reynolds number of 45,000 were also obtained. The flow was seeded with polystyrene particles and illuminated by a laser light sheet. Pressure distribution measurements were made both on the surface with discrete holes and in the flow field with a total pressure probe. The flow-field measurements yielded flow-field velocities at selected locations. A relatively new method, pressure sensitive paint, was also used to measure surface pressure distribution. The pressure paint data obtained at Reynolds numbers of 335,000 and 726,000 compared well with the more standard method of measuring pressures by using discrete holes.

Russell, Louis M.↗
NASA NTRS1974

The optical absorption of solid grains in astrophysical environments

The optical absorptivity of grains of solid material in infrared sources is investigated by the comparison of calculated and observed temperatures and distances of the grains from the source of illumination. It is found that for the few sources for which appropriate measurements have been made, the calculated distances of blackbody particles agree well with the measured values - a result which could lead to misleading conclusions about grain properties. The ratio of optical absorptivity to infrared emissivity is calculated for several sources taking into account expected effects of real grain materials. The measured angular size of dust shells surrounding stars can lead to information about the optical properties of grains under astrophysical conditions.

Stein, W. A.↗
NASA NTRS1975

Large Deployable Antenna Shuttle Experiment

An experiment designed to use the Space Shuttle in tests of the mechanical and electrical properties of spaceborne deployable antennas under zero-gravity conditions is outlined. Space-erectable 20-meter diameter phased arrays or reflector/feed systems, and self-deploying mechanisms, are to be tested. Reflector surface integrity will be tested by an AM laser technique, and electrical behavior will be tested by a spin-stabilized RF beacon injected into orbit prior to unfurlment of the antenna. Focusing and gain measurements, static pattern measurements, dynamic RF gain measurements, and measurements of cross-polarized signals will be conducted, and the reflector will be illuminated by separate feeds for the S-, X-, and K-bands. Mechanical features of the mesh-wrapped rib furlable antenna design are described.

Freeland, R. E.↗
NASA NTRS2003

Energy Scales in X-Ray Microcalorimeters

Microcalorimeter pulse shape characteristics, such as pulse height, decay time and rise time, are dependent on the detector temperature and bias as well as the photon energy and flux. We examine the nature of the temperature dependency by illuminating the ASTRO-E2 X-ray Spectrometer (XRS) microcalorimeter array with X-rays generated by electron impact on a range of foil targets. The resulting pulses are collected for a range of detector temperatures. We observe and model the temperature dependence of the pulse shape characteristics by fitting the data with non-linear pulse models. Our aim is to determine a robust method for correcting the energy scale obtained in ground calibration for slight differences in the operating conditions while in orbit.

Tillotson, W. A.↗
NASA NTRS2013

Tomographic Sounding of Protoplanetary and Transitional Disks: Using Inner Disk Variability at Near to Mid-IR Wavelengths to Probe Conditions in the Outer Disk

Spitzer synoptic monitoring of young stellar associations has demonstrated that variability among young stars and their disks is ubiquitous. The Spitzer studies have been limited by target visibility windows and cover only a short temporal baseline in years. A complementary approach is to focus on stars chosen for high-value observations (e.g. high-contrast imaging, interferometry, or access to wavelengths which are difficult to achieve from the ground) where the synoptic data can augment the imagery or interferometry as well as probing disk structure. In this talk, we discuss how synoptic data for two protoplanetary disks, MWC 480 and HD 163296, constrain the dust disk scale height, account for variable disk illumination, and can be used to locate emission features, such as the IR bands commonly associated with PAHs in the disk, as part of our SOFIA cycle 1 study. Similar variability is now known for several pre-transitional disks, where synoptic data can be used to identify inner disks which are not coplanar with the outer disk, and which may be relicts of giant planet-giant planet scattering events. Despite the logistical difficulties in arranging supporting, coordinated observations in tandem with high-value observations, such data have allowed us to place imagery in context, constrained structures in inner disks not accessible to direct imagery, and may be a tool for identifying systems where planet scattering events have occurred.

target visibility windows↗
DOE OSTI2026

Inexpensive Hydrogen Storage: Propylene to Propane using Plasmonic Photocatalysis

Chemistry-based hydrogen storage media, such as liquid organic hydrogen carriers, offer an attractive alternative to physical hydrogen storage solutions. Here, we investigate propane as a possible hydrogen storage medium, attractive for its low cost and ease of availability. We report the ambient temperature and pressure hydrogenation of propylene using an antenna-reactor Al@TiO 2 −Pt single-atom plasmonic photocatalyst. Illumination at two distinct wavelengths, 450 and 800 nm, corresponds to high reactivity toward propane production. Theoretical insight into wavelength-dependent hot-carrier generation reveals nonequilibrium carriers with sufficient energies to activate both steps of propylene hydrogenation at either wavelength, the dissociation of H 2 and its incorporation into the propylene carbon− carbon double bond. Paired with light-driven propane dehydrogenation, this study demonstrates that photocatalytic cycling of propylene - propane for hydrogen storage and release can be performed under mild conditions.

alkyls↗
DOE OSTI2020

A Digital Imaging Method for Evaluating the Kinetics of Vapochromic Response

This work describes the use of a cell phone camera and the L*a*b method (color space specified by the International Commission on Illumination) to characterize the color change in different vapochromic systems. In this study we have developed a semi-automatic color change analysis software that digitally analyzes images (e.g., video frames) collected while a vapochromic material is absorbing vapor. The advantages of using this method, as compared to reflectance spectroscopy or transmission spectroscopy through a thin film, include low cost, convenience, portability, ease of sample preparation, the absence of need for specialized equipment, and the ease of simultaneously collecting data on different samples under identical conditions. In addition, this method arguably provides direct insight into what a human would observe when monitoring these color changes by eye. Limitations of the method also are discussed in this paper.

cell phone camera, colorimetric sensing, vapor det↗